Chapter 4

In both cases, the firing of the retorts was moderate, though in the second trial greater care was taken to secure uniformity of heat, and the oil was run in more slowly, so that there was more thorough splitting up of the oil into permanent gas. The gas obtained in the two trials was of high quality, owing to its containing a large percentage of heavy hydrocarbons, of which there were, respectively, 39.25 and 37.15 per cent., or an average of 38.2 per cent., while the sulphureted hydrogen was nothing, and the carbonic acid a mere trace. Besides testing the gas on the occasion of the actual trials, he had also examined samples of the gas which he had taken from various cylinders in which the gas had been stored for several months under a pressure of ten atmospheres, and in all cases the gas was found to be practically equal to the quantity mentioned, and hence of a permanent character.

By using Keith's apparatus the results obtained were generally the same, with the exception that an average of 0.27 per cent. of carbonic acid gas and decided proportions of sulphureted hydrogen were found to be present in the gas. Dr. Macadam devoted some remarks to the consideration of the question as to how far the gas obtained from the paraffin oil represented the light power of the oil itself, and then he proceeded to say that, taking the crude paraffin oil at 2d. a gallon, and with a specific gravity of 850 (water = 1,000), or 8½ lb. to the gallon, there were 264 gallons to the ton, at a cost of £2 4s. per ton. The sperm light from the ton of oil as gas being 3,443 lb., he reckoned that fully 6 lb. of sperm light were obtained from a pennyworth of the crude oil as gas.

Then, taking the blue paraffin oil at 4d. per gallon, and there being 255 gallons to the ton, it was found that the cost of one ton was £4 5s., and as the sperm light of a ton of that oil as gas was 5,150 lb., it was calculated that 5 lb. of sperm light were yielded in the gas from a pennyworth of the blue oil. The very rich character of the oil gas rendered it unsuitable for consumption at ordinary gas jets, though it burned readily and satisfactorily at small burners not larger than No. 1 jets.

In practical use it would be advisable to reduce the quality by admixture with thin and feeble gas, or to employ the oil gas simply for enriching inferior gases derived from the more common coals. On the question of dilution, he said that he preferred to use carbonic oxide and hydrogen, and most of the remainder of his paper was devoted to an explanation of the best mode of preparing those gases (water gases).

He concluded by saying: The employment of paraffin oil for gas making has advantages in its favor, in the readiness of charging the retorts, as the oil can be run in continuously for days at a time, and may be discontinued and commenced again without opening, clearing out residual products, recharging and reclosing the retorts. There is necessarily, therefore, less labor and cost in working, and as the gas is cleaner or freer from impurities, purifying plant and material will be correspondingly less. Oil gas is now employed for lighthouse service in the illumination of the lanterns on Ailsa Craig and as motive power in the gas engines connected with the fog horns at Langness and Ailsa Craig lighthouse stations. It is also used largely in the lighting of railway carriages. Various populous places are now introducing oil gas for house service, and he felt sure that the system is one which ought to commend itself for its future development to the careful consideration and practical skill of the members of the Gas Institute.

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THE MANUFACTURE OF SALT NEAR MIDDLESBROUGH.[1]

[Footnote 1: Abstract of paper read before the Institution of Civil Engineers, May 17, 1887.]

By Sir LOWTHIAN BELL, Bart., F.R.S.

The geology of the Middlesbrough salt region was first referred to, and it was stated that the development of the salt industry in that district was the result of accident. In 1859, Messrs. Bolckow & Vaughan sank a deep well at Middlesbrough, in the hope of obtaining water for steam and other purposes in connection with their iron works in that town, although they had previously been informed of the probably unsuitable character of the water if found. The bore hole was put down to a depth of 1,200 feet, when a bed of salt rock was struck, which proved to have a thickness of about 100 feet. At that time one-eighth of the total salt production of Cheshire was being brought to the Tyne for the chemical works on that river, hence the discovery of salt instead of water was regarded by some as the reverse of a disappointment. The mode of reaching the salt rock by an ordinary shaft, however, failed, from the influx of water being too great, and nothing more was heard of Middlesbrough salt until a dozen years later, when Messrs. Bell Brothers, of Port Clarence, decided to try the practicability of raising the salt by a method detailed in the paper. A site was selected 1,314 yards distant from the well of Messrs. Bolckow & Vaughan, and the Diamond Rock Boring Company was intrusted with the work of putting down a hole in order to ascertain whether the bed of salt extended under their land. This occupied nearly two years, when the salt, 65 feet in thickness, was reached at a depth of 1,127 feet. Other reasons induced the owners of the Clarence iron works to continue the bore hole for 150 feet below the bed of salt; a depth of 1,342 feet from the surface was then reached. During the process of boring, considerable quantities of inflammable gas were met with, which, on the application of flame, took fire at the surface of the water in the bore hole. The origin of this gas, in connection with the coal measures underlying the magnesian limestone, will probably hereafter be investigated.

For raising the salt, recourse was had to the method of solution, the principle being that a column of descending water should raise the brine nearly as far as the differences of specific gravity between the two liquids permitted--in the present case about 997 feet. In other words, a column of fresh water of 1,200 feet brought the brine to within 203 feet of the surface. For the practical application of this system a hole of say 12 inches in diameter at the surface was commenced, and a succession of wrought iron tubes put down as the boring proceeded, the pipes being of gradually decreasing diameter, until the bottom of the salt bed was reached. The portion of this outer or retaining tube, where it passed through the bed of salt, was pierced with two sets of apertures, the upper edge of the higher set coinciding with the top of the seam, and the other set occupying the lower portion of the tube. Within the tube so arranged, and secured at its lower extremity by means of a cavity sunk in the limestone, a second tube was lowered, having an outer diameter from two to four inches less than the interior diameter of the first tube. The latter served for pumping the brine. The pump used was of the ordinary bucket and clack type, but, in addition, at the surface, there was a plunger, which served to force the brine into an air vessel for the purposes of distribution. The bucket and clack were placed some feet below the point to which the brine was raised by the column of fresh water descending in the annulus formed between the two tubes. In commencing work, water was let down the annulus until the cavity formed in the salt became sufficiently large to admit of a few hours' pumping of concentrated brine. On the machinery being set in motion, the stronger brine was first drawn, which, from its greater specific gravity, occupied the lower portion of the cavity. As the brine was raised, fresh water flowed down. The solvent power of the newly admitted water was of course greater than that of water partially saturated, and being also lighter it occupied the upper portion of the excavated space. The combined effect was to give the cavity the form of an inverted cone. The mode of extraction thus possessed the disadvantage of removing the greatest quantity of the mineral where it was most wanted for supporting the roof, and had given rise to occasional accidents to the pipes underground. These were referred to in detail, and the question was started as to possible legal complications arising hereafter from new bore holes put down in close proximity to the dividing line of different properties, the pumping of brine formed under the conditions described presenting an altogether different aspect from the pumping of water or natural brine.

The second part of the paper referred to the uses to which the brine was applied, the chief one being the manufacture of common salt. For this purpose the brine, as delivered from the wells, was run into a large reservoir, where any earthy matter held in suspension was allowed to settle. The clear solution was then run into pans sixty feet long by twenty feet wide by two feet deep. Heat was applied at one end by the combustion of small coal, beyond which longitudinal walls, serving to support the pan and to distribute the heat, conducted the products of combustion to the further extremity, where they escaped into the chimney at a temperature of from 500° to 700° Fahr. On the surface of the heated brine, kept at 196° Fahr., minute cubical crystals speedily formed. On the upper surface of these, other small cubes of salt arranged themselves in such a way that, in course of time, a hollow inverted pyramid of crystallized salt was formed. This ultimately sank to the bottom, where other small crystals united with it, so that the shape became frequently completely cubical. Every second day the salt was "fished" out and laid on drainers to permit the adhering brine to run back into the pans. For the production of table salt the boiling was carried on much more rapidly, and at a higher temperature than for salt intended for soda manufacture. The crystals were very minute, and adhered together by the solidification of the brine, effected by exposure on heated flues. For fishery purposes the crystals were preferred very coarse in size. These were obtained by evaporating the brine more slowly and at a still lower temperature than when salt for soda makers was required. At the Clarence works experiments had been made in utilizing surplus gas from the adjacent blast furnaces, instead of fuel, under the evaporating pans, the furnaces supplying more gas than was needed for heating air and raising steam for iron making. By means of this waste heat, from 200 to 300 tons of salt per week were now obtained.

The paper concluded with some particulars of the soda industry. The well-known sulphuric acid process of Leblanc had stood its ground for three-quarters of a century in spite of several disadvantages, and various modes of utilizing the by-products having been from time to time introduced, it had until recent years seemed too firmly established to fear any rivals. About seven years ago, however, Mr. Solvay, of Brussels, revived in a practical form the ammonia process, patented forty years ago by Messrs. Hemming & Dyar, but using brine instead of salt, and thus avoiding the cost of evaporation. This process consisted of forcing into the brine currents of carbonic acid and ammoniacal gases in such proportions as to generate bicarbonate of ammonia, which, reacting on the salt of the brine, gave bicarbonate of soda and chloride of ammonium. The bicarbonate was placed in a reverberatory furnace, where the heat drove off the water and one equivalent of carbonic acid, leaving the alkali as monocarbonate. Near Middlesbrough, the only branch of industry established in connection with its salt trade was the manufacture of soda by an ammonia process, invented by Mr. Schloesing, of Paris. The works were carried on in connection with the Clarence salt works. It was believed that the total quantity of dry soda produced by the two ammonia processes, Solvay's and Schloesing's, in this country was something under 100,000 tons per annum, but this make was considerably exceeded on the Continent.

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COTTON INDUSTRIES OF JAPAN.

The cotton plant principally cultivated in Japan is of the species known as _Gossypium herbaceum_, resembling that of India, China, and Egypt. The plant is of short stature, seldom attaining a growth of over two feet; the flower is deciduous, with yellow petals and purple center, and the staple is short, but fine. It is very widely cultivated in Japan, and is produced in thirty-seven out of the forty-four prefectures forming the empire, but the best qualities and largest quantities are grown in the southern maritime provinces of the mainland and on the islands of Kiusiu and Shikoku. Vice consul Longford, in his last report, says that the plant is not indigenous to Japan, the seed having been first imported from China in the year 1558. There are now many varieties of the original species, and the cultivation of the plant varies in its details in different localities. The variations are, however, mostly in dates, and the general grinding principles of the several operations are nearly the same throughout the whole country. The land best suited for cotton growing is one of a sandy soil, the admixture of earth and sand being in the proportion of two parts earth to one of sand. During the winter and spring months, crops of wheat or barley are raised on it, and it is when these crops have attained their full height during the month of May that the cotton is sown. About fifty days prior to the sowing a manure is prepared consisting of chopped straw, straw ashes, green grass, rice, bran, and earth from the bottom of the stagnant pools. These ingredients are all carefully mixed together in equal proportions, and the manure thus made is allowed to stand till required for use. Ten days before the time fixed for sowing, narrow trenches, about one inch in depth, are dug in the furrows, between the rows of standing wheat or barleys and the manure is liberally sprinkled along them by hand. For one night before sowing the seed is steeped in water. It is then taken out, slightly mixed with straw ashes, and sown in the trenches at intervals of a few inches. When sown, it is covered with earth to the depth of half an inch, and gently trampled down by foot. Four or five days after sowing, the buds begin to appear above the earth, and almost simultaneously the wheat or barley between which they grow is ripe for the sickle. While the latter is being harvested, the cotton may be left to itself, but not for very long. The buds appear in much larger numbers than the soil could support if they were allowed to grow. They have accordingly to be carefully thinned out, so that not more than five or six plants are left in each foot of length. The next process is the sprinkling of a manure composed of one part night soil and three parts water, and again, subsequent to this, there are two further manurings; one of a mixture of dried sardines, lees of oil, and lees of rice beer, which is applied about the middle of June, when the plant has attained a height of four inches; and again early in July, when the plant has grown to a height of six or seven inches, a further manuring of night soil, mixed with a larger proportion of water than before. At this stage the head of the plant is pinched off with the fingers, in order to check the excessive growth of the stem, and direct the strength into the branches, which usually number five or six. From these branches minor ones spring, but the latter are carefully pruned off as they appear. In the middle of August the flowers begin to appear gradually. They fall soon after their appearance, leaving in their place the pod or peach (_momo_), which, after ripening, opens in October by three or four valves and exposes the cotton to view. The cotton is gathered in baskets, in which it is allowed to remain till a bright, sunshiny day, when it is spread out on mats to dry and swell in the sun for two or three days. After drying, the cotton is packed in bags made of straw matting, and either sold or put aside until such time as the farmer's leisure from other agricultural operations enables him to deal with it. The average yield of cotton in good districts in Japan is about 120 lb. to the acre, but as cotton is only a secondary crop, this does not therefore represent the whole profit gained by the farmer from his land. The prefectures in which the production is largest are Aichi on the east coast, Osaka, Hiogo, Hiroshima, and Yamaguchi on the inland sea, and Fukui and Ishikawa on the west coast. Vice-consul Longford says that the manufacture of cotton in Japan is still in all its stages largely a domestic one. Gin, spindle, and loom are all found in the house of the farmer on whose land the cotton is grown, and not only what is required for the wants of his own family is spun and woven by the female members thereof, but a surplus is also produced for sale.

Several spinning factories with important English machinery have been established during the last twenty years, but Consul Longford says that he has only known of one similar cotton-weaving factory, and that has not been a successful experiment. Other so called weaving factories throughout the country consist only of a collection of the ordinary hand looms, to the number of forty or fifty, scarcely ever reaching to one hundred, in one building or shed, wherein individual manufacturers have their own special piece goods made.

The first operation in the manufacture is that of ginning, which is conducted by means of a small implement called the _rokuro_, or windlass. This consists of two wooden rollers revolving in opposite directions, fixed on a frame about 12 inches high and 6 inches in width, standing on a small platform, the dimensions of which slightly exceed that of the frame. The operator, usually a woman, kneels on one side of the frame, holding it firm by her weight, works the roller with one hand, and with the other presses the cotton, which she takes from a heap at her side, between the rollers. The cotton passes through, falling in small lumps on the other side of the frame, while the seeds fall on that nearest the woman. The utmost weight of unginned cotton that one woman working an entire day of ten hours can give is from 8 lb. to 10 lb., which gives, in the end, only a little over 3 lb. weight of ginned cotton, and her daily earnings amount to less than 2d. A few saw gins have been introduced into Japan during the last fifteen years, but no effort has been made to secure their distribution throughout the country districts. After ginning, a certain proportion of the seed is reserved for the agricultural requirements of the following year, and the remainder is sent to oil factories, where it is pressed, and yields about one-eighth of its capacity in measurement in oil, the refuse, after pressing, being used for manure. The ginning having been finished in the country districts, the cotton is either packed in bales and sent to the dealers in the cities, or else the next process, that of carding, is at once proceeded with on the spot.

This process is almost as primitive as that of the ginning. A long bamboo, sufficiently thin to be flexible, is fastened at its base to a pillar or the corner of a small room. It slopes upward into the center of the room, and from its upper end a hempen cord is suspended. To this is fastened the "bow," an instrument made of oak, about five feet in length, two inches in circumference, and shaped like a ladle. A string of coarse catgut is tightly stretched from end to end of the bow, and this is beaten with a small mallet made of willow, bound at the end with a ring of iron or brass. The raw cotton, in its coarse state, is piled on the floor just underneath the string of the bow. The string is then rapidly beaten with the mallet, and as it rises and falls it catches the rough cotton, cuts it to the required degree of fineness, removes impurities from it, and flings it to the side of the operator, where it falls on a hempen net stretched over a four-cornered wooden frame. The spaces of the net are about one-quarter of an inch square, and through these any particles of dust that may still have adhered to the cotton fall to the floor, leaving piled on top of the net the pure cotton wool in its finished state. This work is always performed by a man, and by assiduous toil throughout a long day, one man can card from ten to twenty pounds weight of raw cotton. Payment is made in proportion to the work done, and in the less remote country districts is at the rate of about one penny for each pound carded. As regards spinning and weaving, in the first of these branches of cotton manufacture the Japanese have largely had recourse to the aid of foreign machinery, but it is still to a much greater extent a domestic industry, or at best carried on like weaving in the establishments of cotton traders, in which a number of workers, varying from 20 to 100 or more, each with his own spinning wheel, are collected together. Consul Longford says the spinning wheel used in Japan differs in no respect from that used in the country 300 years ago or (except that bamboo forms an integral part of the materials of which it is made) from that used in England prior to the invention of the jenny. The cost of one of the wheels is about 9d., it will last for five or six years, and with it a woman of ordinary skill can spin about 1 lb. of yarn in a day of ten hours, earning thereby about 2d. There are at present in various parts of Japan, in all, 21 spinning factories worked by foreign machinery. Of four of these there is no information, but of the remainder, one has 120 spindles; eleven, 2,000 spindles; two, 3,000 spindles; two, 4,000 spindles; and one, 18,000 spindles.--_Journal Soc. of Arts._

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[Continued from SUPPLEMENT, No. 612, page 9774.]

CENTRIFUGAL EXTRACTORS.

By ROBERT F. GIBSON.

SUGAR MACHINES.--Besides separating the crystalline sugar and the sirup, secondary objects are to wash the crystals and to pack them in cakes. The cleansing fluid or "white liquor" is introduced at the center of the basket and is hurled against and passes through the sugar wall left from draining. The basket may be divided into compartments and the liquor guided into each. The compartments are removable boxes and are shaped to give bars or cakes or any form desired of sugar in mass. These boxes being removable cannot fit tightly against the liquor guides, and the liquor is apt to escape. This difficulty is overcome by giving the guides radial movement or by having rubber packing around the edges.

Sugar machines proper are of two kinds--those which are loaded, drained and then unloaded and those which are continuous in their working. The various figures preceding are of the first kind, and what has been said of vibrations applies directly to these.

The general advantages claimed for continuous working over intermittent are--that saving is made of time and motive power incident to introducing charge and developing velocity, in retarding and stopping, and in discharging; that, as the power is brought into the machine continuously, no shifting of belts or ungearing is necessary; and that there are less of the dangers incident to variable motion, either in the machine itself or the belting or gearing. The magma (the mixture of crystalline sugar and sirup) is fed in gradually, by which means it is more likely to assume a position of equilibrium in the basket.