The Outline of Science, Vol. 1 (of 4) A Plain Story Simply Told

Chapter 25

Chapter 253,359 wordsPublic domain

In short, a series of the most remarkable and beautiful experiments, checked in all the great laboratories of the world, settled the nature of these so-called rays. They were streams of particles more than a thousand times smaller than the smallest known atom. The mass of each particle is, according to the latest and finest measurements 1/1845 of that of an atom of hydrogen. The physicist has not been able to find any character except electricity in them, and the name "electrons" has been generally adopted.

The Key to many Mysteries

The Electron is an atom, of disembodied electricity; it occupies an exceedingly small volume, and its "mass" is entirely electrical. These electrons are the key to half the mysteries of matter. Electrons in rapid motion, as we shall see, explain what we mean by an "electric current," not so long ago regarded as one of the most mysterious manifestations in nature.

"What a wonder, then, have we here!" says Professor R. K. Duncan. "An innocent-looking little pinch of salt and yet possessed of special properties utterly beyond even the fanciful imaginings of men of past time; for nowhere do we find in the records of thought even the hint of the possibility of things which we now regard as established fact. This pinch of salt projects from its surface bodies [i.e. electrons] possessing the inconceivable velocity of over 100,000 miles a second, a velocity sufficient to carry them, if unimpeded, five times around the earth in a second, and possessing with this velocity, masses a thousand times smaller than the smallest atom known to science. Furthermore, they are charged with negative electricity; they pass straight through bodies considered opaque with a sublime indifference to the properties of the body, with the exception of its mere density; they cause bodies which they strike to shine out in the dark; they affect a photographic plate; they render the air a conductor of electricity; they cause clouds in moist air; they cause chemical action and have a peculiar physiological action. Who, to-day, shall predict the ultimate service to humanity of the beta-rays from radium!"

§ 6

THE ELECTRON THEORY, OR THE NEW VIEW OF MATTER

The Structure of the Atom

There is general agreement amongst all chemists, physicists, and mathematicians upon the conclusions which we have so far given. We know that the atoms of matter are constantly--either spontaneously or under stimulation--giving off electrons, or breaking up into electrons; and they therefore contain electrons. Thus we have now complete proof of the independent existence of atoms and also of electrons.

When, however, the man of science tries to tell us _how_ electrons compose atoms, he passes from facts to speculation, and very difficult speculation. Take the letter "o" as it is printed on this page. In a little bubble of hydrogen gas no larger than that letter there are _trillions_ of atoms; and they are not packed together, but are circulating as freely as dancers in a ball-room. We are asking the physicist to take one of these minute atoms and tell us how the still smaller electrons are arranged in it. Naturally he can only make mental pictures, guesses or hypotheses, which he tries to fit to the facts, and discards when they will _not_ fit.

At present, after nearly twenty years of critical discussion, there are two chief theories of the structure of the atom. At first Sir J. J. Thomson imagined the electrons circulating in shells (like the layers of an onion) round the nucleus of the atom. This did not suit, and Sir E. Rutherford and others worked out a theory that the electrons circulated round a nucleus rather like the planets of our solar system revolving round the central sun. Is there a nucleus, then, round which the electrons revolve? The electron, as we saw, is a disembodied atom of electricity; we should say, of "negative" electricity. Let us picture these electrons all moving round in orbits with great velocity. Now it is suggested that there is a nucleus of "positive" electricity attracting or pulling the revolving electrons to it, and so forming an equilibrium, otherwise the electrons would fly off in all directions. This nucleus has been recently named the proton. We have thus two electricities in the atom: the positive = the nucleus; the negative = the electron. Of recent years Dr. Langmuir has put out a theory that the electrons do not _revolve round_ the nucleus, but remain in a state of violent agitation of some sort at fixed distances from the nucleus.

But we will confine ourselves here to the facts, and leave the contending theories to scientific men. It is now pretty generally accepted that an atom of matter consists of a number of electrons, or charges of negative electricity, held together by a charge of positive electricity. It is not disputed that these electrons are in a state of violent motion or strain, and that therefore a vast energy is locked up in the atoms of matter. To that we will return later. Here, rather, we will notice another remarkable discovery which helps us to understand the nature of matter.

A brilliant young man of science who was killed in the war, Mr. Moseley, some years ago showed that, when the atoms of different substances are arranged in order of their weight, _they are also arranged in the order of increasing complexity of structure_. That is to say, the heavier the atom, the more electrons it contains. There is a gradual building up of atoms containing more and more electrons from the lightest atom to the heaviest. Here it is enough to say that as he took element after element, from the lightest (hydrogen) to the heaviest (uranium) he found a strangely regular relation between them. If hydrogen were represented by the figure one, helium by two, lithium three, and so on up to uranium, then uranium should have the figure ninety-two. This makes it probable that there are in nature ninety-two elements--we have found eighty-seven--and that the number Mr. Moseley found is the number of electrons in the atom of each element; that is to say, the number is arranged in order of the atomic numbers of the various elements.

§ 7

The New View of Matter

Up to the point we have reached, then, we see what the new view of Matter is. Every atom of matter, of whatever kind throughout the whole universe, is built up of electrons in conjunction with a nucleus. From the smallest atom of all--the atom of hydrogen--which consists of one electron, rotating round a positively charged nucleus, to a heavy complicated atom, such as the atom of gold, constituted of many electrons and a complex nucleus, _we have only to do with positive and negative units of electricity_. The electron and its nucleus are particles of electricity. All Matter, therefore, is nothing but a manifestation of electricity. The atoms of matter, as we saw, combine and form molecules. Atoms and molecules are the bricks out of which nature has built up everything; ourselves, the earth, the stars, the whole universe.

But more than bricks are required to build a house. There are other fundamental existences, such as the various forms of energy, which give rise to several complex problems. And we have also to remember, that there are more than eighty distinct elements, each with its own definite type of atom. We shall deal with energy later. Meanwhile it remains to be said that, although we have discovered a great deal about the electron and the constitution of matter, and that while the physicists of our own day seem to see a possibility of explaining positive and negative electricity, the nature of them both is unknown. There exists the theory that the particles of positive and negative electricity, which make up the atoms of matter, are points or centres of disturbances of some kind in a universal ether, and that all the various forms of energy are, in some fundamental way, aspects of the same primary entity which constitutes matter itself.

But the discovery of the property of radio-activity has raised many other interesting questions, besides that which we have just dealt with. In radio-active elements, such as uranium for example, the element is breaking down; in what we call radio-activity we have a manifestation of the spontaneous change of elements. What is really taking place is a transmutation of one element into another, from a heavier to a lighter. The element uranium spontaneously becomes radium, and radium passes through a number of other stages until it, in turn, becomes lead. Each descending element is of lighter atomic weight than its predecessor. The changing process, of course, is a very slow one. It may be that all matter is radio-active, or can be made so. This raises the question whether all the matter in the universe may not undergo disintegration.

There is, however, another side of the question, which the discovery of radio-activity has brought to light, and which has effected a revolution in our views. We have seen that in radio-active substances the elements are breaking down. Is there a process of building up at work? If the more complicated atoms are breaking down into simpler forms, may there not be a converse process--a building up from simpler elements to more complicated elements? It is probably the case that both processes are at work.

There are some eighty-odd chemical elements on the earth to-day: are they all the outcome of an inorganic evolution, element giving rise to element, going back and back to some primeval stuff from which they were all originally derived infinitely long ago? Is there an evolution in the inorganic world which may be going on, parallel to that of the evolution of living things; or is organic evolution a continuation of inorganic evolution? We have seen what evidence there is of this inorganic evolution in the case of the stars. We cannot go deeply into the matter here, nor has the time come for any direct statement that can be based on the findings of modern investigation. Taking it altogether the evidence is steadily accumulating, and there are authorities who maintain that already the evidence of inorganic evolution is convincing enough. The heavier atoms would appear to behave as though they were evolved from the lighter. The more complex forms, it is supposed, have _evolved_ from the simpler forms. Moseley's discovery, to which reference has been made, points to the conclusion that the elements are built up one from another.

§ 8

Other New Views

We may here refer to another new conception to which the discovery of radio-activity has given rise. Lord Kelvin, who estimated the age of the earth at twenty million years, reached this estimate by considering the earth as a body which is gradually cooling down, "losing its primitive heat, like a loaf taken from the oven, at a rate which could be calculated, and that the heat radiated by the sun was due to contraction." Uranium and radio-activity were not known to Kelvin, and their discovery has upset both his arguments. Radio-active substances, which are perpetually giving out heat, introduce an entirely new factor. We cannot now assume that the earth is necessarily cooling down; it may even, for all we know, be getting hotter. At the 1921 meeting of the British Association, Professor Rayleigh stated that further knowledge had extended the probable period during which there had been life on this globe to about one thousand million years, and the total age of the earth to some small multiple of that. The earth, he considers, is not cooling, but "contains an internal source of heat from the disintegration of uranium in the outer crust." On the whole the estimate obtained would seem to be in agreement with the geological estimates. The question, of course, cannot, in the present state of our knowledge, be settled within fixed limits that meet with general agreement.

As we have said, there are other fundamental existences which give rise to more complex problems. The three great fundamental entities in the physical universe are matter, ether, and energy; so far as we know, outside these there is nothing. We have dealt with matter, there remain ether and energy. We shall see that just as no particle of matter, however small, may be created or destroyed, and just as there is no such thing as empty space--ether pervades everything--so there is no such thing as _rest_. Every particle that goes to make up our solid earth is in a state of perpetual unremitting vibration; energy "is the universal commodity on which all life depends." Separate and distinct as these three fundamental entities--matter, ether, and energy--may appear, it may be that, after all, they are only different and mysterious phases of an essential "oneness" of the universe.

§ 9

The Future

Let us, in concluding this chapter, give just one illustration of the way in which all this new knowledge may prove to be as valuable practically as it is wonderful intellectually. We saw that electrons are shot out of atoms at a speed that may approach 160,000 miles a second. Sir Oliver Lodge has written recently that a seventieth of a grain of radium discharges, at a speed a thousand times that of a rifle bullet, thirty million electrons a second. Professor Le Bon has calculated that it would take 1,340,000 barrels of powder to give a bullet the speed of one of these electrons. He shows that the smallest French copper coin--smaller than a farthing--contains an energy equal to eighty million horsepower. A few pounds of matter contain more energy than we could extract from millions of tons of coal. Even in the atoms of hydrogen at a temperature which we could produce in an electric furnace the electrons spin round at a rate of nearly a hundred trillion revolutions a second!

Every man asks at once: "Will science ever tap this energy?" If it does, no more smoke, no mining, no transit, no bulky fuel. The energy of an atom is of course only liberated when an atom passes from one state to another. The stored up energy is fortunately fast bound by the electrons being held together as has been described. If it were not so "the earth would explode and become a gaseous nebula"! It is believed that some day we shall be able to release, harness, and utilise atomic energy. "I am of opinion," says Sir William Bragg, "that atom energy will supply our future need. A thousand years may pass before we can harness the atom, or to-morrow might see us with the reins in our hands. That is the peculiarity of Physics--research and 'accidental' discovery go hand in hand." Half a brick contains as much energy as a small coal-field. The difficulties are tremendous, but, as Sir Oliver Lodge reminds us, there was just as much scepticism at one time about the utilisation of steam or electricity. "Is it to be supposed," he asks, "that there can be no fresh invention, that all the discoveries have been made?" More than one man of science encourages us to hope. Here are some remarkable words written by Professor Soddy, one of the highest authorities on radio-active matter, in our chief scientific weekly (_Nature_, November 6, 1919):

The prospects of the successful accomplishment of artificial transmutation brighten almost daily. The ancients seem to have had something more than an inkling that the accomplishment of transmutation would confer upon men powers hitherto the prerogative of the gods. But now we know definitely that the material aspect of transmutation would be of small importance in comparison with the control over the inexhaustible stores of internal atomic energy to which its successful accomplishment would inevitably lead. It has become a problem, no longer redolent of the evil associations of the age of alchemy, but one big with the promise of a veritable physical renaissance of the whole world.

If that "promise" is ever realised, the economic and social face of the world will be transformed.

Before passing on to the consideration of ether, light, and energy, let us see what new light the discovery of the electron has thrown on the nature and manipulation of electricity.

WHAT IS ELECTRICITY?

The Nature of Electricity

There is at least one manifestation in nature, and so late as twenty years ago it seemed to be one of the most mysterious manifestations of all, which has been in great measure explained by the new discoveries. Already, at the beginning of this century, we spoke of our "age of electricity," yet there were few things in nature about which we knew less. The "electric current" rang our bells, drove our trains, lit our rooms, but none knew what the current was. There was a vague idea that it was a sort of fluid that flowed along copper wires as water flows in a pipe. We now suppose that it is _a rapid movement of electrons from atom to atom_ in the wire or wherever the current is.

Let us try to grasp the principle of the new view of electricity and see how it applies to all the varied electrical phenomena in the world about us. As we saw, the nucleus of an atom of matter consists of positive electricity which holds together a number of electrons, or charges of negative electricity.[4] This certainly tells us to some extent what electricity is, and how it is related to matter, but it leaves us with the usual difficulty about fundamental realities. But we now know that electricity, like matter, is atomic in structure; a charge of electricity is made up of a number of small units or charges of a definite, constant amount. It has been suggested that the two kinds of electricity, i.e. positive and negative, are right-handed and left-handed vortices or whirlpools in ether, or rings in ether, but there are very serious difficulties, and we leave this to the future.

[4] The words "positive" and "negative" electricity belong to the days when it was regarded as a fluid. A body overcharged with the fluid was called positive; an undercharged body was called negative. A positively-electrified body is now one whose atoms have lost some of their outlying electrons, so that the positive charge of electricity predominates. The negatively-electrified body is one with more than the normal number of electrons.

§ 10

What an Electric Current is

The discovery of these two kinds of electricity has, however, enabled us to understand very fairly what goes on in electrical phenomena. The outlying electrons, as we saw, may pass from atom to atom, and this, on a large scale, is the meaning of the electric current. In other words, we believe an electric current to be a flow of electrons. Let us take, to begin with, a simple electrical "cell," in which a feeble current is generated: such a cell as there is in every house to serve its electric bells.

In the original form this simple sort of "battery" consisted of a plate of zinc and a plate of copper immersed in a chemical. Long before anything was known about electrons it was known that, if you put zinc and copper together, you produce a mild current of electricity. We know now what this means. Zinc is a metal the atoms of which are particularly disposed to part with some of their outlying electrons. Why, we do not know; but the fact is the basis of these small batteries. Electrons from the atoms of zinc pass to the atoms of copper, and their passage is a "current." Each atom gives up an electron to its neighbour. It was further found long ago that if the zinc and copper were immersed in certain chemicals, which slowly dissolve the zinc, and the two metals were connected by a copper wire, the current was stronger. In modern language, there is a brisker flow of electrons. The reason is that the atoms of zinc which are stolen by the chemical leave their detachable electrons behind them, and the zinc has therefore more electrons to pass on to the copper.