Part 13

_Obs._ 13. Appointing an Assistant to move the Prism to and fro about its Axis, that all the Colours might successively fall on that part of the Paper which I saw by Reflexion from that part of the Glasses, where the Circles appear'd, so that all the Colours might be successively reflected from the Circles to my Eye, whilst I held it immovable, I found the Circles which the red Light made to be manifestly bigger than those which were made by the blue and violet. And it was very pleasant to see them gradually swell or contract accordingly as the Colour of the Light was changed. The Interval of the Glasses at any of the Rings when they were made by the utmost red Light, was to their Interval at the same Ring when made by the utmost violet, greater than as 3 to 2, and less than as 13 to 8. By the most of my Observations it was as 14 to 9. And this Proportion seem'd very nearly the same in all Obliquities of my Eye; unless when two Prisms were made use of instead of the Object-glasses. For then at a certain great obliquity of my Eye, the Rings made by the several Colours seem'd equal, and at a greater obliquity those made by the violet would be greater than the same Rings made by the red: the Refraction of the Prism in this case causing the most refrangible Rays to fall more obliquely on that plate of the Air than the least refrangible ones. Thus the Experiment succeeded in the colour'd Light, which was sufficiently strong and copious to make the Rings sensible. And thence it may be gather'd, that if the most refrangible and least refrangible Rays had been copious enough to make the Rings sensible without the mixture of other Rays, the Proportion which here was 14 to 9 would have been a little greater, suppose 14-1/4 or 14-1/3 to 9.

_Obs._ 14. Whilst the Prism was turn'd about its Axis with an uniform Motion, to make all the several Colours fall successively upon the Object-glasses, and thereby to make the Rings contract and dilate: The Contraction or Dilatation of each Ring thus made by the variation of its Colour was swiftest in the red, and slowest in the violet, and in the intermediate Colours it had intermediate degrees of Celerity. Comparing the quantity of Contraction and Dilatation made by all the degrees of each Colour, I found that it was greatest in the red; less in the yellow, still less in the blue, and least in the violet. And to make as just an Estimation as I could of the Proportions of their Contractions or Dilatations, I observ'd that the whole Contraction or Dilatation of the Diameter of any Ring made by all the degrees of red, was to that of the Diameter of the same Ring made by all the degrees of violet, as about four to three, or five to four, and that when the Light was of the middle Colour between yellow and green, the Diameter of the Ring was very nearly an arithmetical Mean between the greatest Diameter of the same Ring made by the outmost red, and the least Diameter thereof made by the outmost violet: Contrary to what happens in the Colours of the oblong Spectrum made by the Refraction of a Prism, where the red is most contracted, the violet most expanded, and in the midst of all the Colours is the Confine of green and blue. And hence I seem to collect that the thicknesses of the Air between the Glasses there, where the Ring is successively made by the limits of the five principal Colours (red, yellow, green, blue, violet) in order (that is, by the extreme red, by the limit of red and yellow in the middle of the orange, by the limit of yellow and green, by the limit of green and blue, by the limit of blue and violet in the middle of the indigo, and by the extreme violet) are to one another very nearly as the sixth lengths of a Chord which found the Notes in a sixth Major, _sol_, _la_, _mi_, _fa_, _sol_, _la_. But it agrees something better with the Observation to say, that the thicknesses of the Air between the Glasses there, where the Rings are successively made by the limits of the seven Colours, red, orange, yellow, green, blue, indigo, violet in order, are to one another as the Cube Roots of the Squares of the eight lengths of a Chord, which found the Notes in an eighth, _sol_, _la_, _fa_, _sol_, _la_, _mi_, _fa_, _sol_; that is, as the Cube Roots of the Squares of the Numbers, 1, 8/9, 5/6, 3/4, 2/3, 3/5, 9/16, 1/2.

_Obs._ 15. These Rings were not of various Colours like those made in the open Air, but appeared all over of that prismatick Colour only with which they were illuminated. And by projecting the prismatick Colours immediately upon the Glasses, I found that the Light which fell on the dark Spaces which were between the Colour'd Rings was transmitted through the Glasses without any variation of Colour. For on a white Paper placed behind, it would paint Rings of the same Colour with those which were reflected, and of the bigness of their immediate Spaces. And from thence the origin of these Rings is manifest; namely, that the Air between the Glasses, according to its various thickness, is disposed in some places to reflect, and in others to transmit the Light of any one Colour (as you may see represented in the fourth Figure) and in the same place to reflect that of one Colour where it transmits that of another.

_Obs._ 16. The Squares of the Diameters of these Rings made by any prismatick Colour were in arithmetical Progression, as in the fifth Observation. And the Diameter of the sixth Circle, when made by the citrine yellow, and viewed almost perpendicularly was about 58/100 parts of an Inch, or a little less, agreeable to the sixth Observation.

The precedent Observations were made with a rarer thin Medium, terminated by a denser, such as was Air or Water compress'd between two Glasses. In those that follow are set down the Appearances of a denser Medium thin'd within a rarer, such as are Plates of Muscovy Glass, Bubbles of Water, and some other thin Substances terminated on all sides with air.

_Obs._ 17. If a Bubble be blown with Water first made tenacious by dissolving a little Soap in it, 'tis a common Observation, that after a while it will appear tinged with a great variety of Colours. To defend these Bubbles from being agitated by the external Air (whereby their Colours are irregularly moved one among another, so that no accurate Observation can be made of them,) as soon as I had blown any of them I cover'd it with a clear Glass, and by that means its Colours emerged in a very regular order, like so many concentrick Rings encompassing the top of the Bubble. And as the Bubble grew thinner by the continual subsiding of the Water, these Rings dilated slowly and overspread the whole Bubble, descending in order to the bottom of it, where they vanish'd successively. In the mean while, after all the Colours were emerged at the top, there grew in the center of the Rings a small round black Spot, like that in the first Observation, which continually dilated it self till it became sometimes more than 1/2 or 3/4 of an Inch in breadth before the Bubble broke. At first I thought there had been no Light reflected from the Water in that place, but observing it more curiously, I saw within it several smaller round Spots, which appeared much blacker and darker than the rest, whereby I knew that there was some Reflexion at the other places which were not so dark as those Spots. And by farther Tryal I found that I could see the Images of some things (as of a Candle or the Sun) very faintly reflected, not only from the great black Spot, but also from the little darker Spots which were within it.

Besides the aforesaid colour'd Rings there would often appear small Spots of Colours, ascending and descending up and down the sides of the Bubble, by reason of some Inequalities in the subsiding of the Water. And sometimes small black Spots generated at the sides would ascend up to the larger black Spot at the top of the Bubble, and unite with it.

_Obs._ 18. Because the Colours of these Bubbles were more extended and lively than those of the Air thinn'd between two Glasses, and so more easy to be distinguish'd, I shall here give you a farther description of their order, as they were observ'd in viewing them by Reflexion of the Skies when of a white Colour, whilst a black substance was placed behind the Bubble. And they were these, red, blue; red, blue; red, blue; red, green; red, yellow, green, blue, purple; red, yellow, green, blue, violet; red, yellow, white, blue, black.

The three first Successions of red and blue were very dilute and dirty, especially the first, where the red seem'd in a manner to be white. Among these there was scarce any other Colour sensible besides red and blue, only the blues (and principally the second blue) inclined a little to green.

The fourth red was also dilute and dirty, but not so much as the former three; after that succeeded little or no yellow, but a copious green, which at first inclined a little to yellow, and then became a pretty brisk and good willow green, and afterwards changed to a bluish Colour; but there succeeded neither blue nor violet.

The fifth red at first inclined very much to purple, and afterwards became more bright and brisk, but yet not very pure. This was succeeded with a very bright and intense yellow, which was but little in quantity, and soon chang'd to green: But that green was copious and something more pure, deep and lively, than the former green. After that follow'd an excellent blue of a bright Sky-colour, and then a purple, which was less in quantity than the blue, and much inclined to red.

The sixth red was at first of a very fair and lively scarlet, and soon after of a brighter Colour, being very pure and brisk, and the best of all the reds. Then after a lively orange follow'd an intense bright and copious yellow, which was also the best of all the yellows, and this changed first to a greenish yellow, and then to a greenish blue; but the green between the yellow and the blue, was very little and dilute, seeming rather a greenish white than a green. The blue which succeeded became very good, and of a very bright Sky-colour, but yet something inferior to the former blue; and the violet was intense and deep with little or no redness in it. And less in quantity than the blue.

In the last red appeared a tincture of scarlet next to violet, which soon changed to a brighter Colour, inclining to an orange; and the yellow which follow'd was at first pretty good and lively, but afterwards it grew more dilute until by degrees it ended in perfect whiteness. And this whiteness, if the Water was very tenacious and well-temper'd, would slowly spread and dilate it self over the greater part of the Bubble; continually growing paler at the top, where at length it would crack in many places, and those cracks, as they dilated, would appear of a pretty good, but yet obscure and dark Sky-colour; the white between the blue Spots diminishing, until it resembled the Threds of an irregular Net-work, and soon after vanish'd, and left all the upper part of the Bubble of the said dark blue Colour. And this Colour, after the aforesaid manner, dilated it self downwards, until sometimes it hath overspread the whole Bubble. In the mean while at the top, which was of a darker blue than the bottom, and appear'd also full of many round blue Spots, something darker than the rest, there would emerge one or more very black Spots, and within those, other Spots of an intenser blackness, which I mention'd in the former Observation; and these continually dilated themselves until the Bubble broke.

If the Water was not very tenacious, the black Spots would break forth in the white, without any sensible intervention of the blue. And sometimes they would break forth within the precedent yellow, or red, or perhaps within the blue of the second order, before the intermediate Colours had time to display themselves.

By this description you may perceive how great an affinity these Colours have with those of Air described in the fourth Observation, although set down in a contrary order, by reason that they begin to appear when the Bubble is thickest, and are most conveniently reckon'd from the lowest and thickest part of the Bubble upwards.

_Obs._ 19. Viewing in several oblique Positions of my Eye the Rings of Colours emerging on the top of the Bubble, I found that they were sensibly dilated by increasing the obliquity, but yet not so much by far as those made by thinn'd Air in the seventh Observation. For there they were dilated so much as, when view'd most obliquely, to arrive at a part of the Plate more than twelve times thicker than that where they appear'd when viewed perpendicularly; whereas in this case the thickness of the Water, at which they arrived when viewed most obliquely, was to that thickness which exhibited them by perpendicular Rays, something less than as 8 to 5. By the best of my Observations it was between 15 and 15-1/2 to 10; an increase about 24 times less than in the other case.

Sometimes the Bubble would become of an uniform thickness all over, except at the top of it near the black Spot, as I knew, because it would exhibit the same appearance of Colours in all Positions of the Eye. And then the Colours which were seen at its apparent circumference by the obliquest Rays, would be different from those that were seen in other places, by Rays less oblique to it. And divers Spectators might see the same part of it of differing Colours, by viewing it at very differing Obliquities. Now observing how much the Colours at the same places of the Bubble, or at divers places of equal thickness, were varied by the several Obliquities of the Rays; by the assistance of the 4th, 14th, 16th and 18th Observations, as they are hereafter explain'd, I collect the thickness of the Water requisite to exhibit any one and the same Colour, at several Obliquities, to be very nearly in the Proportion expressed in this Table.

+------------------+---------------- Incidence on | Refraction into | Thickness of the Water. | the Water. | the Water. -----------------+------------------+---------------- Deg. Min. | Deg. Min. | | | 00 00 | 00 00 | 10 | | 15 00 | 11 11 | 10-1/4 | | 30 00 | 22 1 | 10-4/5 | | 45 00 | 32 2 | 11-4/5 | | 60 00 | 40 30 | 13 | | 75 00 | 46 25 | 14-1/2 | | 90 00 | 48 35 | 15-1/5 -----------------+------------------+----------------

In the two first Columns are express'd the Obliquities of the Rays to the Superficies of the Water, that is, their Angles of Incidence and Refraction. Where I suppose, that the Sines which measure them are in round Numbers, as 3 to 4, though probably the Dissolution of Soap in the Water, may a little alter its refractive Virtue. In the third Column, the Thickness of the Bubble, at which any one Colour is exhibited in those several Obliquities, is express'd in Parts, of which ten constitute its Thickness when the Rays are perpendicular. And the Rule found by the seventh Observation agrees well with these Measures, if duly apply'd; namely, that the Thickness of a Plate of Water requisite to exhibit one and the same Colour at several Obliquities of the Eye, is proportional to the Secant of an Angle, whose Sine is the first of an hundred and six arithmetical mean Proportionals between the Sines of Incidence and Refraction counted from the lesser Sine, that is, from the Sine of Refraction when the Refraction is made out of Air into Water, otherwise from the Sine of Incidence.

I have sometimes observ'd, that the Colours which arise on polish'd Steel by heating it, or on Bell-metal, and some other metalline Substances, when melted and pour'd on the Ground, where they may cool in the open Air, have, like the Colours of Water-bubbles, been a little changed by viewing them at divers Obliquities, and particularly that a deep blue, or violet, when view'd very obliquely, hath been changed to a deep red. But the Changes of these Colours are not so great and sensible as of those made by Water. For the Scoria, or vitrified Part of the Metal, which most Metals when heated or melted do continually protrude, and send out to their Surface, and which by covering the Metals in form of a thin glassy Skin, causes these Colours, is much denser than Water; and I find that the Change made by the Obliquation of the Eye is least in Colours of the densest thin Substances.

_Obs._ 20. As in the ninth Observation, so here, the Bubble, by transmitted Light, appear'd of a contrary Colour to that, which it exhibited by Reflexion. Thus when the Bubble being look'd on by the Light of the Clouds reflected from it, seemed red at its apparent Circumference, if the Clouds at the same time, or immediately after, were view'd through it, the Colour at its Circumference would be blue. And, on the contrary, when by reflected Light it appeared blue, it would appear red by transmitted Light.

_Obs._ 21. By wetting very thin Plates of _Muscovy_ Glass, whose thinness made the like Colours appear, the Colours became more faint and languid, especially by wetting the Plates on that side opposite to the Eye: But I could not perceive any variation of their Species. So then the thickness of a Plate requisite to produce any Colour, depends only on the density of the Plate, and not on that of the ambient Medium. And hence, by the 10th and 16th Observations, may be known the thickness which Bubbles of Water, or Plates of _Muscovy_ Glass, or other Substances, have at any Colour produced by them.

_Obs._ 22. A thin transparent Body, which is denser than its ambient Medium, exhibits more brisk and vivid Colours than that which is so much rarer; as I have particularly observed in the Air and Glass. For blowing Glass very thin at a Lamp Furnace, those Plates encompassed with Air did exhibit Colours much more vivid than those of Air made thin between two Glasses.

_Obs._ 23. Comparing the quantity of Light reflected from the several Rings, I found that it was most copious from the first or inmost, and in the exterior Rings became gradually less and less. Also the whiteness of the first Ring was stronger than that reflected from those parts of the thin Medium or Plate which were without the Rings; as I could manifestly perceive by viewing at a distance the Rings made by the two Object-glasses; or by comparing two Bubbles of Water blown at distant Times, in the first of which the Whiteness appear'd, which succeeded all the Colours, and in the other, the Whiteness which preceded them all.

_Obs._ 24. When the two Object-glasses were lay'd upon one another, so as to make the Rings of the Colours appear, though with my naked Eye I could not discern above eight or nine of those Rings, yet by viewing them through a Prism I have seen a far greater Multitude, insomuch that I could number more than forty, besides many others, that were so very small and close together, that I could not keep my Eye steady on them severally so as to number them, but by their Extent I have sometimes estimated them to be more than an hundred. And I believe the Experiment may be improved to the Discovery of far greater Numbers. For they seem to be really unlimited, though visible only so far as they can be separated by the Refraction of the Prism, as I shall hereafter explain.

But it was but one side of these Rings, namely, that towards which the Refraction was made, which by that Refraction was render'd distinct, and the other side became more confused than when view'd by the naked Eye, insomuch that there I could not discern above one or two, and sometimes none of those Rings, of which I could discern eight or nine with my naked Eye. And their Segments or Arcs, which on the other side appear'd so numerous, for the most part exceeded not the third Part of a Circle. If the Refraction was very great, or the Prism very distant from the Object-glasses, the middle Part of those Arcs became also confused, so as to disappear and constitute an even Whiteness, whilst on either side their Ends, as also the whole Arcs farthest from the Center, became distincter than before, appearing in the Form as you see them design'd in the fifth Figure.

The Arcs, where they seem'd distinctest, were only white and black successively, without any other Colours intermix'd. But in other Places there appeared Colours, whose Order was inverted by the refraction in such manner, that if I first held the Prism very near the Object-glasses, and then gradually removed it farther off towards my Eye, the Colours of the 2d, 3d, 4th, and following Rings, shrunk towards the white that emerged between them, until they wholly vanish'd into it at the middle of the Arcs, and afterwards emerged again in a contrary Order. But at the Ends of the Arcs they retain'd their Order unchanged.

I have sometimes so lay'd one Object-glass upon the other, that to the naked Eye they have all over seem'd uniformly white, without the least Appearance of any of the colour'd Rings; and yet by viewing them through a Prism, great Multitudes of those Rings have discover'd themselves. And in like manner Plates of _Muscovy_ Glass, and Bubbles of Glass blown at a Lamp-Furnace, which were not so thin as to exhibit any Colours to the naked Eye, have through the Prism exhibited a great Variety of them ranged irregularly up and down in the Form of Waves. And so Bubbles of Water, before they began to exhibit their Colours to the naked Eye of a Bystander, have appeared through a Prism, girded about with many parallel and horizontal Rings; to produce which Effect, it was necessary to hold the Prism parallel, or very nearly parallel to the Horizon, and to dispose it so that the Rays might be refracted upwards.

THE

SECOND BOOK

OF

OPTICKS

_PART II._

_Remarks upon the foregoing Observations._

Having given my Observations of these Colours, before I make use of them to unfold the Causes of the Colours of natural Bodies, it is convenient that by the simplest of them, such as are the 2d, 3d, 4th, 9th, 12th, 18th, 20th, and 24th, I first explain the more compounded. And first to shew how the Colours in the fourth and eighteenth Observations are produced, let there be taken in any Right Line from the Point Y, [in _Fig._ 6.] the Lengths YA, YB, YC, YD, YE, YF, YG, YH, in proportion to one another, as the Cube-Roots of the Squares of the Numbers, 1/2, 9/16, 3/5, 2/3, 3/4, 5/6, 8/9, 1, whereby the Lengths of a Musical Chord to sound all the Notes in an eighth are represented; that is, in the Proportion of the Numbers 6300, 6814, 7114, 7631, 8255, 8855, 9243, 10000. And at the Points A, B, C, D, E, F, G, H, let Perpendiculars A[Greek: a], B[Greek: b], &c. be erected, by whose Intervals the Extent of the several Colours set underneath against them, is to be represented. Then divide the Line _A[Greek: a]_ in such Proportion as the Numbers 1, 2, 3, 5, 6, 7, 9, 10, 11, &c. set at the Points of Division denote. And through those Divisions from Y draw Lines 1I, 2K, 3L, 5M, 6N, 7O, &c.