Scientific American Supplement, No. 275, April 9, 1881
Chapter 6
The first glimpse of this splendid generalization was caught in 1845, five and thirty years ago, by that prince of pure experimentalists, Michael Faraday. His reasons for suspecting some connection between electricity and light are not clear to us--in fact, they could not have been clear to him; but he seems to have felt a conviction that if he only tried long enough and sent all kinds of rays of light in all possible directions across electric and magnetic fields in all sorts of media, he must ultimately hit upon something. Well, this is very nearly what he did. With a sublime patience and perseverance which remind one of the way Kepler hunted down guess after guess in a different field of research, Faraday combined electricity, or magnetism, and light in all manner of ways, and at last he was rewarded with a result. And a most out-of-the-way result it seemed. First, you have to get a most powerful magnet and very strongly excite it; then you have to pierce its two poles with holes, in order that a beam of light may travel from one to the other along the lines of force; then, as ordinary light is no good, you must get a beam of plane polarized light, and send it between the poles. But still no result is obtained until, finally, you interpose a piece of a rare and out-of-the-way material, which Faraday had himself discovered and made--a kind of glass which contains borate of lead, and which is very heavy, or dense, and which must be perfectly annealed.
And now, when all these arrangements are completed, what is seen is simply this, that if an analyzer is arranged to stop the light and make the field quite dark before the magnet is excited, then directly the battery is connected and the magnet called into action, a faint and barely perceptible brightening of the field occurs, which will disappear if the analyzer be slightly rotated. [The experiment was then shown.] Now, no wonder that no one understood this result. Faraday himself did not understand it at all. He seems to have thought that the magnetic lines of force were rendered luminous, or that the light was magnetized; in fact, he was in a fog, and had no idea of its real significance. Nor had any one. Continental philosophers experienced some difficulty and several failures before they were able to repeat the experiment. It was, in fact, discovered too soon, and before the scientific world was ready to receive it, and it was reserved for Sir William Thomson briefly, but very clearly, to point out, and for Clerk-Maxwell more fully to develop, its most important consequences. [The principle of the experiment was then illustrated by the aid of a mechanical model.]
This is the fundamental experiment on which Clerk-Maxwell's theory of light is based; but of late years many fresh facts and relations between electricity and light have been discovered, and at the present time they are tumbling in in great numbers.
It was found by Faraday that many other transparent media besides heavy glass would show the phenomenon if placed between the poles, only in a less degree; and the very important observation that air itself exhibits the same phenomenon, though to an exceedingly small extent, has just been made by Kundt and Rontgen in Germany.
Dr. Kerr, of Glasgow, has extended the result to opaque bodies, and has shown that if light be passed through magnetized _iron_ its plane is rotated. The film of iron must be exceedingly thin, because of its opacity, and hence, though the intrinsic rotating power of iron is undoubtedly very great, the observed rotation is exceedingly small and difficult to observe; and it is only by a very remarkable patience and care and ingenuity that Dr. Kerr has obtained his result. Mr. Fitzgerald, of Dublin, has examined the question mathematically, and has shown that Maxwell's theory would have enabled Dr. Kerr's result to be predicted.
Another requirement of the theory is that bodies which are transparent to light must be insulators or non-conductors of electricity, and that conductors of electricity are necessarily opaque to light. Simple observation amply confirms this; metals are the best conductors, and are the most opaque bodies known. Insulators such as glass and crystals are transparent whenever they are sufficiently homogeneous, and the very remarkable researches of Prof. Graham Bell in the last few months have shown that even _ebonite_, one of the most opaque insulators to ordinary vision, is certainly transparent to some kinds of radiation, and transparent to no small degree.
[The reason why transparent bodies must insulate, and why conductors must be opaque, was here illustrated by mechanical models.]
A further consequence of the theory is that the velocity of light in a transparent medium will be affected by its electrical strain constant; in other words, that its refractive index will bear some close but not yet quite ascertained relation to its specific inductive capacity. Experiment has partially confirmed this, but the confirmation is as yet very incomplete. But there are a number of results not predicted by theory, and whose connection with the theory is not clearly made out. We have the fact that light falling on the platinum electrode of a voltameter generates a current, first observed, I think, by Sir W. R. Grove--at any rate, it is mentioned in his "Correlation of Forces"--extended by Becquerel and Robert Sabine to other substances, and now being extended to fluorescent and other bodies by Prof. Minchin. And finally--for I must be brief--we have the remarkable action of light on selenium. This fact was discovered accidentally by an assistant in the laboratory of Mr. Willoughby Smith, who noticed that a piece of selenium conducted electricity very much better when light was falling upon it than when it was in the dark. The light of a candle is sufficient, and instantaneously brings down the resistance to something like one-fifth of its original value.
I could show you these effects, but there is not much to see; it is an intensely interesting phenomenon, but its external manifestation is not striking--any more than Faraday's heavy glass experiment was.
This is the phenomenon which, as you know, has been utilized by Prof. Graham Bell in that most ingenious and striking invention, the photophone. By the kindness of Prof. Silvanus Thompson, I have a few slides to show the principle of the invention, and Mr. Shelford Bidwell has been kind enough to lend me his home-made photophone, which answers exceedingly well for short distances.
I have now trespassed long enough upon your patience, but I must just allude to what may very likely be the next striking popular discovery; and that is the transmission of light by electricity; I mean the transmission of such things as views and pictures by means of the electric wire. It has not yet been done, but it seems already theoretically possible, and it may very soon be practically accomplished.
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INTERESTING ELECTRICAL RESEARCHES.
During the last six years Dr. Warren de la Rue has been investigating, in conjunction with Dr. Hugo Muller, the various and highly interesting phenomena which accompany the electric discharge. From time to time the results of their researches were communicated to the Royal Society, and appeared in its Proceedings. Early last year Dr. De la Rue being requested to bring the subject before the members of the Royal Institution, acceded to the pressing invitation of his colleagues and scientific friends. The discourse, which was necessarily long postponed on account of the preparations that had to be made, was finally given on Friday, the 21st of January, and was one of the most remarkable, from the elaborate nature of the experiments, ever delivered in the theater of that deservedly famous institution.
Owing to the great inconvenience of removing the battery from his laboratory, Dr. de la Rue, despite the great expenditure, directed Mr. S. Tisley to prepare, expressly for the lecture, a second series of 14,400 cells, and fit it up in the basement of the Royal Institution. The construction of this new battery occupied Mr. Tisley a whole year, while the charging of it extended over a fortnight.
The "de la Rue cell," if we may so call one of these elements, consists of a zinc rod, the lower portion of which is embedded in a solid electrolyte, viz., chloride of silver, with which are connected two flattened silver wires to serve as electrodes. When these are united and the silver chloride moistened, chemical action begins, and a weak but constant current is generated.
The electromotive force of such a cell is 1.03 volts, and a current equivalent to one volt passing through a resistance of one ohm was found to decompose 0.00146 grain of water in one second. The battery is divided into "cabinets," which hold from 1,200 to 2,160 small elements each. This facilitates removal, and also the detection of any fault that may occur.
It will be remembered that in 1808 Sir Humphry Davy constructed his battery of 2,000 cells, and thus succeeded in exalting the tiny spark obtained in closing the circuit into the luminous sheaf of the voltaic arc. He also observed that the spark passed even when the poles were separated by a distance varying from 1/40 to 1/30 of an inch. This appears to have been subsequently forgotten, as we find later physicists questioning the possibility of the spark leaping over any interpolar distance. Mr. J. P. Gassiot, of Clapham, demonstrated the inaccuracy of this opinion by constructing a battery of 3,000 Leclanché cells, which gave a spark of 0.025 inch; a similar number of "de la Rue" cells gives an 0.0564 inch spark. This considerable increase in potential is chiefly due to better insulation.
The great energy of this battery was illustrated by a variety of experiments. Thus, a large condenser, specially constructed by Messrs. Varley, and having a capacity equal to that of 6,485 large Leyden jars, was almost immediately charged by the current from 10,000 cells. Wires of various kinds, and from 9 inches to 29 inches in length, were instantly volatilized by the passage of the electricity thus stored up. The current induced in the secondary wire of a coil by the discharge of the condenser through the primary, was also sufficiently intense to deflagrate wires of considerable length and thickness.
It was with such power at his command that Dr. De la Rue proceeded to investigate several important electrical laws. He has found, for example, that the positive discharge is more intermittent than the negative, that the arc is always preceded by a streamer-like discharge, that its temperature is about 16,000 deg., and its length at the ordinary pressure of the atmosphere, when taken between two points, varies as the square of the number of cells. Thus, with a battery of 1,000 cells, the arc was 0.0051 inch, with 11,000 cells it increased to 0.62 inch. The same law was found to hold when the discharge took place between a point and a disk; it failed entirely, however, when the terminals were two disks.
It was also shown that the voltaic arc is not a phenomenon of conduction, but is essentially a disruptive discharge, the intervals between the passage of two successive static sparks being the time required for the battery to collect sufficient power to leap over the interposed resistance. This was further confirmed by the introduction of a condenser, when the intervals were perceptibly larger.
Faraday proved that the quantity of electricity necessary to produce a strong flash of lightning would result from the decomposition of a single grain of water, and Dr. de la Rue's experiments confirm this extraordinary statement. He has calculated that this quantity of electricity would be 5,000 times as great as the charge of his large condenser, and that a lightning flash a mile long would require the potential of 3,500,000 cells, that is to say, of 243 of his powerful batteries.
In experimenting with "vacuum" tubes, he has found that the discharge is also invariably disruptive. This is an important point, as many physicists speak and write of the phenomenon as one of conduction. Air, in every degree of tenuity, refuses to act as a conductor of electricity. These experiments show that the resistance of gaseous media diminishes with the pressure only up to a certain point, beyond which it rapidly increases. Thus, in the case of hydrogen, it diminishes up to 0.642 mm., 845 millionths; it then rises as the exhaustion proceeds, and at 0.00065 mm., 8.6 millionths, it requires as high a potential as at 21.7 mm., 28.553 millionths. At 0.00137 mm., 1.8 millionth, the current from 11,000 cells would not pass through a tube for which 430 cells sufficed at the pressure of minimum resistance. At a pressure of 0.0055 mm., 0.066 millionth, the highest exhaust obtained in any of the experiments, even a one-inch spark from an induction coil refused to pass. It was also ascertained that there is neither condensacian nor dilatation of the gas in contact with the terminals prior to the passage of the discharge.
These researches naturally led to some speculation about the conditions under which auroral phenomena may occur. Observers have variously stated the height at which the aurora borealis attains its greatest brilliancy as ranging between 124 and 281 miles. Dr. de la Rue's conclusions fix the upper limit at 124 miles, and that of maximum display at 37 miles, admitting also that the aurora may sometimes occur at an altitude of a few thousand feet.
The aurora was beautifully illustrated by a very large tube, in which the theoretical pressure was carefully maintained, the characteristic roseate tinge being readily produced and maintained.
In studying the stratifications observed in vacuum tubes, Dr. de la Rue finds that they originate at the positive pole, and that their steadiness may be regulated by the resistance in circuit, and that even when the least tremor cannot be detected by the eye, they are still produced by rapid pulsations which may be as frequent as ten millions per second.
Dr. de la Rue concluded his interesting discourse by exhibiting some of the finest tubes of his numerous and unsurpassed collection.--_Engineering_
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MEASURING ELECTROMOTIVE FORCE.
Coulomb's torsion balance has been adapted by M. Baille to the measurement of low electromotive forces in a very successful manner, and has been found preferable by him to the delicate electrometers of Sir W. Thomson. It is necessary to guard it from disturbances due to extraneous electric influences and the trembling of the ground. These can be eliminated completely by encircling the instrument in a metal case connected to earth, and mounting it on solid pillars in a still place. Heat also has a disturbing effect, and makes itself felt in the torsion of the fiber and the cage surrounding the lever. These effects are warded off by inclosing the instrument in a non-conducting jacket of wood shavings.
The apparatus of M. Baille consists of an annealed silver torsion wire of 2.70 meters long, and a lever 0.50 meter long, carrying at each extremity a ball of copper, gilded, and three centimeters in diameter. Similar balls are fixed at the corners of a square 20.5 meters in the side, and connected in diagonal pairs by fine wire. The lever placed at equal distances from the fixed balls communicates, by the medium of the torsion wire, with the positive pole of a battery, P, the other pole being to earth.
Owing to some unaccountable variations in the change of the lever or needle, M. Baille was obliged to measure the change at each observation. This was done by joining the + pole of the battery to the needle, and one pair of the fixed balls, and observing the deflection; then the deflection produced by the other balls was observed. This operation was repeated several times.
The battery, X, to be measured consisted of ten similar elements, and one pole of it was connected to the fixed balls, while the other pole was connected to the earth. The needle, of course, remained in contact with the + pole of the charging battery, P.
The deflections were read from a clear glass scale, placed at a distance of 3.30 meters from the needle, and the results worked out from Coulomb's static formula,
C a = (4 m m')/d², with
______________ / sum((p/g) r²) O = / ------------- \/ C
[TEX: O = \sqrt{\frac{\sum \frac{p}{g} r^2}{C}}]
In M. Baillie's experiments, O = 437³, and sum(pr²)= 32171.6 (centimeter grammes), the needle having been constructed of a geometrical form.
The following numbers represent the potential of an element of the battery--that is to say, the quantity of electricity that the pole of that battery spreads upon a sphere of one centimeter radius. They are expressed in units of electricity, the unit being the quantity of electricity which, acting upon a similar unit at a distance of one centimeter, produces a repulsion equal to one gramme:
Volta pile 0.03415 open circuit. Zinc, sulphate of copper, copper 0.02997 " Zinc, acidulated water, copper, sulphate of copper 0.03709 " Zinc, salt water, carbon peroxide of manganese 0.05282 " Zinc, salt water, platinum, chloride of platinum 0.05027 " Zinc, acidulated water, carbon nitric acid 0.06285 "
These results were obtained just upon charging the batteries, and are, therefore, slightly higher than the potentials given after the batteries became older. The sulphate of copper cells kept about their maximum value longest, but they showed variations of about 10 per cent.
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TELEPHONY BY THERMIC CURRENTS.
While in telephonic arrangements, based upon the principle of magnetic induction, a relatively considerable expenditure of force is required in order to set the tightly stretched membrane in vibration, in the so-called carbon telephones only a very feeble impulse is required to produce the differences in the current necessary for the transmission of sounds. In order to produce relatively strong currents, even in case of sound-action of a minimum strength, Franz Kröttlinger, of Vienna, has made an interesting experiment to use thermo electric currents for the transmission of sound to a distance. The apparatus which he has constructed is exceedingly simple. A current of hot air flowing from below upward is deflected more or less from its direction by the human voice. By its action an adjacent thermo-battery is excited, whose current passes through the spiral of an ordinary telephone, which serves as the receiving instrument. As a source of heat the inventor uses a common stearine candle, the flame of which is kept at one and the same level by means of a spring similar to those used in carriage lamps. On one side of the candle is a sheet metal voice funnel fixed upon a support, its mouth being covered with a movable sliding disk, fitted with a suitable number of small apertures. On the other side a similar support holds a funnel-shaped thermo-battery. The single bars of metal forming this battery are very thin, and of such a shape that they may cool as quickly as possible. Both the speaking-funnel and the battery can be made to approach, at will, to the stream of warm air rising up from the flame. The entire apparatus is inclosed in a tin case in such a manner that only the aperture of the voice-funnel and the polar clamps for securing the conducting wires appear on the outside. The inside of the case is suitably stayed to prevent vibration. On speaking into the mouth-piece of the funnel, the sound-waves occasion undulations in the column of hot air which are communicated to the thermo-battery, and in this manner corresponding differences are produced in the currents in the wires leading to the receiving instrument.--_Oesterreichische-Ungarische Post._
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THE TELECTROSCOPE.
By MONS. SENLECQ, of Ardres.
This apparatus, which is intended to transmit to a distance through a telegraphic wire pictures taken on the plate of a camera, was invented in the early part of 1877 by M. Senlecq, of Ardres. A description of the first specification submitted by M. Senlecq to M. du Moncel, member of the Paris Academy of Sciences, appeared in all the continental and American scientific journals. Since then the apparatus has everywhere occupied the attention of prominent electricians, who have striven to improve on it. Among these we may mention MM. Ayrton, Perry, Sawyer (of New York), Sargent (of Philadelphia), Brown (of London), Carey (of Boston), Tighe (of Pittsburg), and Graham Bell himself. Some experimenters have used many wires, bound together cable-wise, others one wire only. The result has been, on the one hand, confusion of conductors beyond a certain distance, with the absolute impossibility of obtaining perfect insulation; and, on the other hand, an utter want of synchronism. The unequal and slow sensitiveness of the selenium likewise obstructed the proper working of the apparatus. Now, without a relative simplicity in the arrangement of the conducting wires intended to convey to a distance the electric current with its variations of intensity, without a perfect and rapid synchronism acting concurrently with the luminous impressions, so as to insure the simultaneous action of transmitter and receiver, without, in fine, an increased sensitiveness in the selenium, the idea of the telectroscope could not be realized. M. Senlecq has fortunately surmounted most of these main obstacles, and we give to-day a description of the latest apparatus he has contrived.
TRANSMITTER.
A brass plate, A, whereon the rays of light impinge inside a camera, in their various forms and colors, from the external objects placed before the lens, the said plate being coated with selenium on the side intended to face the dark portion of the camera This brass plate has its entire surface perforated with small holes as near to one another as practicable. These holes are filled with selenium, heated, and then cooled very slowly, so as to obtain the maximum sensitiveness. A small brass wire passes through the selenium in each hole, without, however, touching the plate, on to the rectangular and vertical ebonite plate, B, Fig. 1, from under this plate at point, C. Thus, every wire passing through plate, A, has its point of contact above the plate, B, lengthwise. With this view the wires are clustered together when leaving the camera, and thence stretch to their corresponding points of contact on plate, B, along line, C C. The surface of brass, A, is in permanent contact with the positive pole of the battery (selenium). On each side of plate, B, are let in two brass rails, D and E, whereon the slide hereinafter described works.
Rail, E, communicates with the line wire intended to conduct the various light and shade vibrations. Rail, D, is connected with the battery wire. Along F are a number of points of contact corresponding with those along C C. These contacts help to work the apparatus, and to insure the perfect isochronism of the transmitter and receiver. These points of contact, though insulated one from the other on the surface of the plate, are all connected underneath with a wire coming from the positive pole of a special battery. This apparatus requires two batteries, as, in fact, do all autographic telegraphs--one for sending the current through the selenium, and one for working the receiver, etc. The different features of this important plate may, therefore, be summed up thus:
FIGURE 1.
D. Brass rail, grooved and connected with the line wire working the receiver.
F. Contacts connected underneath with a wire permanently connected with battery.
C. Contacts connected to insulated wires from selenium.
E. Brass rail, grooved, etc., like D.
RECEIVER.