Part 15

By what hath been said, the like Phaenomena of Water and thin Plates of Glass may be understood. But in small fragments of those Plates there is this farther observable, that where they lie flat upon a Table, and are turned about their centers whilst they are view'd through a Prism, they will in some postures exhibit Waves of various Colours; and some of them exhibit these Waves in one or two Positions only, but the most of them do in all Positions exhibit them, and make them for the most part appear almost all over the Plates. The reason is, that the Superficies of such Plates are not even, but have many Cavities and Swellings, which, how shallow soever, do a little vary the thickness of the Plate. For at the several sides of those Cavities, for the Reasons newly described, there ought to be produced Waves in several postures of the Prism. Now though it be but some very small and narrower parts of the Glass, by which these Waves for the most part are caused, yet they may seem to extend themselves over the whole Glass, because from the narrowest of those parts there are Colours of several Orders, that is, of several Rings, confusedly reflected, which by Refraction of the Prism are unfolded, separated, and, according to their degrees of Refraction, dispersed to several places, so as to constitute so many several Waves, as there were divers orders of Colours promiscuously reflected from that part of the Glass.

These are the principal Phaenomena of thin Plates or Bubbles, whose Explications depend on the properties of Light, which I have heretofore deliver'd. And these you see do necessarily follow from them, and agree with them, even to their very least circumstances; and not only so, but do very much tend to their proof. Thus, by the 24th Observation it appears, that the Rays of several Colours, made as well by thin Plates or Bubbles, as by Refractions of a Prism, have several degrees of Refrangibility; whereby those of each order, which at the reflexion from the Plate or Bubble are intermix'd with those of other orders, are separated from them by Refraction, and associated together so as to become visible by themselves like Arcs of Circles. For if the Rays were all alike refrangible, 'tis impossible that the whiteness, which to the naked Sense appears uniform, should by Refraction have its parts transposed and ranged into those black and white Arcs.

It appears also that the unequal Refractions of difform Rays proceed not from any contingent irregularities; such as are Veins, an uneven Polish, or fortuitous Position of the Pores of Glass; unequal and casual Motions in the Air or AEther, the spreading, breaking, or dividing the same Ray into many diverging parts; or the like. For, admitting any such irregularities, it would be impossible for Refractions to render those Rings so very distinct, and well defined, as they do in the 24th Observation. It is necessary therefore that every Ray have its proper and constant degree of Refrangibility connate with it, according to which its refraction is ever justly and regularly perform'd; and that several Rays have several of those degrees.

And what is said of their Refrangibility may be also understood of their Reflexibility, that is, of their Dispositions to be reflected, some at a greater, and others at a less thickness of thin Plates or Bubbles; namely, that those Dispositions are also connate with the Rays, and immutable; as may appear by the 13th, 14th, and 15th Observations, compared with the fourth and eighteenth.

By the Precedent Observations it appears also, that whiteness is a dissimilar mixture of all Colours, and that Light is a mixture of Rays endued with all those Colours. For, considering the multitude of the Rings of Colours in the 3d, 12th, and 24th Observations, it is manifest, that although in the 4th and 18th Observations there appear no more than eight or nine of those Rings, yet there are really a far greater number, which so much interfere and mingle with one another, as after those eight or nine revolutions to dilute one another wholly, and constitute an even and sensibly uniform whiteness. And consequently that whiteness must be allow'd a mixture of all Colours, and the Light which conveys it to the Eye must be a mixture of Rays endued with all those Colours.

But farther; by the 24th Observation it appears, that there is a constant relation between Colours and Refrangibility; the most refrangible Rays being violet, the least refrangible red, and those of intermediate Colours having proportionably intermediate degrees of Refrangibility. And by the 13th, 14th, and 15th Observations, compared with the 4th or 18th there appears to be the same constant relation between Colour and Reflexibility; the violet being in like circumstances reflected at least thicknesses of any thin Plate or Bubble, the red at greatest thicknesses, and the intermediate Colours at intermediate thicknesses. Whence it follows, that the colorifick Dispositions of Rays are also connate with them, and immutable; and by consequence, that all the Productions and Appearances of Colours in the World are derived, not from any physical Change caused in Light by Refraction or Reflexion, but only from the various Mixtures or Separations of Rays, by virtue of their different Refrangibility or Reflexibility. And in this respect the Science of Colours becomes a Speculation as truly mathematical as any other part of Opticks. I mean, so far as they depend on the Nature of Light, and are not produced or alter'd by the Power of Imagination, or by striking or pressing the Eye.

THE

SECOND BOOK

OF

OPTICKS

_PART III._

_Of the permanent Colours of natural Bodies, and the Analogy between them and the Colours of thin transparent Plates._

I am now come to another part of this Design, which is to consider how the Phaenomena of thin transparent Plates stand related to those of all other natural Bodies. Of these Bodies I have already told you that they appear of divers Colours, accordingly as they are disposed to reflect most copiously the Rays originally endued with those Colours. But their Constitutions, whereby they reflect some Rays more copiously than others, remain to be discover'd; and these I shall endeavour to manifest in the following Propositions.

PROP. I.

_Those Superficies of transparent Bodies reflect the greatest quantity of Light, which have the greatest refracting Power; that is, which intercede Mediums that differ most in their refractive Densities. And in the Confines of equally refracting Mediums there is no Reflexion._

The Analogy between Reflexion and Refraction will appear by considering, that when Light passeth obliquely out of one Medium into another which refracts from the perpendicular, the greater is the difference of their refractive Density, the less Obliquity of Incidence is requisite to cause a total Reflexion. For as the Sines are which measure the Refraction, so is the Sine of Incidence at which the total Reflexion begins, to the Radius of the Circle; and consequently that Angle of Incidence is least where there is the greatest difference of the Sines. Thus in the passing of Light out of Water into Air, where the Refraction is measured by the Ratio of the Sines 3 to 4, the total Reflexion begins when the Angle of Incidence is about 48 Degrees 35 Minutes. In passing out of Glass into Air, where the Refraction is measured by the Ratio of the Sines 20 to 31, the total Reflexion begins when the Angle of Incidence is 40 Degrees 10 Minutes; and so in passing out of Crystal, or more strongly refracting Mediums into Air, there is still a less obliquity requisite to cause a total reflexion. Superficies therefore which refract most do soonest reflect all the Light which is incident on them, and so must be allowed most strongly reflexive.

But the truth of this Proposition will farther appear by observing, that in the Superficies interceding two transparent Mediums, (such as are Air, Water, Oil, common Glass, Crystal, metalline Glasses, Island Glasses, white transparent Arsenick, Diamonds, &c.) the Reflexion is stronger or weaker accordingly, as the Superficies hath a greater or less refracting Power. For in the Confine of Air and Sal-gem 'tis stronger than in the Confine of Air and Water, and still stronger in the Confine of Air and common Glass or Crystal, and stronger in the Confine of Air and a Diamond. If any of these, and such like transparent Solids, be immerged in Water, its Reflexion becomes, much weaker than before; and still weaker if they be immerged in the more strongly refracting Liquors of well rectified Oil of Vitriol or Spirit of Turpentine. If Water be distinguish'd into two parts by any imaginary Surface, the Reflexion in the Confine of those two parts is none at all. In the Confine of Water and Ice 'tis very little; in that of Water and Oil 'tis something greater; in that of Water and Sal-gem still greater; and in that of Water and Glass, or Crystal or other denser Substances still greater, accordingly as those Mediums differ more or less in their refracting Powers. Hence in the Confine of common Glass and Crystal, there ought to be a weak Reflexion, and a stronger Reflexion in the Confine of common and metalline Glass; though I have not yet tried this. But in the Confine of two Glasses of equal density, there is not any sensible Reflexion; as was shewn in the first Observation. And the same may be understood of the Superficies interceding two Crystals, or two Liquors, or any other Substances in which no Refraction is caused. So then the reason why uniform pellucid Mediums (such as Water, Glass, or Crystal,) have no sensible Reflexion but in their external Superficies, where they are adjacent to other Mediums of a different density, is because all their contiguous parts have one and the same degree of density.

PROP. II.

_The least parts of almost all natural Bodies are in some measure transparent: And the Opacity of those Bodies ariseth from the multitude of Reflexions caused in their internal Parts._

That this is so has been observed by others, and will easily be granted by them that have been conversant with Microscopes. And it may be also tried by applying any substance to a hole through which some Light is immitted into a dark Room. For how opake soever that Substance may seem in the open Air, it will by that means appear very manifestly transparent, if it be of a sufficient thinness. Only white metalline Bodies must be excepted, which by reason of their excessive density seem to reflect almost all the Light incident on their first Superficies; unless by solution in Menstruums they be reduced into very small Particles, and then they become transparent.

PROP. III.

_Between the parts of opake and colour'd Bodies are many Spaces, either empty, or replenish'd with Mediums of other Densities; as Water between the tinging Corpuscles wherewith any Liquor is impregnated, Air between the aqueous Globules that constitute Clouds or Mists; and for the most part Spaces void of both Air and Water, but yet perhaps not wholly void of all Substance, between the parts of hard Bodies._

The truth of this is evinced by the two precedent Propositions: For by the second Proposition there are many Reflexions made by the internal parts of Bodies, which, by the first Proposition, would not happen if the parts of those Bodies were continued without any such Interstices between them; because Reflexions are caused only in Superficies, which intercede Mediums of a differing density, by _Prop._ 1.

But farther, that this discontinuity of parts is the principal Cause of the opacity of Bodies, will appear by considering, that opake Substances become transparent by filling their Pores with any Substance of equal or almost equal density with their parts. Thus Paper dipped in Water or Oil, the _Oculus Mundi_ Stone steep'd in Water, Linnen Cloth oiled or varnish'd, and many other Substances soaked in such Liquors as will intimately pervade their little Pores, become by that means more transparent than otherwise; so, on the contrary, the most transparent Substances, may, by evacuating their Pores, or separating their parts, be render'd sufficiently opake; as Salts or wet Paper, or the _Oculus Mundi_ Stone by being dried, Horn by being scraped, Glass by being reduced to Powder, or otherwise flawed; Turpentine by being stirred about with Water till they mix imperfectly, and Water by being form'd into many small Bubbles, either alone in the form of Froth, or by shaking it together with Oil of Turpentine, or Oil Olive, or with some other convenient Liquor, with which it will not perfectly incorporate. And to the increase of the opacity of these Bodies, it conduces something, that by the 23d Observation the Reflexions of very thin transparent Substances are considerably stronger than those made by the same Substances of a greater thickness.

PROP. IV.

_The Parts of Bodies and their Interstices must not be less than of some definite bigness, to render them opake and colour'd._

For the opakest Bodies, if their parts be subtilly divided, (as Metals, by being dissolved in acid Menstruums, &c.) become perfectly transparent. And you may also remember, that in the eighth Observation there was no sensible reflexion at the Superficies of the Object-glasses, where they were very near one another, though they did not absolutely touch. And in the 17th Observation the Reflexion of the Water-bubble where it became thinnest was almost insensible, so as to cause very black Spots to appear on the top of the Bubble, by the want of reflected Light.

On these grounds I perceive it is that Water, Salt, Glass, Stones, and such like Substances, are transparent. For, upon divers Considerations, they seem to be as full of Pores or Interstices between their parts as other Bodies are, but yet their Parts and Interstices to be too small to cause Reflexions in their common Surfaces.

PROP. V.

_The transparent parts of Bodies, according to their several sizes, reflect Rays of one Colour, and transmit those of another, on the same grounds that thin Plates or Bubbles do reflect or transmit those Rays. And this I take to be the ground of all their Colours._

For if a thinn'd or plated Body, which being of an even thickness, appears all over of one uniform Colour, should be slit into Threads, or broken into Fragments, of the same thickness with the Plate; I see no reason why every Thread or Fragment should not keep its Colour, and by consequence why a heap of those Threads or Fragments should not constitute a Mass or Powder of the same Colour, which the Plate exhibited before it was broken. And the parts of all natural Bodies being like so many Fragments of a Plate, must on the same grounds exhibit the same Colours.

Now, that they do so will appear by the affinity of their Properties. The finely colour'd Feathers of some Birds, and particularly those of Peacocks Tails, do, in the very same part of the Feather, appear of several Colours in several Positions of the Eye, after the very same manner that thin Plates were found to do in the 7th and 19th Observations, and therefore their Colours arise from the thinness of the transparent parts of the Feathers; that is, from the slenderness of the very fine Hairs, or _Capillamenta_, which grow out of the sides of the grosser lateral Branches or Fibres of those Feathers. And to the same purpose it is, that the Webs of some Spiders, by being spun very fine, have appeared colour'd, as some have observ'd, and that the colour'd Fibres of some Silks, by varying the Position of the Eye, do vary their Colour. Also the Colours of Silks, Cloths, and other Substances, which Water or Oil can intimately penetrate, become more faint and obscure by being immerged in those Liquors, and recover their Vigor again by being dried; much after the manner declared of thin Bodies in the 10th and 21st Observations. Leaf-Gold, some sorts of painted Glass, the Infusion of _Lignum Nephriticum_, and some other Substances, reflect one Colour, and transmit another; like thin Bodies in the 9th and 20th Observations. And some of those colour'd Powders which Painters use, may have their Colours a little changed, by being very elaborately and finely ground. Where I see not what can be justly pretended for those changes, besides the breaking of their parts into less parts by that contrition, after the same manner that the Colour of a thin Plate is changed by varying its thickness. For which reason also it is that the colour'd Flowers of Plants and Vegetables, by being bruised, usually become more transparent than before, or at least in some degree or other change their Colours. Nor is it much less to my purpose, that, by mixing divers Liquors, very odd and remarkable Productions and Changes of Colours may be effected, of which no cause can be more obvious and rational than that the saline Corpuscles of one Liquor do variously act upon or unite with the tinging Corpuscles of another, so as to make them swell, or shrink, (whereby not only their bulk but their density also may be changed,) or to divide them into smaller Corpuscles, (whereby a colour'd Liquor may become transparent,) or to make many of them associate into one cluster, whereby two transparent Liquors may compose a colour'd one. For we see how apt those saline Menstruums are to penetrate and dissolve Substances to which they are applied, and some of them to precipitate what others dissolve. In like manner, if we consider the various Phaenomena of the Atmosphere, we may observe, that when Vapours are first raised, they hinder not the transparency of the Air, being divided into parts too small to cause any Reflexion in their Superficies. But when in order to compose drops of Rain they begin to coalesce and constitute Globules of all intermediate sizes, those Globules, when they become of convenient size to reflect some Colours and transmit others, may constitute Clouds of various Colours according to their sizes. And I see not what can be rationally conceived in so transparent a Substance as Water for the production of these Colours, besides the various sizes of its fluid and globular Parcels.

PROP. VI.

_The parts of Bodies on which their Colours depend, are denser than the Medium which pervades their Interstices._

This will appear by considering, that the Colour of a Body depends not only on the Rays which are incident perpendicularly on its parts, but on those also which are incident at all other Angles. And that according to the 7th Observation, a very little variation of obliquity will change the reflected Colour, where the thin Body or small Particles is rarer than the ambient Medium, insomuch that such a small Particle will at diversly oblique Incidences reflect all sorts of Colours, in so great a variety that the Colour resulting from them all, confusedly reflected from a heap of such Particles, must rather be a white or grey than any other Colour, or at best it must be but a very imperfect and dirty Colour. Whereas if the thin Body or small Particle be much denser than the ambient Medium, the Colours, according to the 19th Observation, are so little changed by the variation of obliquity, that the Rays which are reflected least obliquely may predominate over the rest, so much as to cause a heap of such Particles to appear very intensely of their Colour.

It conduces also something to the confirmation of this Proposition, that, according to the 22d Observation, the Colours exhibited by the denser thin Body within the rarer, are more brisk than those exhibited by the rarer within the denser.

PROP. VII.

_The bigness of the component parts of natural Bodies may be conjectured by their Colours._

For since the parts of these Bodies, by _Prop._ 5. do most probably exhibit the same Colours with a Plate of equal thickness, provided they have the same refractive density; and since their parts seem for the most part to have much the same density with Water or Glass, as by many circumstances is obvious to collect; to determine the sizes of those parts, you need only have recourse to the precedent Tables, in which the thickness of Water or Glass exhibiting any Colour is expressed. Thus if it be desired to know the diameter of a Corpuscle, which being of equal density with Glass shall reflect green of the third Order; the Number 16-1/4 shews it to be (16-1/4)/10000 parts of an Inch.

The greatest difficulty is here to know of what Order the Colour of any Body is. And for this end we must have recourse to the 4th and 18th Observations; from whence may be collected these particulars.

_Scarlets_, and other _reds_, _oranges_, and _yellows_, if they be pure and intense, are most probably of the second order. Those of the first and third order also may be pretty good; only the yellow of the first order is faint, and the orange and red of the third Order have a great Mixture of violet and blue.

There may be good _Greens_ of the fourth Order, but the purest are of the third. And of this Order the green of all Vegetables seems to be, partly by reason of the Intenseness of their Colours, and partly because when they wither some of them turn to a greenish yellow, and others to a more perfect yellow or orange, or perhaps to red, passing first through all the aforesaid intermediate Colours. Which Changes seem to be effected by the exhaling of the Moisture which may leave the tinging Corpuscles more dense, and something augmented by the Accretion of the oily and earthy Part of that Moisture. Now the green, without doubt, is of the same Order with those Colours into which it changeth, because the Changes are gradual, and those Colours, though usually not very full, yet are often too full and lively to be of the fourth Order.

_Blues_ and _Purples_ may be either of the second or third Order, but the best are of the third. Thus the Colour of Violets seems to be of that Order, because their Syrup by acid Liquors turns red, and by urinous and alcalizate turns green. For since it is of the Nature of Acids to dissolve or attenuate, and of Alcalies to precipitate or incrassate, if the Purple Colour of the Syrup was of the second Order, an acid Liquor by attenuating its tinging Corpuscles would change it to a red of the first Order, and an Alcali by incrassating them would change it to a green of the second Order; which red and green, especially the green, seem too imperfect to be the Colours produced by these Changes. But if the said Purple be supposed of the third Order, its Change to red of the second, and green of the third, may without any Inconvenience be allow'd.

If there be found any Body of a deeper and less reddish Purple than that of the Violets, its Colour most probably is of the second Order. But yet there being no Body commonly known whose Colour is constantly more deep than theirs, I have made use of their Name to denote the deepest and least reddish Purples, such as manifestly transcend their Colour in purity.

The _blue_ of the first Order, though very faint and little, may possibly be the Colour of some Substances; and particularly the azure Colour of the Skies seems to be of this Order. For all Vapours when they begin to condense and coalesce into small Parcels, become first of that Bigness, whereby such an Azure must be reflected before they can constitute Clouds of other Colours. And so this being the first Colour which Vapours begin to reflect, it ought to be the Colour of the finest and most transparent Skies, in which Vapours are not arrived to that Grossness requisite to reflect other Colours, as we find it is by Experience.