Part 2

Now, the virial must be nearly independent of the temperature, and therefore the last term almost disappears. The virial would not be quite independent of the temperature, because if the temperature (i. e. the square of the velocity of the molecules) is lowered, and the pressure correspondingly lowered, so as to make the volume the same, the attractions of the molecules will have more time to produce their effects, and consequently, the pairs of molecules the closest together will be held together longer and closer; so that the virial will generally be increased by a decrease of temperature. Now, Amagat’s experiments do show an excessively minute effect of this sort, at least, when the volumes are not too small. However, the observations are well enough satisfied by assuming the “coefficient of expansion at constant volume” to consist wholly of the first term, _a_/(_V_). Thus, Amagat’s experiments enable us to determine the values of _a_ and thence to calculate the virial; and this we find varies for carbonic acid gas nearly inversely to (_V_)⁰˙⁹. There is, thus, a rough approximation to satisfying Van der Waals’s equation. But the most interesting result of Amagat’s experiments, for our purpose at any rate, is that the quantity _a_, though nearly constant for any one volume, differs considerably with the volume, nearly doubling when the volume is reduced fivefold. This can only indicate that the mean kinetic energy of a given mass of the gas for a given temperature is greater the more the gas is compressed. But the laws of mechanics appear to enjoin that the mean kinetic energy of a moving particle shall be constant at any given temperature. The only escape from contradiction, then, is to suppose that the mean mass of a moving particle diminishes upon the condensation of the gas. In other words, many of the molecules are dissociated, or broken up into atoms or sub-molecules. The idea that dissociation should be favored by diminishing the volume will be pronounced by physicists, at first blush, as contrary to all our experience. But it must be remembered that the circumstances we are speaking of, that of a gas under fifty or more atmospheres pressure, are also unusual. That the “coefficient of expansion under constant volume” when multiplied by the volumes should increase with a decrement of the volume is also quite contrary to ordinary experience; yet it undoubtedly takes place in all gases under great pressure. Again, the doctrine of Arrhenius[7] is now generally accepted, that the molecular conductivity of an electrolyte is proportional to the dissociation of ions. Now the molecular conductivity of a fused electrolyte is usually superior to that of a solution. Here is a case, then, in which diminution of volume is accompanied by increased dissociation.

The truth is that several different kinds of dissociation have to be distinguished. In the first place, there is the dissociation of a chemical molecule to form chemical molecules under the regular action of chemical laws. This may be a double decomposition, as when iodhydric acid is dissociated, according to the formula

HI + HI = HH + II;

or, it may be a simple decomposition, as when pentachloride of phosphorus is dissociated according to the formula

PCl₅ = PCl₃ + ClCl.

All these dissociations require, according to the laws of thermochemistry, an elevated temperature. In the second place, there is the dissociation of a physically polymerous molecule, that is, of several chemical molecules joined by physical attractions. This I am inclined to suppose is a common concomitant of the heating of solids and liquids; for in these bodies there is no increase of compressibility with the temperature at all comparable with the increase of the expansibility. But, in the third place, there is the dissociation with which we are now concerned, which must be supposed to be a throwing off of unsaturated sub-molecules or atoms from the molecule. The molecule may, as I have said, be roughly likened to a solar system. As such, molecules are able to produce perturbations of one another’s internal motions; and in this way a planet, i. e. a sub-molecule, will occasionally get thrown off and wander about by itself, till it finds another unsaturated sub-molecule with which it can unite. Such dissociation by perturbation will naturally be favored by the proximity of the molecules to one another.

Let us now pass to the consideration of that special substance, or rather class of substances, whose properties form the chief subject of botany and of zoölogy, as truly as those of the silicates form the chief subject of mineralogy: I mean the life-slimes, or protoplasm. Let us begin by cataloguing the general characters of these slimes. They one and all exist in two states of aggregation, a solid or nearly solid state and a liquid or nearly liquid state; but they do not pass from the former to the latter by ordinary fusion. They are readily decomposed by heat, especially in the liquid state; nor will they bear any considerable degree of cold. All their vital actions take place at temperatures very little below the point of decomposition. This extreme instability is one of numerous facts which demonstrate the chemical complexity of protoplasm. Every chemist will agree that they are far more complicated than the albumens. Now, albumen is estimated to contain in each molecule about a thousand atoms; so that it is natural to suppose that the protoplasms contain several thousands. We know that while they are chiefly composed of oxygen, hydrogen, carbon, and nitrogen, a large number of other elements enter into living bodies in small proportions; and it is likely that most of these enter into the composition of protoplasms. Now, since the numbers of chemical varieties increase at an enormous rate with the number of atoms per molecule, so that there are certainly hundreds of thousands of substances whose molecules contain twenty atoms or fewer, we may well suppose that the number of protoplasmic substances runs into the billions or trillions. Professor Cayley has given a mathematical theory of “trees,” with a view of throwing a light upon such questions; and in that light the estimate of trillions (in the English sense) seems immoderately moderate. It is true that an opinion has been emitted, and defended among biologists, that there is but one kind of protoplasm; but the observations of biologists, themselves, have almost exploded that hypothesis, which from a chemical standpoint appears utterly incredible. The anticipation of the chemist would decidedly be that enough different chemical substances having protoplasmic characters might be formed to account, not only for the differences between nerve-slime and muscle-slime, between whale-slime and lion-slime, but also for those minuter pervasive variations which characterise different breeds and single individuals.

Protoplasm, when quiescent, is, broadly speaking, solid; but when it is disturbed in an appropriate way, or sometimes even spontaneously without external disturbance, it becomes, broadly speaking, liquid. A moner in this state is seen under the microscope to have streams within its matter; a slime-mould slowly flows by force of gravity. The liquefaction starts from the point of disturbance and spreads through the mass. This spreading, however, is not uniform in all directions; on the contrary it takes at one time one course, at another another, through the homogeneous mass, in a manner that seems a little mysterious. The cause of disturbance being removed, these motions gradually (with higher kinds of protoplasm, quickly) cease, and the slime returns to its solid condition.

The liquefaction of protoplasm is accompanied by a mechanical phenomenon. Namely, some kinds exhibit a tendency to draw themselves up into a globular form. This happens particularly with the contents of muscle-cells. The prevalent opinion, founded on some of the most exquisite experimental investigations that the history of science can show, is undoubtedly that the contraction of muscle-cells is due to osmotic pressure; and it must be allowed that that is a factor in producing the effect. But it does not seem to me that it satisfactorily accounts even for the phenomena of muscular contraction; and besides, even naked slimes often draw up in the same way. In this case, we seem to recognise an increase of the surface-tension. In some cases, too, the reverse action takes place, extraordinary pseudopodia being put forth, as if the surface-tension were diminished in spots. Indeed, such a slime always has a sort of skin, due no doubt to surface-tension, and this seems to give way at the point where a pseudopodium is put forth.

Long-continued or frequently repeated liquefaction of the protoplasm results in an obstinate retention of the solid state, which we call fatigue. On the other hand repose in this state, if not too much prolonged, restores the liquefiability. These are both important functions.

The life-slimes have, further, the peculiar property of growing. Crystals also grow; their growth, however, consists merely in attracting matter like their own from the circumambient fluid. To suppose the growth of protoplasm of the same nature, would be to suppose this substance to be spontaneously generated in copious supplies wherever food is in solution. Certainly, it must be granted that protoplasm is but a chemical substance, and that there is no reason why it should not be formed synthetically like any other chemical substance. Indeed, Clifford has clearly shown that we have overwhelming evidence that it is so formed. But to say that such formation is as regular and frequent as the assimilation of food is quite another matter. It is more consonant with the facts of observation to suppose that assimilated protoplasm is formed at the instant of assimilation, under the influence of the protoplasm already present. For each slime in its growth preserves its distinctive characters with wonderful truth, nerve-slime growing nerve-slime and muscle-slime muscle-slime, lion-slime growing lion-slime, and all the varieties of breeds and even individual characters being preserved in the growth. Now it is too much to suppose there are billions of different kinds of protoplasm floating about wherever there is food.

The frequent liquefaction of protoplasm increases its power of assimilating food; so much so, indeed, that it is questionable whether in the solid form it possesses this power.

The life-slime wastes as well as grows; and this too takes place chiefly if not exclusively in its liquid phases.

Closely connected with growth is reproduction; and though in higher forms this is a specialised function, it is universally true that wherever there is protoplasm, there is, will be, or has been a power of reproducing that same kind of protoplasm in a separated organism. Reproduction seems to involve the union of two sexes; though it is not demonstrable that this is always requisite.

Another physical property of protoplasm is that of taking habits. The course which the spread of liquefaction has taken in the past is rendered thereby more likely to be taken in the future; although there is no absolute certainty that the same path will be followed again.

Very extraordinary, certainly, are all these properties of protoplasm; as extraordinary as indubitable. But the one which has next to be mentioned, while equally undeniable, is infinitely more wonderful. It is that protoplasm feels. We have no direct evidence that this is true of protoplasm universally, and certainly some kinds feel far more than others. But there is a fair analogical inference that all protoplasm feels. It not only feels but exercises all the functions of mind.

Such are the properties of protoplasm. The problem is to find a hypothesis of the molecular constitution of this compound which will account for these properties, one and all.

Some of them are obvious results of the excessively complicated constitution of the protoplasm molecule. All very complicated substances are unstable; and plainly a molecule of several thousand atoms may be separated in many ways into two parts in each of which the polar chemical forces are very nearly saturated. In the solid protoplasm, as in other solids, the molecules must be supposed to be moving as it were in orbits, or, at least, so as not to wander indefinitely. But this solid cannot be melted, for the same reason that starch cannot be melted; because an amount of heat insufficient to make the entire molecules wander is sufficient to break them up completely and cause them to form new and simpler molecules. But when one of the molecules is disturbed, even if it be not quite thrown out of its orbit at first, sub-molecules of perhaps several hundred atoms each are thrown off from it. These will soon acquire the same mean kinetic energy as the others, and therefore velocities several times as great. They will naturally begin to wander, and in wandering will perturb a great many other molecules and cause them in their turn to behave like the one originally deranged. So many molecules will thus be broken up, that even those that are intact will no longer be restrained within orbits, but will wander about freely. This is the usual condition of a liquid, as modern chemists understand it; for in all electrolytic liquids there is considerable dissociation.

But this process necessarily chills the substance, not merely on account of the heat of chemical combination, but still more because the number of separate particles being greatly increased, the mean kinetic energy must be less. The substance being a bad conductor, this heat is not at once restored. Now the particles moving more slowly, the attractions between them have time to take effect, and they approach the condition of equilibrium. But their dynamic equilibrium is found in the restoration of the solid condition, which therefore takes place, if the disturbance is not kept up.

When a body is in the solid condition, most of its molecules must be moving at the same rate, or, at least, at certain regular sets of rates; otherwise the orbital motion would not be preserved. The distances of neighboring molecules must always be kept between a certain maximum and a certain minimum value. But if, without absorption of heat, the body be thrown into a liquid condition, the distances of neighboring molecules will be far more unequally distributed, and an effect upon the virial will result. The chilling of protoplasm upon its liquefaction must also be taken into account. The ordinary effect will no doubt be to increase the cohesion and with that the surface-tension, so that the mass will tend to draw itself up. But in special cases, the virial will be increased so much that the surface-tension will be diminished at points where the temperature is first restored. In that case, the outer film will give way and the tension at other places will aid in causing the general fluid to be poured out at those points, forming pseudopodia.

When the protoplasm is in a liquid state, and then only, a solution of food is able to penetrate its mass by diffusion. The protoplasm is then considerably dissociated; and so is the food, like all dissolved matter. If then the separated and unsaturated sub-molecules of the food happen to be of the same chemical species as sub-molecules of the protoplasm, they may unite with other sub-molecules of the protoplasm to form new molecules, in such a fashion that when the solid state is resumed, there may be more molecules of protoplasm than there were at the beginning. It is like the jack-knife whose blade and handle, after having been severally lost and replaced, were found and put together to make a new knife.

We have seen that protoplasm is chilled by liquefaction, and that this brings it back to the solid state, when the heat is recovered. This series of operations must be very rapid in the case of nerve-slime and even of muscle-slime, and may account for the unsteady or vibratory character of their action. Of course, if assimilation takes place, the heat of combination, which is probably trifling, is gained. On the other hand, if work is done, whether by nerve or by muscle, loss of energy must take place. In the case of the muscle, the mode by which the instantaneous part of the fatigue is brought about is easily traced out. If when the muscle contracts it be under stress, it will contract less than it otherwise would do, and there will be a loss of heat. It is like an engine which should work by dissolving salt in water and using the contraction during the solution to lift a weight, the salt being recovered afterwards by distillation. But the major part of fatigue has nothing to do with the correlation of forces. A man must labor hard to do in a quarter of an hour the work which draws from him enough heat to cool his body by a single degree. Meantime, he will be getting heated, he will be pouring out extra products of combustion, perspiration, etc., and he will be driving the blood at an accelerated rate through minute tubes at great expense. Yet all this will have little to do with his fatigue. He may sit quietly at his table writing, doing practically no physical work at all, and yet in a few hours be terribly fagged. This seems to be owing to the deranged sub-molecules of the nerve-slime not having had time to settle back into their proper combinations. When such sub-molecules are thrown out, as they must be from time to time, there is so much waste of material.

In order that a sub-molecule of food may be thoroughly and firmly assimilated into a broken molecule of protoplasm, it is necessary not only that it should have precisely the right chemical composition, but also that it should be at precisely the right spot at the right time and should be moving in precisely the right direction with precisely the right velocity. If all these conditions are not fulfilled, it will be more loosely retained than the other parts of the molecule; and every time it comes round into the situation in which it was drawn in, relatively to the other parts of that molecule and to such others as were near enough to be factors in the action, it will be in special danger of being thrown out again. Thus, when a partial liquefaction of the protoplasm takes place many times to about the same extent, it will, each time, be pretty nearly the same molecules that were last drawn in that are now thrown out. They will be thrown out, too, in about the same way, as to position, direction of motion, and velocity, in which they were drawn in; and this will be in about the same course that the ones last before them were thrown out. Not exactly, however; for the very cause of their being thrown off so easily is their not having fulfilled precisely the conditions of stable retention. Thus, the law of habit is accounted for, and with it its peculiar characteristic of not acting with exactitude.

It seems to me that this explanation of habit, aside from the question of its truth or falsity, has a certain value as an addition to our little store of mechanical examples of actions analogous to habit. All the others, so far as I know, are either statical or else involve forces which, taking only the sensible motions into account, violate the law of energy. It is so with the stream that wears its own bed. Here, the sand is carried to its most stable situation and left there. The law of energy forbids this; for when anything reaches a position of stable equilibrium, its momentum will be at a maximum, so that it can according to this law only be left at rest in an unstable situation. In all the statical illustrations, too, things are brought into certain states and left there. A garment receives folds and keeps them; that is, its limit of elasticity is exceeded. This failure to spring back is again an apparent violation of the law of energy; for the substance will not only not spring back of itself (which might be due to an unstable equilibrium being reached) but will not even do so when an impulse that way is applied to it. Accordingly, Professor James says “the phenomena of habit ... are due to the plasticity of the ... materials.” Now, plasticity of materials means the having of a low limit of elasticity. (See the “Century Dictionary,” under _solid_.) But the hypothetical constitution of protoplasm here proposed involves no forces but attractions and repulsions strictly following the law of energy. The action here, that is, the throwing of an atom out of its orbit in a molecule, and the entering of a new atom into nearly, but not quite the same orbit, is somewhat similar to the molecular actions which may be supposed to take place in a solid strained beyond its limit of elasticity. Namely, in that case certain molecules must be thrown out of their orbits, to settle down again shortly after into new orbits. In short, the plastic solid resembles protoplasm in being partially and temporarily liquefied by a slight mechanical force. But the taking of a set by a solid body has but a moderate resemblance to the taking of a habit, inasmuch as the characteristic feature of the latter, its inexactitude and want of complete determinacy, is not so marked in the former, if it can be said to be present there, at all.

The truth is that though the molecular explanation of habit is pretty vague on the mathematical side, there can be no doubt that systems of atoms having polar forces would act substantially in that manner, and the explanation is even too satisfactory to suit the convenience of an advocate of tychism. For it may fairly be urged that since the phenomena of habit may thus result from a purely mechanical arrangement, it is unnecessary to suppose that habit-taking is a primordial principle of the universe. But one fact remains unexplained mechanically, which concerns not only the facts of habit, but all cases of actions apparently violating the law of energy; it is that all these phenomena depend upon aggregations of trillions of molecules in one and the same condition and neighborhood; and it is by no means clear how they could have all been brought and left in the same place and state by any conservative forces. But let the mechanical explanation be as perfect as it may, the state of things which it supposes presents evidence of a primordial habit-taking tendency. For it shows us like things acting in like ways because they are alike. Now, those who insist on the doctrine of necessity will for the most part insist that the physical world is entirely individual. Yet law involves an element of generality. Now to say that generality is primordial, but generalisation not, is like saying that diversity is primordial but diversification not. It turns logic upside down. At any rate, it is clear that nothing but a principle of habit, itself due to the growth by habit of an infinitesimal chance tendency toward habit-taking, is the only bridge that can span the chasm between the chance-medley of chaos and the cosmos of order and law.

I shall not attempt a molecular explanation of the phenomena of reproduction, because that would require a subsidiary hypothesis, and carry me away from my main object. Such phenomena, universally diffused though they be, appear to depend upon special conditions; and we do not find that all protoplasm has reproductive powers.