Soap-Bubbles and the Forces Which Mould Them

Part 6

Chapter 64,363 wordsPublic domain

This is easily made by taking a light glass globe about two inches in diameter, such, for instance, as a silvered ball used to ornament a Christmas-tree or the bulb of a pipette, which is what I used. Pass through the open necks of the bulb a piece of wire about one-twentieth of an inch in diameter, and fix it permanently and water-tight upon the wire by working into the necks melted sealing-wax. An inch or two above the globe, fasten a flat frame of thin wire by soldering, or if this is too difficult, by tying and sealing-wax. A lump of lead must then be fastened or hung on to the lower end, and gradually scraped away until the wire frame will just be unable to force its way through the surface of the water. None of the dimensions or materials mentioned are of importance.

_Paraffined Sieve._

Obtain a piece of copper wire gauze with about twenty wires to the inch, and cut out from it a round piece about eight inches in diameter. Lay it on a round block, of such a size that it projects about one inch all round. Then gently go round and round with the hands pressing the edge down and keeping it flat above, until the sides are evenly turned down all round. This is quite easy, because the wires can allow of the kind of distortion necessary. Then wind round the turned-up edge a few turns of thick wire to make the sides stiff. This ought to be soldered in position, but probably careful wiring will be good enough.

Melt some paraffin wax or one or two paraffin candles of the best quality in a clean flat dish, not over the fire, which would be dangerous, but on a hot plate. When melted and clear like water, dip the sieve in, and when all is hot quickly take it out and knock it once or twice on the table to shake the paraffin out of the holes. Leave upside down until cold, and then be careful not to scratch or rub off the paraffin. This had best be done in a place where a mess is of no consequence.

There is no difficulty in filling it or in setting it to float upon water.

_Narrow Tubes and Capillarity._

Get some quill-glass tube from a chemist, that is, tube about the size of a pen. If it is more than, say, a foot long, cut off a piece by first making a firm scratch in one place with a three-cornered file, when it will break at the place easily. To make very narrow tube from this, hold it near the ends in the two hands very lightly, so that the middle part is high up in the brightest part of an ordinary bright and flat gas flame. Keep it turning until at last it becomes so soft that it is difficult to hold it straight. It can then be bent into any shape, but if it is wanted to be drawn out it must be held still longer until the black smoke upon it begins to crack and peel up. Then quickly take it out of the flame, and pull the two ends apart, when a long narrow tube will be formed between. This can be made finer or coarser by regulating the heat and the manner in which it is pulled out. No directions will tell any one so much as a very little practice. For drawing out tubes the flame of a Bunsen burner or of a blow-pipe is more convenient; but for bending tubes nothing is so good as the flat gas flame. Do not clean off smoke till the tubes are cold, and do not hurry their cooling by wetting or blowing upon them. In the country where gas is not to be had, the flame of a large spirit-lamp can be made to do, but it is not so good as a gas-flame. The narrower these tubes are, the higher will clean water be observed to rise in them. To colour the water, paints from a colour-box must not be used. They are not liquid, and will clog the very fine tubes. Some dye that will quite dissolve (as sugar does) must be used. An aniline dye, called soluble blue, does very well. A little vinegar added may make the colour last better.

_Capillarity between Plates._

Two plates of flat glass, say three to five inches square, are required. Provided they are quite clean and well wetted there is no difficulty. A little soap and hot water will probably be sufficient to clean them.

_Tears of Wine._

These are best seen at dessert in a glass about half filled with port. A mixture of from two to three parts of water, and one part of spirits of wine containing a very little rosaniline (a red aniline dye), to give it a nice colour, may be used, if port is not available. A piece of the dye about as large as a mustard-seed will be enough for a large wine-glass. The sides of the glass should be wetted with the wine.

_Cat-Boxes._

Every school-boy knows how to make these. They are not the boxes made by cutting slits in paper. They are simply made by folding, and are then blown out like the "frog," which is also made of folded paper.

_Liquid Beads._

Instead of melting gold, water rolled on to a table thickly dusted with lycopodium, or other fine dust, or quicksilver rolled or thrown upon a smooth table, will show the difference in the shape of large and small beads perfectly. A magnifying-glass will make the difference more evident. In using quicksilver, be careful that none of it falls on gold or silver coins, or jewellery, or plate, or on the ornamental gilding on book-covers. It will do serious damage.

_Plateau's Experiment._

To perform this with very great perfection requires much care and trouble. It is easy to succeed up to a certain point. Pour into a clean bottle about a table-spoonful of salad-oil, and pour upon it a mixture of nine parts by volume spirits of wine (not methylated spirits), and seven parts of water. Shake up and leave for a day if necessary, when it will be found that the oil has settled together by itself. Fill a tumbler with the same mixture of spirit and water, and then with a fine glass pipe, dipping about half-way down, slowly introduce a very little water. This will make the liquid below a little heavier. Dip into the oil a pipe and take out a little by closing the upper end with the finger, and carefully drop this into the tumbler. If it goes to the bottom, a little more water is required in the lower half of the tumbler. If by chance it will not sink at all, a little more spirit is wanted in the upper half. At last the oil will just float in the middle of the mixture. More can then be added, taking care to prevent it from touching the sides. If the liquid below is ever so little heavier, and the liquid above ever so little lighter than oil, the drop of oil perhaps as large as a halfpenny will be almost perfectly round. It will not appear round if seen through the glass, because the glass magnifies it sideways, but not up and down, as may be seen by holding a coin in the liquid just above it. To see the drop in its true shape the vessel must either be a globe, or one side must be made of flat glass.

Spinning the oil so as to throw off a ring is not material, but if the reader can contrive to fix a disc about the size of a threepenny-piece upon a straight wire, and spin it round without shaking it, then he will see the ring break off, and either return if the rotation is quickly stopped, or else break up into three or four perfect little balls. The disc should be wetted with oil before being dipped into the mixture of spirit and water.

_A Good Mixture for Soap-Bubbles._

Common yellow soap is far better than most of the fancy soaps, which generally contain a little soap and a lot of rubbish. Castille soap is very good, and this may be obtained from any chemist.

Bubbles blown with soap and water alone do not last long enough for many of the experiments described, though they may sometimes be made to succeed. Plateau added glycerine, which greatly improves the lasting quality. The glycerine should be pure; common glycerine is not good, but Price's answers perfectly. The water should be pure distilled water, but if this is not available, clean rain-water will do. Do not choose the first that runs from a roof after a spell of dry weather, but wait till it has rained for some time, the water that then runs off is very good, especially if the roof is blue slate or glass. If fresh rain-water is not to be had, the softest water should be employed that can be obtained. Instead of Castille soap, Plateau found that a pure soap prepared from olive-oil is still better. This is called oleate of soda. It should be obtained freshly prepared from a manufacturing chemist. Old, dry stuff that has been kept a long time is not so good. I have always used a modification of Plateau's formula, which Professors Reinold and Rucker found to answer so well. They used less glycerine than Plateau. It is best made as follows. Fill a clean stoppered bottle three-quarters full of water. Add one-fortieth part of its weight of oleate of soda, which will probably float on the water. Leave it for a day, when the oleate of soda will be dissolved. Nearly fill up the bottle with Price's glycerine and shake well, or pour it into another clean bottle and back again several times. Leave the bottle, stoppered of course, for about a week in a dark place. Then with a syphon, that is, a bent glass tube which will reach to the bottom inside and still further outside, draw off the clear liquid from the scum which will have collected at the top. Add one or two drops of strong liquid ammonia to every pint of the liquid. Then carefully keep it in a stoppered bottle in a dark place. Do not get out this stock bottle every time a bubble is to be blown, but have a small working bottle. Never put any back into the stock. In making the liquid _do not warm or filter it_. Either will spoil it. Never leave the stoppers out of the bottles or allow the liquid to be exposed to the air more than is necessary. This liquid is still perfectly good after two years' keeping. I have given these directions very fully, not because I feel sure that all the details are essential, but because it exactly describes the way I happen to make it, and because I have never found any other solution so good. Castille soap, Price's glycerine, and rain-water will almost certainly answer every purpose, and the same proportions will probably be found to work well.

_Rings for Bubbles._

These may be made of any kind of wire. I have used tinned iron about one-twentieth of an inch in diameter. The joint should be smoothly soldered without lumps. If soldering is a difficulty, then use the thinnest wire that is stiff enough to support the bubbles steadily, and make the joint by twisting the end of the wire round two or three times. Rings two inches in diameter are convenient. I have seen that dipping the rings in melted paraffin is recommended, but I have not found any advantage from this. The nicest material for the light rings is thin aluminium wire, about as thick as a fine pin (No. 26 to 30, B. W. G.), and as this cannot be soldered, the ends must be twisted. If this is not to be had, very fine wire, nearly as fine as a hair (No. 36, B. W. G.), of copper or of any other metal, will answer. The rings should be wetted with the soap mixture before a bubble is placed upon them, and must always be well washed and dried when done with.

_Threads in Ring._

There is no difficulty in showing these experiments. The ring with the thread may be dipped in the soap solution, or stroked across with the edge of a piece of paper or india-rubber sheet that has been dipped in the liquid, so as to form a film on both sides of the thread. A needle that has also been wetted with the soap may be used to show that the threads are loose. The same needle held for a moment in a candle-flame supplies a convenient means of breaking the film.

_Blow out Candle with Soap-Bubble._

For this, the bubble should be blown on the end of a short wide pipe, spread out at one end to give a better hold for the bubble. The tin funnel supplied with an ordinary gazogene answers perfectly. This should be washed before it is used again for filling the gazogene.

_Bubbles balanced against one another._

These experiments are most conveniently made on a small scale. Pieces of thin brass tube, three-eighths or half an inch in diameter, are suitable. It is best to have pieces of apparatus, specially prepared with taps, for easily and quickly stopping the air from leaving either bubble, and for putting the two bubbles into communication when required. It should not be difficult to contrive to perform the experiments, using india-rubber connecting tubes, pinched with spring clips to take the place of taps. There is one little detail which just makes the difference between success and failure. This is to supply a mouth-piece for blowing the bubble, made of glass tube, which has been drawn out so fine that these little bubbles cannot be blown out suddenly by accident. It is very difficult, otherwise, to adjust the quantity of air in such small bubbles with any accuracy. In balancing a spherical against a cylindrical bubble, the short piece of tube, into which the air is supplied, must be made so that it can be easily moved to or from a fixed piece of the same size closed at the other end. Then the two ends of the short tube must have a film spread over them with a piece of paper, or india-rubber, but there must be _no_ film stretched across the end of the fixed tube. The two tubes must at first be near together, until the spherical bubble has been formed. They may then be separated gradually more and more, and air blown in so as to keep the sides of the cylinder straight, until the cylinder is sufficiently long to be nearly unstable. It will then far more evidently show, by its change of form, than it would if it were short, when the pressure due to the spherical bubble exactly balances that due to a cylindrical one. If the shadow of the bubbles, or an image formed by a lens on a screen, is then measured, it will be found that the sphere has a diameter which is very accurately double that of the cylinder.

_Thaumatrope for showing the Formation and Oscillations of Drops._

The experiment showing the formation of water-drops can be very perfectly imitated, and the movements actually made visible, without any necessity for using liquids at all, by simply converting Fig. 35 (at end of book) into the old-fashioned instrument called a thaumatrope. What will then be seen is a true representation, because the forms in the figure are copies of a series of photographs taken from the moving drops at the rate of forty-three photographs in two seconds.[2]

[Footnote 2: For particulars see _Philosophical Magazine_, September 1890.]

Obtain a piece of good card-board as large as the figure, and having brushed it all over on one side with thin paste, lay the figure upon it, and press it down evenly. Place it upon a table, and cover it with a few thicknesses of blotting-paper, and lay over all a flat piece of board large enough to cover it. Weights sufficient to keep it all flat may be added. This must be left all night at least, until the card is quite dry, or else it will curl up and be useless. Now with a sharp chisel or knife, but a chisel if possible, cut out the forty-three slits near the edge, accurately following the outline indicated in black and white, and keeping the slits as narrow as possible. Then cut a hole in the middle, so as to fit the projecting part of a sewing-machine cotton-reel, and fasten the cotton-reel on the side away from the figure with glue or small nails. It must be fixed exactly in the middle. The edge should of course be cut down to the outside of the black rim.

Now having found a pencil or other rod on which the cotton-reel will freely turn, use this as an axle, and holding the disc up in front of a looking-glass, and in a good light, slowly and steadily make it turn round. The image of the disc seen through the slit in the looking-glass will then perfectly represent every feature of the growing and falling drop. As the drop grows it will gradually become too heavy to be supported, a waist will then begin to form which will rapidly get narrower, until the drop at last breaks away. It will be seen to continue its fall until it has disappeared in the liquid below, but it has not mixed with this, and so it will presently appear again, having bounced out of the liquid. As it falls it will be seen to vibrate as the result of the sudden release from the one-sided pull. The neck which was drawn out will meanwhile have gathered itself in the form of a little drop, which will then be violently hit by the oscillations of the remaining pendant drop above, and driven down. The pendant drop will be seen to vibrate and grow at the same time, until it again breaks away as before, and so the phenomena are repeated.

In order to perfectly reproduce the experiment, the axle should be firmly held upon a stand, and the speed should not exceed one turn in two seconds.

The effect is still more real if a screen is placed between the disc and the mirror, which will only allow one of the drops to be seen.

_Water-drops in Paraffin and Bisulphide of Carbon._

All that was said in describing the Plateau experiment applies here. Perfectly spherical and large drops of water can be formed in a mixture so made that the lower parts are very little heavier, and the upper parts very little lighter, than water. The addition of bisulphide of carbon makes the mixture heavier. This liquid--bisulphide of carbon--is very dangerous, and has a most dreadful smell, so that it had better not be brought into the house. The form of a hanging drop, and the way in which it breaks off, can be seen if water is used in paraffin alone, but it is much more evident if a little bisulphide of carbon is mixed with the paraffin, so that water will sink slowly in the mixture. Pieces of glass tube, open at both ends from half an inch to one inch in diameter, show the action best. Having poured some water coloured blue into a glass vessel, and covered it to a depth of several inches with paraffin, or the paraffin mixture, dip the pipe down into the water, having first closed the upper end with the thumb or the palm of the hand. On then removing the hand, the water will rush up inside the tube. Again close the upper end as before, and raise the tube until the lower end is well above the water, though still immersed in the paraffin. Then allow air to enter the pipe very slowly by just rolling the thumb the least bit to one side. The water will escape slowly and form a large growing drop, the size of which, before it breaks away, will depend on the density of the mixture and the size of the tube.

To form a water cylinder in the paraffin the tube must be filled with water as before, but the upper end must now be left open. Then when all is quiet the tube is to be rather rapidly withdrawn in the direction of its own length, when the water which was within it will be left behind in form of a cylinder, surrounded by the paraffin. It will then break up into spheres so slowly, in the case of a large tube, that the operation can be watched. The depth of paraffin should be quite ten times the diameter of the tube.

To make bubbles of water in the paraffin, the tube must be dipped down into the water with the upper end open all the time, so that the tube is mostly filled with paraffin. It must then be closed for a moment above and raised till the end is completely out of the water. Then if air is allowed to enter slowly, and the tube is gently raised, bubbles of water filled with paraffin will be formed which can be made to separate from the pipe, like soap-bubbles from a "churchwarden," by a suitable sudden movement. If a number of water-drops are floating in the paraffin in the pipe, and this can be easily arranged, then the bubbles made will contain possibly a number of other drops, or even other bubbles. A very little bisulphide of carbon poured carefully down a pipe will form a heavy layer above the water, on which these compound bubbles will remain floating.

Cylindrical bubbles of water in paraffin may be made by dipping the pipe down into the water and withdrawing it quickly without ever closing the top at all. These break up into spherical bubbles in the same way that the cylinder of liquid broke up into spheres of liquid.

_Beaded Spider-webs._

These are found in the spiral part of the webs of all the geometrical spiders. The beautiful geometrical webs may be found out of doors in abundance in the autumn, or in green-houses at almost any time of the year. To mount these webs so that the beads may be seen, take a small flat ring of any material, or a piece of card-board with a hole cut out with a gun-wad cutter, or otherwise. Smear the face of the ring, or the card, with a very little strong gum. Choose a freshly-made web, and then pass the ring, or the card, across the web so that some of the spiral web (not the central part of the web) remains stretched across the hole. This must be done without touching or damaging the pieces that are stretched across, except at their ends. The beads are too small to be seen with the naked eye. A strong magnifying-glass, or a low power microscope, will show the beads and their marvellous regularity. The beads on the webs of very young spiders are not so regular as those on spiders that are fully grown. Those beautiful beads, easily visible to the naked eye, on spider lines in the early morning of an autumn day, are not made by the spider, but are simply dew. They very perfectly show the spherical form of small water-drops.

_Photographs of Water-jets._

These are easily taken by the method described by Mr. Chichester Bell. The flash of light is produced by a short spark from a few Leyden-jars. The fountain, or jet, should be five or six feet away from the spark, and the photographic plate should be held as close to the stream of water as is possible without touching. The shadow is then so definite that the photograph, when taken, may be examined with a powerful lens, and will still appear sharp. Any rapid dry plate will do. The room, of course, must be quite dark when the plate is placed in position, and the spark then made. The regular breaking up of the jet may be effected by sound produced in almost any way. The straight jet, of which Fig. 41 is a representation, magnified about three and a quarter times, was regularly broken up by simply whistling to it with a key. The fountains were broken up regularly by fastening the nozzle to one end of a long piece of wood clamped at the end to the stand of a tuning-fork, which was kept sounding by electrical means. An ordinary tuning-fork, made to rest when sounding against the wooden support of the nozzle, will answer quite as well, but is not quite so convenient. The jet will break up best to certain notes, but it may be tuned to a great extent by altering the size of the orifice or the pressure of the water, or both.

_Fountain and Sealing-wax._

It is almost impossible to fail over this very striking yet simple experiment. A fountain of almost any size, at any rate between one-fiftieth and a quarter of an inch in the smooth part, and up to eight feet high, will cease to scatter when the sealing-wax is rubbed with flannel and held a few feet away. A suitable size of fountain is one about four feet high, coming from an orifice anywhere near one-sixteenth of an inch in diameter. The nozzle should be inclined so that the water falls slightly on one side. The sealing-wax may be electrified by being rubbed on the coat-sleeve, or on a piece of fur or flannel which is _dry_. It will then make little pieces of paper or cork dance, but it will still act on the fountain when it has ceased to produce any visible effect on pieces of paper, or even on a delicate gold-leaf electroscope.

_Bouncing Water-jets._