Soap-Bubbles and the Forces Which Mould Them

Part 4

Chapter 44,214 wordsPublic domain

The water is only a very little heavier than the mixture. If I now dip a pipe into the water and let it fill, I can then raise it and allow drops to slowly form. Drops as large as a shilling are now forming, and when each one has reached its full size, a neck forms above it, which is drawn out by the falling drop into a little cylinder. You will notice that the liquid of the neck has gathered itself into a little drop which falls away just after the large drop. The action is now going on so slowly that you can follow it. Fig. 35 contains forty-three consecutive views of the growth and fall of the drop taken photographically at intervals of one-twentieth of a second. For the use to which this figure is to be put, see page 149. If I again fill the pipe with water, and this time draw it rapidly out of the liquid, I shall leave behind a cylinder which will break up into balls, as you can easily see (Fig. 36). I should like now to show you, as I have this apparatus in its place, that you can blow bubbles of water containing paraffin in the paraffin mixture, and you will see some which have other bubbles and drops of one or other liquid inside again. One of these compound bubble drops is now resting stationary on a heavier layer of liquid, so that you can see it all the better (Fig. 37). If I rapidly draw the pipe out of the box I shall leave a long cylindrical bubble of water containing paraffin, and this, as was the case with the water-cylinder, slowly breaks up into spherical bubbles.

Having now shown that a very large liquid cylinder breaks up regularly into drops, I shall next go the other extreme, and take as an example an excessively fine cylinder. You see a photograph of a spider on her geometrical web (Fig. 38). If I had time I should like to tell you how the spider goes to work to make this beautiful structure, and a great deal about these wonderful creatures, but I must do no more than show you that there are two kinds of web--those that point outwards, which are hard and smooth, and those that go round and round, which are very elastic, and which are covered with beads of a sticky liquid. Now there are in a good web over a quarter of a million of these beads which catch the flies for the spider's dinner. A spider makes a whole web in an hour, and generally has to make a new one every day. She would not be able to go round and stick all these in place, even if she knew how, because she would not have time. Instead of this she makes use of the way that a liquid cylinder breaks up into beads as follows. She spins a thread, and at the same time wets it with a sticky liquid, which of course is at first a cylinder. This cannot remain a cylinder, but breaks up into beads, as the photograph taken with a microscope from a real web beautifully shows (Fig. 39). You see the alternate large and small drops, and sometimes you even see extra small drops between these again. In order that you may see exactly how large these beads really are, I have placed alongside a scale of thousandths of an inch, which was photographed at the same time. To prove to you that this is what happens, I shall now show you a web that I have made myself by stroking a quartz fibre with a straw dipped in castor-oil. The same alternate large and small beads are again visible just as perfect as they were in the spider's web. In fact it is impossible to distinguish between one of my beaded webs and a spider's by looking at them. And there is this additional similarity--my webs are just as good as a spider's for catching flies. You might say that a large cylinder of water in oil, or a microscopic cylinder on a thread, is not the same as an ordinary jet of water, and that you would like to see if it behaves as I have described. The next photograph (Fig. 40), taken by the light of an instantaneous electric spark, and magnified three and a quarter times, shows a fine column of water falling from a jet. You will now see that it is at first a cylinder, that as it goes down necks and bulges begin to form, and at last beads separate, and you can see the little drops as well. The beads also vibrate, becoming alternately long and wide, and there can be no doubt that the sparkling portion of a jet, though it appears continuous, is really made up of beads which pass so rapidly before the eye that it is impossible to follow them. (I should explain that for a reason which will appear later, I made a loud note by whistling into a key at the time that this photograph was taken.)

Lord Rayleigh has shown that in a stream of water one twenty-fifth of an inch in diameter, necks impressed upon the stream, even though imperceptible, develop a thousandfold in depth every fortieth of a second, and thus it is not difficult to understand that in such a stream the water is already broken through before it has fallen many inches. He has also shown that free water drops vibrate at a rate which may be found as follows. A drop two inches in diameter makes one complete vibration in one second. If the diameter is reduced to one quarter of its amount, the time of vibration will be reduced to one-eighth, or if the diameter is reduced to one-hundredth, the time will be reduced to one-thousandth, and so on. The same relation between the diameter and the time of breaking up applies also to cylinders. We can at once see how fast a bead of water the size of one of those in the spider's web would vibrate if pulled out of shape, and let go suddenly. If we take the diameter as being one eight-hundredth of an inch, and it is really even finer, then the bead would have a diameter of one sixteen-hundredth of a two-inch bead, which makes one vibration in one second. It will therefore vibrate sixty-four thousand times as fast, or sixty-four thousand times a second. Water-drops the size of the little beads, with a diameter of rather less than one three-thousandth of an inch, would vibrate half a million times a second, under the sole influence of the feebly elastic skin of water! We thus see how powerful is the influence of the feebly elastic water-skin on drops of water that are sufficiently small.

I shall now cause a small fountain to play, and shall allow the water as it falls to patter upon a sheet of paper. You can see both the fountain itself and its shadow upon the screen. You will notice that the water comes out of the nozzle as a smooth cylinder, that it presently begins to glitter, and that the separate drops scatter over a great space (Fig. 41). Now why should the drops scatter? All the water comes out of the jet at the same rate and starts in the same direction, and yet after a short way the separate drops by no means follow the same paths. Now instead of explaining this, and then showing experiments to test the truth of the explanation, I shall reverse the usual order, and show one or two experiments first, which I think you will all agree are so like magic, so wonderful are they and yet so simple, that if they had been performed a few hundred years ago, the rash person who showed them might have run a serious risk of being burnt alive.

You now see the water of the jet scattering in all directions, and you hear it making a pattering sound on the paper on which it falls. I take out of my pocket a stick of sealing-wax and instantly all is changed, even though I am some way off and can touch nothing. The water ceases to scatter; it travels in one continuous line (Fig. 42), and falls upon the paper making a loud rattling noise which must remind you of the rain of a thunder-storm. I come a little nearer to the fountain and the water scatters again, but this time in quite a different way. The falling drops are much larger than they were before. Directly I hide the sealing-wax the jet of water recovers its old appearance, and as soon as the sealing-wax is taken out it travels in a single line again.

Now instead of the sealing-wax I shall take a smoky flame easily made by dipping some cotton-wool on the end of a stick into benzine, and lighting it. As long as the flame is held away from the fountain it produces no effect, but the instant that I bring it near so that the water passes through the flame, the fountain ceases to scatter; it all runs in one line and falls in a dirty black stream upon the paper. Ever so little oil fed into the jet from a tube as fine as a hair does exactly the same thing.

I shall now set a tuning-fork sounding at the other side of the table. The fountain has not altered in appearance. I now touch the stand of the tuning-fork with a long stick which rests against the nozzle. Again the water gathers itself together even more perfectly than before, and the paper upon which it falls is humming out a note which is the same as that produced by the tuning-fork. If I alter the rate at which the water flows you will see that the appearance is changed again, but it is never like a jet which is not acted upon by a musical sound. Sometimes the fountain breaks up into two or three and sometimes many more distinct lines, as though it came out of as many tubes of different sizes and pointing in slightly different directions (Fig. 43). The effect of different notes could be very easily shown if any one were to sing to the piece of wood by which the jet is held. I can make noises of different pitches, which for this purpose are perhaps better than musical notes, and you can see that with every new noise the fountain puts on a different appearance. You may well wonder how these trifling influences--sealing-wax, the smoky flame, or the more or less musical noise--should produce this mysterious result, but the explanation is not so difficult as you might expect.

I hope to make this clear when we meet again.

LECTURE III.

At the conclusion of the last lecture I showed you some curious experiments with a fountain of water, which I have now to explain. Consider what I have said about a liquid cylinder. If it is a little more than three times as long as it is wide, it cannot retain its form; if it is made very much more than three times as long, it will break up into a series of beads. Now, if in any way a series of necks could be developed upon a cylinder which were less than three diameters apart, some of them would tend to heal up, because a piece of a cylinder less than three diameters long is stable. If they were about three diameters apart, the form being then unstable, the necks would get more pronounced in time, and would at last break through, so that beads would be formed. If necks were made at distances more than three diameters apart, then the cylinder would go on breaking up by the narrowing of these necks, and it would most easily break up into drops when the necks were just four and a half diameters apart. In other words, if a fountain were to issue from a nozzle held perfectly still, the water would most easily break into beads at the distance of four and a half diameters apart, but it would break up into a greater number closer together, or a smaller number further apart, if by slight disturbances of the jet very slight waists were impressed upon the issuing cylinder of water. When you make a fountain play from a jet which you hold as still as possible, there are still accidental tremors of all kinds, which impress upon the issuing cylinder slightly narrow and wide places at irregular distances, and so the cylinder breaks up irregularly into drops of different sizes and at different distances apart. Now these drops, as they are in the act of separating from one another, and are drawing out the waist, as you have seen, are being pulled for the moment towards one another by the elasticity of the skin of the waist; and, as they are free in the air to move as they will, this will cause the hinder one to hurry on, and the more forward one to lag behind, so that unless they are all exactly alike both in size and distance apart they will many of them bounce together before long. You would expect when they hit one another afterwards that they would join, but I shall be able to show you in a moment that they do not; they act like two india-rubber balls, and bounce away again. Now it is not difficult to see that if you have a series of drops of different sizes and at irregular distances bouncing against one another frequently, they will tend to separate and to fall, as we have seen, on all parts of the paper down below. What did the sealing-wax or the smoky flame do? and what can the musical sound do to stop this from happening? Let me first take the sealing-wax. A piece of sealing-wax rubbed on your coat is electrified, and will attract light bits of paper up to it. The sealing-wax acts electrically on the different water-drops, causing them to attract one another, feebly, it is true, but with sufficient power where they meet to make them break through the air-film between them and join. To show that this is no fancy, I have now in front of the lantern two fountains of clean water coming from separate bottles, and you can see that they bounce apart perfectly (Fig. 44). To show that they do really bounce, I have coloured the water in the two bottles differently. The sealing-wax is now in my pocket; I shall retire to the other side of the room, and the instant it appears the jets of water coalesce (Fig. 45). This may be repeated as often as you like, and it never fails. These two bouncing jets are in fact one of the most delicate tests for the presence of electricity that exist. You are now able to understand the first experiment. The separate drops which bounced away from one another, and scattered in all directions, are unable to bounce when the sealing-wax is held up, because of its electrical action. They therefore unite, and the result is, that instead of a great number of little drops falling all over the paper, the stream pours in a single line, and great drops, such as you see in a thunder-storm, fall on the top of one another. There can be no doubt that it is for this reason that the drops of rain in a thunder-storm are so large. This experiment and its explanation are due to Lord Rayleigh.

The smoky flame, as lately shown by Mr. Bidwell, does the same thing. The reason probably is that the dirt breaks through the air-film, just as dust in the air will make the two fountains join as they did when they were electrified. However, it is possible that oily matter condensed on the water may have something to do with the effect observed, because oil alone acts quite as well as a flame, but the action of oil in this case, as when it smooths a stormy sea, is not by any means so easily understood.

When I held the sealing-wax closer, the drops coalesced in the same way; but they were then so much more electrified that they repelled one another as similarly electrified bodies are known to do, and so the electrical scattering was produced.

You possibly already see why the tuning-fork made the drops follow in one line, but I shall explain. A musical note is, as is well known, caused by a rapid vibration; the more rapid the vibration the higher is the pitch of the note. For instance, I have a tooth-wheel which I can turn round very rapidly if I wish. Now that it is turning slowly you can hear the separate teeth knocking against a card that I am holding in the other hand. I am now turning faster, and the card is giving out a note of a low pitch. As I make the wheel turn faster and faster, the pitch of the note gradually rises, and it would, if I could only turn fast enough, give so high a note that we should not be able to hear it. A tuning-fork vibrates at a certain definite rate, and therefore gives a definite note. The fork now sounding vibrates 128 times in every second. The nozzle, therefore, is made to vibrate, but almost imperceptibly, 128 times a second, and to impress upon the issuing cylinder of water 128 imperceptible waists every second. Now it just depends what size the jet is, and how fast the water is issuing, whether these waists are about four and a half diameters apart in the cylinder. If the jet is larger, the water must pass more quickly, or under a greater pressure, for this to be the case; if the jet is finer, a smaller speed will be sufficient. If it should happen that the waists so made are anywhere about four diameters apart, then even though they are so slightly developed that if you had an exact drawing of them, you would not be able to detect the slightest change of diameter, they will grow at a great speed, and therefore the water column will break up regularly, every drop will be like the one behind it, and like the one in front of it, and not all different, as is the case when the breaking of the water merely depends upon accidental tremors. If the drops then are all alike in every respect, of course they all follow the same path, and so appear to fall in a continuous stream. If the waists are about four and a half diameters apart, then the jet will break up most easily; but it will, as I have said, break up under the influence of a considerable range of notes, which cause the waists to be formed at other distances, provided they are more than three diameters apart. If two notes are sounded at the same time, then very often each will produce its own effect, and the result is the alternate formation of drops of different sizes, which then make the jet divide into two separate streams. In this way, three, four, or even many more distinct streams may be produced.

I can now show you photographs of some of these musical fountains, taken by the instantaneous flash of an electric spark, and you can see the separate paths described by the drops of different sizes (Fig. 46). In one photograph there are eight distinct fountains all breaking from the same jet, but following quite distinct paths, each of which is clearly marked out by a perfectly regular series of drops. You can also in these photographs see drops actually in the act of bouncing against one another, and flattened when they meet, as if they were india-rubber balls. In the photograph now upon the screen the effect of this rebound, which occurs at the place marked with a cross, is to hurry on the upper and more forward drop, and to retard the other one, and so to make them travel with slightly different velocities and directions. It is for this reason that they afterwards follow distinct paths. The smaller drops had no doubt been acted on in a similar way, but the part of the fountain where this happened was just outside the photographic plate, and so there is no record of what occurred. The very little drops of which I have so often spoken are generally thrown out from the side of a fountain of water under the influence of a musical sound, after which they describe regular little curves of their own, quite distinct from the main stream. They, of course, can only get out sideways after one or two bouncings from the regular drops in front and behind. You can easily show that they are really formed below the place where they first appear, by taking a piece of electrified sealing-wax and holding it near the stream close to the nozzle and gradually raising it. When it comes opposite to the place where the little drops are really formed, it will act on them more powerfully than on the large drops, and immediately pull them out from a place where the moment before none seemed to exist. They will then circulate in perfect little orbits round the sealing-wax, just as the planets do round the sun; but in this case, being met by the resistance of the air, the orbits are spirals, and the little drops after many revolutions ultimately fall upon the wax, just as the planets would fall into the sun after many revolutions, if their motion through space were interfered with by friction of any kind.

There is only one thing needed to make the demonstration of the behaviour of a musical jet complete, and that is, that you should yourselves see these drops in their different positions in an actual fountain of water. Now if I were to produce a powerful electric spark, then it is true that some of you might for an instant catch sight of the drops, but I do not think that most would see anything at all. But if, instead of making merely one flash, I were to make another when each drop had just travelled to the position which the one in front of it occupied before, and then another when each drop had moved on one place again, and so on, then all the drops, at the moments that the flashes of light fell upon them, would occupy the same positions, and thus all these drops would appear fixed in the air, though of course they really are travelling fast enough. If, however, I do not quite succeed in keeping exact time with my flashes of light, then a curious appearance will be produced. Suppose, for instance, that the flashes of light follow one another rather too quickly, then each drop will not have had quite time enough to get to its proper place at each flash, and thus at the second flash all the drops will be seen in positions which are just behind those which they occupied at the first flash, and in the same way at the third flash they will be seen still further behind their former places, and so on, and therefore they will appear to be moving slowly backwards; whereas if my flashes do not follow quite quickly enough, then the drops will, every time that there is a flash, have travelled just a little too far, and so they will all appear to be moving slowly forwards. Now let us try the experiment. There is the electric lantern sending a powerful beam of light on to the screen. This I bring to a focus with a lens, and then let it pass through a small hole in a piece of card. The light then spreads out and falls upon the screen. The fountain of water is between the card and the screen, and so a shadow is cast which is conspicuous enough. Now I place just behind the card a little electric motor, which will make a disc of card which has six holes near the edge spin round very fast. The holes come one after the other opposite the hole in the fixed card, and so at every turn six flashes of light are produced. When the card is turning about 21-1/2 times a second, then the flashes will follow one another at the right rate. I have now started the motor, and after a moment or two I shall have obtained the right speed, and this I know by blowing through the holes, when a musical note will be produced, higher than the fork if the speed is too high, and lower than the fork if the speed is too low, and exactly the same as the fork if it is right.