Scientific American Supplement, No. 312, December 24, 1881
Chapter 6
When the current of electricity enters the battery, the Pb3O4 on the positive plate is reduced to Pb, and the oxygen so set free attacks the Pb3O4 on the negative plate, and oxidizes it to PbO2. In this chemical action, caloric is occluded in the Pb and unlocked in the PbO2, but a much greater amount of caloric is locked up than is unlocked, although the amount of oxygen used in both cases is precisely the same, which has been fully explained in the oxidation of carbon.
Now after the battery has been thus charged and the wires disengaged, the chemical action ceases for want of the reducing agent (_dynamic caloric_), and the apparatus may be held at rest, or transported to any distance required. When it is desired to utilize the force thus stored, the poles are changed by grounding the positive wire, and attaching the other to the conduit through which the electricity is to flow. The chemical action is thus reversed, and the PbO2 is reduced to Pb3O4, the oxygen thus set free attacks the Pb on the other plate, oxidizing it to Pb3O4, thus unlocking all the caloric which was occluded by the first action. In a battery of this kind weighing 75 pounds, we are informed by Sir William Thomson, that one million foot pounds of force may be stored, and again set free for use.
Thus we find that the principle upon which the Faure battery is formed is not new, and the prime factor producing the phenomena is the same as has been shown to have caused all other phenomena referred to, and indeed the principle is the same as now employed by the author in the basic dephosphorizing process, i.e., caloric is occluded in phosphorus by smelting in a blast furnace, and unlocked in the converter, for the purpose of securing the fluidity of the metal during treatment. The difference being, that one is done by non-luminous, while the other is by luminous combustion.
If we consider the phenomenon of light, we find that it is due to the same force. As before stated, when we oxidize carbon, or hydrogen, as in the rapid combustion of wood, oil, or coal, the escaping caloric flies off with such great speed as to cause the molecules in the circumambient medium to assume a velocity which exhibits luminosity. Thus the light produced by burning candles, oil, gas, wood, and coal, is caused by the same prime factor, dynamic caloric.
The force of caloric is imponderable and invisible, and is only known by its effects. We do know that it is occluded in metals and other material, because we can unlock it and set it free, or we can transfer it from one body to another, and by measuring its effects, we can determine its quantity. We know that it prefers to travel over one vehicle more than another, and by this knowledge we are able to insulate it, and thus conduct it in any direction desired. The materials through which it passes with the greatest freedom are called conductors, and the materials which most retard its passage, non-conductors; but these terms must be taken in a comparative sense only, as in fact there are no absolute non-conductors of dynamic caloric, or of what we call electricity.
The dynamo-electric generator simply draws the dynamic caloric from the air or earth, or both, and confines it in an insulated path. Now if that path be a No. 10 wire, the conduit may be sufficient to permit the caloric to pass without increasing the molecular velocity of the metal to an appreciable degree, but if we cut the No. 10 wire and insert a piece of No. 40 platinum wire in the path, the amount of caloric flowing through the No. 10 wire cannot pass through the No. 40 wire, and the resistance so caused increases the molecular velocity of the No. 40 wire to such degree as to exhibit the phenomenon of incandescence, and this is the incandescent electric light. And if we consider the carbon light, we find that the current of caloric, in passing from one pencil to the other, produces a molecular velocity of luminosity in the adjoining atmosphere, and in addition a portion of the carbon is consumed, which sets free an additional amount of caloric, at a very high velocity, hence the intensity of the carbon electric light is largely due to the dynamic caloric unlocked from the pencils, and thus we find that the electric light produced by either method is due to the action of dynamic caloric.
Taking this theory based upon physical science, and the facts which we know pertaining to electricity, I conceive that caloric exists in two conditions. _Static caloric_ is what we call _latent heat_, and _dynamic caloric_ is what we call _electricity_. Therefore what may we expect of it (electricity) is merely a matter of economy in the development and utilization of dynamic caloric; in other words, can we unlock static caloric by non-luminous combustion, and thus develop _dynamic caloric as a first power_ more economically per foot pound than we now do or can hereafter do by luminous combustion? Second, can we utilize water and wind for the production of _dynamic caloric as a first power_? Third, can we utilize the differential tension of dynamic caloric in the earth and the atmosphere as _a first power_? Fourth, will it pay to use luminous combustion as a first power to generate dynamic caloric as _a second power_?
WHAT MAY WE EXPECT OF IT.
Let us take the steam engine, and see what we are now doing by luminous combustion. Good Pittsburg coal contains 87 per cent. of carbon, 5 per cent. of hydrogen, 2 per cent. of oxygen and 6 per cent. of ash; we therefore have in one pound of such coal:
8,080 × 9 14,544 × 87 --------- = ----------- = 12,653 units in carbon. 5 100
34,662 × 9 62,391 × 5 3,119 units in hydrogen. ---------- = ---------- = ------ 5 100 15,772 units in coal.
15,772 × 772[2] = 12,175,984 foot pounds of energy is occluded in the static caloric contained in one pound of such coal.
[Footnote 2: Dr. Joule--foot pounds in one unit.]
A horse-power is estimated as capable of raising 33,000 pounds one foot high per minute, and for this reason it is termed 33,000 foot pounds per minute. So we have 33,000 × 60 = 1,980,000 foot pounds per hour, as a horse-power.
The best class of _compound condensing_ engines,[3] with all the modern improvements, require 1.828 pounds of coal per 1 h.p. per hour. Thus we have--
12,175,984 × 1.828 .................22,257,699 Foot pounds in one h.p. .............1,980,000 ---------- Foot pounds lost per h.p. ..........20,277,699
Per cent utilized per h.p. ..............8.94 Per cent lost per h.p. .................91.06 ------ 100.00
[Footnote 3: "American Engineer," Vol. II., No. 10, page 182.]
In the ordinary practice of stationary non-condensing engines, from three to four pounds of coal are required per horse-power per hour. Now, taking the best of this class at 3 pounds, we have--
12,175,984 × 3 = 36,527,952 One h.p. 1,980,000 ---------- Loss per h.p. 34,547,952
Per cent utilized per h.p. 5.42 Per cent lost per h.p. 94.58 ------ 100.00
From these facts it may be assumed that after making due allowance for variable qualities of the coal, the steam engine process, as at present practiced, will not utilize more than from 5 to 10 per cent. of the energy contained in the fuel used. It will thus be seen that the process of converting static to dynamic caloric by luminous combustion, by means of the steam engine, is an exceedingly wasteful and costly method, and leaves much room for economy.
Taking an ordinary grade of petroleum as consisting of 13 per cent. hydrogen, 78 carbon, 6 oxygen, 3 nitrogen and ash, we have as its energy in foot pounds per pound of oil--
62,391 × 13 } ----------- = 8,110 H. } 100 } } 19,454 units. 14,544 × 78 } ----------- = 11,344 C. } 100 }
19,454 × 772 = 15,018,488 foot pounds. Thus, while our best coal contains twelve million, the petroleum contains fifteen million foot pounds of occluded energy in each pound, which is equal to 118,000,000 foot pounds, or 60 horse power for one hour, from one gallon of such oil.
At present electricity is generated by two methods, and both of these are _second powers_. Metals are smelted by luminous combustion as a first power, and then oxidized by non-luminous combustion as a _second power_, and coal is consumed by luminous combustion, by which steam is generated as a first power, to drive a dynamo-generator whereby electricity is obtained as a _second power_. Now, of the two methods, the latter is much the cheaper, and as I have shown that the best compound condensing engines only utilize 8.94, and a fair average single cylinder condensing engine only utilizes 5.42 per cent. of the energy of the fuel consumed, and as at the best not over 70 per cent. of the foot pounds obtained from the engine can be utilized as electricity, from which we must deduct loss by friction, etc., it will be readily seen that not more than 5 per cent. of the energy of the fuel can be developed by the dynamo-generator as electricity by the present method.
The great want of the present age is a process by which the static caloric of carbon or a hydrocarbon maybe set free by non-luminous combustion; or, in other words, a process by which coal or oil may be oxidized at a low degree, within an insulated vessel; if this can be accomplished (and I can see no reason why we should not look for such invention), we would be able to produce from twelve to fifteen million foot pounds of energy (electricity) from one pound of petroleum, or from ten to twelve million foot pounds from one pound of good coal, which would be a saving of from 90 to 95 per cent. of present cost, and leave the steam engine for historical remembrance.
Electricity may be generated by water or wind power to great advantage, and conveyed to a distance for motive power. The practicability of generating electricity at Niagara by which to propel trains to New York and return may be considered almost settled; and I conceive a second invention of importance which is now needed is an apparatus by which the rising and falling tides may be utilized for driving dynamo machines, by which electricity may be generated for lighting the coast cities, and it is not unreasonable to expect that such an apparatus will soon be provided; and in such an event gas companies would suffer.
It is a well known fact among electricians that the volume and tension of electricity vary both in the earth and in the atmosphere at different sections of the earth's surface, and I conceive that we may yet find means of utilizing this differential tension of electricity; indeed, it is reported that during a recent storm the wires of an ocean cable were grounded at both ends and a sufficient current for all practical purpose flowed from the European to the American continent, with all batteries removed, showing that the tension was so much greater in Europe as to cause the electricity to flow through the copper cable to this side in preference to passing through the earth or the sea. It is also said that during an east-going storm it was found impossible to work the telegraph lines between New York and Buffalo, but on taking off the batteries at both ends and looping the ends of the wire in the air, that a constant current of electricity passed from Buffalo to New York, and the line was kept in constant use in that direction without any battery connection until the storm abated. Now, how far or to what advantage we may be able to utilize this differential tension of electricity in the earth and the air, we cannot now say; but I think that we may justly look for valuable developments in this direction.
If, as I verily believe, a process will soon be discovered by which dynamic caloric can be produced by the oxidation of petroleum with non-luminous combustion in an insulated chamber, as we now oxidize zinc, electricity will then be obtained from so small a weight, and at such a low cost, as to insure aerial navigation beyond a doubt. Not with balloons and their cumbrous inflations, but with machines capable of carrying the load, and traveling by displacement of the air at high velocities. Therefore we may expect that aerial navigation will be developed in the near future to be one of the greatest enterprises of the world.
And lastly, will it pay to use luminous combustion as a first power for generating dynamic caloric for use as a second power, as is now practiced?
At the University of Pennsylvania, in Philadelphia, gas is consumed in an Otto gas engine, which drives a Gramme generator; and the lecture room is lighted with electricity, and I am informed that the light is both better _and cheaper_ than when they used the gas in the ordinary gas burners. Hence we may expect to see gas consumed to advantage for producing electric lights.
Considering the difficulties of transmitting steam power to a considerable distance, and the comparative great cost of running small engines, it is more than likely that electricity as at present generated will be found to be economical for driving small motors.
Having thus endeavored to explain what electricity is, and the laws which govern the occlusion of static caloric, and the development of dynamic caloric (electricity), in conclusion I call the attention of the inventors of the age to the great need of a process for oxidizing coal or oil at a low degree, within an insulated vessel. With such an invention electricity would be obtained at such a low cost that it would be used exclusively to light and heat our houses, to smelt, refine, and manipulate our metals, to propel our cars, wagons, carriages, and ships, cook our food, and drive all machinery requiring motive power.
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ELECTRIC LIGHT APPARATUS FOR PHOTOGRAPHIC PURPOSES.
By A.J. JARMAN.
For some time past it has been the desire of many photographers to have at hand a ready means of producing a powerful and highly actinic artificial light, suitable for the production of negatives, and easily controllable. Several forms of apparatus have been designed, and I believe have been, to a certain extent, employed successfully in portraiture. But it has been well known for many years that the electric light was just the light that would answer the photographer's requirements, owing to its possessing great actinic power; but the cost of its production was too great for general adoption; indeed, such might be said of it now as far as dynamo-electric machines and steam or gas motors are concerned, for the majority of photographers. It is true that several influential photographers have already adopted the use of the electric light for portraiture, but the primary cost of the apparatus employed by these firms is far beyond the reach of most portraitists. The apparatus about to be described is one that has been carefully worked out to meet the wants of the photographer in almost every particular; in fact, with this apparatus, portraits can, and have been, produced in an ordinary sitting room, as good and as perfect as if taken in a well-lighted studio.
The generator of the electric current consists of a series of voltaic elements of zinc and carbon--forty-eight in number--these elements being made up of ninety-six zinc plates and forty-eight carbon plates; thus the generator consists of forty-eight voltaic elements arranged in rows of twelve; they are all carefully screwed upon suitable bars of wood, and these bars are joined by other cross bars, which bind the whole in a compact form; the battery being suitably connected so as to produce a current of very high electro-motive force, and so arranged over their exciting trough that the plates can be raised or lowered at will, as seen in Fig. 1, which will explain itself almost at first sight.
The troughs are made of mahogany, put together with brass screws, and well saturated with an insulating compound which also makes them acid proof; the cells are charged with a saturated solution of bichromate of potash, to which has been added twenty fluid ounces of sulphuric acid to each gallon.
To produce the electric current, all that is needed is to lower these suspended elements down into the trough, having previously connected the wires as shown in Fig. 1, to the electric lamp, Fig 2. At once a light starts up, between the carbon pencils, of a thousand-candle power or more. With a light of this power, a large head on cabinet or carte size plate may be produced in three or four seconds.
The generator occupies a floor space of three feet six inches by two feet, and stands two feet six inches high. The cells will cost 5s. to charge, and will produce upward of sixty negatives before being exhausted. All that is necessary, in recharging, is to lift the elements up out of the way, take out the troughs by their handles and empty them, charging them again by means of a toilet jug. When replaced, the whole apparatus is fit for use again; the whole of the above operation occupies but a quarter of an hour, and as there are no earthenware cells employed, there is no fear of breakage.
The small amount of labor and cost of working the above apparatus will compare favorably with the production of the electric light from a dynamo-electric machine for the photographer, and when we consider that the cost of the whole of the above apparatus, consisting of a generator automatic lamp, reflector, and all the necessary appendages, is less then one-tenth of the dynamo machine, motor, shafting, etc., to produce the same result, it would seem to have a greater claim for its adoption with those who wish to employ the electric light, whether for work at night, use in the sitting room, or to assist daylight on the dark and foggy days of winter.
Fig. 2 shows the arrangement of the electric lamp. A is the automatic regulator; B, the reflector; C, top extension of the reflector; D, small tissue paper screen to prevent the intense arc-rays from coming in contact with the sitter; E, stand with sliding rod. This appendage can be wheeled about with ease, as it is arranged to run upon four casters.
When the generator is in use it may be placed within easy reach of the operator, so that the exposure may be made by lowering the elements in their troughs just for the requisite time, and withdrawing immediately the exposure is made; there is no need to fear any inconvenience from deleterious fumes as none are given off, so it may be used in any studio or sitting-room without any inconvenience from this source, and as far as many trials have gone, it seems to meet every requirement demanded by the photographer for the production of portraits by means of the electric light.--_Photo. News._
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DESRUELLES'S ELECTRIC LIGHTER
The little apparatus shown in the accompanying cut will certainly find favor with smokers, as well as with persons generally who often have need of a fire or light. It forms one of the most direct applications of dry piles of all the systems on the Desruelles plan. Instead of filling piles with a liquid, this plan contemplates the introduction into them of a sort of asbestos sponge saturated with an acid or any suitable solution. In this way there is obtained the advantage of having a pile which is in some sort _dry_, that may be moved, shaken, or upset without any outflow of liquid, and which will prove of special value when applied to movable apparatus, such as portable lighters, alarms on ships, railroads, etc. It is hardly necessary to say that while the introduction of this inert substance diminishes the volume of the liquid, the electro-motive force of the pile is thereby in nowise affected, but its internal resistance is increased. This, however, is of no consequence in the application under consideration. The lighter consists of a small, round, wooden box containing the pile, and surmounted by a spirit lamp. A platinum spiral opposite the wick serves for producing the light. The pile is a bichromate of potash element, in which there is substituted for the liquid a solution of bichromate identical with that used in bottle piles. The zinc is suspended from a small lever, in which it is only necessary to press slightly to bring the former in contact with the asbestos paste, when, the zinc being attached, a current is set up which traverses the spiral, heats it to redness, and lights the spirit. The pile, when once charged, may be used for several hundred lightings. When the spiral no longer becomes red hot, it is only necessary to replace the paste--an operation of extreme simplicity. When the pressure is removed from the little lever, the zinc, being raised, is no longer acted upon by the liquid with which the asbestos is saturated. Mr Desruelles is constructing upon the same principle a gas lighter, the pile of which is fixed at the extremity of a handle whose length varies with the height of the gas burners to be reached. These little domestic apparatus are being exhibited at the Paris Electrical Exhibition.
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SOLENOID UNDERGROUND WIRES IN PHILADELPHIA.
The _Evening Bulletin_ of the 29th October has the following:
This afternoon a series of experiments were conducted at the Public Buildings which will be of great interest to electricians all over the country, and upon which the success of a number of underground telegraph projects in different parts of the United States depends. In all projects of this kind the problem which has given most trouble to inventors has been to overcome the induction. In other words, electric currents will leave their original conductors and pass to other conductors which may be near at hand. This interchange of currents may take place without seriously hindering ordinary telegraphy, as the indicators are not delicate enough to detect the induction. When telephones came into use, however, the induction became a great source of trouble to electricians, it often being the case that the sounds and influences from without were sufficient to drown out sounds in a telephone. To-day's experiment was conducted by Mr. J.F. Shorey, a well-known electrician, who exhibited Dr. Orazio Lugo's cables for electric light, telephone, and telegraphic purposes.
A large number of prominent electricians were present, including the following: General J.H. Wilson, President of the N.Y. and N.E. Railroad, of Boston; Messrs. Frank L Pope, S.L.M Barlow, George B. Post, Charles G. Francklyn, Col. J.F. Casey, W.H. Bradford, and Selim R. Grant, of New York; James Gamble, General Manager of the Mutual Union Telegraph Co.; T.E. Cornich and W.D. Sargent, of the Bell Telegraph Co.; S.S. Garwood and J.E. Zeublen, of the Western Union, and others.