Scientific American Supplement No. 819, September 12, 1891
Chapter 7
The Tynwald is 265 feet long, 34 feet 6 inches beam, and 14 feet 6 inches depth moulded, the gross tonnage being 946 tons. The desire of the owners to put the vessel alternately on two distinct services required special arrangement of the saloons. Running between Liverpool and the island there was no necessity for sleeping accommodation, as the passage is made in about three hours; and the ship had to be suited to carry immense crowds. But as the owners wished on special occasions to run the vessel from Glasgow to Manxland it was necessary to so arrange the saloons as to admit of sleeping accommodation being provided on these occasions. On the Liverpool run the vessel will carry from 800 to 900 passengers. A spacious promenade is an indispensable desideratum, and the upper or shelter deck has been made flush from stem to stern, the only obstructions in addition to the engine and boiler casings, and the deck and cargo working machinery, being a small deck house aft with special state rooms, ticket and post offices, and the companion way to the saloons below. On the main deck forward is a sheltered promenade for second class passengers, while on the lower deck below are dining saloons, the sofas of which may be improvised for sleeping accommodation. At the extreme after end of the main deck is the first class saloon, with the ladies' room forward on the starboard side, and, there being no alley way forward, the ladies' lavatories are provided on the starboard side of the engine casing. On the port side are the gentlemen's lavatories, and smoking saloon and bar. The dining saloon is aft on the lower deck, with ladies' room forward. In the two saloons and ladies' rooms sofa berths can be arranged to accommodate 252 passengers. The crew and petty officers are accommodated in the forward part of the ship. As the profile shows, the vessel is divided by transverse bulkheads into seven watertight compartments, and there are double bottoms. She has six large boats and several rafts.
The twin screws are revolved by separate triple expansion engines, steam being supplied by two double-ended boilers. Each boiler is placed fore and aft, and each has a separate uptake and funnel. There are three stokeholds, and to ventilate them and supply sufficient air for the furnaces there is in each a 6 foot fan driven by an independent engine running at 250 revolutions. These have been supplied by Messrs. W.H. Allen & Co., London. The boilers are of steel and adapted for a working pressure of 160 lb. to the square inch. They are 16 feet in diameter and 18 feet long, and there are eight furnaces in each boiler, sixteen in all, the diameter of each furnace being 3 feet 4½ inches.
The cylinders of the main engines are 22 in., 36 in., and 57 in. in diameter respectively, with a piston stroke of 3 ft. The high-pressure cylinders are each fitted with a piston valve, and the intermediate and low-pressure cylinders with double-ported slide valves, all of which are worked by the usual double eccentric and link motion valve gear, by which the cut-off can be varied as required. All the shafting is forged of Siemens-Martin mild steel of the best quality, each of the three separate cranks being built up. The condensers are placed at the outsides of the engine room, and the air, feed, and bilge pumps are between the engines and the condensers and worked by levers from the low-pressure engine crosshead. There are two centrifugal pumps, each worked by a separate engine for circulating water through the condenser, and these are so arranged that they can be connected to the bilges in the event of an accident to the ship. In the engine room there is fitted an auxiliary feed donkey of the duplex type and made by the Fairfield Company.
This pump has all the usual connections, so that it can be used for feeding the boilers from the hot well, for filling the fresh water tanks, for pumping from the bilges, or from the sea as a fire engine. The engines are arranged in the ship with the starting platform between them; and the handles for working the throttle valves, starting valves, reversing gear (Brown's combined steam and hydraulic), and drain cocks are brought together at one end of the platform, so that the engineer in charge can readily control both engines. The two sets of engines are bound together by two beams bolted to the framing of each engine. This feature was introduced into the design for steadiness.
The method of supporting the propeller shaft brackets is interesting, and we reproduce a photograph that indicates the arrangement adopted. Instead of the A frame forming part of the same forging as the stern frame, the Fairfield Company have built up the supporting arms of steel plates riveted together, as is clearly shown. There is an advantage in cost and with less risk in undiscovered flaws in material.
An interesting change has been made in the steam pipes. Cases of copper steam pipes bursting when subjected to high pressure have not been infrequent, and Mr. A. Laing, the engineering director on the Fairfield Board, with characteristic desire to advance engineering practice, has been devoting much attention to this question lately. He has made very exhaustive tests with lap welded iron steam pipes of all diameters, but principally of 10 in. diameter and 3/8 in. thickness of material, made by Messrs. A. & J. Stuart & Clydesdale, Limited, and the results have been such as to induce him to introduce these into vessels recently built by the company. It may be stated that the pipes only burst at a hydraulic pressure of 3,000 lb. to the square inches.
The Tynwald was tried on the Clyde about a month ago, and on two runs on the mile, the one with and the other against the tide, the mean speed was 19.38 knots--the maximum was 19½ knots--and the indicated horse power developed was 5,200, the steam pressure being 160 lb., and the vacuum 28 lb. Since that time the vessel has made several runs from Liverpool and from Glasgow to the Isle of Man, and has maintained a steady seagoing speed of between 18 and 19 knots.--_Engineering._
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THE TREATMENT OF REFRACTORY ORES.
Mr. Jas. J. Shedlock, with the assistance of Mr. T. Denny, of Australia, has constructed on behalf of the Metallurgical Syndicate, of 105 Gresham House, London, an apparatus on a commercial scale, which, it is said, effects at the smallest expense, and with the best economical results, the entire separation of metals from their ores. In treating ores by this process, the stone is crushed in the usual way, either by rolls or stamps, the crushed ore being conveyed into an apparatus, where each atom is subjected to the action of gases under pressure, whereby the whole of the sulphur and other materials which render the ore refractory are separated. The ore is then conveyed into a vessel containing an absorbing fluid metal, so constructed that every particle of the ore is brought into contact with the metal. For the production of reducing gases, steam and air are passed through highly heated materials, having an affinity for oxygen, and the gases so produced are utilized for raising the ore to a high temperature. By this means the sulphur and other metalloids and base metals are volatilized and eliminated, and the gold in the ore is then in such a condition as to alloy itself or become amalgamated with the fluid metal with which it is brought into close contact. The tailings passing off, worthless, are conveyed to the dump.
The apparatus in the background is that in which the steam is generated, and which, in combination with the due proportion of atmospheric air, is first superheated in passing through the hearth or bed on which the fire is supported. The superheated steam and air under pressure are then forced through the fire, which is automatically maintained at a considerable depth, by which means the products of combustion are mainly hydrogen and carbonic oxide. These gases are then conveyed by means of the main and branch pipes to the cylindrical apparatus in the foreground, into which the ore to be acted upon is driven under pressure by means of the gases, which, being ignited, raise the ore to a high temperature. The ore is maintained in a state of violent agitation. Each particle being kept separate from its fellows is consequently very rapidly acted upon by the gases. The ore freed from its refractory constituents is then fed into a vessel containing the fluid metal, in which each particle of ore is separated from the others, and being acted upon by the fluid metal is absorbed into it, the tailings or refuse passing off freed from any gold which may have been in the ore.
Quantities of refractory ores treated by this process are said to have demonstrated that the whole of the gold in the ore is extracted. The successful outcome of these trials is stated to have resulted in the Anglo-French Exploration Co. acquiring the right to work the process on the various gold fields of South Africa. It is anticipated that the process will thus be immediately brought to a test by means of apparatus erected on the gold fields under circumstances and conditions of absolute practical work. As is well known, gold-bearing ores in South Africa which are below the water line are, by reason of the presence of sulphur, extremely difficult to deal with, and are consequently of small commercial value. The gold in these ores, it is maintained, will, by the new process, be extracted and saved, and make all the difference between successful and unsuccessful mining in that country.
It will have been seen that the peculiar and essential features of the invention consist in subjecting every particle of the ore under treatment to the process in all its stages instead of in bulk, thereby insuring that no portion shall escape being acted upon by the gases and the absorbing metal. This is done automatically and in a very rapid manner. It is stated that this method of treatment is applicable to all ores, the most refractory being readily reducible by its means. The advantages claimed for this process are: simplicity of the apparatus, it being practically automatic; that every particle of the ore is separately acted upon in a rapid and efficient manner; that the apparatus is adaptable to existing milling plants; and that there is an absence of elaborate and expensive plant and of the refinements of electrical or chemical science. These advantages imply that the work can be done so economically as to commend the new process to the favorable consideration of all who are interested in mines or mining property.--_Iron._
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REFINING SILVER BULLION.
A number of years ago the author devised a method for refining silver bullion by sulphuric acid, in which iron was substituted for copper as precipitant of silver, the principal feature being the separation of pure crystals of silver sulphate. A full description of this process may be found in Percy's Metallurgy, "Silver and Gold," page 479. The process has been extensively worked in San Francisco and in Germany in refining bullion to the amount of more than a hundred million dollars' worth of silver. Its more general application has been hampered, however, by the circumstance that the patent had been secured by one firm which limited itself to its utilization in its California works. The patent having expired, the author lately introduced a modification of the process by which the apparatus and manipulations are greatly cheapened and simplified. In the following account is given a short description of the process in its present shape.
_Preparing the Silver Sulphate._--The bullion, containing, essentially, silver, copper and gold, is dissolved by boiling with sulphuric acid in cast iron pots. The difference between the new process and the usual practice consists in the use of a much larger quantity of acid. Thus, in refining ordinary silver "dore," four parts of acid are used to one part of bullion. Of this acid one part is chemically and mechanically consumed in the dissolving process, and the remaining three parts are fully recovered and at once ready for reutilization, as will be described hereafter. In the usual process--understanding thereby, here and in the following, the process practiced at the United States mints, for instance--two parts of acid are employed for one of bullion; all of this is lost, partly through the dissolving and partly in being afterward mixed with water, previous to the precipitation of the silver by copper. Economy in acid being therefore imperative, the silver solution finally becomes much concentrated, and it requires high heat and careful management to finish the solution of the bullion. Bars containing more than about 10 per cent. of copper cannot be dissolved at all, owing to the separation of copper sulphate insoluble in the small amount of free acid finally remaining. The advantage gained by dissolving bullion with abundance of free acid in the improved process is so evident that it merely requires to be pointed out. For bullion containing 20 per cent. of copper the author employs six parts of acid to one of bullion; for baser metal still more acid, and so on, never losing more than the stochiometrical percentage of acid and recovering the remainder. In this description he, however, confines himself to the treatment of ordinary silver ore with less than 10 per cent. of copper.
In the diagram A A represent two refining pots, 4 ft. in diameter and 3 ft. in depth, each capable of dissolving at one operation as much as 400 pounds of bullion. The acid is stored in the cast iron reservoir, B, which is placed on a level sufficiently high to charge into A by gravitation, and is composed of fresh concentrated acid mixed with the somewhat dilute acid regained from a previous operation. After the bullion is fully dissolved all the acid still available is run from B into A A. The temperature and strength are thereby reduced, the fuming ceases, any still undissolved copper sulphate dissolves, and the gold settles. In assuming that the settling of the gold takes place in A itself, the author follows the practice of the United States mints. In private refineries, where refining is carried on continuously, the settling may take place in an intermediate vessel, and A A be at once recharged. Owing to the large amount of free acid present, the temperature must fall considerably before the separation of silver sulphate commences, and sufficient time may be allowed for settling if the intermediate vessel be judiciously arranged.
_Separating the Silver Sulphate._--The clarified solution is siphoned off the gold from A A into C, which is an open cast iron pan, say 8 ft. by 4 ft. and 1 ft. deep. It is supported by means of a flange in another larger pan--not shown in the diagram--into which water may be admitted for cooling. Steam is blown into the acid solution, still very hot, as soon as C is filled. The steam is introduced about 1 in. below the surface of the liquid, blowing perpendicularly downward from a nozzle made of lead pipe through an aperture 1/8 in. in diameter. Under these circumstances the absorption of the steam is nearly perfect, and takes place without any splashing. The temperature rises with the increasing dilution, and may be regulated by the less experienced by manipulating the cooling tank. An actual boiling is not desired, because it protracts unnecessarily the operation by the less perfect condensation of the steam. No separation of silver sulphate occurs during this operation (and, consequently, there is no clotting of the steam nozzle), the large amount of free acid, combined with the increase of temperature, compensating for the diminution of the solubility of the sulphate by the dilution. The most important point in this procedure is to know when to stop the admission of steam. To determine this, the operator takes a drop or two of the solution upon a cold iron plate by means of a glass rod and observes whether after cooling the sample congeals partly or wholly into a white mass of silver bisulphate, or whether the silver separates as a monosulphate in detached yellow crystals, leaving a mother liquor behind. As soon as the latter point has been reached, steam is shut off and the solution is allowed to crystallize, cold water being admitted into the outer pan. The operator may now be certain that the liquid will no longer congeal into a soft mass of silver bisulphate, which on contact with water will disintegrate into powder, obstinately retaining a large amount of free acid; but the silver will separate as a monosulphate in hard and large yellow crystals retaining no acid and preserving their physical characteristics when thrown into water. After cooling to, say, 80° F., the silver sulphate will have coated the pan C about 1 in. thick. There will also be found a deposit of copper sulphate when the mother acid, after having been used over and over again, has been sufficiently saturated therewith. Lead sulphate separates in a cloud, which, however, will hardly settle at this stage.
The whole operation just described, which constitutes the most essential feature of the author's improvement upon his old process described in Dr. Percy's work, is a short one, as the acid requires by no means great dilution. The steam has merely to furnish enough water to dilute the free acid present to, say, 62° B. Areometrical determination is, of course, not possible, on account of the dissolved sulphates.
_Reducing the Silver Sulphate to Fine Silver._--The mother acid is pumped from C to the reservoir, B, for this purpose an iron pipe connecting the top of B with a recess in the bottom of C. The tank, B, is cast as a closed vessel, with a manhole in the top, which is ordinarily kept closed by an iron plate resting on a rubber packing. The air is exhausted from B by a steam injector, and the acid rises from C and enters B without coming in contact with any valves. The volume of fresh commercial acid necessary for another dissolving operation, say 800 pounds, more or less, for refining 800 pounds of bullion in A A, is lifted from some other receptacle into B in the same manner. The mixture of the two acids in B now represents the volume of acid to be employed for dissolving and settling the next charge of 800 pounds of bullion in A A. In this reservoir, B, the cloud of lead sulphate mentioned above finds an opportunity for settling.
The crystals of silver sulphate are detached from C by an iron shovel and thrown into D. D is a lead lined tank about 4 ft. by 4 ft. and 3 ft. deep. It is divided into two compartments by means of a horizontal, perforated false bottom made of wood. From the lower compartment a lead pipe discharges into the lead lined reservoir, E. Warm distilled water is allowed to percolate the crystals until the usual ammonia test indicates that the copper sulphate has been sufficiently dissolved. Then the outflow is closed, sheets of iron are thrown on and into the crystals, the apparatus is filled with hot distilled water, and steam is moderately admitted into the lower compartment. Ferrous sulphate is formed, and in connection with the iron rapidly reduces the silver sulphate to the metallic state, the reduced silver retaining the heavy compact character of the crystals. When the reaction is completed, as indicated by the chlorine test, the liquid is discharged into E, the iron sheets are removed and the silver is sweetened either in the same vessel, D, or in a special filtering vessel which rests on wheels and may be run directly to the hydraulic press.
The vat, E, is the great reservoir where all liquids holding silver sulphate in solution are collected; for instance, that from sweetening the gold and from washing the tools. Sheets of iron here precipitate all silver and copper, and the resulting solution of ferrous sulphate is, with the usual precautions, discharged into the sewer. Occasionally when copper and silver have accumulated in E in sufficient amount the mass is thrown into D, silver sulphate crystals are added and sheet copper is thrown in, instead of sheet iron. There results a hot, neutral, concentrated solution of copper sulphate, which may be run at once into a crystallizing vat for the separation of commercial crystals of copper sulphate. It will be readily understood, of course, that if there should be any advantage in manufacturing that commercial article, besides the amount prepared as described, which represents merely the copper contained in the bullion, copper sheets may be regularly employed for reducing the silver sulphate in D. The author trusts that the practical refiner will recognize that the manufacture of commercial copper sulphate is thus effected in a more rational and economical manner than by the present method of evaporating from 25° B. to 35° B., and of saturating by oxidized copper, generally in a very incomplete manner, the large amount of free acid left from the refining by the usual process. However, the sale of copper sulphate is but rarely so profitable that a refinery should not gladly dispense with that troublesome and bulky manufacture, especially the government establishments, which, besides, waste much valuable space with the crystallizing vats.
The great saving in sulphuric acid, amounting to about 50 per cent. of the present consumption, has already been pointed out. Another advantage the author merely mentions, namely, the easier condensation of the sulphurous fumes in refineries situated in cities, because the larger amount of acid available for dissolving greatly facilitates working and makes the usual frequent admission of air into the refining pot for the purpose of stirring and testing unnecessary.
The more air is excluded from the refining fumes the easier they can be condensed.
Work may be carried on continuously, the vessels C and D being empty by the time a new solution is finished in A A. Thus, the plant shown in the diagram, covering 26 ft. by 16 ft., allows the refining of 40,000 ounces of fine silver in 24 hours; that is, four charges in A A of 800 pounds each.--_F. Gutzkow, Eng. and Mining J._
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A CASE OF DROWNING, WITH RESUSCITATION.
By F.A. BURRALL, M.D., New York.
As is usual at this season, casualties from drowning are of frequent occurrence. No class of emergencies is of a more startling character, and I think that a history of the case which I now present offers some peculiar features, and will not be without interest to physicians.
The accident which forms the subject of this paper occurred August 29, 1890, at South Harpswell, Casco Bay, Me., where I was passing my vacation.