Part 7

If, however, a _lump_ of antimony be dropped into the chlorine, there will be no spontaneous combustion, nor immediate change: but, in the course of time, the antimony will become incrusted with a white powder, and no chlorine will be found in the bottle.

Or, provide copper in fine leaves, known as “Dutch metal;” slightly breathe on one end of a glass rod, about ten inches long, and cause one or two leaves of the metal to adhere to the damp end; then open a bottle of chlorine, quickly plunge in the leaves, when they will instantly take fire, and burn with a fine red light, leaving in the bottle a greenish-yellow solid substance.

A small _lump_ of copper, or “Dutch metal,” will not burn as above, but will be slowly acted upon, like the antimony.

Immerse gold leaf in a jar of chlorine gas, and combustion with a beautiful green flame will take place.

PHOSPHORUS IN CHLORINE.

Put into a deflagrating spoon about four grains of phosphorus, and let it down into a bottle of chlorine, when the phosphorus will ignite instantaneously.

Or, fold a slip of blotting-paper into a match five inches long; dip it into oil of turpentine, drain it an instant, drop it into another bottle of chlorine, when it will burst into a flame, and deposit much carbon.

CAOUTCHOUC BALLOONS.

Put a little ether into a bottle of caoutchouc, close it tightly, soak it in hot water, and it will become inflated to a considerable size. These globes may be made so thin as to be transparent.

A piece of caoutchouc, the size of a walnut, has thus been extended to a ball fifteen inches in diameter; and a few years since, a caoutchouc balloon, thus made, escaped from Philadelphia, and was found 130 miles from that city.

TO INCREASE THE LIGHT OF COAL GAS.

Lay a piece of wire-gauze upon the glass chimney of a common argand gas burner, when the flame will be enlarged to twice its former dimensions, and its light fully doubled. If the experiment be made with a common argand oil-lamp, the flame will be often enlarged, but so discoloured as to yield less light.

GAS FROM INDIAN RUBBER.

Put caoutchoucine, or the spirit distilled from caoutchouc, or Indian rubber, into a phial, little more than sufficient to cover the bottom, and the remainder of the phial will be filled with a heavy vapour; pour this off the spirit into another phial, apply to it a piece of lighted paper, and the vapour will burn with a brilliant flame.

ETHER GAS.

Let fall a few drops of ether into a large drinking-glass, and cover it with a plate for a few minutes; during this time the glass will be filled with vapour from the ether, so that, on removing the plate, and applying a piece of lighted paper at the mouth of the glass, the invisible vapour will take fire; thus proving how readily a volatile fluid, such as ether, combines with the air.

MAGIC VAPOUR.

Provide a glass tube, about three feet long and half an inch in diameter, nearly fill it with water, upon the surface of which pour a little coloured ether; then close the open end of the tube carefully with the palm of the hand, invert it in a basin of water, and rest the tube against the wall: the ether will rise through the water to the upper end of the tube; pour a little hot water over the tube, and it will soon cause the ether to boil within, and its vapour may thus be made to drive nearly all the water out of the tube into the basin; if, however, you then cool the tube by pouring cold water over it, the vaporized ether will again become a liquid, and float upon the water as before.

GAS FROM THE UNION OF METALS.

Nearly fill a wine-glass with diluted sulphuric acid, and place in it a wire of silver and another of zinc, taking care that they do not touch each other; when the zinc will be changed by the acid, but the silver will remain inert. But, cause the upper ends of the wires to touch each other, and a stream of gas will issue from them.

INVISIBLE GASES MADE VISIBLE.

Pour a little sulphuric acid upon some common salt in a saucer. Into another saucer put a mixture of about two parts of quick-lime and one of sal ammoniac, both in powder, adding to these a very small quantity of boiling water. Each saucer apart will yield an invisible gas: but the moment they are brought closely together, very visible vapours will be the result.

LIGHT UNDER WATER.

Put into an _eau de Cologne_ bottle two drams of chlorate of potass, and upon that salt about a dozen chips of phosphorous, and fill up the bottle with cold water: provide a glass tube which will reach to the potass, through which pour half-an-ounce, by measure, of strong sulphuric acid, when a gas will instantly rise, give to the liquid a deep yellow colour, and inflame the phosphorous in a striking manner.

GASEOUS EVANESCENCE.

Add a tea-spoonful of fuming nitric acid to two tea-spoonfuls of spirit of wine, in a cup, and the liquids will presently disappear in the form of vapour.

VIOLET-COLOURED GAS.

Put three or four grains of iodine into a small clean Florence oil flask, and close it with a cork. Warm the flask gently over a candle, or before the fire, and the iodine will become converted into a beautiful violet-coloured vapour, which condenses again into brilliant metallic crystals, when the flask is suffered to become cold. The experiment may be repeated with the same flask for any number of times.

Or, upon a small sheet of any metal, place a few grains of iodine, and add a chip of dry phosphorous; when the latter will inflame, and the iodine pass off in a violet vapour.

TO COLLECT GASES.

Provide a moistened bladder, tie a piece of tobacco-pipe firmly into its neck, twisting it so as to expel the common air. This may be fitted to any vessel by means of the pipe, which may be fixed in the cork of a bottle containing gas, and closely luted with putty or clay, or powdered lime and white of egg.

THE DEFLAGRATING SPOON.

To introduce substances into gases, a deflagrating spoon is required. It may be bought for half-a-crown; but an instrument equally useful may be made as follows: cut a piece of sheet copper somewhat larger than a sixpence, and bend it into a shallow, cup-like form; twist four fine brass wires, each nine inches long, tightly together, leaving an inch at the extremities, which must be spread to hold the copper, as the strings or chains of a balance support the scale-pan. To complete it, take a piece of sheet-lead, the size of a penny-piece; make a hole through the centre large enough to admit the twisted wires, but, at the same time, retaining them firmly in their position: then, if the wires will not rest in the lead by adhesion, the hole may be enlarged, the wire put in, and secured by a piece of solder. The spoon being then let down through the mouth of a bottle, the circular piece of lead rests upon and stops the mouth.

WHAT IS STEAM?

Invert a glass goblet over a cup of hot water, when the vapour or steam will be seen to rise in it, to condense upon the cold glass, and then to run down its inside; thus showing that steam is vaporized water, and will, when the heat is abstracted from it, become water again.

THE STEAM-ENGINE SIMPLIFIED.

The steam-engine is much more intelligible than its name first suggests. That part by which the machinery is set in motion, may be compared to a syringe, or squirt, the rod of which is driven up and down by steam admitted above and below, one end of the rod being connected with the machinery to be worked. Thus, the piston is made to turn the wheels of a railway carriage, or the paddles of a steam-boat.

The elastic force of the steam, or vapour, by which the rod is driven up and down, may be explained by this simple experiment. Provide a test tube, put into it a little water, hold the thumb over the mouth, and cause the water to boil by holding it over a spirit-lamp. There will soon be felt a pressure against the thumb; when, if the tube be dipped into cold water, the thumb being still held at the end, a kind of suction will be felt against it. Now, the tube resembles the cylinder of the steam-engine, in which the piston moves up and down; to imitate which, wrap a little tow about the end of a piece of stick, grease it with tallow, and fit it moderately tight into the tube; when the water is made to boil, the stick will be raised, and when the end is dipped into cold water, the stick will fall as the piston rises and falls in the cylinder.

TO BOIL WATER BY STEAM.

Nearly fill a retort with water, and boil it over a lamp; then immerse the beak into a tumbler of cold water, and the disengaged steam will raise the water to the boiling temperature, though it be at a distance from the source of heat.

DISTILLATION IN MINIATURE.

Fill a kettle with water, and set it on the fire; fix a long metal tube to the spout, and as soon as the water boils, the steam will pass into the tube, and being condensed into water, will drip at the other end of the tube, which corresponds with the worm in the still; it soon, however, becomes as hot as the water, and then the condensation will cease: but, were the tube passed through cold water, as is the worm of the still in a tub, the whole water in the kettle might be boiled away, but reproduced in the tube, and collected from it without the loss of a drop. This simple process resembles distillation, and the kettle and tube the still.

CANDLE OR FIRE CRACKERS.

Provide a number of little glass bulbs, put into each a drop of water, and seal it up; if it be then put into the flame of a candle, or the fire, the heat will soon convert the water into steam, and cause the bulb to burst with a loud report.

STEAM FROM THE KETTLE.

Observe attentively the steam that escapes from the spout of a tea-kettle, at the moment the water begins to boil, and you will perceive the steam to be condensed in minute drops on the interior edges of the spout. A few moments afterwards, provided the water continue to boil, the spout of the kettle will become perfectly dry; and, at the same time, close to it, there will be a certain space, say from one-half to three-fourths of an inch, throughout which not a particle of steam will be perceptible. This may be easily explained. When the water in the kettle begins to boil, the spout being cooler than the steam issuing from it, a portion of that steam is condensed. As more steam escapes, the metal soon becomes as hot as the steam, will no longer condense it, and the spout becomes dry. By this time the steam will displace the air immediately opposite the orifice of the spout, whence it will issue dry and invisible. As it is cooled by mixing with the surrounding air, it assumes its well-known cloudy appearance.

FIRE, WATER, AND AIR.

COLOURED FLAMES.

A VARIETY of rays of light is exhibited by coloured flames, which are not to be seen in white light. Thus, pure hydrogen gas will burn with a blue flame, in which many of the rays of light are wanting. The flame of an oil-lamp contains most of the rays which are wanting in sunlight. Alcohol, mixed with water, when heated or burned, affords a flame with no other rays but yellow. The following salts, if finely powdered, and introduced into the exterior flame of a candle, or into the wick of a spirit-lamp will communicate to flame their peculiar colours:

Muriate of Soda (common salt) Yellow. Muriate of Potash Pale violet. Muriate of Lime Brick red. Muriate of Strontia Bright crimson. Muriate of Lithia Red. Muriate of Baryta Pale _apple_-green. Muriate of Copper Bluish green. Borax Green.

Or, either of the above salts may be mixed with spirit of wine, as directed for Red Fire.

YELLOW FLAME.

Burn spirits of wine on common table salt or saltpetre.

ORANGE-COLOURED FLAME.

Burn spirit of wine on chloride of calcium, a substance obtained by evaporating muriate of lime to dryness.

EMERALD GREEN FLAME.

Burn spirit of wine on a little powdered nitrate of copper.

INSTANTANEOUS FLAME.

Heat together potassium and sulphur, and they will instantly burn very vividly.

Heat a little nitre in a fire-shovel, sprinkle on it flour of sulphur, and it will instantly burn. If iron filings be thrown upon red-hot nitre, they will detonate and burn.

Pound, separately, equal parts of chlorate of potash and lump sugar; mix them, and put upon a plate a small quantity; dip a thread into sulphuric acid, touch the powder with it, and it will burst into a brilliant flame.

Or, put a few grains of chlorate of potash into a table-spoonful of spirit of wine; add one or two drops of sulphuric acid, and the whole will burst into a beautiful flame.

THE CUP OF FLAME.

Put a little newly calcined magnesia into a tea-cup upon the hearth or hob, and suddenly pour in as much concentrated sulphuric acid as will cover the magnesia; in an instant, sparks will be thrown out, and the mixture will become completely ignited. To prevent accidents, the phial containing the sulphuric acid should be tied to the end of a long stick.

TO COOL FLAME BY METAL.

Encircle the very small flame of a lamp with a cold iron wire, which will instantly cause its extinction.

PROOF THAT FLAME IS HOLLOW.

Pour some spirit of wine into a watch-glass, and inflame it; place a straw across this flame, and it will only be ignited and charred at the outer edge; the middle of the straw will be uninjured, for there is no ignited matter in the centre of the flame.

Or, introduce into the middle of the flame one end of a glass tube, when the vapour will rise through it, and may be lighted at the other end of the tube.

CAMPHOR SUBLIMED BY FLAME.

Set a metallic plate over the flame of a spirit-lamp; place upon it a small portion of camphor under a glass funnel; and the camphor will be beautifully sublimed by the heat of the lamp, in an efflorescent crust on the sides of the funnel.

GREEN FIRE.

A beautiful green fire may be thus made. Take of flour of sulphur, thirteen parts; nitrate of baryta, seventy-seven; oxymuriate of potassa, five; metallic arsenic, two; and charcoal, three. Let the nitrate of baryta be well dried and powdered; then add to it the other ingredients, all finely pulverized, and exceedingly well mixed and rubbed together. Place a portion of the composition in a small tin pan, having a polished reflector fitted to one side, and set light to it; when a splendid green illumination will be the result. By adding a little calamine, it will burn more slowly.

BRILLIANT RED FIRE.

Weigh five ounces of dry nitrate of strontia, one ounce and a half of finely-powdered sulphur, five drams of chlorate of potash, and four drams of sulphuret of antimony. Powder the chlorate of potash and the sulphuret of antimony separately in a mortar, and mix them on paper; after which, add them to the other ingredients, previously powdered and mixed. No other kind of mixture than rubbing together on paper is required. For use, mix with a portion of the powder a small quantity of spirit of wine, in a tin pan resembling a cheese-toaster, light the mixture, and it will shed a rich crimson hue: when the fire burns dim and badly, a very small quantity of finely-powdered charcoal or lamp-black will revive it.

PURPLE FIRE.

Dissolve chloride of lithium in spirit of wine; and when lighted, it will burn with a purplish flame.

SILVER FIRE.

Place upon a piece of burning charcoal a morsel of the dried crystals of nitrate of silver, (not the lunar caustic,) and it will immediately throw out the most beautiful sparks that can be imagined, whilst the surface of the charcoal will be coated with silver.

THE FIERY MOUNTAIN.

Put into a glass tumbler fifteen grains of finely granulated zinc, and six grains of phosphorus cut into very small pieces, beneath water. Mix in another glass, gradually, a dram of sulphuric acid with two drams of water. Remove both glasses into a dark room, and there pour the diluted acid over the zinc and phosphorus in the glass: in a short time, beautiful jets of bluish flame will dart from all parts of the surface of the mixture; it will become quite luminous, and beautiful luminous smoke will rise in a column from the glass; thus representing a fountain of fire.

THE ARTIFICIAL CONFLAGRATION.

Put into a small, narrow-necked earthen bottle, half an ounce of muriate of ammonia, an ounce of camphor, and two ounces of highly rectified spirit of wine; set fire to it, and the room will seem to be in flames. This experiment should be performed in the dark.

INFLAMMABLE POWDER.

Heat a small portion of the grey powder of aluminum, and it will ignite, inflame, and burn with great rapidity. Or, blow a little of this powder into the flame of a candle, and it will produce a small shower of sparks, brilliant as those from iron filings.

COMBUSTION WITHOUT FLAME.

Light a small _green_ wax-taper; in a minute or two, blow out the flame, and the wick will continue red-hot for many hours; and, if the taper were regularly and carefully uncoiled, and the room kept free from currents of air, the wick would burn on in this manner until the whole taper were consumed. The same effect is not produced when the colour of the wax is red, on which account, red wax-tapers are safer than green; for the latter, if left imperfectly extinguished, may set fire to any object with which they are in contact.

COMBUSTION OF THREE METALS.

Mix a grain or two of potassium with an equal quantity of sodium; add a globule of quicksilver, and the three metals, when shaken, will take fire, and burn vividly.

TO MAKE PAPER INCOMBUSTIBLE.

Take a smooth cylindrical piece of metal, about one inch and a half in diameter, and eight inches long; wrap very closely round it a piece of clean writing paper, then hold the paper in the flame of a spirit-lamp, and it will not take fire; but it may be held there for a considerable time, without being in the least affected by the flame.

SINGULAR EXPERIMENTS WITH GLASS TUBES.

A most remarkable phenomenon is produced in glass tubes, under certain circumstances. When these are laid before a fire in a horizontal position, having their extremities properly supported, they acquire a rotatory motion round their axis, and also a progressive motion towards the fire, even when their supports are declining from the fire, so that the tubes will move a little way upwards to the fire. When the progressive motion of the tubes towards the fire is stopped by any obstacle, their rotation still continues. When the tubes are placed in a nearly upright posture, leaning to the right hand, the motion will be from east to west; but if they lean to the left hand, the motion will be from west to east; and the nearer they are placed to the upright posture, the less will the motion be either way. If the tube be placed horizontally on a glass plane, the fragment, for instance, of coach window glass, instead of moving towards the fire, it will move from it, and about its axis in a contrary direction to what it had done before; nay, it will recede from the fire, and move a little upwards, when the plane inclines towards the fire. These experiments succeed best with tubes about twenty or twenty-two inches long, which have in each end a pretty strong pin fixed in cork for their axis.

AQUATIC BOMB.

Drop about two grains of potassium into a saucer of cold water. It will instantly burst into flame, with a slight explosion, burn vividly on the surface, and dart about with great violence in the form of a red-hot fire ball.

HEAT NOT TO BE ESTIMATED BY TOUCH.

Hold both hands in water which causes the thermometer to rise to ninety degrees, and when the liquid has become still, you will be insensible of the heat, and that the hand is touching any thing. Then remove one hand to water that causes the thermometer to rise to 200 degrees, and the other in water at thirty-two degrees. After holding the hands thus for some time, remove them, and again immerse them in the water at ninety degrees; when you will feel _warmth_ in one hand and _cold_ in the other. To the hand which had been immersed in the water at thirty-two degrees, the water at ninety degrees will feel hot; and to the hand which had been immersed in the water at 200 degrees, the water at ninety degrees will feel cold. If, therefore, the touch in this case be trusted, the same water will be judged to be hot and cold at the _same_ time.

FLAME UPON WATER.

Fill a wine-glass with cold water, pour lightly upon its surface a little ether; light it by a slip of paper, and it will burn for some time.

ROSE-COLOURED FLAME ON WATER.

Drop a globule of potassium, about the size of a large pea, into a small cup nearly full of water, containing a drop or two of strong nitric acid; the moment that the metal touches the liquid, it will float upon its surface, enveloped with a beautiful rose-coloured flame, and entirely dissolve.

TO SET A MIXTURE ON FIRE WITH WATER.

Pour into a saucer a little sulphuric acid, and place upon it a chip of sodium, which will float and remain uninflamed; but the addition of a drop of water will set it on fire.

WAVES OF FIRE ON WATER.

On a lump of refined sugar let fall a few drops of phosphuretted ether, and put the sugar into a glass of warm water, which will instantly appear on fire at the surface, and in waves, if gently blown with the breath. This experiment should be exhibited in the dark.

EXPLOSION IN WATER.

Throw very small pieces of phosphuret of potassium into a basin of water, and they will produce separate explosions. The same substance will also burn with great brilliancy, when exposed to air.

WATER FROM THE FLAME OF A CANDLE.

Hold a cold and dry bell-glass over a lighted candle, and watery vapour will be directly condensed on the cold surface; then close the mouth of the glass with a card or plate, and turn the mouth uppermost; remove the card, quickly pour in a little lime-water, a perfectly clear liquid, and it will instantly become turbid and milky, upon meeting with the contents of the glass, just as lime-water changes when dropped into a glass of water.

FORMATION OF WATER BY FIRE.

Put into a tea-cup a little spirit of wine, set it on fire, and invert a large bell-glass over it. In a short time, a thick watery vapour will be seen upon the inside of the bell, which may be collected by a dry sponge.

BOILING UPON COLD WATER.

Provide a tall glass jar, filled with cold water, and place in it an air thermometer, which will nearly reach the surface; upon the surface place a small copper basin, into which put a little live charcoal: the surface of the water will soon be made to boil, while the thermometer will show that the water beneath is scarcely warmer than it was at first.

CURRENTS IN BOILING WATER.

Fill a large glass tube with water, and throw into it a few particles of bruised amber; then hold the tube, by a handle for the purpose, upright in the flame of a lamp, and, as the water becomes warm, it will be seen that currents, carrying with them the pieces of amber, will begin to ascend in the centre, and to descend towards the circumference of the tube. These currents will soon become rapid in their motions, and continue till the water boils.

HOT WATER LIGHTER THAN COLD.

Pour into a glass tube, about ten inches long, and one inch in diameter, a little water coloured with pink or other dye; then fill it up gradually and carefully with colourless water, so as not to mix them: apply heat at the bottom of the tube, and the coloured water will ascend and be diffused throughout the whole.

The circulation of warm water may be very pleasingly shown, by heating water in a tube similar to the foregoing; the water having diffused in it some particles of amber, or other light substance not soluble in water.

EXPANSION OF WATER BY COLD.