Chapter 7

_II.--Electro-Chemical Action_

The theory of definite electrolytical or electro-chemical action appears to me to touch immediately upon the absolute quantity of electricity belonging to different bodies. As soon as we perceive that chemical powers are definite for each body, and that the electricity which we can loosen from each body has definite chemical action which can be measured, we seem to have found the link which connects the proportion of that we have evolved to the proportion belonging to the particles in their natural state.

Now, it is wonderful to observe how small a quantity of a compound body is decomposed by a certain quantity of electricity. One grain of water, for instance, acidulated to facilitate conduction, will require an electric current to be continued for three minutes and three-quarters to effect its decomposition, and the current must be powerful enough to keep a platina wire 1/104 inch in thickness red hot in the air during the whole time, and to produce a very brilliant and constant star of light if interrupted anywhere by charcoal points. It will not be too much to say that this necessary quantity of electricity is equal to a very powerful flash of lightning; and yet when it has performed its full work of electrolysis, it has separated the elements of only a single grain of water.

On the other hand, the relation between the conduction of the electricity and the decomposition of the water is so close that one cannot take place without the other. If the water be altered only in that degree which consists in its having the solid instead of the fluid state, the conduction is stopped and the decomposition is stopped with it. Whether the conduction be considered as depending upon the decomposition or not, still the relation of the two functions is equally intimate.

Considering this close and twofold relation--namely, that without decomposition transmission of electricity does not occur, and that for a given definite quantity of electricity passed an equally definite and constant quantity of water or other matter is decomposed; considering also that the agent, which is electricity, is simply employed in overcoming electrical powers in the body subjected to its action, it seems a probable and almost a natural consequence that the quantity which passes is the equivalent of that of the particles separated; _i.e._, that if the electrical power which holds the elements of a grain of water in combination, or which makes a grain of oxygen and hydrogen in the right proportions unite into water when they are made to combine, could be thrown into a current, it would exactly equal the current required for the separation of that grain of water into its elements again; in other words, that the electricity which decomposes and that which is evolved by the decomposition of a certain quantity of matter are alike.

This view of the subject gives an almost overwhelming idea of the extraordinary quantity or degree of electric power which naturally belongs to the particles of matter, and the idea may be illustrated by reference to the voltaic pile.

The source of the electricity in the voltaic instrument is due almost entirely to chemical action. Substances interposed between its metals are all electrolytes, and the current cannot be transmitted without their decomposition. If, now, a voltaic trough have its extremities connected by a body capable of being decomposed, such as water, we shall have a continuous current through the apparatus, and we may regard the part where the acid is acting on the plates and the part where the current is acting upon the water as the reciprocals of each other. In both parts we have the two conditions, _inseparable in such bodies as these_: the passing of a current, and decomposition. In the one case we have decomposition associated with a current; in the other, a current followed by decomposition.

Let us apply this in support of my surmise respecting the enormous electric power of each particle or atom of matter.

Two wires, one of platina, and one of zinc, each one-eighteenth of an inch in diameter, placed five-sixteenths of an inch apart, and immersed to the depth of five-eighths of an inch in acid, consisting of one drop of oil of vitriol and four ounces of distilled water at a temperature of about 60° Fahrenheit, and connected at the other ends by a copper wire eighteen feet long, and one-eighteenth of an inch in thickness, yielded as much electricity in little more than three seconds of time as a Leyden battery charged by thirty turns of a very large and powerful plate electric machine in full action. This quantity, although sufficient if passed at once through the head of a rat or cat to have killed it, as by a flash of lightning, was evolved by the mutual action of so small a portion of the zinc wire and water in contact with it that the loss of weight by either would be inappreciable; and as to the water which could be decomposed by that current, it must have been insensible in quantity, for no trace of hydrogen appeared upon the surface of the platina during these three seconds. It would appear that 800,000 such charges of the Leyden battery would be necessary to decompose a single grain of water; or, if I am right, to equal the quantity of electricity which is naturally associated with the elements of that grain of water, endowing them with their mutual chemical affinity.

This theory of the definite evolution and the equivalent definite action of electricity beautifully harmonises the associated theories of definite proportions and electro-chemical affinity.

According to it, the equivalent weights of bodies are simply those quantities of them which contain equal quantities of electricity, or have naturally equal electric powers, it being the electricity which _determines_ the equivalent number, _because_ it determines the combining force. Or, if we adopt the atomic theory or phraseology, then the atoms of bodies which are equivalent to each other in their ordinary chemical action have equal quantities of electricity naturally associated with them. I cannot refrain from recalling here the beautiful idea put forth, I believe, by Berzelius in his development of his views of the electro-chemical theory of affinity, that the heat and light evolved during cases of powerful combination are the consequence of the electric discharge which is at the moment taking place. The idea is in perfect accordance with the view I have taken of the quantity of electricity associated with the particles of matter.

The definite production of electricity in association with its definite action proves, I think, that the current of electricity in the voltaic pile is sustained by chemical decomposition, or, rather, by chemical action, and not by contact only. But here, as elsewhere, I beg to reserve my opinion as to the real action of contact.

Admitting, however, that chemical action is the source of electricity, what an infinitely small fraction of that which is active do we obtain and employ in our voltaic batteries! Zinc and platina wires one-eighteenth of an inch in diameter and about half an inch long, dipped into dilute sulphuric acid, so weak that it is not sensibly sour to the tongue, or scarcely sensitive to our most delicate test papers, will evolve more electricity in one-twentieth of a minute than any man would willingly allow to pass through his body at once.

The chemical energy represented by the satisfaction of the chemical affinities of a grain of water and four grains of zinc can evolve electricity equal in quantity to that of a powerful thunderstorm. Nor is it merely true that the quantity is active; it can be directed--made to perform its full equivalent duty. Is there not, then, great reason to believe that, by a closer investigation of the development and action of this subtile agent, we shall be able to increase the power of our batteries, or to invent new instruments which shall a thousandfold surpass in energy those we at present possess?

_III.--The Gymnotus, or Electric Eel_

Wonderful as are the laws and phenomena of electricity when made evident to us in inorganic or dead matter, their interest can bear scarcely any comparison with that which attaches to the same force when connected with the nervous system and with life.

The existence of animals able to give the same concussion to the living system as the electrical machine, the voltaic battery, and the thunderstorm being made known to us by various naturalists, it became important to identify their electricity with the electricity produced by man from dead matter. In the case of the _Torpedo_ [a fish belonging to the family of Electric Rings] this identity has been fully proved, but in the case of the _Gymnotus_ the proof has not been quite complete, and I thought it well to obtain a specimen of the latter fish.

A gymnotus being obtained, I conducted a series of experiments. Besides the hands two kinds of collectors of electricity were used--one with a copper disc for contact with the fish, and the other with a plate of copper bent into saddle shape, so that it might enclose a certain extent of the back and sides of the fish. These conductors, being put over the fish, collected power sufficient to produce many electric effects.

SHOCK. The shock was very powerful when the hands were placed one near the head and the other near the tail, and the nearer the hands were together, within certain limits, the less powerful was the shock. The disc conductors conveyed the shock very well when the hands were wetted.

GALVANOMETER. A galvanometer was readily affected by using the saddle conductors, applied to the anterior and posterior parts of the gymnotus. A powerful discharge of the fish caused a deflection of thirty or forty degrees. The deflection was constantly in a given direction, the electric current being always from the anterior part of the animal through the galvanometer wire to the posterior parts. The former were, therefore, for the time externally positive and the latter negative.

MAKING A MAGNET. When a little helix containing twenty-two feet of silked wire wound on a quill was put into a circuit, and an annealed steel needle placed in the helix, the needle became a magnet; and the direction of its polarity in every cast indicated a current from the anterior to the posterior parts of the gymnotus.

CHEMICAL DECOMPOSITION. Polar decomposition of a solution of iodide of potassium was easily obtained.

EVOLUTION OF HEAT. Using a Harris' thermo-electrometer, we thought we were able, in one instance, to observe a feeble elevation of temperature.

SPARK. By suitable apparatus a spark was obtained four times.

Such were the general electric phenomena obtained from the gymnotus, and on several occasions many of the phenomena were obtained together. Thus, a magnet was made, a galvanometer deflected, and, perhaps, a wire heated by one single discharge of the electric force of the animal. When the shock is strong, it is like that of a large Leyden battery charged to a low degree, or that of a good voltaic battery of, perhaps, one hundred or more pairs of plates, of which the circuit is completed for a moment only.

I endeavoured by experiment to form some idea of the quantity of electricity, and came to the conclusion that a single medium discharge of the fish is at least equal to the electricity of a Leyden battery of fifteen jars, containing 3,500 square inches of glass coated on both sides, charged to its highest degree. This conclusion is in perfect accordance with the degree of deflection which the discharge can produce in a galvanometer needle, and also with the amount of chemical decomposition produced in the electrolysing experiments.

The gymnotus frequently gives a double and even a triple shock, with scarcely a sensible interval between each discharge.

As at the moment of shock the anterior parts are positive and the posterior negative, it may be concluded that there is a current from the former to the latter through every part of the water which surrounds the animal, to a considerable distance from its body. The shock which is felt, therefore, when the hands are in the most favourable position is the effect of a very small portion only of the electricity which the animal discharges at the moment, by far the largest portion passing through the surrounding water.

This enormous external current must be accompanied by some effect within the fish _equivalent_ to a current, the direction of which is from the tail towards the head, and equal to the sum of _all these external_ forces. Whether the process of evolving or exciting the electricity within the fish includes the production of the internal current, which is not necessarily so quick and momentary as the external one, we cannot at present say; but at the time of the shock the animal does not apparently feel the electric sensation which he causes in those around him.

The gymnotus can stun and kill fish which are in very various relations to its own body. The extent of surface which the fish that is about to be struck offers to the water conducting the electricity increases the effect of the shock, and the larger the fish, accordingly, the greater must be the shock to which it will be subjected.

The Chemical History of a Candle

"The Chemical History of a Candle" was the most famous course in the long and remarkable series of Christmas lectures, "adapted to a juvenile auditory," at the Royal Institution, and remains a rarely-approached model of what such lectures should be. They were illustrated by experiments and specimens, but did not depend upon these for coherence and interest. They were delivered in 1860-61, and have just been translated, though all but half-a-century old, into German.

_I.--Candles and their Flames_

There is not a law under which any part of this universe is governed that does not come into play in the phenomena of the chemical history of a candle. There is no better door by which you can enter into the study of natural philosophy than by considering the physical phenomena of a candle.

And now, my boys and girls, I must first tell you of what candles are made. Some are great curiosities. I have here some bits of timber, branches of trees particularly famous for their burning. And here you see a piece of that very curious substance taken out of some of the bogs in Ireland, called _candle-wood_--a hard, strong, excellent wood, evidently fitted for good work as a resister of force, and yet withal burning so well that, where it is found, they make splinters of it, and torches, since it burns like a candle, and gives a very good light indeed. And in this wood we have one of the most beautiful illustrations of the general nature of a candle that I can possibly give. The fuel provided, the means of bringing that fuel to the place of chemical action, the regular and gradual supply of air to that place of action--heat and light all produced by a little piece of wood of this kind, forming, in fact, a natural candle.

But we must speak of candles as they are in commerce. Here are a couple of candles commonly called dips. They are made of lengths of cotton cut off, hung up by a loop, dipped into melted tallow, taken out again and cooled; then re-dipped until there is an accumulation of tallow round the cotton. However, a candle, you know, is not now a greasy thing like an ordinary tallow candle, but a clean thing; and you may almost scrape off and pulverise the drops which fall from it without soiling anything.

The candle I have in my hand is a stearine candle, made of stearine from tallow. Then here is a sperm candle, which comes from the purified oil of the spermaceti whale. Here, also, are yellow beeswax and refined beeswax from which candles are made. Here, too, is that curious substance called paraffin, and some paraffin candles made of paraffin obtained from the bogs of Ireland. I have here also a substance brought from Japan, a sort of wax which a kind friend has sent me, and which forms a new material for the manufacture of candles.

Now, as to the light of the candle. We will light one or two, and set them at work in the performance of their proper function. You observe a candle is a very different thing from a lamp. With a lamp you take a little oil, fill your vessel, put in a little moss, or some cotton prepared by artificial means, and then light the top of the wick. When the flame runs down the cotton to the oil, it gets stopped, but it goes on burning in the part above. Now, I have no doubt you will ask, how is it that the oil, which will not burn of itself, gets up to the top of the cotton, where it will burn? We shall presently examine that; but there is a much more wonderful thing about the burning of a candle than this. You have here a solid substance with no vessel to contain it; and how is it that this solid substance can get up to the place where the flame is? Or, when it is made a fluid, then how is it that it keeps together? This is a wonderful thing about a candle.

You see, then, in the first instance, that a beautiful cup is formed. As the air comes to the candle, it moves upwards by the force of the current which the heat of the candle produces, and it so cools all the sides of the wax, tallow, or fuel as to keep the edge much cooler than the part within; the part within melts by the flame that runs down the wick as far as it can go before it is stopped, but the part on the outside does not melt. If I made a current in one direction, my cup would be lopsided, and the fluid would consequently run over--for the same force of gravity which holds worlds together, holds this fluid in a horizontal position. You see, therefore, that the cup is formed by this beautifully regular ascending current of air playing upon all sides, which keeps the exterior of the candle cool. No fuel would serve for a candle which has not the property of giving this cup, except such fuel as the Irish bogwood, where the material itself is like a sponge, and holds its own fuel.

You see now why you have such a bad result if you burn those beautiful fluted candles, which are irregular, intermittent in their shape, and cannot therefore have that nicely-formed edge to the cup which is the great beauty in a candle. I hope you will now see that the perfection of a process--that is, its utility--is the better point of beauty about it. It is not the best-looking thing, but the best-acting thing which is the most advantageous to us. This good-looking candle is a bad burning one. There will be a guttering round about it because of the irregularity of the stream of air and the badness of the cup which is formed thereby.

You may see some pretty examples of the action of the ascending current when you have a little gutter run down the side of a candle, making it thicker there than it is elsewhere. As the candle goes on burning, that keeps its place and forms a little pillar sticking up by the side, because, as it rises higher above the rest of the wax or fuel, the air gets better round it, and it is more cooled and better able to resist the action of the heat at a little distance. Now, the greatest mistakes and faults with regard to candles, as in many other things, often bring with them instruction which we should not receive if they had not occurred. You will always remember that whenever a result happens, especially if it be new, you should say: "What is the cause? Why does it occur?" And you will in the course of time find out the reason.

Then there is another point about these candles which will answer a question--that is, as to the way in which this fluid gets out of the cup, up to the wick, and into the place of combustion. You know that the flames on these burning wicks in candles made of beeswax, stearine, or spermaceti, do not run down to the wax or other matter, and melt it all away, but keep to their own right place. They are fenced off from the fluid below, and do not encroach on the cup at the sides.

I cannot imagine a more beautiful example than the condition of adjustment under which a candle makes one part subserve to the other to the very end of its action. A combustible thing like that, burning away gradually, never being intruded upon by the flame, is a very beautiful sight; especially when you come to learn what a vigorous thing flame is, what power it has of destroying the wax itself when it gets hold of it, and of disturbing its proper form if it come only too near.

But how does the flame get hold of the fuel? There is a beautiful point about that. It is by what is called capillary attraction that the fuel is conveyed to the part where combustion goes on, and is deposited there, not in a careless way, but very beautifully in the very midst of the centre of action which takes place around it.

_II.--The Brightness of the Candle_

Air is absolutely necessary for combustion; and, what is more, I must have you understand that _fresh_ air is necessary, or else we should be imperfect in our reasoning and our experiments. Here is a jar of air. I place it over a candle, and it burns very nicely in it at first, showing that what I have said about it is true; but there will soon be a change. See how the flame is drawing upwards, presently fading, and at last going out. And going out, why? Not because it wants air merely, for the jar is as full now as it was before, but it wants pure, fresh air. The jar is full of air, partly changed, partly not changed; but it does not contain sufficient of the fresh air for combustion.

Suppose I take a candle, and examine that part of it which appears brightest to our eyes. Why, there I get these black particles, which are just the smoke of the candle; and this brings to mind that old employment which Dean Swift recommended to servants for their amusement, namely, writing on the ceiling of a room with a candle. But what is that black substance? Why, it is the same carbon which exists in the candle. It evidently existed in the candle, or else we should not have had it here. You would hardly think that all those substances which fly about London in the form of soots and blacks are the very beauty and life of the flame. Here is a piece of wire gauze which will not let the flame go through it, and I think you will see, almost immediately, that, when I bring it low enough to touch that part of the flame which is otherwise so bright, it quells and quenches it at once, and allows a volume of smoke to rise up.

Whenever a substance burns without assuming the vaporous state--whether it becomes liquid or remains solid--it becomes exceedingly luminous. What I say is applicable to all substances--whether they burn or whether they do not burn--that they are exceedingly bright if they retain their solid state when heated, and that it is to this presence of solid particles in the candle-flame that it owes its brilliancy.

I have here a piece of carbon, or charcoal, which will burn and give us light exactly in the same manner as if it were burnt as part of a candle. The heat that is in the flame of a candle decomposes the vapour of the wax, and sets free the carbon particles--they rise up heated and glowing as this now glows, and then enter into the air. But the particles when burnt never pass off from a candle in the form of carbon. They go off into the air as a perfectly invisible substance, about which we shall know hereafter.

Is it not beautiful to think that such a process is going on, and that such a dirty thing as charcoal can become so incandescent? You see, it comes to this--that all bright flames contain these solid particles; all things that burn and produce solid particles, either during the time they are burning, as in the candle, or immediately after being burnt, as in the case of the gunpowder and iron-filings--all these things give us this glorious and beautiful light.