Chapter 3

thing there is sometimes, along with very large amounts of thorium, an almost entire absence of lead in thorianites and thorites. And in some urano--thorites the lead may be noticed to follow the uranium in approximate proportionality, notwithstanding the presence of large amounts of thorium.[1] This is in favour of the assumption that all the lead present is derived from the uranium. The actinium is present in negligibly small amounts.

On the other hand, there is evidence arising from the atomic weight of lead which seems to involve some other parent than uranium. Soddy, in the work referred to, points this out. The atomic weight of radium is well known, and uranium in its descent has to change to this element. The loss of mass between radium and uranium-derived lead can be accurately estimated by the number of alpha rays given off. From this we get the atomic weight of uranium-derived lead as closely 206. Now the best determinations of the atomic weight of normal lead assign to this element an atomic weight of closely

[1] It seems very difficult at present to suggest an end product for thorium, unless we assume that, by loss of electrons, thorium E, or thorium-lead, reverts to a substance chemically identical with thorium itself. Such a change--whether considered from the point of view of the periodic law or of the radioactive theory would involve many interesting consequences. It is, of course, quite possible that the nature of the conditions attending the deposition of the uranium ores, many of which are comparatively recent, are responsible for the difficulties observed. The thorium and uranium ores are, again, specially prone to alteration.

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207. By a somewhat similar calculation it is deduced that thorium-derived lead would possess the atomic weight of 208. Thus normal lead might be an admixture of uranium- and thorium-derived lead. However, as we have seen, the view that thorium gives rise to stable lead is beset with some difficulties.

If we are going upon reliable facts and figures, we must, then, assume: (a) That some other element than uranium, and genetically connected with it (probably as parent substance), gives rise, or formerly gave rise, to lead of heavier atomic weight than normal lead. It may be observed respecting this theory that there is some support for the view that a parent substance both to uranium and thorium has existed or possibly exists. The evidence is found in the proportionality frequently observed between the amounts of thorium and uranium in the primary rocks.[1] Or: (b) We may meet the difficulties in a simpler way, which may be stated as follows: If we assume that all stable lead is derived from uranium, and at the same time recognise that lead is not perfectly homogeneous in atomic weight, we must, of necessity, ascribe to uranium a similar want of homogeneity; heavy atoms of uranium giving rise to heavy

[1] Compare results for the thorium content of such rocks (appearing in a paper by the author Cong. Int. _de Radiologie et d'Electricité_, vol. i., 1910, p. 373), and those for the radium content, as collected in _Phil. Mag._, October, 1912, p. 697. Also A. L. Fletcher, _Phil. Mag._, July, 1910; January, 1911, and June, 1911. J. H. J. Poole, _Phil. Mag._, April, 1915

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atoms of lead and light atoms of uranium generating light atoms of lead. This assumption seems to be involved in the figures upon, which we are going. Still relying on these figures, we find, however, that existing uranium cannot give rise to lead of normal atomic weight. We can only conclude that the heavier atoms of uranium have decayed more rapidly than the lighter ones. In this connection it is of interest to note the complexity of uranium as recently established by Geiger, although in this case it is assumed that the shorter-lived isotope bears the relation of offspring to the longer-lived and largely preponderating constituent. However, there does not seem to be any direct proof of this as yet.

From these considerations it would seem that unless the atomic weight of lead in uraninites, etc., is 206, the former complexity and more accelerated decay of uranium are indicated in the data respecting the atomic weights of radium and lead[1]. As an alternative view, we may assume, as in our first hypothesis, that some elementally different but genetically connected substance, decaying along branching lines of descent at a rate sufficient to practically remove the whole of it during geological time, formerly existed. Whichever hypothesis we adopt

[1] Later investigation has shown that the atomic weight of lead in uranium-bearing ores is about 206.6 (see Richards and Lembert, _Journ. of Am. Claem. Soc._, July, 1914). This result gives support to the view expressed above.

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we are confronted by probabilities which invalidate time-measurements based on the lead and helium ratio in minerals. We have, in short, grave reason to question the measure of uniformitarianism postulated in finding the age by any of the known radioactive methods.

That we have much to learn respecting our assumptions, whether we pursue the geological or the radioactive methods of approaching the age of our era, is, indeed, probable. Whatever the issue it is certain that the reconciling facts will leave us with much more light than we at present possess either as respects the Earth's history or the history of the radioactive elements. With this necessary admission we leave our study of the Birth-Time of the World.

It has led us a long way from Lucretius. We do not ask if other Iliads have perished; or if poets before Homer have vainly sung, becoming a prey to all-consuming time. We move in a greater history, the landmarks of which are not the birth and death of kings and poets, but of species, genera, orders. And we set out these organic events not according to the passing generations of man, but over scores or hundreds of millions of years.

How much Lucretius has lost, and how much we have gained, is bound up with the question of the intrinsic value of knowledge and great ideas. Let us appraise knowledge as we would the Homeric poems, as some-

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thing which ennobles life and makes it happier. Well, then, we are, as I think, in possession today of some of those lost Iliads and Odysseys for which Lucretius looked in vain.[1]

[1] The duration in the past of Solar heat is necessarily bound up with the geological age. There is no known means (outside speculative science) of accounting for more than about 30 million years of the existing solar temperature in the past. In this direction the age seems certainly limited to 100 million years. See a review of the question by Dr. Lindemann in Nature, April 5th, 1915.

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DENUDATION

THE subject of denudation is at once one of the most interesting and one of the most complicated with which the geologist has to deal. While its great results are apparent even to the most casual observer, the factors which have led to these results are in many cases so indeterminate, and in some cases apparently so variable in influence, that thoughtful writers have even claimed precisely opposite effects as originating from, the same cause. Indeed, it is almost impossible to deal with the subject without entering upon controversial matters. In the following pages I shall endeavour to keep to broad issues which are, at the present day, either conceded by the greater number of authorities on the subject, or are, from their strictly quantitative character, not open to controversy.

It is evident, in the first place, that denudation--or the wearing away of the land surfaces of the earth--is mainly a result of the circulation of water from the ocean to the land, and back again to the ocean. An action entirely conditioned by solar heat, and without which it would completely cease and further change upon the land come to an end.

To what actions, then, is so great a potency of the

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circulating water to be traced? Broadly speaking, we may classify them as mechanical and chemical. The first involves the separation of rock masses into smaller fragments of all sizes, down to the finest dust. The second involves the actual solution in the water of the rock constituents, which may be regarded as the final act of disintegration. The rivers bear the burden both of the comminuted and the dissolved materials to the sea. The mud and sand carried by their currents, or gradually pushed along their beds, represent the former; the invisible dissolved matter, only to be demonstrated to the eye by evaporation of the water or by chemical precipitation, represents the latter.

The results of these actions, integrated over geological time, are enormous. The entire bulk of the sedimentary rocks, such as sandstones, slates, shales, conglomerates, limestones, etc., and the salt content of the ocean, are due to the combined activity of mechanical and solvent denudation. We shall, later on, make an estimate of the magnitude of the quantities actually involved.

In the Swiss valleys we see torrents of muddy water hurrying along, and if we follow them up, we trace them to glaciers high among the mountains. From beneath the foot of the glacier, we find, the torrent has birth. The first debris given to the river is derived from the wearing of the rocky bed along which the glacier moves. The river of ice bequeaths to the river of water--of which it is the parent--the spoils which it has won from the rocks

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The work of mechanical disintegration is, however, not restricted to the glacier's bed. It proceeds everywhere over the surface of the rocks. It is aided by the most diverse actions. For instance, the freezing and expansion of water in the chinks and cracks in those alpine heights where between sunrise and sunset the heat of summer reigns, and between sunset and sunrise the cold of winter. Again, under these conditions the mere change of surface temperature from night to day severely stresses the surface layers of the rocks, and, on the same principles as we explain the fracture of an unequally heated glass vessel, the rocks cleave off in slabs which slip down the steeps of the mountain and collect as screes in the valley. At lower levels the expansive force of vegetable growth is not unimportant, as all will admit who have seen the strong roots of the pines penetrating the crannies of the rocks. Nor does the river which flows in the bed of the valley act as a carrier only. Listening carefully we may detect beneath the roar of the alpine torrent the crunching and knocking of descending boulders. And in the potholes scooped by its whirling waters we recognise the abrasive action of the suspended sand upon the river bed.

A view from an Alpine summit reveals a scene of remarkable desolation (Pl. V, p. 40). Screes lie piled against the steep slopes. Cliffs stand shattered and ready to fall in ruins. And here the forces at work readily reveal themselves. An occasional wreath of white smoke among

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the far-off peaks, followed by a rumbling reverberation, marks the fall of an avalanche. Water everywhere trickles through the shaly _débris_ scattered around. In the full sunshine the rocks are almost too hot to bear touching. A few hours later the cold is deadly, and all becomes a frozen silence. In such scenes of desolation and destruction, detrital sediments are actively being generated. As we descend into the valley we hear the deep voice of the torrents which are continually hurrying the disintegrated rocks to the ocean.

A remarkable demonstration of the activity of mechanical denudation is shown by the phenomenon of "earth pillars." The photograph (Pl. IV.) of the earth pillars of the Val d'Hérens (Switzerland) shows the peculiar appearance these objects present. They arise under conditions where large stones or boulders are scattered in a deep deposit of clay, and where much of the denudation is due to water scour. The large boulders not only act as shelter against rain, but they bind and consolidate by their mere weight the clay upon which they rest. Hence the materials underlying the boulders become more resistant, and as the surrounding clays are gradually washed away and carried to the streams, these compacted parts persist, and, finally, stand like walls or pillars above the general level. After a time the great boulders fall off and the underlying clay becomes worn by the rainwash to fantastic spikes and ridges. In the Val d'Hérens the earth pillars are formed

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of the deep moraine stuff which thickly overlies the slopes of the valley. The wall of pillars runs across the axis of the valley, down the slope of the hill, and crosses the road, so that it has to be tunnelled to permit the passage of traffic. It is not improbable that some additional influence--possibly the presence of lime--has hardened the material forming the pillars, and tended to their preservation.

Denudation has, however, other methods of work than purely mechanical; methods more noiseless and gentle, but not less effective, as the victories of peace ate no less than those of war.

Over the immense tracts of the continents chemical work proceeds relentlessly. The rock in general, more especially the primary igneous rock, is not stable in presence of the atmosphere and of water. Some of the minerals, such as certain silicates and carbonates, dissolve relatively fast, others with extreme slowness. In the process of solution chemical actions are involved; oxidation in presence of the free oxygen of the atmosphere; attack by the feeble acid arising from the solution of carbon dioxide in water; or, again, by the activity of certain acids--humous acids--which originate in the decomposition of vegetable remains. These chemical agents may in some instances, _e.g._ in the case of carbonates such as limestone or dolomite--bring practically the whole rock into solution. In other instances--_e.g._ granites, basalts, etc.--they may remove some of the

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constituent minerals completely or partially, such as felspar, olivine, augite, and leave more resistant substances to be ultimately washed down as fine sand or mud into the river.

It is often difficult or impossible to appraise the relative efficiency of mechanical and chemical denudation in removing the materials from a certain area. There can be, indeed, little doubt that in mountainous regions the mechanical effects are largely predominant. The silts of glacial rivers are little different from freshly-powdered rock. The water which carries them but little different from the pure rain or snow which falls from the sky. There has not been time for the chemical or solvent actions to take place. Now while gravitational forces favour sudden shock and violent motions in the hills, the effect of these on solvent and chemical denudation is but small. Nor is good drainage favourable to chemical actions, for water is the primary factor in every case. Water takes up and removes soluble combinations of molecules, and penetrates beneath residual insoluble substances. It carries the oxygen and acids downwards through the soils, and finally conveys the results of its own work to the rivers and streams. The lower mean temperature of the mountains as well as the perfect drainage diminishes chemical activities.

Hence we conclude that the heights are not generally favourable to the purely solvent and chemical actions. It is on the lower-lying land that soils tend to accumulate,

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and in these the chief solvent and the chief chemical denudation of the Earth are effected.

The solvent and chemical effects which go on in the finely-divided materials of the soils may be observed in the laboratory. They proceed faster than would be anticipated. The observation is made by passing a measured quantity of water backwards and forwards for some months through a tube containing a few grammes of powdered rock. Finally the water is analysed, and in this manner the amount of dissolved matter it has taken up is estimated. The rock powder is examined under the microscope in order to determine the size of the grains, and so to calculate the total surface exposed to the action of the water. We must be careful in such experiments to permit free oxidation by the atmosphere. Results obtained in this way of course take no account of the chemical effects of organic acids such as exist in the soils. The quantities obtained in the laboratory will, therefore, be deficient as compared with the natural results.

In this manner it has been found that fresh basalt exposed to continually moving water will lose about 0.20 gramme per square metre of surface per year. The mineral orthoclase, which enters largely into the constitution of many granites, was found to lose under the same conditions 0.025 gramme. A glassy lava (obsidian) rich in silica and in the chemical constituents of an average granite, was more resistant still; losing but 0.013 gramme per square metre per year. Hornblende, a mineral

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abundant in many rocks, lost 0.075 gramme. The mean of the results showed that 0.08 gramme was washed in a year from each square metre. Such results give us some indication of the rate at which the work of solution goes on in the finely divided soils.[1]

It might be urged that, as the mechanical break up of rocks, and the production in this way of large surfaces, must be at the basis of solvent and chemical denudation, these latter activities should be predominant in the mountains. The answer to this is that the soils rarely owe their existence to mechanical actions. The alluvium of the valleys constitutes only narrow margins to the rivers; the finer _débris_ from the mountains is rapidly brought into the ocean. The soils which cover the greater part of continental areas have had a very different origin.

In any quarry where a section of the soil and of the underlying rock is visible, we may study the mode of formation of soils. Our observations are, we will suppose, pursued in a granite quarry. We first note that the material of the soil nearest the surface is intermixed with the roots of grasses, trees, or shrubs. Examining a handful of this soil, we see glistening flakes of mica which plainly are derived from the original granite. Washing off the finer particles, we find the largest remaining grains are composed of the all but indestructible quartz.

[1] Proc. Roy. Irish Acad., VIII., Ser. A, p. 21.

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This also is from the granite. Some few of the grains are of chalky-looking felspar; again a granitic mineral. What is the finer silt we have washed off? It, too, is composed of mineral particles to a great extent; rock dust stained with iron oxide and intermixed with organic remains, both animal and vegetable. But if we make a chemical analysis of the finer silt we find that the composition is by no means that of the granite beneath. The chemist is able to say, from a study of his results, that there has been, in the first place, a large loss of material attending the conversion of the granite to the soil. He finds a concentration of certain of the more resistant substances of the granite arising from the loss of the less resistant. Thus the percentage amount of alumina is increased. The percentage of iron is also increased. But silica and most other substances show a diminished percentage. Notably lime has nearly disappeared. Soda is much reduced; so is magnesia. Potash is not so completely abstracted. Finally, owing to hydration, there is much more combined water in the soil than in the rock. This is a typical result for rocks of this kind.

Deeper in the soil we often observe a change of texture. It has become finer, and at the same time the clay is paler in colour. This subsoil represents the finer particles carried by rain from above. The change of colour is due to the state of the iron which is less oxidised low down in the soil. Beneath the subsoil the soil grows

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again coarser. Finally, we recognise in it fragments of granite which ever grow larger as we descend, till the soil has become replaced by the loose and shattered rock. Beneath this the only sign of weathering apparent in the rock is the rusty hue imparted by the oxidised iron which the percolating rain has leached from iron-bearing minerals.

The soil we have examined has plainly been derived in situ from the underlying rock. It represents the more insoluble residue after water and acids have done their work. Each year there must be a very slow sinking of the surface, but the ablation is infinitesimal.

The depth of such a soil may be considerable. The total surface exposed by the countless grains of which it is composed is enormous. In a cubic foot of average soil the surface area of the grains may be 50,000 square feet or more. Hence a soil only two feet deep may expose 100,000 square feet for each square foot of surface area.

It is true that soils formed in this manner by atmospheric and organic actions take a very long time to grow. It must be remembered, however, that the process is throughout attended by the removal in solution: of chemically altered materials.

Considerations such as the foregoing must convince us that while the accumulation of the detrital sediments around the continents is largely the result of activities progressing on the steeper slopes of the land, that is,

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among the mountainous regions, the feeding of the salts to the ocean arises from the slower work of meteorological and organic agencies attacking the molecular constitution of the rocks; processes which best proceed where the drainage is sluggish and the quiescent conditions permit of the development of abundant organic growth and decay.

Statistics of the solvent denudation of the continents support this view. Within recent years a very large amount of work has been expended on the chemical investigation of river waters of America and of Europe. F. W. Clarke has, at the expense of much labour, collected and compared these results. They are expressed as so many tonnes removed in solution per square mile per annum. For North America the result shows 79 tonnes so removed; for Europe 100 tonnes. Now there is a notable difference between the mean elevations of these two continents. North America has a mean elevation of 700 metres over sea level, whereas the mean elevation of Europe is but 300 metres. We see in these figures that the more mountainous land supplies less dissolved matter to the ocean than the land of lower elevation, as our study has led us to expect.

We have now considered the source of the detrital sediments, as well as of the dissolved matter which has given to the ocean, in the course of geological time, its present gigantic load of salts. It is true there are further solvent and chemical effects exerted by the sea water

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upon the sediments discharged into it; but we are justified in concluding that, relatively to the similar actions taking place in the soils, the solvent and chemical work of the ocean is small. The fact is, the deposited detrital sediments around the continents occupy an area small when contrasted with the vast stretches of the land. The area of deposition is much less than that of denudation; probably hardly as much as one twentieth. And, again, the conditions of aeration and circulation which largely promote chemical and solvent denudation in the soils are relatively limited and ineffective in the detrital oceanic deposits.

The summation of the amounts of dissolved and detrital materials which denudation has brought into the ocean during the long denudative history of the Earth, as we might anticipate, reveals quantities of almost unrealisable greatness. The facts are among the most impressive which geological science has brought to light. Elsewhere in this volume they have been mentioned when discussing the age of the Earth. In the present connection, however, they are deserving of separate consideration.