Scientific American Supplement, No. 799, April 25, 1891

Chapter 8

Chapter 83,790 wordsPublic domain

"In producing this result two agencies are at work, there is the action of electrolysis and the formation of a hydrated oxide of iron. It is not possible, perhaps, to define the exact action, but as the formation of an iron oxide is part of it, it seemed desirable to ascertain whether the simple addition of a salt of iron with lime sufficient to neutralize the acid of the salt would produce results similar to those attained by Webster's process.

"In order to make these experiments, samples of fresh raw sewage were taken at Crossness at intervals of one hour during the day. As much as 10 grains of different salts of iron were added per gallon, plus 15.7 grains of lime in some cases and 125 grains of lime in another, and the treated sewage was allowed to settle twenty-four hours; the results obtained were not nearly as good as the electrical method."

During the present year a very searching investigation of the merits of various processes of sewage treatment has been made by the corporation of Salford; among others of my electrical process. As the matter is at present under discussion by the council, I am not in a position to give extracts from the reports of the engineers and chemists under whose supervision and control the work was done, but I may go so far as to say that the results of my system of electrical treatment have proved its efficiency and applicability to sewages of even such a foul nature as that of Salford and Pendleton. The system was controlled continuously for the corporation by Mr. A. Jacob, B.A., C.E., the borough engineer; Mr. J. Carter Bell, F.I.C., etc., county analyst; Messrs John Newton & Sons, engineers, Manchester; Mr. Giles, of Messrs. Mather & Pratt, electrical engineers, Manchester; Dr. Charles A. Burghardt, lecturer in mineralogy at Owens College.

I would also refer you to a paper recently read before the Manchester Section of this Society by Mr Carter Bell, the borough analyst for Salford, in whose remarks Dr. Burghardt, an independent authority, permits me to add that he concurs. He cannot give details until his report has gone in, which will be very shortly.

Mr. Carter Bell's report _has_ gone in, and although he is precluded also from giving full details, he has kindly put at my disposal samples sealed by him of the effluents produced by the electrical treatment, which I now submit, together with the analyses in the table.

The samples are taken at random.

Whether the process will or will not be adopted by the Salford authorities I am of course unable to say, but I think I may safely say that the electrical process has now absolutely proved its case in regard to the solution of the sewage problem. It is simple, efficient and, I am sure, more economical than any other known process where duration is taken into account.

In regard to the Salford trials it may be interesting to give the following particulars:

______________________________________________________________________ | | Parts in 100,000. |________________________________________________ | | | | | May 15. | June 7. | June 30. | July 25. |_____________|___________|___________|__________ |Not filtered.| | | Total solids. | 109 | 125 | 141 | 132 Loss on ignition. | 33 | 21 | 29 | 23 Chlorine. | 32 | 44 | 42 | 43 Oxygen required | | | | for 15 minutes. | 2.56 | 0.76 | 0.27 | 0.79 Oxygen required | | | | for three hours. | 4.27 | 0.79 | 0.50 | 1.00 Free ammonia. | 2.20 | 0.88 | 0.50 | 0.92 Albuminoid am- | | | | monia. | 0.32 | 0.17 | 0.092 | 0.19 _____________________|_____________|___________|___________|__________

The electrical shoot was built in brick and contained 28 cells arranged in series.

Each cell contained 13 cast iron plates 4 in. × 2 ft. 8 in. × ½ in. thick connected in parallel.

The available electrode surface in each cell was 256 sq. ft.

The ampere hour treatment required for Salford was found to be about 0.37 ampere hours per gallon, and the I.H.P. per million gallons based on these figures would be 37.

NOTE.--In estimating for the plant necessary for treating the whole of the Salford sewage, a margin was allowed on above figures. The A.H.T. was taken at 0.4 and the I.H.P. per million at 39 to 39.5.

Mr. Octavius March, electrical engineer, who has followed the process from the commencement, and who superintended the electrical details both at Crossness and Salford, will give you on the blackboard a rough sketch of the above trial plant.

The Salford tanks are admirably adapted to the application of the electrical or in fact any process of precipitation. They are 12 in number, and it is proposed to take two end tanks for the electrical channels, in which the iron electrodes would be placed.

The total I.H.P. required for treating the whole of the Salford and Pendleton sewage, taken at 10,000,000 gallons per 24 hours, is calculated at 400 I.H.P., based on the actual work done during the trial. The electrical plant would consist of four engines and dynamos, any three of which could do the whole work, and three boilers, each of 200 I.H.P.

The total cost of plant, including alterations, is estimated at £16,000, to which must be added the cost of about 5,000 tons of iron plates--ordinary cast iron--at say £4 per ton. These plates would last for several years.

If filtration were required, there would be an extra expenditure for this, but it will be remarked that as the treated sewage is practically purified when it leaves the electrical channels, these filters would be only required for complete clarification, which for most places would not be a necessity.

The filtering material used could be gradually prepared from the sludge obtained after electrical treatment, unless it could be more profitably sold as a manure, and I am not a believer in the value of sewage sludge in large quantities. This sludge, a waste product, is converted into _magnetic oxide of iron_, of which I have here two small samples. This magnetic oxide is a good filtering material, but, like every other filtering material, it would of course require renewal. There would, however, always be a supply of the waste product--sewage sludge--on the spot, and the spent magnetic oxide recarbonized could be used indefinitely.

The annual cost for dealing with the Salford sewage is estimated at in round figures £2,500 for coal, labor, maintenance of engines, boilers and dynamos. To this must be added the consumption of iron and its replacement, which would have to be written off capital expenditure.

If a colorless effluent were required, absolutely free from suspended matter, the additional cost is estimated at from £1,200 to £1,500.

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LAVENDER AND ITS VARIETIES.

By J. CH. SAWER, F.L.S.

Lavender--technically _Lavandula_. This name is generally considered to be derived from the word _lavando_, gerund of the verb _lavare_, "to wash" or "to bathe," and to originate from the ancient Roman custom of perfuming baths with the flowers of this plant.

The general aspect of the various species which compose this genus of labiate plants, although presenting very characteristic differences, merges gradually from one species to another; all are, in their native habitat, small ligneous undershrubs of from one to two feet in height, with a thin bark, which detaches itself in scales; the leaves are linear, persistent, and covered with numerous hairs, which give the plant a hoary appearance.

The flowers, which are produced on the young shoots, approximate into terminal simple spikes, which are, in vigorous young plants, branched at the base and usually naked under the spikes.

As a rule, lavender is a native of the countries bordering on the great basin of the Mediterranean--at least eight out of twelve species are there found to be indigenous on mountain slopes.

The most commonly known species are _L. vera, L. spica_ and _L stæchas_. Commercially the _L. vera_ is the most valuable by reason of the superior delicacy of its perfume; it is found on the sterile hills and stony declivities at the foot of the Alps of Provence, the lower Alps of Dauphiné and Cevannes (growing in some places at an altitude of 4,500 feet above the sea level), also northward, in exposed situations, as far as Monton, near Lyons, but not beyond the 46th degree of latitude; in Piedmont as far as Tarantaise, and in Switzerland, in Lower Vallais, near Nyon, in the canton of Vaud, and at Vuilly. It has been gathered between Nice and Cosni, in the neighborhood of Limoné, on the elevated slopes of the mountains of western Liguria, and in Etruria on hills near the sea. The _L. spica_, which is the only species besides _L. vera_ hardy in this country, was formerly considered only a variety of _L. vera_; it is distinguished by its lower habit, much whiter color, the leaves more congested at the base of the branches, the spikes denser and shorter, the floral leaves lanceolate or linear, and the presence of linear and subulate bractes.

It yields by distillation an oil termed "oil of spike," or, to distinguish it from oil of _L. stæchas_, "true oil of spike." It is darker in color than the oil of _L. vera_, and much less grateful in odor, reminding one of turpentine and rancid coker nut oil. It is used by painters on porcelain, and in the manufacture of varnishes. It is often largely admixed with essence of turpentine.

_L. Stæchas_ (Stichas) was discovered prior to the year 50 A.D. in the Stæchades Islands (now the Islands of Hyères), hence the name. At present it is found wild in the South of Europe and North of Africa, also at Teneriffe. The leaves are oblong linear, about half an inch long (sometimes an inch long when cultivated), with revolute edges and clothed with hoary tomentum on both surfaces; the spike is tetragonal, compact, with a tuft of purple leaves at the top; the calyces are ovate and slightly shorter than the tube of the corolla. The whole plant has a strong aromatic and agreeable flavor. There is a variety of this species (_L. macrostàchya_) native of Corsica, Sicily, and Naples, which has broader leaves and thicker octagonal spikes.

_L. stæchas_ is known in Spain as "Romero Santo" (sacred rosemary). Its essential oil (also that of _L. dentata_) is there obtained for household use by suspending the fresh flowering stalks, flowers downward, in closed bottles and exposing them for some time in the sun's rays; a mixture of water and essential oil collects at the bottom, which is used as a hæmostatic and for cleansing wounds.

The specific gravity of Spanish oil of _L. stæchas_ is 0.942 at 15° C. It boils between 180° and 245°. The odor of this oil is not at all suggestive of that of lavender, but resembles more that of oil of rosemary, possessing also the camphoraceous odor of that oil. In India this oil is much prized as an expectorant and antispasmodic.

The other species which are distinctly characterized are _L. pedunculata, L. viridis, L. dentata, L. heterophylla, L. pyrenaica, L. pinnata, L. coronopifolia, L. abrotonoides, L. Lawii_, and _L. multifida_.

The _L. multifida_ is synonymous with _L. Burmanii_. In Spain the therapeutic properties of _L. dentata_ are alleged to be even more marked than in the oils of any of the other species of lavender. It is said to promote the healing of sluggish wounds, and when used in the form of inhalation to have given good results in cases of severe catarrh, and even in cases of diphtheria. In odor this oil strongly suggests rosemary and camphor. Its specific gravity is 0.926 at 15° C. It distills almost completely between 170° and 200°.

The specific gravity of the oil of _L. vera_ (according to Flückiger and Hanbury, _Pharmacographia_) ranges between 0.87 and 0.94. The same authorities state that in a tube of 50 millimeters the plane of polarization is diverted 4.2° to the left.

Dr. Gladstone found (_Jnl. Ch. Soc._, xviii., 3) that a sample of pure oil of _L. vera_, obtained from Dr. S. Piesse, indicated a specific gravity of 0.8903 at 15° C., and that its power of rotating the plane of polarization (observed with a tube ten inches long) was -20°. Compared with these results he found the sp. gr. of oil of turpentine to be 0.8727, and the rotatory power -79°.

Although _L. stæchas_ was well known to the ancients, no allusion unquestionably referring to _L. vera_ has been found in the writings of classical authors, the earliest mention of this latter plant being in the twelfth century, by the Abbess Hildegard, who lived near Bergen-on-the-Rhine. Under the name of _Llafant_ or _Llafantly_, it was known to the Welsh physicians as a medicinal plant in the thirteenth century. The best variety of _L. vera_--and there are several, although unnamed--improved by cultivation in England, presents the appearance of an evergreen undershrub of about two feet in height, with grayish green linear leaves, rolled under at the edges, when young; the branches are erect and give a bushy appearance to the plant; the flowers are borne on a terminal spike, at the summit of along naked stalk, the spike being composed of six to ten verticillasters, more widely separated toward the base of the spike; in young plants two or four sub-spikes will branch alternately in pairs from the main stalk; this indicates great vigor in the plant, and occurs rarely after the second year of the plant's growth. The floral leaves are rhomboidal, acuminate, and membraneous, the upper ones being shorter than the calyces, bracteas obovate; the calyces are bluish, nearly cylindrical, contracted toward the mouth, and ribbed with many veins. The corolla is of a pale bluish violet, of a deeper tint on the inner surface than the outer, tubular, two-lipped, the upper lip with two and the lower with three lobes. Both the corolla and calyx are covered with stellate hairs, among which are embedded shining oil glands, to which the fragrance of the plant is due. The _L. vera_ was identified in 1541, and introduced into England in 1568, flourishing remarkably well under cultivation, and yielding an oil far superior in delicacy of fragrance to that obtained from the wild plant, or to that obtained from the same plant cultivated in any other country.

When it is remembered that north of the 50th degree of latitude the vine yields little but garlands of leaves, and that we should attempt in vain to cultivate the olive north of the 44th degree, it may seem strange that the _Lavandula vera_, which is a native of about the same climate as these, should resist, unprotected, the vigorous frosts of this country. Even at Upsala, latitude 59° 51' N., in the Botanic Garden, it merely requires the shelter of a few branches to protect it in the winter; but this hardiness may be accounted for by several physiological reasons. Like all fruticulose labiates which have a hard compact tissue and contain much oily matter, the lavender absorbs less moisture than herbs which are soft and spongy, and, as it always prefers a dry calcareous, even stony, soil, the northern cultivators find that by selecting such localities the tissues of the plant take up so little water that the frost does not injure them.

In a northern climate the length of the days in summer, and the natural dryness of the air, compensate in some measure the reduction of temperature, and mature the plant only to the extent sufficient for the purpose for which it is grown. Perhaps the suspension of vital action during winter, which must be more complete in northern latitudes, as our frosts are more severe, tends to preserve certain plants, native of the south, for it is observed that all plants are more sensitive to cold when vegetation is active than when it is at rest. The vine is an instance of this. On the other hand, when the plant is cultivated further south than its natural boundary, the same causes seem to exert their influence, but in the reverse sense. Lavender is cultivated on the mountains of Yemen, in Arabia; the humidity, increasing inversely to the latitude, compensates the exhaling force of the sun's rays, and the elevation of the locality the effects of the heat.

Thus is confirmed, both in north and south, the law of vegetable physiology observed by De Candolle, in the temperate climates of France, and published in his "Essai de Geographie Botanique," that "plants can best resist the effects of cold in a dry atmosphere, and the effects of heat in a humid atmosphere." A mild, damp winter, like the one of 1889-1890, does more harm than a hard, seasonable frost, as the plants are apt to make green shoots prematurely, and the late frosts nip off these tender portions, each of which would otherwise have produced a flower spike.

The very severe winter of 1890-1891 did not kill so many plants as the one of 1889-1890. The stems and branches of lavender being ligneous and strong are able to resist the force of the wind, and the plant thrives best in a perfectly open locality, where the air circulates freely; the oil and resin which it contains in abundance enable it to resist the parching action of the wind and sun. Thus, on the most arid and sterile ground on the mountain sides in the south, and especially in Spain, plants of this genus flourish with more vigor in the season when most other vegetation is scorched up by the ardent rays of the sun, and the _Lavandula vera_ seems to have a predilection for such spots.

Certainly the plants then assume a more stunted appearance than in richer soil, but at the same time the perfume is stronger and sweeter. The calyces become charged with oil glands, and yield a greater abundance of volatile oil.

In a very moist soil the water penetrates too much into the tissues, detaches the bark, the plant blackens at the root, and a white fungus attaches to the main stem and lower branches; it becomes feeble, diseased, and dies. A rich soil furnishes too much nutriment, the plant grows very large and herbaceous, becomes overcharged with water relative to its assimilating and elaboratory power, especially if growing in a cold climate, and the equilibrium of the chemical proportions necessary for the formation of natural juices becomes deranged at the expense of quantity and quality of the volatile oil produced.

These facts, long ago pointed out by Linnæus, have been verified in England. Some years ago a disease manifested itself in most of the plantations, which, not being understood by the growers, was not remedied (in fact, is not generally understood and remedied at the present time), the acreage under cultivation decreased, and, partly owing to this and a scarcity occasioned by a failure in the crop, the price of the oil rapidly rose from 50s. to 200s. per lb. Consequently, with the continually increasing demand and the continued rise in price, manufacturers of lavender water and of compound perfumes in which oil of lavender is a necessary ingredient commenced to buy the French oil, and venders of the English oil commenced to adulterate largely the English with the French oil.

By degrees the French oil become almost entirely substituted in England for the English, and at present it is difficult to purchase true English lavender water of a quality equal to that vended twenty years ago, except at a few first class houses.

The exorbitant profits demanded by chemists and druggists, and the incomprehensible will of the public to buy anything _cheap_, however bad, have encouraged a marvelous increase in the figures of the imports of French (and German, which is worse) oil.

In 1880, when the price had reached 125s. per lb., it was pointed out by an eminent London firm that unless the cultivation in England were extended, the price would become prohibitive, inferior oils would be introduced into the market, and so destroy the popularity of this beautiful perfume.

The price still rising did, in fact, induce this importation, and to this day the bulk of chemists and perfumers continue to use these foreign oils, notwithstanding the fall in the price of the English oil.

The constant demand, however, in America (where people will have things good) will yet support the price of the genuine article--that is, of the English oil, which is the finest the world produces. Attempts were made by a French manufacturing perfumer to establish a plantation in the south of France of plants taken from parent stems grown in England.

The result was that the young plants deteriorated to their original condition--even there in their native habitat. The character of a plant and the character of its produce depend even on more than a similarity of soil and geographical position. It is asserted that a good judge can distinguish between the oils produced by two adjacent fields, and the difference in odor is very apparent between the oils produced in Hertfordshire and in Surrey. The oil produced in Sussex is different from both.--_Chemist and Druggist_.

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SPECTRUM OF THE SUN AND ELEMENTS.

The _Johns Hopkins University Circular_, No. 85, issued in February, contains Prof. Rowland's report of progress in spectrum work. The spectra of all known elements, with the exception of a few gaseous ones, or those too rare to be yet obtained, have been photographed in connection with the solar spectrum, from the extreme ultra-violet down to the D line, and eye observations have been made on many to the limit of the solar spectrum. A table of standard wave lengths of the impurities in the carbon poles extending to wave length 2,000 has been constructed to measure wave lengths beyond the limits of the solar spectrum. In addition to this, maps of the spectra of some of the elements have been drawn up on a large scale, ready for publication, and the greater part of the lines in the map of the solar spectrum have been identified. The following rough table of the solar elements has been constructed entirely according to Prof. Rowland's own observations, although, of course, most of them have been given by others:

_Elements in the Sun, arranged according to Intensity and the Number of Lines in the Solar Spectrum_.

According to intensity. According to number.

Calcium Zirconium Iron (2,000 or more) Magnesium (20 or more) Iron Molybdenum Nickel Sodium (11) Hydrogen Lanthanum Titanium Silicon Sodium Niobium Manganese Strontium Nickel Palladium Chromium Barium Magnesium Neodymium Cobalt Aluminum (4) Cobalt Copper Carbon (200 or more) Cadmium Silicon Zinc Vanadium Rhodium Aluminum Cadmium Zirconium Erbium Titanium Cerium Cerium Zinc Chromium Glucinum Calcium (75 or more) Copper (2) Manganese Germanium Scandium Silver (2) Strontium Rhodium Neodymium Glucinum (2) Vanadium Silver Lanthanum Germanium Barium Tin Yttrium Tin Carbon Lead Niobium Lead (1) Scandium Erbium Molybdenum Potassium (1) Yttrium Potassium Palladium

_Doubtful Elements_.

Iridium, osmium, platinum, ruthenium, tantalum, thorium, tungsten, uranium.