Chapter 6

The results in the table were obtained by changing the strength of current by throwing in more or less of the battery. Like results can be obtained by varying the current through the cell by any of the other methods before specified. The above measurements were in dark.

5. _Dual state of selenium_.--My cells, when first made seem to have two states or conditions. In one, their resistance is very low, in the other it is high. When in the low state they are usually not very sensitive, in any respect. I therefore raise the resistance, by sending an intermittent or an alternating current though the cells, and in their new condition they at once become extremely sensitive to light, currents, and other influences. In some cases they drop to the low state again, and require to be again brought up, until, after a number of such treatments, they remain in the sensitive state. Occasionally a cell will persist in remaining in the insensitive state. The before mentioned treatment raises it up for a moment, but, before the bridge can be balanced and the resistance measured, it again drops into the low or insensitive state. Some cells have been thus stimulated into the high or sensitive state repeatedly, and every means used to make them stay there, but without avail; and they have had to be laid aside as intractable.

In the earlier stages of my investigations, before the discovery of this dual state and the method of changing a cell from the insensitive to the sensitive condition, hundreds of cells were made, finished, and tested, only to be then ruthlessly destroyed and melted over, under the impression that they were worthless. Now, I consider nothing worthless, but expect sooner or later to make every cell useful for one purpose or another.

The most singular part of this phenomenon is the wide difference in the resistance of the cells in the two states. In the low state, it may be a few ohms, or even a few hundredths of an ohm. In the high state, it is the normal working resistance of the cell, usually between 5,000 and 200,000 ohms, but is often up among the millions. The spectacle of a little selenium being stimulated, by a few interruptions of the current through it, into changing its resistance from a fraction of an ohm up to a million or several millions of ohms, and repeatedly and instantly changing back and forth, up and down, through such a wide range, we might almost say changing from zero to infinity, and the reverse, instantly, is one which suggests some very far-reaching inquiries to the electrician and the physicist. What is the nature of electrical conductivity or resistance, and how is it so greatly and so suddenly changed?

6. _Radio-electric current generators_.--My cells can be so treated that will generate a current by simple exposure to light or heat. The light, for instance, passes through the gold and acts upon its junction with the selenium, developing an electromotive force which results in a current proceeding from the metal back, through the external circuit, to the gold in front, thus forming a photo-electric dry pile or battery. It should preferably be protected from overheating, by an alum water cell or other well known means.

The current thus produced is radiant energy converted into electrical energy directly and without chemical action, and flowing in the same direction as the original radiant energy, which thus continues its course, but through a new conducting medium suited to its present form. This current is continuous, constant, and of considerable electromotive force. A number of cells can be arranged in multiple arc or in series, like any other battery. The current appears instantly when the light is thrown upon the cell, and ceases instantly when the light is shut off. If the light is varied properly, by any suitable means, a telephonic or other corresponding current is produced, which can be utilized by any suitable apparatus, thus requiring no battery but the selenium cell itself. The strength of the current varies with the amount of light on the cell, and with the extent of the surface which is lighted.

I produce current not only by exposure to sunlight, but also to dim diffused daylight, to moonlight, and even to lamplight. I use this current for actual working purposes, among others, for measuring the resistance of other selenium cells, with the usual Wheatstone's bridge arrangement, and for telephonic and similar purposes. Its use for photometric purposes and in current regulators will be mentioned further on. It is undoubtedly available for all uses for which other battery currents are employed, and I regard it as the most constant, convenient, lasting, readily used, and easily managed pile or battery of which I have any knowledge. On the commercial scale, it could be produced very cheaply, and its use is attended by no expense, inasmuch as no liquids or chemicals are used, the whole cell being of solid metal with a glass in front, for protection against moisture and dust. It can be transported or carried around as easily and safely as an electro-magnet, and as easily connected in a circuit for use wherever required. The current, if not wanted immediately, can either be "stored" where produced, in storage batteries of improved construction devised by me, or transmitted over suitable conductors to a distance, and there used, or stored as usual till required.

7. _Singing and speaking cells_.--When a current of electricity flowing through one of my selenium cells is rapidly interrupted, a sound is given out by the cell, and that sound is the tone having the same number of air vibrations per second as the number of interruptions in the current. The strength of the sound appears to be independent of the direction of the current through the cell. It is produced on the face of the cell, no sound being audible from the back of the cell. An alternating current also produces a sound corresponding to the number of changes of direction. Experiments also show that, if a telephonically undulating current is passed through the cell, it will give out the speech or other sound corresponding to the undulations of the current--and, furthermore, that the cell will sing or speak in like manner, without the use of a current, if a suitably varied light is thrown upon it while in closed circuit.

My experiments having been devoted especially to those branches of the subject which promised to be more immediately practically valuable, I have not pursued this inquiry very far, and offer it for your consideration as being not only interesting, but possibly worthy of full investigation.

GENERAL OBSERVATIONS ON THE PROPERTIES OF CELLS.

From the number of different properties possessed by my cells, it might be anticipated that the different combinations of those properties would result in cells having every variety of action. This is found to be the case. As a general rule, the cells are noteworthy in one respect only. Thus, if a cell is extremely sensitive to light, it may not be specially remarkable in other respects. As a matter of fact, however, the cells most sensitive to the light are also "U B cells."

The property of sensitiveness to light is independent of the power to generate current by exposure to light--the best current-generating cells being only very moderately sensitive to light, and some of the most sensitive cells generate scarcely any current at all. Current-generating cells are, almost without exception, "U B cells;" and the best current-generating cells are strongly polarized, showing a considerable change of resistance by reversing the direction of a current through them; and they are also strong "anode cells," i.e., the surface next to the gold offers a higher resistance to a battery current than the other surface of the selenium does. The power to generate a current is temporarily weakened by sending a battery current through the cell while exposed to light, in either direction. The current generated by exposure to light is also weakened by warming the cell, unless the cell is arranged for producing current by exposure to heat.

The properties of sensitiveness to light and to change of battery power are independent of each other, as I have cells which are sensitive to change of current but absolutely insensitive to light--their resistance remaining exactly the same whether the cells are in darkness or in sunlight. I also have cells which are sensitive to light, but are unaffected by change of battery power, or by reversing the direction of the current through them.

The sensitiveness to change of battery power is also independent of the sensitiveness to reversal of direction of the current. Among the best "L B cells," some are "anode cells" and others are "cathode cells," while still others are absolutely insensitive to reversal of current or to the action of light.

_Constancy of the resistance_.--A noticeable point in my cells is the remarkable constancy of the resistance in sunlight. Allowing for differences in the temperature, the currents, and the light, at different times, the resistance of a cell in sunlight will remain practically constant during months of use and experiments, although during that time the treatments received may have varied the resistance in dark hundreds of thousands of ohms--sometimes carrying it up, and at others carrying it down again, perhaps scores of times, until it is "matured," or reaches the condition in which its resistance becomes constant.

As has already been stated, the sensitiveness of a cell to light is increased by proper usage. This increased sensitiveness is shown, not by a lowered resistance in light, but by an increased resistance in dark. This change in the cells goes on, more or less rapidly, according as it is retarded or favored by the treatment it receives, until a maximum is reached, after which the resistance remains practically constant in both light and dark, and the cell is then "matured," or finished. The resistance in dark may now be 50 or even 100 times as high as when the cell was first made, yet, whenever exposed to sunlight it promptly shows the same resistance that it did in the beginning. The various treatments, and even accidents, through which it has passed in the mean time, seem not to have stirred its molecular arrangement under the action of light, but to have expended their forces in modifying the positions which the molecules must normally assume in darkness.

_Practical applications_.--There are many peculiarities of action occasionally found, and the causes of such actions are not always discernible. In practice, I have been accustomed to find the peculiarities and weaknesses of each cell by trial, developing its strongest properties and avoiding its weaknesses, until, when the cell is finished, it has a definite and known character, and is fitted for certain uses and a certain line of treatment, which should not be departed from, as it will be at the risk of temporarily disabling it. In consequence of the time and labor expended in making cells, in the small way, testing, repairing damages done during experiments, etc., the cost of the cells now is unavoidably rather high. But if made in a commercial way, all this would be reduced to a system, and the cost would be small. I may say here that I do not make cells for sale.

The applications or uses for these cells are almost innumerable, embracing every branch of electrical science, especially telegraphy, telephony, and electric lighting, but I refrain from naming them. I may be permitted, however, to lay before you two applications, because they are of such general scientific interest. The first is my

_Photometer_.--The light to be measured is caused to shine upon a photo-electric current-generating cell, and the current thus produced flows through a galvano-metric coil in circuit, whose index indicates upon its scale the intensity of the light. The scale may be calibrated by means of standard candles, and the deflections of the index will then give absolute readings showing the candle power of the light being tested. Or, the current produced by that light and that produced by the standard candle may be compared, according to any of the known ways of arranging and comparing different lights--the cell being lastly exposed alternately to the two lights, to see if the index gives exactly the same deflection with each light.

This arrangement leaves untouched the old difficulty in photometry, that arising from the different _colors_ of different lights. I propose to obviate that difficulty in the following manner. As is well known, gold transmits the green rays, silver the blue rays, and so on; therefore, a cell faced with gold will be acted upon by the green rays, one faced with silver by the blue rays, etc. Now, if we construct three cells (or any other number), so faced that the three, collectively, will be acted upon by all the colors, and arrange them around the light to be tested, at equal distances therefrom, each cell will produce a current corresponding to the colored rays suited to it, and all together will produce a current corresponding to all the rays emitted by the light, no matter what the proportions of the different colors may be. The three currents may act upon the same index, but each should have its own coil, not only for the sake of being able to join or to isolate their influences upon the index, but also to avoid the resistances of the other cells. If a solid transparent conductor of electricity could be found which could be thick enough for practical use and yet would transmit all the rays perfectly, i.e., transmit white light unchanged, that would be still better. I have not yet found a satisfactory conductor of that kind, but I think the plan stated will answer the same purpose. This portion of my system I have not practically tested, but it appears to me to give good promise of removing the color stumbling-block, which has so long defied all efforts to remove it, and I therefore offer it for your consideration.

_Photo-electric regulator_.--My regulator consists of a current-generating cell arranged in front of a light, say an electric lamp, whose light represents the varying strength of the current which supports it. The current produced in the cell by this light flows through an electro-magnetic apparatus by means of which mechanical movement is produced, and this motion is utilized for changing resistances, actuating a valve, rotating brushes, moving switches, levers, or other devices. This has been constructed on a small scale, and operates well, and I think it is destined to be largely used, as a most sensitive, simple, and perfect regulator for currents, lights, dynamos, motors, etc., etc., whether large or small.

In conclusion, I would say that the investigation of the physical properties of selenium still offers a rare opportunity for making very important discoveries. But candor compels me to add that whoever undertakes the work will find it neither an easy nor a short one. My own experience would enable me to describe to you scores of curious experiments and still more curious and suggestive results, but lack of time prevents my giving more than this very incomplete outline of my discoveries.

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ELECTRICITY APPLIED TO THE MANUFACTURE OF VARNISH.

Messrs. Müthel & Lütche, of Berlin, recommend the following process for the manufacture of varnish: The oils are treated by gases or gaseous mixtures that have previously been submitted to the action of electric discharges. The strongly oxidized oxygenated compounds that are formed under such circumstances give rise, at a proper elevation of temperature, to compounds less rich in oxygen, and the oxygen that is set free acts upon the fatty acid that it is proposed to treat. A mixture of equal parts of chlorine and steam may be very advantageously employed, as well as anhydrous sulphuric acid and water, or oxygen, anhydrous sulphuric acid and protoxide of nitrogen, nitrogen, oxygen, and hydrogen, protoxide of nitrogen and air, or oxygen, and so on.

The apparatus is shown in section in the accompanying engraving; a is a steam-pipe running from the boiler to the motor. From this pipe branch conduits, b, that enter the vessels, B, in which the treatment is effected, and that run spirally through the oil. At the lower part of the vessel, B, there is tube wound into a flat spiral, and containing a large number of exceedingly small apertures.

The oxidizing apparatus is shown at p. The gaseous mixture enters through the tube, n, traverses the apparatus, p, and enters the vessel, B, through the tubes, g and D. Fig. 2 gives the details of the oxidizing apparatus, which consists of two concentric glass tubes, A and F, soldered at x. A is closed beneath and held in a cylinder, C; F contains a small aperture through which passes a tube, E. The gaseous mixture enters through the latter, traverses the annular space between the tubes, A and F, and then makes its exit through H, whence it goes to a similar apparatus placed alongside of the other. The shaded parts of the engraving represent bodies that are good conductors of electricity and that communicate with the two poles of any electrice source whatever.

The operation is as follows: After opening the tube, e, linseed oil is introduced into the vessel, B, until the latter is half full, and, after this, e is closed and the worm, S, is allowed to raise the temperature to between 60° and 80°. Then the cock of the tube, d, which communicates with an air pump, is opened, and the pressure is diminished to about 730 mm. of mercury. At this moment the oxidizing apparatus are put in communication with an induction bobbin that is interposed in the circuit of a dynamo, while through the tube, n, there is made to enter a mixture of equal parts (in volume) of sulphurous acid, oxygen, and air. At the same time, the cock of the tube, g, is opened, while the stirrer, T, is set in motion. In this way we obtain, in a much shorter time than by ordinary processes, a very liquid, transparent varnish, which, when exposed to the air, quickly hardens. It is possible, with the same process, to employ a mixture (in volumes) of two parts of protoxide of nitrogen with one and a half parts of atmospheric air, or even protoxide of nitrogen alone.

When it is judged that the operation is finished, the tube, g, is opened, the stirrer is stopped, and the tube, c, is opened after d has been closed. The steam then forces the varnish to pass through the tube, f, and traverse the washing apparatus, which is filled half full of water, that is slightly ammoniacal, and is heated by a circulation of steam, S. Finally, the product, washed and free from every trace of acid is collected upon making its exit from the tube, h.--_La Lumiere Electrique._

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NAGLO BROTHERS' TELEPHONE SYSTEM.

We borrow from the _Elektrotechnische Zeitung_ the following details in regard to the telephonic installations made by the Brothers Naglo at Berlin. Fig. 1 gives the general arrangement of a station, where J is an inductor set in motion through a winch, K, and a pair of friction rollers; W, a polarized call; U, an ordinary two-direction commutator; B, a lightning protector; and L and T, the two terminals of the apparatus, one of them connecting with the line and the other with the earth. The interesting point of this system is the automatic communication which occurs when the inductor, J, is moved. At the same moment that the winch, K, is being moved, the disk, P, is carried from right to left and brought into contact with the spring, f_{2}. As soon as the winch is left to itself a counter-spring forces the disk, P, to return to a contact with the spring, f_{1}. Figs. 2 and 3 show the details of such communication. The winch, K, is keyed to one of the extremities of a sleeve that carries the disk, P, at its other extremity. This sleeve is fixed upon the axle of the first friction roller, that is to say, upon the axle that controls the motion of the inductor, and is provided at the center with two helicoidal grooves, e, at right angles with one another. In these grooves slides a tappet, n, connected with the axle.

Under the influence of the counter-spring at the left of the disk, P, the latter constantly tends to occupy the position shown in Fig. 2, which is that of rest. As soon as the winch, K, is revolved, whatever be the direction of the motion, the axle can only be carried along when the tappet, n, has come to occupy the position shown in Fig. 3, that is to say, when the disk has moved from right to left a distance corresponding to the fraction of the helix formed in the sleeve.

This stated, it is easy to understand the travel of the currents. Fig. 1 shows the station at rest. The current that arrives through L passes through the lightning protector, the body of the commutator, U, the terminal, v, and the call, W, bifurcates at P, and is closed by the earth. The inductor is in circuit, but, as it is in derivation, upon a very feeble resistance, v, nearly the whole of the current passes through the latter. When it is the station that is calling, the call, W, is put in derivation upon the circuit, f_{2} p, h, so that the portion of the circuit that passes through q W v is exceedingly feeble, and incapable of operating the bell of the post that is calling.

Finally, when the telephone is unhooked, the inductor, J, and the bell, W, are thrown out of circuit, and the telephone is interposed between d and i, that is, between L and T.--_La Lumiere Electrique_.

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THE GERARD ELECTRIC LAMP.

In the Gerard incandescent lamp the carbons have the form of a V. They are obtained by agglomerating very finely powdered carbon, and passing it through a draw plate. At their extremity they are cemented together with a small quantity of carbon paste, and their connection with the platinum conducting wires is effected by means of a cylinder of the same paste surmounted by a cone. These couplings secure a good contact, and, by their dimensions, prevent the attachments from becoming hot and consequently injuring the carbon at this point. The cone forms a connection of decreasing section, and prevents the carbon from getting broken during carriage.

This process of manufacture permits of obtaining lamps of all intensities, from 3 candles up. The following, according to Mr. Gerard, are the consumptions of energy in each size of lamp:

Candles. Volts. Amperes. No. 0. 10 16 1.5 " 1. 25 25 2 " 2. 50 30 2.5

It will be seen that these lamps require a relatively intense current with much less fall of potential than the Swan, for example--this being due to the diameter of the filament. But, what is an inconvenience as regards mounting, if we wish to supply them by ordinary machines (for they must be mounted in series of 3 on each derived circuit if the machine gives, as most frequently the case, 100 volts), is an advantage as regards the quality and steadiness of the light and the duration of the lamps.

The part in which the energy is expended is homogeneous, as might be supposed from the mode of manufacture, and as may be ascertained from a microscopical examination, and it is exempt from those variations in composition that are found in carbons of a vegetable nature, like the Edison. Besides, being of relatively large diameter, the lamp is capable of supporting a very great increase of temperature.