Chapter 9

Mr. Biot, in 1840, speaking of Mr. Fox Talbot's beautiful calotype pictures, considers as an illusion "the hope to reconcile, not only the intensity but the tints of the chemical impressions produced by radiations, with the colors of the object from which these radiations emanated." It is true that three years have passed away, and we have not yet produced colored images; yet I am not inclined to consider the hope as entirely illusive.

It must be remembered that the color of bodies depends entirely upon the arrangement of their molecules. We have numerous very beautiful experiments in proof of this. The bi-niodide of mercury is a fine scarlet when precipitated. If this precipitate is heated between plates of glass, it is converted into crystals of a fine sulphur yellow, which remain of that color if undisturbed, but which becomes very speedily scarlet if touched with any pointed instrument. This very curious optical phenomena has been investigated by Mr. Talbot and by Mr. Warrington. Perfectly dry sulphate of copper is white; the slightest moisture turns it blue. Muriate of cobalt is of a pale pink color; a very slight heat, by removing a little moisture, changes it to a green. These are a few instances selected from many which might be given.

If we receive a prismatic spectrum on some papers, we have evidence that the molecular or chemical disturbance bears some relation to the color of each ray, or, in other words, that colored light so modifies the action of ENERGIA that the impression it makes is in proportion to the color of the light it accompanies, and hence there results a molecular arrangement capable of reflecting colors differently. Some instances have been given in which the rays impressed correspond with the colors of the luminous rays in a very remarkable manner.* One of the most decided cases is that of the paper prepared with the fluoride of soda and nitrate of silver. Sir John Herschel was, however, the first to obtain any good specimens of photographically impressed prismatic colorations.

* See Mr. Hunt's "Researches on Light."

It was noticed by Daguerre that a red house gave a reddish image on his iodized silver plate in the camera obscura; and Mr. Talbot observed, very early in his researches, that the red of a colored print was copied of a red color, on paper spread with the chloride of silver.**

** In 1842, I had shown me a picture of a house in the Bowery, which had been repaired a few days previous, and in the wall a red brick left. This brick was brought out on the Daguerreotype plate of precisely the same color as the brick itself. The same artist also exhibited to me, the full length portrait of a gentleman who were a pair of pantaloons having a blue striped figure. This blue stripe was fully brought out, of the same color, in the picture.--AMER. ED.

"In 1840 I communicated to Sir John Herschel some very curious results obtained by the use of colored media, which he did me the honor of publishing in one of his memoirs on the subject from which I again copy it."

"A paper prepared with muriate of barytes and nitrate of silver, allowed to darken whilst wet in the sunshine to a chocolate color, was placed under a frame containing a red, a yellow, a green, and a blue glass. After a week's exposure to diffused light, it became red under the red glass, a dirty yellow under the yellow glass, a dark green under the green, and a light olive under the blue.

"The above paper washed with a solution of salt of iodine, is very sensitive to light, and gives a beautiful picture. A picture thus taken was placed beneath the above glasses, and another beneath four flat bottles containing colored fluids. In a few days, under the red glass and fluid, the picture became a dark blue, under the yellow a light blue, under the green it remained unchanged, whilst under the blue it became a rose red, which in about three weeks changed into green. Many other experiments of a similar nature have been tried since that time with like results.

"In the summer of 1843, when engaged in some experiments on papers prepared according to the principles of Mr. Talbot's calotype, I had placed in a camera obscura a paper prepared with the bromide of silver and gallic acid. The camera embraced a picture of a clear blue sky, stucco-fronted houses, and a green field. The paper was unavoidably exposed for a longer period than was intended--about fifteen minutes,--a very beautiful picture was impressed, which, when held between the eye and the light, exhibited a curious order of colors. The sky was of a crimson hue, the houses of a slaty blue, and the green fields of a brick red tint. Surely these results appear to encourage the hope, that we may eventually arrive at a process by which external nature may be made to impress its images on prepared surfaces, in all the beauty of their native coloration."

PHOTOGRAPHIC DEVIATIONS.

Before taking leave of the subject of photogenic drawing, I must mention one or two facts, which may be of essential service to operators.

It has been observed by Daguerre, and others, in Europe, and probably by some of our own artists, that the sun two hours after it has passed the meridian, is much less effective in the photographic process, than it is two hours previous to its having reached that point. This may depend upon an absorptive power of the air, which may reasonably be supposed to be more charged with vapor two hours before noon. The fuse of the hygrometer may possibly establish the truth or falsity of this supposition. The fact, however, of a better result being produced before noon being established, persons wishing their portraits taken, will see the advantage of obtaining an early sitting, if they wish good pictures. On the other hand, if the supposition above mentioned prove true, a too early sitting must be avoided.

If we take a considerable thickness of a dense purple fluid, as, for instance, a solution of the ammonia-sulphate of copper, we shall find that the quantity of light is considerably diminished, at least four-fifths of the luminous rays being absorbed, while the chemical rays permeate it with the greatest facility, and sensitive preparations are affected by its influence, notwithstanding the deficiency of light, nearly as powerfully as if exposed to the undecomposed sunbeams.

It was first imagined that under the brilliant sun and clear skies of the south, photographic pictures would be produced with much greater quickness than they could be in the atmosphere of Paris. It is found, however, that a much longer time is required. Even in the clear and beautiful light of the higher Alps, it has been proved that the production of the photographic picture requires many minutes more, even with the most sensitive preparations, than it does in London. It has also been found that under the brilliant light of Mexico, twenty minutes, and half an hour, are required to produce effects which in England would occupy but a minute; and travellers engaged in copying the antiquities of Yucatan have on several occasions abandoned the use of the photographic camera, and taken to their sketch books. Dr. Draper* has observed a similar difference between the chemical action of light in New York and Virginia. This can be only explained by the supposition that the intensity of the light and heat of these climes interferes with the action of the ENERGIC rays on those sensitive preparations which are employed.

* I would here take occasion to remark that our country man, Dr. Draper, is very frequently quoted by Mr. Hunt in his "Researches."

LUNAR PICTURES--DRUMMOND LIGHT.

The Roman Astronomers state that they have procured Daguerreotype impressions of the Nebula of the sword of Orion. Signor Rondini has a secret method of receiving photographic images on lithographic stone; on such a prepared stone they have succeeded in impressing an image of the Nebula and its stars; "and from that stone they have been enabled to take impressions on paper, unlimited in number, of singular beauty, and of perfect precision." Experiments have, however, proved that "no heating power exists in the moon's rays, and that lunar light will not act chemically upon the iduret of silver."

It was at one time supposed that terrestrial or artificial light possessed no chemical rays, but this is incorrect--Mr. Brande discovered that although the concentrated light of the moon, or the light even of olefiant gas, however intense, had no effect on chloride of silver, or on a mixture of chloride and hydrogen, yet the light emitted by electerized charcoal blackens the salt. At the Royal Polytechnic Institution pictures have been taken by means of sensitive paper acted upon by the Drummond Light; but it must of course be distinctly understood, that they are inferior to those taken by the light of the sun, or diffused daylight.

If our operators could manage to produce good pictures in this way they would put money in their pockets, as many who cannot find time during the day would resort to their rooms at night. I throw out the hint in hopes some one will make the experiment.

I have learned, since the above was written, that an operator in Boston succeeded a short time since in procuring very good pictures by the aid of the Drummond Light; but that the intensity of the light falling directly upon the sitter's face caused great difficulty, and he abandoned it. This may, probably, be remedied by interposing a screen of very thin tissue paper tinged slightly of a bluish color.

CHAP. XII.

ON COLORING DAGUERREOTYPES.

Nearly, if not quite all the various colors used in painting may be made from the five primitive colors, black, white, blue, red and yellow, but for the Daguerrean artist it would be the best policy to obtain such as are required by their art already prepared. In a majority of cases, the following will be found sufficient, viz.

Carmine. Prussian Blue. White. Chrome Yellow, Gamboge, Yellow Ochre; or all three.* *Gamboge is best for drapery; Ochre for the face. Light Red. Indigo. Burnt Sienna. Bistre, or Burnt Umber.

If, in coloring any part of a lady's or gentleman's apparel, it is found necessary to produce other tints and shades, the following combinations may be used:

Orange--Mix yellow with red, making it darker or lighter by using more or less red.

Purple--This is made with Prussian blue, or indigo and red. Carmine and Prussian blue producing the richest color, which may be deepened in the shadows by a slight addition of indigo or brown.

Greens--Prussian blue and gamboge makes a very fine green, which may be varied to suit the taste of the sitter or operator, by larger portions of either, or by adding white, burnt sienna, indigo, and red, as the case may require. These combinations, under different modifications, give almost endless varieties of green.

Brown--May be made of different shades of umber, carmine and lamp-black.

Neutral tint--Is composed of indigo and lamp-black.

Crimson--Mix carmine and white, deepening the shaded parts of the picture with additional carmine.

Flesh Color--The best representative of flesh color is light red, brightened in the more glowing or warmer parts, with carmine, softened off in the lighter portions with white, and shaded with purple and burnt sienna.

Lead Color--Mix indigo and white in proportions to suit.

Scarlet--Carmine and light red.

For Jewelry cups of gold and silver preparations accompany each box for Daguerreotypists, or may be procured separately.

The method of laying colors on Daguerreotypes is one of considerable difficulty, inasmuch as they are used in the form of perfectly dry impalpable powder. The author of this little work is now experimenting, in order, if possible, to discover some more easy, artistic and unexceptionable method. If successful, the result will be published in a future edition.

The rules we shall give for coloring Daguerreotypes depends, and are founded, upon those observed in miniature painting, and are intended more as hints to Daguerrean artists, in hopes of leading them to attempt improvements, than as instructions wholly to be observed.

The writer is confident that some compound or ingredient may yet be discovered which, when mixed with the colors, will give a more delicate, pleasing, and natural appearance to the picture than is derived from the present mode of laying them on, which in his estimation is more like plastering than coloring.

IN COLORING DAGUERREOTYPES, the principal shades of the head are to be made with bistre, mixed with burnt sienna, touching some places with a mixture of carmine and indigo. The flesh tints are produced by the use of light red, deepened towards the shaded parts with yellow ochre, blue and carmine mixed with indigo, while the warmer, or more highly colored parts have a slight excess of carmine or lake. Color the shades about the mouth and neck with yellow ochre, blue, and a very little carmine, heightening the color of the lips with carmine and light red, letting the light red predominate on the upper, and the carmine on the lower lip; the shades in the corner of the mouth being touched slightly with burnt sienna, mixed with carmine.

In coloring the eyes, the artist will of course be guided by nature, observing a very delicate touch in laying on the colors, so as to preserve as much transparency as possible. A slight touch of blue--ultramarine would be best if it would adhere to the Daguerreotype plate--in the whites of the eye near the iris, will produce a good effect.

In coloring the heads of men it will be necessary to use the darker tints with more freedom, according to the complexion of the sitter. For women, the warmer tints should predominate, and in order to give that transparency so universal with the softer sex--and which gives so much loveliness and beauty to the face--a little white may be judiciously intermingled with the red tints about the lighter portions of the face.

In taking a picture of a lady with light or auburn hair, by the Daguerrean process, much of the beauty of the face is destroyed, on account of the imperfect manner in which light conveys the image of light objects to the spectrum of the camera. This may be obviated in some measure by proper coloring. To do this, touch the shaded parts with burnt sienna and bistre, filling up the lighter portions with yellow ochre, delicate touches of burnt sienna, and in those parts which naturally have a bluish tint, add very delicate touches of purple--so delicate in fact as hardly to be perceived. The roots of the hair at the forehead should also be touched with blue, and the eyebrows near the temples made of a pinkish tint.

The chin of a woman is nearly of the same color as the cheeks in the most glowing parts. In men it is stronger, and of a bluish tint, in order to produce the effect given by the beard.

In portraits of women--the middle tints on the side of the light, which are perceived on the bosom and arms, are made of a slight mixture of ochre, blue and lake, (or carmine), to which add, on the shaded sides, ochre, bistre and purple, the latter in the darker parts. The tints of the hands should be the same as the other parts of the flesh, the ends of the fingers being a little pinkish and the nails of a violet hue. If any portion of the fleshy parts is shaded by portions of the dress, or by the position of the hand, this shade should be colored with umber mixed with purple.

TO COLOR THE DRAPERY.--Violet Velvet--Use purple made of Prussian blue and carmine, touching up the shaded parts with indigo blue.

Green Velvet--Mix Prussian blue and red-orpiment, shade with purple, and touch up the lights with a little white.

Red Velvet--Mix a very little brown with carmine, shading with purple, marking the lights in the strongest parts with pure carmine, and touch the most brilliant slightly with white.

White Feathers--May be improved by delicately touching the shaded parts with a little blue mixed with white. White muslin, linen, lace, satin, silk, etc., may also be colored in the same way, being careful not to lay the color on too heavily.

FURS--Red Furs may be imitated by using light red and a little masticot, shaded with umber. Gray Furs--black and white mixed and shaded with bistre. Sable--white shaded lightly with yellow ochre.

These few directions are quite sufficient for the art, and it is quite unnecessary for me to pursue the subject further. I would, however, remark that the Daguerreotypists would find it greatly to their advantage to visit the studies of our best artists, our public galleries of paintings, and statuary, and wherever else they can obtain a sight of fine paintings, and study the various styles of coloring, attitudes, folds of drapery and other points of the art. In coloring Daguerreotypes, artists will find the magnifying glass of much advantage in detecting any imperfections in the plate or in the image, which may be remedied by the brush. In selecting brushes choose those most susceptible of a fine point, which may be ascertained by wetting them between the lips, or in a glass of water.

CHAP. XIII.

THE PHOTOGRAPHOMETER.

The last number (for March, 1849) of the London Art-Journal, gives the following description of a recent improvement in Photographic Manipulation, and as I am desirous of furnishing everything new in the art, I stop the press to add it, entire, to my work.

"Since the photographic power of the solar rays bears no direct relation to their luminous influence, it becomes a question of considerable importance to those who practice the beautiful art of photography, to have the means of readily measuring the ever changing activity of this force. Several plans more or less successful, have been devised by Sir John Herschel, Messrs. Jordan, Shaw and Hunt. The instrument, however, which is now brought forward by Mr. Claudet, who is well known as one of our most successful Daguerreotypists, appears admirably suited to all those purposes which the practical man requires. The great difficulty which continually annoys the photographic amateur and artist, is the determination of the sensibility of each tablet employed, relatively to the amount of radiation, luminous and chemical, with which he is working. With the photographometer of Mr. Claudet this is easily ascertained. The following woodcuts and concise description will sufficiently indicate this useful and simple apparatus.

"For an instrument of this kind it is important in the first place to have a motion always uniform, without complicated or expensive mechanism. This is obtained by means founded upon the principle of the fall of bodies sliding down an inclined plane. The sensitive surface is exposed to the light by the rapid and uniform passage of a metal plate, A, B, (Fig. 31,) having openings of different length, which follow a geometric progression. It is evident that the exposure to light will be the same for each experiment, because the plate furnished with the proportional openings falls always with the same rapidity, the height of the fall being constant, and the angle of the inclined plane the same. Each opening of this moveable plate allows the light to pass during the same space of time, and the effect upon the sensitive surface indicates exactly the intensity of the chemical rays. The rapidity of the fall may be augmented or diminished by altering the inclination of the plane by means of a graduated arc, C, D, (Fig. 30,) furnished with a screw, E, by which it may be fixed at any angle. The same result may be obtained by modifying the height of the fall or the weight of the moveable plate. The photogenic surface, whether it be the Daguerreotype plate, the Talbotype paper, or any other preparation sensitive to light, is placed near the bottom of the inclined plane, F. It is covered by a thin plate of metal, pierced with circular holes, which correspond to the openings of the moveable plate at the moment of the passage of the latter, during which the sensitive surface receives the light wherever the circular holes leave it exposed.

"The part of the apparatus which contains the sensitive surface is an independent frame, and it slides from a dark box into an opening on the side of the inclined plane.

"A covering of black cloth impermeable to light is, attached to the sides of the moveable plate, enveloping the whole inclined plane, rolling freely over two rollers, R, R, placed the one at the upper and the other at the lower part of the inclined plane. This cloth prevents the light striking the sensitive surface before and after the passage of the moveable plate.

"It will be seen that this apparatus enables the experimentalist to ascertain with great precision the exact length of time which is required to produce a given amount of actinic change upon any sensitive photographic surface, whether on metal or paper. Although at present some calculation is necessary to determine the difference between the time which is necessary for exposure in direct radiation, and to the action of the secondary radiations of the camera obscura; this is, however, a very simple matter, and it appears to us exceedingly easy to adapt an instrument of this description to the camera itself.

"By this instrument Mr. Claudet has already determined many very important points. Among others, he has proved that on the most sensitive Daguerreotype plate an exposure of .0001 part of a second is sufficient to produce a decided effect.

"Regarding photography as an auxiliary aid to the artist of no mean value, we are pleased to record a description of an instrument which, without being complicated, promises to be exceedingly useful. In this opinion we are not singular; at a recent meeting of the Photographic Club, to which this instrument was exhibited, it was with much real satisfaction that we learned that several of our most eminent artists were now eager and most successful students in Photography. The beautiful productions of the more prominent members of this club excited the admiration of all, particularly the copies of architectural beauties, and small bits of landscape, by Messrs. Cundell and Owen. We think that now the artist sees the advantage he may derive from the aid of science, that both will gain by the union."

I hope the above description will induce our townsman, Mr. Roach, to successfully produce an instrument that will meet the wants of our artists in that part of the Daguerrean process referred to.

FINIS.

INDEX.

Accelerating Liquids. 65 Amphitype. 116 Anthotype. 113 Apparatus. Daguerreotype. 43 Calotype 97 Photogenic 87 Application of Photogenic Drawing. 95 Applying the Sensitive. 64

Bringing out the Picture. 71 Bromine Box. 51 Chloride of 68 Roach's Tripple Compound of 67 water. 65 Bromide of Iodine. 67 of Lime. 68 Paper. 91 of silver. 35 Brushes. 88 Buff Sticks. 60

Calotype process. 97 paper. Exposure in Camera of 100 Pictures. Bringing out ib. Fixing 101 Camera. Description of the 43 Stand. 49 Woodbridge's ib. Calotype. 50 Voigtlander 45 Chloride of Bromine. 68 of Gold. 36 to make a solution of 75 of Iodine. 66 of Silver. 31 Chromatype. 112 Chrysotype. 106 Cleaning and Polishing the plate. 61 Coating Boxes. 51 Color Boxes. 53 Colored Daguerreotypes on Copper. 77 Coloring the Picture. 76 Daguerreotypes. 129 Concave Mirrors. 19 Convex Mirrors 19 Corchorus Japonica. 37 Crayon Daguerreotypes. 120 Cyanotype 109