Part 7

Calcite is transparent or translucent, and—depending on the variety—its luster is glassy to earthy. Most calcite is white or colorless, but it can be a shade of pink, blue, green, brown, yellow, or gray. It gives a white streak when you rub it across a streak plate.

Two properties of calcite to notice are the hardness and the cleavage. This mineral cleaves perfectly in three directions that are not at right angles to each other, and some of the cleavage fragments are rhombohedrons. Calcite is rather soft—you can scratch it with a copper penny but not with a fingernail. A drop or two of dilute hydrochloric acid also will help you to identify this mineral. The acid will readily fizz and bubble when it is placed on calcite.

Calcite occurs in more different kinds of crystal shapes than any other mineral. Some of these crystals are flat and tabular; some are rhombohedrons; some are prisms. Pointed crystals, called _dog-tooth spar_, and twinned crystals have been found in the Terlingua area of Brewster County in west Texas. A somewhat unusual occurrence of calcite crystals is in geodes. Some of these are found in Lower Cretaceous rocks west of Austin in Travis County.

Transparent crystals and cleavage fragments of calcite show a property called _double refraction_ (other minerals show it, too). To test this property, you can mark a single dot on paper. When you look at the dot through a piece of clear calcite, you will see two dots instead of one. This happens because a ray of light is bent (refracted) and is split into two rays as it enters the mineral. These two rays travel through the calcite in slightly different directions, and each carries an image of the dot through the mineral. The two images that you see are at the points where the two rays leave the calcite.

Calcite that is deposited at springs, along river and creek banks, and in caves is known as _travertine_. Cave forms of travertine, including stalagmites and stalactites, occur in several caves in Texas. Another kind of travertine is called _calcareous tufa_ or _calcareous sinter_. It is a porous and spongy-looking material deposited from water carrying dissolved limestone and is found around the openings of some springs and along some creek and river banks.

A dull, earthy calcite deposit, known as _caliche_, occurs in areas of Texas that have scant rainfall, such as the High Plains, west Texas, and the southwestern part of the Gulf Coastal Plain. Caliche commonly is found mixed with other materials, such as clay, sand, or gravel. This substance may be firm and compact or loose and powdery.

It is thought that caliche forms when ground moisture, containing dissolved calcium bicarbonate, moves upward. In dry areas of the country, this moisture evaporates. As it does, it leaves a crust of calcium carbonate in the form of caliche on or near the surface of the ground.

Caliche is quarried in many counties in Texas and is used chiefly as road material and as an aggregate.

Caliche. _See_ Calcite.

Carnotite. _See_ Uranium Minerals.

Cassiterite

Cassiterite, tin dioxide, is the mineral that serves as the chief source of tin. Tin does not corrode and tarnish, and one of its main uses is in the making of tin cans. (Actually, our tin cans are made from thin sheets of steel that have been coated with a protective layer of tin.)

Cassiterite has either a nonmetallic or a submetallic luster. Some specimens are brilliant and shiny; others are dull. Cassiterite may be translucent to transparent. It may be black, brown, gray, reddish brown, or yellowish brown. When rubbed across a streak plate, this mineral leaves a pale brown, a pale yellow, or a white streak. Cassiterite is quite heavy—it has a specific gravity of 6.8 to 7.1. It is too hard to be scratched by an average pocket knife.

Sometimes, prospectors use a chemical test to help them identify cassiterite. They put small pieces of metallic zinc into a jar or test tube containing dilute hydrochloric acid. Then they add a few fragments of the mineral that they suspect is cassiterite. If the fragments are cassiterite, they become covered with a pale gray coating of metallic tin.

Cassiterite’s most common crystal shape is a short, 8-sided prism with pyramids at each end, but perfect crystals are not often found. Most Texas cassiterite does not show a crystal shape. Instead, it occurs as crystalline masses in igneous rocks and as loose pebbles that have weathered out of these rocks.

Cassiterite occurs in a number of places in the United States but not in large quantities. A small amount of cassiterite has been found in quartz veins in Precambrian granite in both central Texas and west Texas. In El Paso County, the cassiterite is found on the east side of the Franklin Mountains a few miles north of El Paso, where some of it has been mined. In central Texas, cassiterite occurs in the Streeter area of Mason County.

When the granite rocks in these areas were formed, probably not all of the hot magmas cooled and hardened at the same time. The fluids given off by the remaining magmas contained tin and several other elements. It is believed that these fluids moved up into cracks in the granite rocks and formed the cassiterite.

Celestite

Celestite is a strontium sulfate mineral. It is colorless, white, yellow, or gray. Light blue specimens of this mineral also are found, and it is because of this sky-like color that celestite gets its name. The word celestite comes from the Latin word _caelestis_, meaning _of the sky_.

Celestite has a glassy to a pearly luster, and it is either transparent or translucent. It gives a white streak when rubbed across a streak plate. Celestite has a specific gravity of 3.95 to 3.97. It is, however, lighter than barite, a mineral that it resembles. Celestite is not very hard—a knife will scratch it, although your fingernail will not. It cleaves in three directions, and some of the fragments are flat and slabby.

Celestite occurs commonly either as prism-shaped or flat crystals and as cleavable, granular, or fibrous crystalline masses. In Texas, it is found in geodes, as rounded nodules, or as bedded or layer-like deposits in limestones and other sedimentary rocks. In Real County, celestite occurs on the walls of a cave in Cretaceous limestone.

Some celestite may be deposited by sea water, but much of the Texas celestite is believed to have been deposited by underground water that seeped through cracks and pores in the limestones and other sedimentary rocks. This water picked up and dissolved strontium compounds that were scattered in small amounts through the rocks. Then, it re-deposited the strontium in the rocks as celestite.

In Texas, beds of celestite occur in Permian rocks in Coke, Fisher, and Nolan counties and in Lower Cretaceous rocks in Brown, Comanche, and Mills counties. Celestite geodes and nodules are found in Lower Cretaceous limestone rocks in Lampasas, Travis, and Williamson counties, and in Permian rocks in Coke, Fisher, Nolan, and Taylor counties.

Celestite is one of two minerals (the other mineral is _strontianite_, strontium carbonate) used as a source of strontium. Strontium compounds give a crimson-red color to a flame, so they are used in fireworks, tracer bullets, and flares. Perhaps you have seen a red flare set out on the highway at night to warn motorists that a truck has stalled. The chances are good that the flare’s red flame was due to a strontium compound. Some of the Texas celestite has been mined, but most of the strontium minerals now used in the United States are imported from England and Mexico.

Cerargyrite. _See_ Silver Minerals.

Chalcedony. _See_ Quartz.

Chalcocite. _See_ Copper Minerals.

Chalcopyrite. _See_ Copper Minerals.

Chalk. _See_ Limestone.

Chert (Flint). _See_ Quartz.

Chrysotile. _See_ Asbestos; Serpentine.

Cinnabar

Cinnabar, which is mercuric sulfide, is the most common mercury mineral. It has a dark red or a bright yellowish-red color and is transparent to translucent. When rubbed across a streak plate, it leaves a dark red streak. If pure, cinnabar has a brilliant, shiny, nonmetallic luster. It is, however, commonly found mixed with impurities, such as clay, calcite, iron oxide, or bituminous material, and then it looks dull and earthy. Cinnabar is quite heavy—it has a specific gravity of 8.10. It is rather soft, and you can scratch it with a copper penny.

Some prospectors use a quick chemical test to identify cinnabar. They rub a clean, shiny copper coin with a mineral sample that has been moistened with a drop or two of dilute hydrochloric acid. If the sample is cinnabar, a light silvery-gray coating appears on the coin.

Cinnabar occurs as small crystals or as fine-grained or compact crystalline masses. It is found in veins that fill cracks in rocks and also occurs as crusts and coatings on rocks. It also may be widely scattered through rocks, such as limestones.

Cinnabar occurs in the Terlingua area of Brewster and Presidio counties in west Texas. It has been mined there, off and on, since about 1894, and during this time, mercury worth many millions of dollars has been produced.

Most of this west Texas cinnabar is found in cracks, pores, and breccia-filled cavities of Cretaceous limestones and clays. If you will look at the Texas geologic map (pp. 4-5), you will see that igneous rocks occur in this district. Many millions of years ago during the Tertiary Period, when these igneous rocks were still hot magma, some of them pushed up under the Cretaceous rocks and emitted fluids containing mercury. The fluids moved upward through cracks and pores in the Cretaceous rocks where they deposited the mercury as cinnabar and as other mercury minerals.

Mercury is an unusual element. Instead of occurring as a solid metal at ordinary room temperatures, as do gold, silver, and lead, it remains a liquid until it is cooled to 38 degrees below zero Fahrenheit. Because the silvery little drops of liquid mercury roll about as if they were alive, this element long has been called _quicksilver_.

Mercury is used in a variety of ways. In some noiseless light-switches, a glass tube containing a small ball of mercury tilts when the switch is turned “on.” The mercury then rolls to the end of the tube that contains electrical contacts and quietly completes the electrical circuit. In other uses, mercury is added to silver, tin, and other metals to make fillings for teeth. Some medicines, such as calomel and mercurochrome, contain mercury. Fulminate of mercury helps to set off dynamite and other explosives. Mercury is used in many barometers and thermometers, and farmers use mercury poisons to control insects and fungi.

Mercury also commonly is used to obtain gold from its ores. One method of accomplishing this is to pass wet gold-bearing gravel or crushed rock over metal plates that are coated with mercury. The gold particles quickly mix with the mercury to form an _amalgam_, which later can be scraped off the plates. The gold is then recovered by heating the amalgam to drive off the mercury.

Clay

Clay is a smooth, soft, earthy rock made up of mineral particles no bigger than specks of dust. Some of the particles are clay minerals, which consist of aluminum, silicon, and other elements. In addition, tiny particles of quartz, calcite, and other minerals may also be present in the clay.

The clay particles are all that remain of rocks and of minerals, such as feldspar, that have been broken into fragments or altered into clay minerals by weathering. Some clay remains at the place where it formed, but some is carried away and deposited elsewhere.

Clay is white, tan, brown, red, green, blue, gray—almost any color. When moist, it has an earthy odor. You can moisten a piece of clay enough to notice this just by breathing on it. Most clays, when wet, can be molded into many different shapes—that is, they are plastic, but when they are dry, they are firm and solid.

Clay is abundant in Texas and has a number of uses. Some goes to make portland cement, and some is baked or burned in a kiln to make brick, tile, sewer pipes, pottery, and other products. This kind of clay is obtained from Tertiary formations of the Gulf Coastal Plain, from Upper Cretaceous formations in central Texas, and from Pennsylvanian formations in north-central Texas. (You can locate Tertiary, Cretaceous, and Pennsylvanian rocks on the Texas geologic map, pp. 4-5.)

A special kind of white burning clay that can be used to make chinaware is called _kaolin_ or _china clay_. It contains particles of the clay mineral _kaolinite_ as well as several other clay minerals. Deposits of china clay occur in southern Jeff Davis County and in Real County near Leakey, but none is being produced.

Another kind of clay, _bentonite_, forms from weathered volcanic ash. Bentonite contains the clay mineral _montmorillonite_ and looks smooth and soap-like. Fresh samples of this clay are white, pale green, or pale blue, but dried-out or weathered samples are tan, brown, yellow, or reddish. When wet, bentonite absorbs water, swells, and then has a jelly-like appearance.

Surface deposits of bentonite occur chiefly in Eocene Tertiary formations of the Gulf Coastal Plain, in Cretaceous formations of the Big Bend area of west Texas, and in Quaternary formations of the High Plains.

Some bentonite is used to absorb unwanted coloring material in petroleum and in vegetable oils. It is then known as a _bleaching clay_. Bentonite bleaching clay is obtained from some of the Tertiary formations along the Texas Gulf Coastal Plain. It has been produced in Angelina, Fayette, Gonzales, Jasper, Walker, and other counties in this area.

Another important use of bentonite, and of other clay, too, is as _drilling mud_. In the rotary method of drilling for oil and gas, mud is pumped down into the drilled hole. This mud carries the rock cuttings up to the surface, it cools the drilling tools, and it coats and seals the walls of the hole. Along the Gulf Coastal Plain, drilling clay is obtained from Tertiary formations.

Common Opal. _See_ Opal.

Copper Minerals (Chalcocite, Chalcopyrite, Malachite, Azurite)

A number of minerals containing copper, such as _chalcocite_, _chalcopyrite_, _malachite_, and _azurite_, occur in small deposits in Texas. They are found chiefly in the Llano uplift area of central Texas, in the Van Horn area of Culberson and Hudspeth counties in west Texas, and in a group of counties in north-central Texas.

Copper is an important element. Because it is an unusually good conductor of electricity (only silver, which costs much more, is a better one), it is used for many kinds of wires for switchboards, generators, motors, telephone and telegraph equipment, and light and power lines.

Manufacturers commonly combine copper with other elements. For example, some copper is mixed with zinc to make _brass_ and with tin and a little zinc to make _bronze_. These mixtures are called _alloys_. Many products are made from copper alloys, including tubing, pipes, jewelry, pots, and pans. Even our coins contain copper.

Sometimes, a prospector uses a chemical test to find out if copper is present in a mineral. First, he crushes a small sample of what he believes is a copper mineral (such as chalcocite, chalcopyrite, azurite, or malachite). He then puts the sample in a glass jar or test tube and pours in a small amount of dilute nitric acid (this acid, like hydrochloric acid, is poisonous). After the sample has dissolved in the acid, he adds enough ammonium hydroxide to make the solution alkaline. If the sample is a copper mineral, the solution turns a deep-blue color.

One of the copper minerals, _chalcocite_, copper sulfide, also is known as _copper glance_. It is a metallic mineral that commonly tarnishes to a dull black. By chipping off a fragment to obtain a fresh surface, you will see that it has a shiny lead-gray color. Chalcocite is rather soft, and it is sectile, that is, a knife will cut through it as well as scratch it. When you rub chalcocite across a streak plate, it gives a grayish-black streak. This mineral commonly occurs as compact masses or as granular masses.

Chalcocite, with its dark color, does not look at all like copper, which is a bright reddish brown. Chalcocite, however, is the chief copper mineral at the most important copper mine in Texas, the Hazel mine, which is about 15 miles northwest of Van Horn in Culberson County in west Texas. This mine, although now idle and almost filled with water, has produced about one and a half million pounds of copper along with more valuable silver ores. Here, the chalcocite and other minerals occur in material that fills large cracks in red sandstone of the Precambrian Hazel Formation. It is thought that long ago, molten igneous rock material far below the surface sent out hot solutions containing copper and other elements. These solutions moved upward and deposited minerals in the fracture zone in the sandstone.

Chalcocite occurs also in north-central Texas. It is found in Archer, Baylor, Clay, Foard, Hardeman, King, Knox, Stonewall, and several other counties of this area. Here, it occurs in Permian sedimentary rocks (called “red beds”) as rounded masses, as scattered grains, and as petrified wood. Because these deposits are far from any igneous rocks, they apparently did not form in the same way as those at the Hazel mine. These north-central Texas deposits have never really been commercially developed. During the Civil War, however, some copper from this area was made into percussion caps for the Confederacy.

Another copper mineral, _chalcopyrite_, is a copper-iron sulfide. It also is known as _copper pyrites_ and _yellow copper ore_. This mineral has a metallic luster and a brass-yellow or a golden-yellow color. When rubbed across a streak plate, it gives a greenish-black streak. Chalcopyrite will tarnish and then has bronze, blue, purple, and other rainbow-like colors. This mineral is fairly soft—you can scratch it with a pocket knife. Because of chalcopyrite’s yellow color, it has often been mistaken for gold. For this reason, it, like iron pyrite, is often called _fool’s gold_. (See Gold, p. 60, for ways to tell them apart.)

Chalcopyrite commonly is found in compact masses that show no crystal shapes. These masses either are scattered through rocks or occur in material that fills cracks in rocks.

Some chalcopyrite is found in Precambrian sandstone at the Hazel mine and in other deposits in the Van Horn area of Culberson and Hudspeth counties. It also occurs in Precambrian rocks at the Sheridan and Pavitte prospects in Burnet County. These chalcopyrite localities are in districts where igneous rocks occur.

It is likely that, long ago, hot solutions containing copper moved upward, out of deeply buried molten magma. While still far below the surface, the solutions deposited the chalcopyrite in cracks and other openings in the nearby rocks.

Two copper minerals of Texas, _azurite_ and _malachite_, are copper carbonates. Azurite is commonly called _chessylite_ and _blue copper_; malachite is called _green copper carbonate_. Because these minerals are carbonates, a drop of dilute hydrochloric acid will fizz and bubble when placed on either of them.

Azurite has a bright, intense blue color and leaves a blue streak when rubbed across a streak plate. Malachite has a bright green color and leaves a green streak. These minerals have a nonmetallic luster and a glassy to dull appearance. Commonly, they are translucent, although some specimens of azurite are transparent. Both azurite and malachite are fairly soft—a pocket knife will scratch them, but a copper penny will not.

Azurite and malachite occur as individual crystals, but you are more likely to find them as crusts on rocks and on other minerals. Malachite is also found in rounded fibrous masses that resemble bunches of grapes (described then as _botryoidal_).

Both azurite and malachite are formed in the same way. Underground waters seep through rocks that contain deposits of copper minerals (such as chalcocite and chalcopyrite) and cause chemical reactions which change these minerals into malachite and azurite.

Malachite is more plentiful than azurite, but both minerals can be found together. You can expect to find at least one of them at the same localities where chalcocite, chalcopyrite, and other copper minerals occur.

Coquina. _See_ Limestone.

Diatomite. _See_ Opal.

Dolomite

Dolomite is the name given both to a rock and to a mineral. The mineral is a calcium-magnesium carbonate and has a glassy or a pearly luster. It is any of a number of colors, such as white, pink, brown, or gray, or it can be colorless. Dolomite leaves a white streak on a streak plate and is transparent to translucent. It is not particularly hard and can be scratched with a pocket knife, although not with a copper penny. Dolomite cleaves perfectly in three directions, and some of the cleavage fragments are rhombohedrons. However, the cleavages of the individual mineral grains in specimens of fine-grained massive dolomite are not readily distinguishable.

Most Texas dolomite occurs as coarse-, medium-, and fine-grained crystalline masses as the chief mineral in dolomite rock and in dolomitic marble. It is also found as 6-sided crystals that are rhomb-shaped; when the faces are curved, they have a saddle-like appearance.

Crystals of the mineral dolomite commonly occur in cavities in the dolomite rocks. It is believed that they were deposited there by seeping underground waters. The waters dissolved some of the dolomite in the rocks and then re-deposited it as crystals.

Dolomite rock is made up mostly of crystalline grains of the mineral dolomite. In addition, quartz grains, calcite, and other minerals may be present. Dolomite rock is almost any color—white, buff, pink brown, gray. It resembles some limestone, and these two rocks actually are closely related.

To help tell them apart, dilute hydrochloric acid often is used. A few drops of this acid will readily fizz and bubble if the rock you put them on is a limestone. If the rock is dolomite, the acid will effervesce only very little or not at all. (If, however, the acid is put on powdered dolomite, it then will fizz readily.) Dolomite is slightly harder than limestone, and it also is slightly heavier.

Some dolomite rocks formed directly from materials that were dissolved in sea water, and others are altered limestone rocks. Some limestones altered into dolomite on the sea floor by the addition of magnesium from the sea water. Others changed into dolomite much later after the sea had withdrawn and the limestones had become a part of the land; underground waters containing magnesium seeped through these limestones and altered them into dolomite.

Many of the dolomite rocks are found with limestones. In Texas they occur mostly in Cambrian, Ordovician, Mississippian, Pennsylvanian, Permian, and Cretaceous formations. The geologic map (pp. 4-5) indicates where these strata appear at the surface in Texas.