The Sceptical Chymist or Chymico-Physical Doubts & Paradoxes, Touching the Spagyrist's Principles Commonly call'd Hypostatical; As they are wont to be Propos'd and Defended by the Generality of Alchymists. Whereunto is præmis'd Part of another Discourse relating to the same Subject.

Part 4

Chapter 43,863 wordsPublic domain

To what may be deduc'd, in favour of this Assertion, from the Nature of the Thing it self, I will add something out of Experience, which though I have not known it used to such a purpose, seems to me more fairly to make out that there May be Elementary Bodies, then the more questionable Experiments of Peripateticks and Chymists prove that there Are such. I consider then that Gold will mix and be colliquated not only with Silver, Copper, Tin and Lead, but with Antimony, _Regulus Martis_ and many other Minerals, with which it will compose Bodies very differing both from Gold, and the other Ingredients of the resulting Concretes. And the same Gold will also by common _Aqua Regis_, and (I speak it knowingly) by divers other _Menstruums_ be reduc'd into a seeming Liquor, in so much that the Corpuscles of Gold will, with those of the _Menstruum_, pass through Cap-Paper, and with them also coagulate into a Crystalline Salt. And I have further try'd, that with a small quantity of a certain Saline Substance I prepar'd, I can easily enough sublime Gold into the form of red Crystalls of a considerable length; and many other wayes may Gold be disguis'd, and help to constitute Bodies of very differing Natures both from It and from one another, and neverthelesse be afterward reduc'd to the self-same Numerical, Yellow, Fixt, Ponderous and Malleable Gold it was before its commixture. Nor is it only the fixedst of Metals, but the most fugitive, that I may employ in favour of our Proposition: for Quicksilver will with divers Metals compose an _Amalgam_, with divers _Menstruums_ it seems to be turn'd into a Liquor, with _Aqua fortis_ will be brought into either a red or white Powder or precipitate, with Oyl of Vitriol into a pale Yellow one, with Sulphur it will compose a blood-red and volatile Cinaber, with some Saline Bodies it will ascend in form of a Salt which will be dissoluble in water; with _Regulus_ of Antimony and Silver I have seen it sublim'd into a kinde of Crystals, with another Mixture I reduc'd it into a malleable Body, into a hard and brittle Substance by another: And some there are who affirm, that by proper Additaments they can reduce Quicksilver into Oyl, nay into Glass, to mention no more. And yet out of all these exotick Compounds, we may recover the very same running Mercury that was the main Ingredient of them, and was so disguis'd in them. Now the Reason (proceeds _Carneades_) that I have represented these things concerning Gold and Quicksilver, is, That it may not appear absurd to conceive, that such little primary Masses or Clusters, as our Proposition mentions, may remain undissipated, notwithstanding their entring into the composition of various Concretions, since the Corpuscle of Gold and Mercury, though they be not primary Concretions of the most minute Particles or matter, but confessedly mixt Bodies, are able to concurre plentifully to the composition of several very differing Bodies, without losing their own Nature or Texture, or having their cohæsion violated by the divorce of their associated parts or Ingredients.

Give me leave to add (sayes _Eleutherius_) on this occasion, to what you now observ'd, that as confidently as some Chymists, and other modern Innovators in Philosophy are wont to object against the Peripateticks, That from the mixture of their four Elements there could arise but an inconsiderable variety of compound Bodies; yet if the _Aristotelians_ were but half as well vers'd in the works of Nature as they are in the Writings of their Master, the propos'd Objection would not so calmly triumph, as for want of Experiments they are fain to suffer it to do. For if we assigne to the Corpuscles, whereof each Element consists, a peculiar size and shape, it may easily enough be manifested, That such differingly figur'd Corpuscles may be mingled in such various Proportions, and may be connected so many several wayes, that an almost incredible number of variously qualified Concretes may be compos'd of them. Especially since the Corpuscles of one Element may barely, by being associated among themselves, make up little Masses of differing size and figure from their constituent parts: and since also to the strict union of such minute Bodies there seems oftentimes nothing requisite, besides the bare Contact of a great part of their Surfaces. And how great a variety of _Phænomena_ the same matter, without the addition of any other, and only several ways dispos'd or contexed, is able to exhibit, may partly appear by the multitude of differing Engins which by the contrivances of skilful Mechanitians, and the dexterity of expert Workmen, may be made of Iron alone. But in our present case being allow'd to deduce compound Bodies from four very differently qualified sorts of matter, he who shall but consider what you freshly took notice of concerning the new Concretes resulting from the mixture of incorporated Minerals, will scarce doubt but that the four Elements mannag'd by Natures Skill may afford a multitude of differing Compounds.

I am thus far of your minde (sayes _Carneades_) that the _Aristotelians_ might with probability deduce a much greater number of compound Bodies from the mixture of their four Elements, than according to their present _Hypothesis_ they can, if instead of vainly attempting to deduce the variety and properties of all mixt Bodies from the Combinations and Temperaments of the four Elements, as they are (among them) endowd with the four first Qualities, they had endeavoured to do it by the Bulk and Figure of the smallest parts of those supposed Elements. For from these more Catholick and Fruitfull Accidents of the Elementary matter may spring a great variety of Textures, upon whose Account a multitude of compound Bodies may very much differ from one another. And what I now observe touching the four Peripatetick Elements, may be also applyed, _mutatis mutandis_, (as they speak) to the Chymical Principles. But (to take notice of that by the by) both the one and the other, must, I fear, call in to their assistance something that is not Elementary, to excite or regulate the motion of the parts of the matter, and dispose them after the manner requisite to the Constitution of particular Concretes. For that otherwise they are like to give us but a very imperfect account of the Origine of very many mixt Bodies, It would, I think, be no hard matter to perswade you, if it would not spend time, and were no Digression, to examine, what they are wont to alledge of the Origine of the Textures and Qualities of mixt Bodies, from a certain substantial Form, whose Origination they leave more obscure than what it is assum'd to explicate.

But to proceed to a new Proposition.

[Sidenote: Propos. III.]

_I shall not peremptorily deny, that from most of such mixt Bodies as partake either of Animal or Vegetable Nature, there may by the Help of the Fire, be actually obtain'd a determinate number (whether Three, Four or Five, or fewer or more) of Substances, worthy of differing Denominations._

Of the Experiments that induce me to make this Concession, I am like to have occasion enough to mention several in the prosecution of my Discourse. And therefore, that I may not hereafter be oblig'd to trouble You and my self with needless Repetitions, I shall now only desire you to take notice of such Experiments, when they shall be mention'd, and in your thoughts referre them hither.

To these three Concessions I have but this Fourth to add, That

[Sidenote: Propos. IV.]

_It may likewise be granted, that those distinct Substances, which Concretes generally either afford or are made up of, may without very much Inconvenience be call'd the Elements or Principles of them._

When I said, _without very much Inconvenience_, I had in my Thoughts that sober Admonition of _Galen_, _Cum de re constat, de verbis non est Litigandum_. And therefore also I scruple not to say _Elements_ or _Principles_, partly because the Chymists are wont to call the Ingredients of mixt Bodies, _Principles_, as the _Aristotelians_ name them _Elements_; I would here exclude neither. And, partly, because it seems doubtfull whether the same Ingredients may not be call'd _Principles_? as not being compounded of any more primary Bodies: and _Elements_, in regard that all mix'd Bodies are compounded of them. But I thought it requisite to limit my Concession by premising the words, _very much_, to the word _Inconvenience_, because that though the Inconvenience of calling the distinct Substances, mention'd in the Proposition _Elements_ or _Principles_, be not very great, yet that it is an Impropriety of Speech, and consequently in a matter of this moment not to be altogether overlook'd, You will perhaps think, as well as I, by that time you shall have heard the following part of my Discourse, by which you will best discern what Construction to put upon the former Propositions, and how far they may be look'd upon, as things that I concede as true, and how far as things I only represent as specious enough to be fit to be consider'd.

And now _Eleutherius_ (continues _Carneades_) I must resume the person of a Sceptick, and as such, propose some part of what may be either dislik't, or at least doubted of in the common _Hypothesis_ of the Chymists: which if I examine with a little the more freedom, I hope I need not desire you (a Person to whom I have the Happinesse of being so well known) to look upon it as something more suitable to the Employment whereto the Company has, for this Meeting, doom'd me; then either to my Humour or my Custom.

Now though I might present you many things against the Vulgar Chymical Opinion of the three Principles, and the Experiments wont to be alledg'd as Demonstrations of it, yet those I shall at present offer you may be conveniently enough comprehended in four Capital Considerations; touching all which I shall only premise this in general, That since it is not my present Task so much to assert an _Hypothesis_ of my own, as to give an Account wherefore I suspect the Truth of that of the Chymists, it ought not to be expected that all my Objections should be of the most cogent sort, since it is reason enough to Doubt of a propos'd Opinion, that there appears no cogent Reason for it.

To come then to the Objections themselves; I consider in the first place, That notwithstanding what common Chymists have prov'd or taught, it may reasonably enough be Doubted, how far, and in what sence, Fire ought to be esteem'd the genuine and universal Instrument of analyzing mixt Bodies.

This Doubt, you may remember, was formerly mention'd, but so transiently discours'd of, that it will now be fit to insist upon it; And manifest that it was not so inconsiderately propos'd as our Adversaries then imagin'd.

But, before I enter any farther into this Disquisition, I cannot but here take notice, that it were to be wish'd, our Chymists had clearly inform'd us what kinde of Division of Bodies by Fire must determine the number of the Elements: For it is nothing near so easy as many seem to think, to determine distinctly the Effects of Heat, as I could easily manifest, if I had leasure to shew you how much the Operations of Fire may be diversify'd by Circumstances. But not wholly to pass by a matter of this Importance, I will first take notice to you, that _Guajacum_ (for Instance) burnt with an open Fire in a Chimney, is sequestred into Ashes and Soot, whereas the same Wood distill'd in a Retort does yield far other Heterogeneities, (to use the _Helmontian_ expression) and is resolv'd into Oyl, Spirit, Vinager, Water and Charcoal; the last of which to be reduc'd into Ashes, requires the being farther calcin'd then it can be in a close Vessel: Besides having kindled Amber, and held a clean Silver Spoon, or some other Concave and smooth Vessel over the Smoak of its Flame, I observ'd the Soot into which that Fume condens'd, to be very differing from any thing that I had observ'd to proceed from the steam of Amber purposely (for that is not usual) distilled _per se_ in close Vessels. Thus having, for Tryals sake, kindled Camphire, and catcht the Smoak that copiously ascended out of the Flame, it condens'd into a Black and unctuous Soot, which would not have been guess'd by the Smell or other Properties to have proceeded from Camphire: whereas having (as I shall otherwhere more fully declare) expos'd a quantity of that Fugitive Concrete to a gentle heat in a close Glass-Vessel, it sublim'd up without seeming to have lost any thing of its whiteness, or its Nature, both which it retain'd, though afterwards I so encreased the Fire as to bring it to Fusion. And, besides Camphire, there are divers other Bodies (that I elsewhere name) in which the heat in close Vessels is not wont to make any separation of Heterogeneities, but only a comminution of Parts, those that rise first being Homogeneal with the others, though subdivided into smaller Particles: whence Sublimations have been stiled, _The Pestles of the Chymists_. But not here to mention what I elsewhere take notice of, concerning common Brimstone once or twice sublim'd, that expos'd to a moderate Fire in Subliming-Pots, it rises all into dry, and almost tastless, Flowers; Whereas being expos'd to a naked Fire it affords store of a Saline and Fretting Liquor: Not to mention this, I say, I will further observe to you, that as it is considerable in the _Analysis_ of mixt Bodies, whether the Fire act on them when they are expos'd to the open Air, or shut up in close Vessels, so is the degree of Fire by which the _Analysis_ is attempted of no small moment. For a milde _Balneum_ will sever unfermented Blood (for Instance) but into Phlegme and _Caput mortuum_, the later whereof (which I have sometimes had) hard, brittle, and of divers Colours, (transparent almost like Tortoise-shell) press'd by a good Fire in a Retort yields a Spirit, an Oyl or two, and a volatile Salt, besides a [Errata: another] _Caput mortuum_. It may be also pertinent to our present Designe, to take notice of what happens in the making and distilling of Sope; for by one degree of Fire the Salt, the Water and the Oyl or Grease, whereof that factitious Concrete is made up, being boyl'd up together are easily brought to mingle and incorporate into one Mass; but by another and further degree of Heat the same Mass may be again divided into an oleagenous, an aqueous, a Saline, and an Earthy part. And so we may observe that impure Silver and Lead being expos'd together to a moderate Fire, will thereby be colliquated into one Mass, and mingle _per minima_, as they speak, whereas a much vehementer Fire will drive or carry off the baser Metals (I mean the Lead, and the Copper or other Alloy) from the Silver, though not, for ought appears, separate them from one another. Besides, when a Vegetable abounding in fixt Salt is analyz'd by a naked Fire, as one degree of Heat will reduce it into Ashes, (as the Chymists themselves teach us) so, by only a further degree of Fire, those Ashes may be vitrified and turn'd into Glass. I will not stay to examine how far a meere Chymist might on this occasion demand, If it be lawful for an _Aristotelian_ to make Ashes, (which he mistakes for meere Earth) pass for an Element, because by one degree of Fire it may be produc'd, why a Chymist may not upon the like Principle argue, that Glass is one of the Elements of many Bodies, because that also may be obtain'd from them, barely by the Fire? I will not, I say, lose time to examine this, but observe, that by a Method of applying the Fire, such similar Bodies may be obtain'd from a Concrete, as Chymists have not been able to separate; either by barely burning it in an open Fire, or by barely distilling it in close Vessels. For to me it seems very considerable, and I wonder that men have taken so little notice of it, that I have not by any of the common wayes of Distillation in close Vessels, seen any separation made of such a volatile Salt as is afforded us by Wood, when that is first by an open Fire divided into Ashes and Soot, and that Soot is afterwards plac'd in a strong Retort, and compell'd by an urgent Fire to part with its Spirit, Oyl and Salt; for though I dare not peremptorily deny, that in the Liquors of _Guajacum_ and other Woods distill'd in Retorts after the common manner, there may be Saline parts, which by reason of the Analogy may pretend to the name of some kinde of volatile Salts; yet questionless there is a great disparity betwixt such Salts and that which we have sometimes obtain'd upon the first Distillation of Soot (though for the most part it has not been separated from the first or second Rectification, and sometimes not till the third) For we could never yet see separated from Woods analyz'd only the vulgar way in close vessels any volatile Salt in a dry and Saline form, as that of Soot, which we have often had very Crystalline and Geometrically figur'd. And then, whereas the Saline parts of the Spirits of _Guajacum_, &c. appear upon distillation sluggish enough, the Salt of Soot seems to be one of the most volatile Bodies in all Nature; and if it be well made will readily ascend with the milde heat of a Furnace, warm'd only by the single Wieck of a Lamp, to the top of the highest Glass Vessels that are commonly made use of for Distillation: and besides all this, the taste and smell of the Salt of Soot are exceeding differing from those of the Spirits of _Guajacum_, &c. and the former not only smells and tastes much less like a vegetable Salt, than like that of Harts-horn, and other Animal Concretes; but in divers other Properties seems more of Kinne to the Family of Animals, than to that of vegetable Salts, as I may elsewhere (God permitting) have an occasion more particularly to declare. I might likewise by some other Examples manifest, That the Chymists, to have dealt clearly, ought to have more explicitly and particularly declar'd by what Degree of Fire, and in what manner of Application of it, they would have us Judge a Division made by the Fire to be a true _Analysis_ into their Principles, and the Productions of it to deserve the name of Elementary Bodies. But it is time that I proceed to mention the particular Reasons that incline me to Doubt, whether the Fire be the true and universal Analyzer of mixt Bodies; of which Reasons what has been already objected may pass for one.

In the next place I observe, That there are some mixt Bodies from which it has not been yet made appear, that any degree of Fire can separate either Salt or Sulphur or Mercury, much less all the Three. The most obvious Instance of this Truth is Gold, which is a Body so fix'd, and wherein the Elementary Ingredients (if it have any) are so firmly united to each other, that we finde not in the operations wherein Gold is expos'd to the Fire, how violent soever, that it does discernably so much as lose of its fixednesse or weight, so far is it from being dissipated into those Principles, whereof one at least is acknowledged to be Fugitive enough; and so justly did the Spagyricall Poet somewhere exclaim,

_Cuncta adeo miris illic compagibus harent._

And I must not omit on this occasion to mention to you, _Eleutherius_, the memorable Experiment that I remember I met with in _Gasto Claveus_,[2] who, though a Lawyer by Profession, seems to have had no small Curiosity and Experience in Chymical affairs: He relates then, that having put into one small Earthen Vessel an Ounce of the most pure Gold, and into another the like weight of pure Silver, he plac'd them both in that part of a Glass-house Furnace wherein the Workmen keep their Metal, (as our English Artificers call their Liquid Glass) continually melted, and that having there kept both the Gold and the Silver in constant Fusion for two Moneths together, he afterwards took them out of the Furnace and the Vessels, and weighing both of them again, found that the Silver had not lost above a 12th part of its weight, but the Gold had not of his lost any thing at all. And though our Author endeavours to give us of this a Scholastick Reason, which I suppose you would be as little satisfied with, as I was when I read it; yet for the matter of Fact, which will serve our present turne, he assures us, that though it be strange, yet Experience it self taught it him to be most true.

[Footnote 2: _Gasto Claveus_ Apolog. Argur. & Chrysopera.]

And though there be not perhaps any other Body to be found so perfectly fix'd as Gold, yet there are divers others so fix'd or compos'd, at least of so strictly united parts, that I have not yet observ'd the Fire to separate from them any one of the Chymists Principles. I need not tell you what Complaints the more Candid and Judicious of the Chymists themselves are wont to make of those Boasters that confidently pretend, that they have extracted the Salt or Sulphur of Quicksilver, when they have disguis'd it by Additaments, wherewith it resembles the Concretes whose Names are given it; whereas by a skilful and rigid _Examen_, it may be easily enough stript of its Disguises, and made to appear again in the pristine form of running Mercury. The pretended Salts and Sulphurs being so far from being Elementary parts extracted out of the Bodie of Mercurie, that they are rather (to borrow a terme of the Grammarians) De-compound Bodies, made up of the whole Metal and the _Menstruum_ or other Additaments imploy'd to disguise it. And as for Silver, I never could see any degree of Fire make it part with any of its three Principles. And though the Experiment lately mentioned from _Claveus_ may beget a Suspition that Silver may be dissipated by Fire, provided it be extreamly violent and very lasting: yet it will not necessarily follow, that because the Fire was able at length to make the Silver lose a little of its weight, it was therefore able to dissipate it into its Principles. For first I might alledge that I have observ'd little Grains of Silver to lie hid in the small Cavities (perhaps glas'd over by a vitrifying heat) in Crucibles, wherein Silver has been long kept in Fusion, whence some Goldsmiths of my Acquaintance make a Benefit by grinding such Crucibles to powder, to recover out of them the latent particles of Silver. And hence I might argue, that perhaps _Claveus_ was mistaken, and imagin'd that Silver to have been driven away by the Fire, that indeed lay in minute parts hid in his Crucible, in whose pores so small a quantity as he mist of so ponderous a Bodie might very well lie conceal'd.