i. LAVAS

The term Lava is a convenient and comprehensive designation for all those volcanic products which have flowed out in a molten condition. They differ from each other in composition and structure, but their variations are comprised within tolerably definite limits.

As regards their composition they are commonly classed in three divisions--1st, The Acid lavas, in which the proportion of silicic acid ranges from a little below 70 per cent upwards; 2nd, The Intermediate lavas, wherein the percentage of silica may vary from 55 to near 70; and 3rd, The Basic lavas, where the acid constituent ranges from 55 per cent downwards. Sometimes the most basic kinds are distinguished as a fourth group under the name of Ultrabasic, in which the percentage of silica may fall below 40.

The structures of lavas, however, furnish their most easily appreciated characteristics. Four of these structures deserve more particular attention: 1st, Cellular, vesicular or pumiceous structure; 2nd, The presence of glass, or some result of the devitrification of an original glass; 3rd, Flow-structure; and 4th, The arrangement of the rocks in sheets or beds, with columnar and other structures.

1. The CELLULAR, VESICULAR, SCORIACEOUS or PUMICEOUS STRUCTURE of volcanic rocks (Fig. 1) could only have arisen in molten masses from the expansion of imprisoned vapours or gases, and is thus of crucial importance in deciding the once liquid condition of the rocks which display it. The vesicles may be of microscopic minuteness, but are generally quite visible to the naked eye, and are often large and conspicuous. Sometimes these cavities have been subsequently filled up with calcite, quartz, agate, zeolites or other mineral deposition. As the kernels thus produced are frequently flattened or almond-shaped (_amygdales_), owing to elongation of the steam-holes by movement of the lava before its consolidation, the rocks containing them are said to be _amygdaloidal_.

This structure, though eminently characteristic of superficial lavas, is not always by itself sufficient to distinguish them from the intrusive rocks. Examples will be given in later chapters where dykes, sills and other masses of injected igneous material are conspicuously cellular in some parts. But, in such cases, the cavities are generally comparatively small, usually spherical or approximately so, tolerably uniform in size and distribution, and, especially when they occur in dykes, distributed more particularly along certain lines or bands, sometimes with considerable regularity (see Figs. 90, 91, and 236).

Among the superficial lavas, however, such regularity is rarely to be seen. Now and then, indeed, a lava, which is not on the whole cellular, may be found to have rows of vesicles arranged parallel to its under or upper surface, or it may have acquired a peculiar banded structure from the arrangement of its vesicles in parallel layers along the direction of flow. The last-named peculiarity is widely distributed among the Tertiary lavas of North-Western Europe, and gives to their weathered surfaces a deceptive resemblance to tuffs or other stratified rocks (see Figs. 260, 310 and 311). It will be more particularly referred to a few pages further on. In general, however, we may say that the steam-cavities of lavas are quite irregular in size, shape and distribution, sometimes increasing to such relative proportions as to occupy most of the bulk of the rock, and in other places disappearing, so as to leave the lava tolerably compact. When a lava presents an irregularly vesicular character, like that of the slags of an iron-furnace, it is said to be _slaggy_. When its upper surface is rugged and full of steam-vesicles of all sizes up to large cavernous spaces, it is said to be _scoriaceous_, and fragments of such a rock ejected from a volcanic vent are spoken of as _scoriæ_.

Attention to the flattening of the steam-vesicles in cellular lavas, which has just been alluded to as the result of the onward movement of the still molten mass, may show, by the trend and grouping of these elongated cavities, the probable direction of the flow of the lava before it came to rest. Sometimes the vesicles have been drawn out and flattened to such a degree that the rock has acquired in consequence a fissile structure. In other instances, the vesicles have been originally formed as long parallel and even branching tubes, like the burrows of Annelids or the borings of _Teredo_. Some remarkable examples of this exceptional structure have been obtained from the Tertiary plateau-basalts of the Western Isles, of which an example is represented in Fig. 2.

In many cases the vesicles extend through the whole thickness of a lava. Frequently they may be found most developed towards the top and bottom; the central portion of the sheet being compact, while the top and bottom are rugged, cavernous or scoriaceous.

Though originally the vesicles and cavernous spaces, blown open by the expansion of the vapours dissolved in molten lava, remained empty on the consolidation of the rock, they have generally been subsequently filled up by the deposit within them of mineral substances carried in aqueous solution. The minerals thus introduced are such as might have been derived from the removal of their constituent ingredients by the solvent action of water on the surrounding rock. And as amygdaloids are generally more decayed than the non-vesicular lavas, it has been generally believed that the abstraction of mineral material and its re-deposit within the steam-vesicles have been due to the influence of meteoric water, which at atmospheric temperatures and pressures has slowly percolated from the surface through the cellular lava, long after the latter had consolidated and cooled, and even after volcanic energy at the locality had entirely ceased.

Examples, however, are now accumulating which certainly prove that, in some cases, the vesicles were filled up during the volcanic period. Among the Tertiary basalt-plateaux of the Inner Hebrides, for instance, it can be shown that the lavas were already amygdaloidal before the protrusion of the gabbros and granophyres which mark later stages of the same continuous volcanic history, and even before the outpouring of much of the basalt of these plateaux. Not improbably the mineral secretions were largely due to the influence of hot volcanic vapours during the eruption of the basalts. This subject will be again referred to in the description of the Tertiary volcanic series.

Vesicular structure is more commonly and perfectly developed among the lavas which are basic and intermediate in composition than among those which are acid.

While the existence of a highly vesicular or scoriaceous structure may generally be taken as proof that the rock displaying it flowed out at the surface as a lava, other evidence pointing to the same conclusion may often be gathered from the rocks with which the supposed lava is associated. Where, for example, a scoriaceous lava is covered with stratified deposits which contain pieces of that lava, we may be confident that the rock is an interstratified or contemporaneous sheet. It has been erupted after the deposition of the strata on which it rests, and before that of the strata which cover it and contain pieces of it. In such a case, the geological date of the eruption could be precisely defined. Illustrations of this reasoning will be given in