Opticks

Part 8

Chapter 84,127 wordsPublic domain

_Exper._ 5. Now, that these Colours could not be changed by Refraction, I knew by refracting with a Prism sometimes one very little Part of this Light, sometimes another very little Part, as is described in the twelfth Experiment of the first Part of this Book. For by this Refraction the Colour of the Light was never changed in the least. If any Part of the red Light was refracted, it remained totally of the same red Colour as before. No orange, no yellow, no green or blue, no other new Colour was produced by that Refraction. Neither did the Colour any ways change by repeated Refractions, but continued always the same red entirely as at first. The like Constancy and Immutability I found also in the blue, green, and other Colours. So also, if I looked through a Prism upon any Body illuminated with any part of this homogeneal Light, as in the fourteenth Experiment of the first Part of this Book is described; I could not perceive any new Colour generated this way. All Bodies illuminated with compound Light appear through Prisms confused, (as was said above) and tinged with various new Colours, but those illuminated with homogeneal Light appeared through Prisms neither less distinct, nor otherwise colour'd, than when viewed with the naked Eyes. Their Colours were not in the least changed by the Refraction of the interposed Prism. I speak here of a sensible Change of Colour: For the Light which I here call homogeneal, being not absolutely homogeneal, there ought to arise some little Change of Colour from its Heterogeneity. But, if that Heterogeneity was so little as it might be made by the said Experiments of the fourth Proposition, that Change was not sensible, and therefore in Experiments, where Sense is Judge, ought to be accounted none at all.

_Exper._ 6. And as these Colours were not changeable by Refractions, so neither were they by Reflexions. For all white, grey, red, yellow, green, blue, violet Bodies, as Paper, Ashes, red Lead, Orpiment, Indico Bise, Gold, Silver, Copper, Grass, blue Flowers, Violets, Bubbles of Water tinged with various Colours, Peacock's Feathers, the Tincture of _Lignum Nephriticum_, and such-like, in red homogeneal Light appeared totally red, in blue Light totally blue, in green Light totally green, and so of other Colours. In the homogeneal Light of any Colour they all appeared totally of that same Colour, with this only Difference, that some of them reflected that Light more strongly, others more faintly. I never yet found any Body, which by reflecting homogeneal Light could sensibly change its Colour.

From all which it is manifest, that if the Sun's Light consisted of but one sort of Rays, there would be but one Colour in the whole World, nor would it be possible to produce any new Colour by Reflexions and Refractions, and by consequence that the variety of Colours depends upon the Composition of Light.

_DEFINITION._

The homogeneal Light and Rays which appear red, or rather make Objects appear so, I call Rubrifick or Red-making; those which make Objects appear yellow, green, blue, and violet, I call Yellow-making, Green-making, Blue-making, Violet-making, and so of the rest. And if at any time I speak of Light and Rays as coloured or endued with Colours, I would be understood to speak not philosophically and properly, but grossly, and accordingly to such Conceptions as vulgar People in seeing all these Experiments would be apt to frame. For the Rays to speak properly are not coloured. In them there is nothing else than a certain Power and Disposition to stir up a Sensation of this or that Colour. For as Sound in a Bell or musical String, or other sounding Body, is nothing but a trembling Motion, and in the Air nothing but that Motion propagated from the Object, and in the Sensorium 'tis a Sense of that Motion under the Form of Sound; so Colours in the Object are nothing but a Disposition to reflect this or that sort of Rays more copiously than the rest; in the Rays they are nothing but their Dispositions to propagate this or that Motion into the Sensorium, and in the Sensorium they are Sensations of those Motions under the Forms of Colours.

_PROP._ III. PROB. I.

_To define the Refrangibility of the several sorts of homogeneal Light answering to the several Colours._

For determining this Problem I made the following Experiment.[J]

_Exper._ 7. When I had caused the Rectilinear Sides AF, GM, [in _Fig._ 4.] of the Spectrum of Colours made by the Prism to be distinctly defined, as in the fifth Experiment of the first Part of this Book is described, there were found in it all the homogeneal Colours in the same Order and Situation one among another as in the Spectrum of simple Light, described in the fourth Proposition of that Part. For the Circles of which the Spectrum of compound Light PT is composed, and which in the middle Parts of the Spectrum interfere, and are intermix'd with one another, are not intermix'd in their outmost Parts where they touch those Rectilinear Sides AF and GM. And therefore, in those Rectilinear Sides when distinctly defined, there is no new Colour generated by Refraction. I observed also, that if any where between the two outmost Circles TMF and PGA a Right Line, as [Greek: gd], was cross to the Spectrum, so as both Ends to fall perpendicularly upon its Rectilinear Sides, there appeared one and the same Colour, and degree of Colour from one End of this Line to the other. I delineated therefore in a Paper the Perimeter of the Spectrum FAP GMT, and in trying the third Experiment of the first Part of this Book, I held the Paper so that the Spectrum might fall upon this delineated Figure, and agree with it exactly, whilst an Assistant, whose Eyes for distinguishing Colours were more critical than mine, did by Right Lines [Greek: ab, gd, ez,] &c. drawn cross the Spectrum, note the Confines of the Colours, that is of the red M[Greek: ab]F, of the orange [Greek: agdb], of the yellow [Greek: gezd], of the green [Greek: eethz], of the blue [Greek: eikth], of the indico [Greek: ilmk], and of the violet [Greek: l]GA[Greek: m]. And this Operation being divers times repeated both in the same, and in several Papers, I found that the Observations agreed well enough with one another, and that the Rectilinear Sides MG and FA were by the said cross Lines divided after the manner of a Musical Chord. Let GM be produced to X, that MX may be equal to GM, and conceive GX, [Greek: l]X, [Greek: i]X, [Greek: e]X, [Greek: e]X, [Greek: g]X, [Greek: a]X, MX, to be in proportion to one another, as the Numbers, 1, 8/9, 5/6, 3/4, 2/3, 3/5, 9/16, 1/2, and so to represent the Chords of the Key, and of a Tone, a third Minor, a fourth, a fifth, a sixth Major, a seventh and an eighth above that Key: And the Intervals M[Greek: a], [Greek: ag], [Greek: ge], [Greek: ee], [Greek: ei], [Greek: il], and [Greek: l]G, will be the Spaces which the several Colours (red, orange, yellow, green, blue, indigo, violet) take up.

Now these Intervals or Spaces subtending the Differences of the Refractions of the Rays going to the Limits of those Colours, that is, to the Points M, [Greek: a], [Greek: g], [Greek: e], [Greek: e], [Greek: i], [Greek: l], G, may without any sensible Error be accounted proportional to the Differences of the Sines of Refraction of those Rays having one common Sine of Incidence, and therefore since the common Sine of Incidence of the most and least refrangible Rays out of Glass into Air was (by a Method described above) found in proportion to their Sines of Refraction, as 50 to 77 and 78, divide the Difference between the Sines of Refraction 77 and 78, as the Line GM is divided by those Intervals, and you will have 77, 77-1/8, 77-1/5, 77-1/3, 77-1/2, 77-2/3, 77-7/9, 78, the Sines of Refraction of those Rays out of Glass into Air, their common Sine of Incidence being 50. So then the Sines of the Incidences of all the red-making Rays out of Glass into Air, were to the Sines of their Refractions, not greater than 50 to 77, nor less than 50 to 77-1/8, but they varied from one another according to all intermediate Proportions. And the Sines of the Incidences of the green-making Rays were to the Sines of their Refractions in all Proportions from that of 50 to 77-1/3, unto that of 50 to 77-1/2. And by the like Limits above-mentioned were the Refractions of the Rays belonging to the rest of the Colours defined, the Sines of the red-making Rays extending from 77 to 77-1/8, those of the orange-making from 77-1/8 to 77-1/5, those of the yellow-making from 77-1/5 to 77-1/3, those of the green-making from 77-1/3 to 77-1/2, those of the blue-making from 77-1/2 to 77-2/3, those of the indigo-making from 77-2/3 to 77-7/9, and those of the violet from 77-7/9, to 78.

These are the Laws of the Refractions made out of Glass into Air, and thence by the third Axiom of the first Part of this Book, the Laws of the Refractions made out of Air into Glass are easily derived.

_Exper._ 8. I found moreover, that when Light goes out of Air through several contiguous refracting Mediums as through Water and Glass, and thence goes out again into Air, whether the refracting Superficies be parallel or inclin'd to one another, that Light as often as by contrary Refractions 'tis so corrected, that it emergeth in Lines parallel to those in which it was incident, continues ever after to be white. But if the emergent Rays be inclined to the incident, the Whiteness of the emerging Light will by degrees in passing on from the Place of Emergence, become tinged in its Edges with Colours. This I try'd by refracting Light with Prisms of Glass placed within a Prismatick Vessel of Water. Now those Colours argue a diverging and separation of the heterogeneous Rays from one another by means of their unequal Refractions, as in what follows will more fully appear. And, on the contrary, the permanent whiteness argues, that in like Incidences of the Rays there is no such separation of the emerging Rays, and by consequence no inequality of their whole Refractions. Whence I seem to gather the two following Theorems.

1. The Excesses of the Sines of Refraction of several sorts of Rays above their common Sine of Incidence when the Refractions are made out of divers denser Mediums immediately into one and the same rarer Medium, suppose of Air, are to one another in a given Proportion.

2. The Proportion of the Sine of Incidence to the Sine of Refraction of one and the same sort of Rays out of one Medium into another, is composed of the Proportion of the Sine of Incidence to the Sine of Refraction out of the first Medium into any third Medium, and of the Proportion of the Sine of Incidence to the Sine of Refraction out of that third Medium into the second Medium.

By the first Theorem the Refractions of the Rays of every sort made out of any Medium into Air are known by having the Refraction of the Rays of any one sort. As for instance, if the Refractions of the Rays of every sort out of Rain-water into Air be desired, let the common Sine of Incidence out of Glass into Air be subducted from the Sines of Refraction, and the Excesses will be 27, 27-1/8, 27-1/5, 27-1/3, 27-1/2, 27-2/3, 27-7/9, 28. Suppose now that the Sine of Incidence of the least refrangible Rays be to their Sine of Refraction out of Rain-water into Air as 3 to 4, and say as 1 the difference of those Sines is to 3 the Sine of Incidence, so is 27 the least of the Excesses above-mentioned to a fourth Number 81; and 81 will be the common Sine of Incidence out of Rain-water into Air, to which Sine if you add all the above-mentioned Excesses, you will have the desired Sines of the Refractions 108, 108-1/8, 108-1/5, 108-1/3, 108-1/2, 108-2/3, 108-7/9, 109.

By the latter Theorem the Refraction out of one Medium into another is gathered as often as you have the Refractions out of them both into any third Medium. As if the Sine of Incidence of any Ray out of Glass into Air be to its Sine of Refraction, as 20 to 31, and the Sine of Incidence of the same Ray out of Air into Water, be to its Sine of Refraction as 4 to 3; the Sine of Incidence of that Ray out of Glass into Water will be to its Sine of Refraction as 20 to 31 and 4 to 3 jointly, that is, as the Factum of 20 and 4 to the Factum of 31 and 3, or as 80 to 93.

And these Theorems being admitted into Opticks, there would be scope enough of handling that Science voluminously after a new manner,[K] not only by teaching those things which tend to the perfection of Vision, but also by determining mathematically all kinds of Phaenomena of Colours which could be produced by Refractions. For to do this, there is nothing else requisite than to find out the Separations of heterogeneous Rays, and their various Mixtures and Proportions in every Mixture. By this way of arguing I invented almost all the Phaenomena described in these Books, beside some others less necessary to the Argument; and by the successes I met with in the Trials, I dare promise, that to him who shall argue truly, and then try all things with good Glasses and sufficient Circumspection, the expected Event will not be wanting. But he is first to know what Colours will arise from any others mix'd in any assigned Proportion.

_PROP._ IV. THEOR. III.

_Colours may be produced by Composition which shall be like to the Colours of homogeneal Light as to the Appearance of Colour, but not as to the Immutability of Colour and Constitution of Light. And those Colours by how much they are more compounded by so much are they less full and intense, and by too much Composition they maybe diluted and weaken'd till they cease, and the Mixture becomes white or grey. There may be also Colours produced by Composition, which are not fully like any of the Colours of homogeneal Light._

For a Mixture of homogeneal red and yellow compounds an Orange, like in appearance of Colour to that orange which in the series of unmixed prismatick Colours lies between them; but the Light of one orange is homogeneal as to Refrangibility, and that of the other is heterogeneal, and the Colour of the one, if viewed through a Prism, remains unchanged, that of the other is changed and resolved into its component Colours red and yellow. And after the same manner other neighbouring homogeneal Colours may compound new Colours, like the intermediate homogeneal ones, as yellow and green, the Colour between them both, and afterwards, if blue be added, there will be made a green the middle Colour of the three which enter the Composition. For the yellow and blue on either hand, if they are equal in quantity they draw the intermediate green equally towards themselves in Composition, and so keep it as it were in AEquilibrion, that it verge not more to the yellow on the one hand, and to the blue on the other, but by their mix'd Actions remain still a middle Colour. To this mix'd green there may be farther added some red and violet, and yet the green will not presently cease, but only grow less full and vivid, and by increasing the red and violet, it will grow more and more dilute, until by the prevalence of the added Colours it be overcome and turned into whiteness, or some other Colour. So if to the Colour of any homogeneal Light, the Sun's white Light composed of all sorts of Rays be added, that Colour will not vanish or change its Species, but be diluted, and by adding more and more white it will be diluted more and more perpetually. Lastly, If red and violet be mingled, there will be generated according to their various Proportions various Purples, such as are not like in appearance to the Colour of any homogeneal Light, and of these Purples mix'd with yellow and blue may be made other new Colours.

_PROP._ V. THEOR. IV.

_Whiteness and all grey Colours between white and black, may be compounded of Colours, and the whiteness of the Sun's Light is compounded of all the primary Colours mix'd in a due Proportion._

The PROOF by Experiments.

_Exper._ 9. The Sun shining into a dark Chamber through a little round hole in the Window-shut, and his Light being there refracted by a Prism to cast his coloured Image PT [in _Fig._ 5.] upon the opposite Wall: I held a white Paper V to that image in such manner that it might be illuminated by the colour'd Light reflected from thence, and yet not intercept any part of that Light in its passage from the Prism to the Spectrum. And I found that when the Paper was held nearer to any Colour than to the rest, it appeared of that Colour to which it approached nearest; but when it was equally or almost equally distant from all the Colours, so that it might be equally illuminated by them all it appeared white. And in this last situation of the Paper, if some Colours were intercepted, the Paper lost its white Colour, and appeared of the Colour of the rest of the Light which was not intercepted. So then the Paper was illuminated with Lights of various Colours, namely, red, yellow, green, blue and violet, and every part of the Light retained its proper Colour, until it was incident on the Paper, and became reflected thence to the Eye; so that if it had been either alone (the rest of the Light being intercepted) or if it had abounded most, and been predominant in the Light reflected from the Paper, it would have tinged the Paper with its own Colour; and yet being mixed with the rest of the Colours in a due proportion, it made the Paper look white, and therefore by a Composition with the rest produced that Colour. The several parts of the coloured Light reflected from the Spectrum, whilst they are propagated from thence through the Air, do perpetually retain their proper Colours, because wherever they fall upon the Eyes of any Spectator, they make the several parts of the Spectrum to appear under their proper Colours. They retain therefore their proper Colours when they fall upon the Paper V, and so by the confusion and perfect mixture of those Colours compound the whiteness of the Light reflected from thence.

_Exper._ 10. Let that Spectrum or solar Image PT [in _Fig._ 6.] fall now upon the Lens MN above four Inches broad, and about six Feet distant from the Prism ABC and so figured that it may cause the coloured Light which divergeth from the Prism to converge and meet again at its Focus G, about six or eight Feet distant from the Lens, and there to fall perpendicularly upon a white Paper DE. And if you move this Paper to and fro, you will perceive that near the Lens, as at _de_, the whole solar Image (suppose at _pt_) will appear upon it intensely coloured after the manner above-explained, and that by receding from the Lens those Colours will perpetually come towards one another, and by mixing more and more dilute one another continually, until at length the Paper come to the Focus G, where by a perfect mixture they will wholly vanish and be converted into whiteness, the whole Light appearing now upon the Paper like a little white Circle. And afterwards by receding farther from the Lens, the Rays which before converged will now cross one another in the Focus G, and diverge from thence, and thereby make the Colours to appear again, but yet in a contrary order; suppose at [Greek: de], where the red _t_ is now above which before was below, and the violet _p_ is below which before was above.

Let us now stop the Paper at the Focus G, where the Light appears totally white and circular, and let us consider its whiteness. I say, that this is composed of the converging Colours. For if any of those Colours be intercepted at the Lens, the whiteness will cease and degenerate into that Colour which ariseth from the composition of the other Colours which are not intercepted. And then if the intercepted Colours be let pass and fall upon that compound Colour, they mix with it, and by their mixture restore the whiteness. So if the violet, blue and green be intercepted, the remaining yellow, orange and red will compound upon the Paper an orange, and then if the intercepted Colours be let pass, they will fall upon this compounded orange, and together with it decompound a white. So also if the red and violet be intercepted, the remaining yellow, green and blue, will compound a green upon the Paper, and then the red and violet being let pass will fall upon this green, and together with it decompound a white. And that in this Composition of white the several Rays do not suffer any Change in their colorific Qualities by acting upon one another, but are only mixed, and by a mixture of their Colours produce white, may farther appear by these Arguments.

If the Paper be placed beyond the Focus G, suppose at [Greek: de], and then the red Colour at the Lens be alternately intercepted, and let pass again, the violet Colour on the Paper will not suffer any Change thereby, as it ought to do if the several sorts of Rays acted upon one another in the Focus G, where they cross. Neither will the red upon the Paper be changed by any alternate stopping, and letting pass the violet which crosseth it.

And if the Paper be placed at the Focus G, and the white round Image at G be viewed through the Prism HIK, and by the Refraction of that Prism be translated to the place _rv_, and there appear tinged with various Colours, namely, the violet at _v_ and red at _r_, and others between, and then the red Colours at the Lens be often stopp'd and let pass by turns, the red at _r_ will accordingly disappear, and return as often, but the violet at _v_ will not thereby suffer any Change. And so by stopping and letting pass alternately the blue at the Lens, the blue at _v_ will accordingly disappear and return, without any Change made in the red at _r_. The red therefore depends on one sort of Rays, and the blue on another sort, which in the Focus G where they are commix'd, do not act on one another. And there is the same Reason of the other Colours.

I considered farther, that when the most refrangible Rays P_p_, and the least refrangible ones T_t_, are by converging inclined to one another, the Paper, if held very oblique to those Rays in the Focus G, might reflect one sort of them more copiously than the other sort, and by that Means the reflected Light would be tinged in that Focus with the Colour of the predominant Rays, provided those Rays severally retained their Colours, or colorific Qualities in the Composition of White made by them in that Focus. But if they did not retain them in that White, but became all of them severally endued there with a Disposition to strike the Sense with the Perception of White, then they could never lose their Whiteness by such Reflexions. I inclined therefore the Paper to the Rays very obliquely, as in the second Experiment of this second Part of the first Book, that the most refrangible Rays, might be more copiously reflected than the rest, and the Whiteness at Length changed successively into blue, indigo, and violet. Then I inclined it the contrary Way, that the least refrangible Rays might be more copious in the reflected Light than the rest, and the Whiteness turned successively to yellow, orange, and red.