Chapter 7

3. CaCO_{3} + (ClH)_{2} = CaCl_{2} + CO_{2} + H_{2}O.

That is, in 1 chloride of lime and carbonic acid react upon each other, producing chalk and nascent chlorine; in 2 the nascent chlorine reacts upon the water of the solution and decomposes it, producing hydrochloric acid and nascent oxygen, which bleaches; in 3 the hydrochloric acid just formed reacts upon chalk formed in 1, and produces calcium chloride and one equivalent of water, and at the same time frees the carbonic acid to be used again in the process of decomposing the chloride of lime.

When the process was first brought to the notice of the Lancashire bleachers, it met with an amount of opposition. Some bleaching chemists declared the process was not patentable, as fully half a century ago carbonic acid was known to decompose chloride of lime. The patentee's answer was emphatic, that carbonic acid gas had never been applied in bleaching before. After some delay one of the largest English cotton bleachers, Messrs. Ainsworth, Son & Co., Halliwell, Bolton, threw open their works for a fair test of the Thompson process on a commercial scale.

The result of trial was so satisfactory that a company was formed to work the patent. Soon after this the well-known authorities on the oxidation of cellulose, Messrs. Cross & Bevan and Mr. Mather, the principal partner in the engineering firm of Mather & Platt, of Salford, Lancashire, joined the company. For the last twelve months these gentlemen have devoted considerable attention to improving the original contrivance of Thompson, and a few weeks since they handed over to Messrs. Ainsworth the machinery and instructions for what they considered the most complete and best process of bleaching that has ever been introduced.

Recently a "demonstration" of the "Mather-Thompson" process of bleaching took place at Halliwell, and to which were invited numerous chemists and practical bleachers. Having been favored with an invitation, I propose to lay before your readers a concise report of the proceedings.

It is usual in this country to give a short preliminary boil to the cloth before it is brought in contact with the alkali, the object being to well scour the cloth from the loose impurities present in the raw fiber and also the added sizing materials. In the new process the waste or spent alkaline liquors of the succeeding process are employed, with the result that the bleaching proper is much facilitated. The economy effected by this change is considerable, but in the next operation, that of saponification, the new process differs even more widely from those generally in use. In England, "market" or "white" bleaching requires a number of operations. There is first the alkaline treatment divided into the two stages or processes of lime stewing and bowking in soda-ash, which only imperfectly breaks down the motes. There is consequently a second round given to the goods, consisting of a bowk in soda-ash, followed by the second and usually final chemicking. There is, therefore, much handling of the cloth, with the consequent increase of time and therefore expense.

Now, in the saponification process, the Mather-Thompson Company claim to have achieved a complete triumph. They use a "steamer keir," the invention of Mr. Mather. This keir is so constructed that it will allow of two wire wagons being run in and the door securely fastened. At the top of the keir is fixed a mechanical appliance for steaming the cloth. The steamer keir process consists essentially in:

1. The application of the alkali in solution and in its most effective form, viz., as caustic alkali, to each portion of fiber in such quantity as to produce the complete result upon that portion.

2. The immediate and sustained action of heat in the most effective form of steam.

Before the cloth is run into the steamer keir on the wire wagons, it is saturated with about twice its weight of a dilute solution of caustic soda (2° to 4° Twaddell = 0.5 to 1% Na_{2}O) at a boiling-temperature, when in the steamer keir it is exposed to an atmosphere of steam at four pounds pressure for five hours. This part of the process is entirely new. The advantage of using caustic soda alone in the one operation, such as I describe, has been long recognized, but hitherto no one has been able to effect this improvement. It will be observed that the Mather-Thompson process does away entirely with the use of lime and soda-ash in at least two boilings and the accessory souring operation. In the space of the five hours necessary for the steamer keir process the goods are thoroughly bottomed and all the motes removed, no matter what be the texture or weight of the cloth. After the cloth is washed in hot water it is removed from the steamer keir, then follows a rinse in cold water, and the goods are ready for the bleaching process.

In passing to the bleaching and whitening process, it may be necessary to say that thus far the original Thompson process has been entirely altered. Now we come to that part of the bleaching operation where the essential feature in Thompson's patent is utilized. The patentee has apparently thoroughly grasped the fact that carbonic acid has great affinity for lime and that it liberates, in its gaseous condition, the hypochlorous acid, which bleaches. The most perfect contact is realized between the _nascent_ hypochlorous acid resulting from its action and the fiber constituent in the exposure of the cloth treated with the bleaching solution to the action of the gas. The order of treatment is as follows:

(1) Saturation with weak chemic (1° Tw.), squeeze, and passage to gas chamber. (2) Wash (running). (3) Soda scald. (4) Wash. (5) Repetition of 1, but with weaker chemic (½° Tw.). (6) Wash. (7) Scouring.

The whole of the above operations are carried out on a continuous plan, the machinery being the invention of Mr. Mather. The cloth travels along at the rate of sixty or eighty yards a minute, and comes out a splendid white bleach. The company consider, however, that it is necessary in the case of some cloth to give a second treatment with chemic and gas, each of thirty seconds duration, with an intermediate scald in a boiling very dilute alkaline solution. Mr. Thompson originally claimed that the use of carbonic acid gas rendered the employment of a mineral acid for souring unnecessary. It is considered now to be advisable to employ it, and the souring is included, as will be observed, in the continuous operation.

The new process for treating cloth differs materially from that originally proposed by Mr. Thompson. His plan was to use an air-tight keir in conjunction with a gas-holder. It is obvious that the "continuous" process would not answer for yarns; Thompson's keir is, therefore, employed for these and all heavy piece-goods.

Thus far I have given a concise outline of the Mather-Thompson process of bleaching, which, it cannot be denied, differs materially from any system hitherto recommended to the trade. Beyond doubt the goods are as perfectly bleached by this process as by any now in use. The question arises, What pecuniary advantage does it offer? Mr. Manby, the manager of Messrs. Ainsworth, has informed me that he has bleached as much as ten miles of cloth by the new process, and is, therefore, entitled to be heard on the subject of cost. In regard to the consumption of chemicals, he estimates the saving to amount to (in money value) one-fourth; steam (coal), one-half; labor, one-half; water, four-fifths; time, two-thirds.

It might be well to contrast the process formerly employed by Messrs. Ainsworth with that they have recently adopted:

"MATHER-THOMPSON" SYSTEM.

Alkali. Bleach Acid Machine (chemic). Washes. / Saturate. (1) < \ Steam. / (2) Continuous | (chemic) | machine | (or keir if (2) < for yarns, | etc.). | (2a) Machine or \ pit sour. (3) Wash up for finishing.

ORDINARY SYSTEM.

Alkali. Bleach. Acid Machine Washes.

(1) Lime stew. (1) Wash. (2) Sour. (2) " (3) Gray bowk (3) " (soda ash). (4)I Chemic. (4) " (5) Sour. (5) " (6) White bowk. (6) " (7)II Chemic. (7) " (8) Sour. (8) "

It will be understood that 2 and 2a are merged into a single process by using the "continuous" machine. Of course, it will be understood that the cloth has in each case to be cleansed from size and loose impurities. The "Mather-Thompson" Company claim that their system takes twelve hours in the case of "market" or "white" bleaching. They reckon eight hours for the steaming process and four for bleaching and washing. This has to be compared with the old system, which generally takes forty hours, made up as follows: 8 treatments with reagents and the necessary washings, the former taking four hours and the latter one hour each.

The "Mather-Thompson" system has created considerable commotion in English bleaching circles. It is generally considered that the bleachers throughout the whole country will be compelled to adopt it, so great is the saving in time and cost. In commencing a bleachery, the cost of plant by this system is, I understand, less than by the old processes.--_Textile Colorist_.

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INSTRUMENTS FOR DRAWING CURVES.

By Prof. C.W. MacCord, Sc.D.

I. THE HYPERBOLA.

We are free to express the opinion at the outset, that for various reasons the draughtsman is likely to gain very little advantage by the use of mechanical devices for describing mathematical curves by continuous motion. Such instruments are as a rule not only complicated and expensive, but cumbersome and difficult of adjustment. It may be suggested, _per contra_, that these objections do not apply to the familiar combination of two pins and a string, for tracing the "gardener's ellipse." But we question the propriety of classing a string among strictly mechanical devices; it has its uses, to be sure, but in respect to perfect flexibility and inextensibility it cannot be relied on when rigid accuracy is required in drawing any of the conic sections.

Nevertheless, the construction of such apparatus affords a study which to some is fascinating, and even in the abstract is not devoid of utility. In each case a definite object is presented, and usually a choice of methods of attaining it; success requires a thorough knowledge of the properties of the curve in hand, while ingenuity is stimulated, and familiarity with expedients is cultivated, by the effort to select the most available of those properties, and to arrange parts whose motions shall be in accordance with them. Such exercise of the inventive faculties, then, is good training for the mechanician. And it must not be forgotten that a mechanical movement thus devised for one purpose very frequently is either itself applicable to a different one, or proves to be the germ from which are developed new movements which can be made so; the solution of one problem sometimes furnishing a hint or clew of great value in dealing with another.

We proceed, then, to describe a few instruments of this kind, which we believe to be new, in the hope that in the manner just pointed out they may render a greater service than that for which they are directly intended.

The first of these, shown in Fig. 1, is for the purpose of describing the hyperbola. The properties of the curve, upon which the action of the instrument depends, are illustrated in Fig. 2, where MM, NN, are the two branches of an hyperbola; C the center; AB the major axis; F and F' the foci. If now a tangent TT be drawn at any point as P of either branch, and a perpendicular let fall upon it from the nearer focus F be produced to cut at G a line drawn from P to the farther focus F', then this perpendicular will cut the tangent at a point I upon the circumference of a circle described about C upon AB as a diameter, and also the distance F'G will be equal to AB.

In Fig. 1, then, we have a crank CI, whose radius is equal to CB, half the major axis, turning about a fixed center C. Upon the crank-pin I is hung, so as to turn freely, a rigid cross composed of a long slotted piece TT, in which slides a block, and two cylindrical arms at right angles to it and in line with each other, the axis EE passing through I. The arm on the right slides through a socket pivoted at the focus F; the one on the left slides through a similar socket, which is pivoted at G to a third socket longer than the others, which again is pivoted at the focus F'; the distance F'G being equal to AB. Through this long socket slides a rod KP, the end P being formed into an eye, by which this rod is pivoted to the block which slides in the long slot, and thus controls the motion of the block; and the pivot at P is centrally drilled to carry the pencil. It is thus apparent that the center line of the slot TT must in all positions be tangent to the hyperbola PBR, which will be traced by the pencil, whose motions are so restricted as always to satisfy the conditions explained in connection with Fig. 2.

The apparatus as thus represented does not at first sight appear unduly complicated. But in order to render it adjustable, so that hyperbolas of varying eccentricities and on different scales may be drawn with it, several parts not here shown must be added. A frame must be provided, in which to arrange supports for the pivots at F and F', and these supports connected by a right and left handed screw, or equivalent means of altering the distance between the foci; the crank CI and the socket F'G must be of variable length, and these in each case would require to be carefully adjusted. So that, as we stated in the beginning, it is questionable whether a draughtsman of ordinary skill could draw the curve any more readily by the aid of such a piece of mechanism than he could without it; but it may claim a passing notice as a novel device, and the first one, we believe, for describing the hyperbola by a combination of rigid parts.

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EXPERIMENTS WITH FIBERS.

By Dr. THOMAS TAYLOR.

As Microscopist of the United States Department of Agriculture, I am frequently called upon to make investigations as to the character of textile fibers and fabrics, not only for the public generally, but also for several departments of the Government.

Textile fibers are presented both in the raw and as articles of manufacture. In the latter case they may have been dyed, stained, or painted. It is obvious that under these conditions the fibers should be subjected to chemical reaction to bring them as nearly as possible to their normal condition.

Considering how well the structures of the common textile fibers of commerce--cotton, flax, ramie, hemp, jute, Manila hemp, silk, and wool--have been investigated and minutely described by able and exact microscopists, I will in this paper confine myself chiefly to such experiments as I have personally made with textile fibers, treating them with chemical agents while under the objective.

While I am aware that this method is not wholly new, I am satisfied that comparatively little work has been done in this direction, and that a wide field is still open for future research.

As microscopists, we have to fortify ourselves in every way that will sustain, by truthful work, the value of the microscope as a means of research, sometimes conducting our experiments under the most trying circumstances. Fibers may be so treated by experts as to make it difficult to determine how their changed appearance has been effected, and it may happen in this age of experiment and of fraud that important decisions in commercial transactions and in criminal cases may depend on our observations.

DETECTION OF A FRAUD.

A case in point will illustrate this. While Dr. Dyrenforth was chief of the chemical division of the U.S. Patent Office, a person applied for a patent on what he called "cottonized silk," inclosing specimens. He claimed that he had discovered a mode of covering cotton fiber with a solution of silk which could be woven into goods of various kinds; in order to satisfy the public of the reality of his invention, he placed on exhibition, in various localities, specimens of silk-like goods in the form of ribbons in the web and skeins of thread, representing them to be "cottonized silk."

Dr. Dyrenforth was not satisfied that the so-called discovery was an accomplished fact, and he forwarded a few fibers of the material to the division of which I have charge for investigation. I subjected them to my usual tests, and found them to consist of pure silk, and I so reported to Dr. Dyrenforth, who rejected the application for a patent. The microscope was thus usefully employed to protect capitalists from imposition.

METHODS EMPLOYED.

It may be well to state briefly the methods I employed in detecting the real character of the material. The fibers were first viewed under plain transmitted light, secondly, polarized light and selenite plate. Since silk and cotton are polarizing bodies, "cottonized silk," if such could be made as described, would give, in this case, the prismatic colors of both fibers, and the complementary colors would differ greatly because of the great disparity of their respective polarizing and refractive powers.

The fact will be observed that a cotton fiber presents the appearance of a twisted ribbon when viewed by the microscope, while silk, owing to its cylindrical form, cannot twist on itself. It should also be considered that the diameter of "cottonized silk," so called, would be greater than that of a fiber of silk, because the silk solution would have to be applied to an actual thread of cotton, and not to a single cotton fiber, by reason of the shortness of the original hairs of the latter. Were a single fiber of such a combination put under a suitable objective, and a drop of nitric acid brought in contact with the fiber, it would be seen that the acid would destroy the silk and leave the fibers of cotton untouched, the latter being insoluble in cold nitric acid. The action of muriatic acid is similar in this respect. Were a fiber of cotton present and a drop of pure sulphuric acid placed on it, followed quickly by a drop of a transparent solution of the tincture of iodine, a peculiar change in the fiber would take place, provided the right proportion of acid be used. Cotton fiber, and especially flax fiber, under such conditions, forms into disks or beads of a beautiful blue color.

Fig. 1 represents a cotton fiber, and 2, 3, 4, 5 those of flax, as they appear under the acid treatment. Every textile amylaceous fiber is convertible into these forms, more or less, by strong sulphuric acid. The fibers of cotton, flax, and ramie are examples of amylaceous cellulose, that is to say, these fibers are converted into starchy matter by treatment with the last-named acid. Therefore combinations of these fibers in any composition of non-amylaceous fiber (ligneous or woody fiber) will be dissolved, leaving the latter unharmed; the woody fibers remaining will prove suitable objects for examination under the microscope.

COTTON MIXED WITH LINEN.

Again, it might be important to know whether a certain pulp or composition contained flax in combination with cotton. The composition might be of such a well-digested character as to destroy all appearance of normal form, that is to say, the "twisted ribbon" character of cotton, as well as that of the cylindrical and jointed characteristic of flax, might be lost to ordinary view. In this case make a watery solution of the pulp, spread it out thinly on a glass slide 3 inches by one, draw off any superfluous water, then add one or two drops of a strong solution of chromic acid to the preparation, and place over it a glass cover; when viewed by the microscope, any portion of the flax joints present will appear of a dark brown color; a solution of iodine has a similar effect. The brown portions of the joints are nitrogenous in character; cotton fibers are devoid of nitrogen.

EXPERIMENTS WITH FLAX.

A chemist of the Department of Agriculture had once occasion to make experiments with flax fibers, his object being to make them chemically pure; and to this end he treated them with excess of bleaching agents, thus rendering them of a beautiful white, silky appearance, to the naked eye; but when I examined them under the microscope, I found the brown nitrogenous matter of the joints still present, and on using the chromic acid test, they became deeply stained. A chemical solution of flax therefore would prove for some purposes undesirable, owing to the presence of this ligneous matter. A chemical solution of cotton which is destitute of ligneous matter will give a chemically pure solution. Cotton is therefore better adapted than flax for collodion compounds.

WOOL TESTED WITH ACID.

It is known that when wool is treated with the sulphuric acid of commerce or in strong dilute sulphuric acid, the surface scales of the fiber are liberated at one end, and appear, under a low power, as hairs proceeding from the body of the fibers. Wool may remain thus saturated in the acid for several hours, without appearing to undergo any further change, as far as is revealed by the microscope. When treated in mass in a bath of sulphuric acid, strength 60° B., for several minutes, and afterward quickly washed in a weak solution of soda, and finally in pure water and dried, it feels rough to the fingers, owing to the separation of the scales. I have preserved a small quantity of wool thus treated for the last twelve years, my object being to ascertain whether the chemical action to which it was exposed would impair its strength. As far as I can observe, without the aid of the proper tests, it seems to have retained its original tenacity. Wool thus treated seems to possess the property of resisting the ravages of the larvæ of the moth. This specimen, although openly exposed for the period named, suffered no injury from them. Under the microscope, the lubrications appear to have resumed their natural position, and appear finer.

From these experiments it would seem not improbable that a new article of commerce might be produced from wool thus treated, considering that it seems to be moth-proof.

I find in practice that when sable brushes are washed in a weak solution of pure phenic alcohol and afterward in warm water, the moth worm will not eat them. In this way I preserve sable brushes. I mention this chemical fact because it shows that a change of this material is brought about by the phenol as to its edibility, and this may explain why wool treated with sulphuric acid is rendered moth-proof.

I find that when brain matter has been subjected to a solution of weak phenic alcohol, weak alkaline solutions afterward applied fail to separate its nerve-cells on the process of maceration. (This is probably owing to its albuminoids being coagulated by the action of the phenol.) When brain matter is subjected to a weak solution of soda alone, the nerve-cells are easily separated by maceration, and well adapted for microscopic use.

TESTS OF DYED BLACK SILK.