Henley's Twentieth Century Formulas, Recipes and Processes
Part 22
«Weiss Beer.»—This differs from the ordinary lager beer in that it contains wheat malt. The proportions are 2/3 wheat to 1/3 barley malt, 1 pound hops being used with a peck of the combined malt to each 20 gallons of water. A good deal depends on the yeast, which must be of a special kind, the best grades being imported from Germany.
«Yellow Coloring for Beverages.»—The coloring agents employed are fustic, saffron, turmeric, quercitron, and the various aniline dyes. Here are some formulas:
I.—Saffron 1 ounce Deodorized alcohol 4 fluidounces Distilled water 4 fluidounces
Mix alcohol and water, and then add the saffron. Allow the mixture to stand in a warm place for several days, shaking occasionally; then filter. The tincture thus prepared has a deep orange color, and when diluted or used in small quantities gives a beautiful yellow tint to syrups, etc.
II.—Ground fustic wood 1 1/2 ounces Deodorized alcohol 4 fluidounces Distilled water 4 fluidounces
This color may be made in the same manner as the liquid saffron, and is a fine coloring for many purposes.
III.—Turmeric powder 2 ounces Alcohol, dilute 16 ounces
Macerate for several days, agitating frequently, and filter. For some beverages the addition of this tincture is not to be recommended, as it possesses a very spicy taste.
The nonpoisonous aniline dyes recommended for coloring confectionery, beverages, liquors, essences, etc., yellow are those known as acid yellow R and tropæolin 000 (orange I).
BICYCLE-TIRE CEMENT: See Adhesives, under Rubber Cements.
BICYCLE VARNISHES: See Varnishes. {120}
BIDERY METAL: See Alloys.
BILLIARD BALLS: See Ivory and Casein.
BIRCH BALSAM: See Balsam.
BIRCH WATER: See Hair Preparations.
BIRD DISEASES AND THEIR REMEDIES: See Veterinary Formulas.
«BIRD FOODS:»
See also Veterinary Formulas.
«Mixed Birdseed.»—
Canary seed 6 parts Rape seed 2 parts Maw seed 1 part Millet seed 2 parts
«Mocking-Bird Food.»—
Cayenne pepper 2 ounces Rape seed 8 ounces Hemp seed 16 ounces Corn meal 2 ounces Rice 2 ounces Cracker 8 ounces Lard oil 2 ounces
Mix the solids, grinding to a coarse powder, and incorporate the oil.
«Food for Redbirds.»—
Sunflower seed 8 ounces Hemp seed 16 ounces Canary seed 10 ounces Wheat 8 ounces Rice 6 ounces
Mix and grind to coarse powder.
BIRD LIME: See Lime.
BIRD PASTE: See Canary-Bird Paste.
BISCHOFF: See Wines and Liquors.
BISCUIT, DOG: See Dog Biscuit.
BISMUTH ALLOYS: See Alloys.
BISMUTH, PURIFICATION OF: See Gold.
BITTERS: See Wines and Liquors.
BITTER WATER: See Waters.
BLACKING FOR HARNESS: See Leather.
BLACKING FOR SHOES: See Shoedressings.
BLACKING, STOVE: See Stove Blackings and Polishes.
BLACKBERRY CORDIAL AND BLACKBERRY MIXTURE AS A CHOLERA REMEDY: See Cholera Remedy.
BLACKBOARD PAINT AND VARNISH: See Paint and Varnish.
BLACKHEAD REMEDIES: See Cosmetics.
BLANKET WASHING: See Household Formulas.
BLASTING POWDER: See Explosives.
«Bleaching»
«Linen.»—Mix common bleaching powder in the proportion of 1 pound to a gallon of water; stir it occasionally for 3 days, let it settle, and pour it off clear. Then make a lye of 1 pound of soda to 1 gallon of boiling water, in which soak the linen for 12 hours, and boil it half an hour; next soak it in the bleaching liquor, made as above; and lastly, wash it in the usual manner. Discolored linen or muslin may be restored by putting a portion of bleaching liquor into the tub wherein the articles are soaking.
«Straw.»—I.—Dip the straw in a solution of oxygenated muriatic acid, saturated with potash. (Oxygenated muriate of lime is much cheaper.) The straw is thus rendered very white, and its flexibility is increased.
II.—Straw is bleached by simply exposing it in a closed chamber to the fumes of burning sulphur. An old flour barrel is the apparatus most used for the purpose by milliners, a flat stone being laid on the ground, the sulphur ignited thereon, and the barrel containing the goods to be bleached turned over it. The goods should be previously washed in pure water.
«Wool, Silk, or Straw.»—Mix together 4 pounds of oxalic acid, 4 pounds of table salt, water 50 gallons. The goods are laid in this mixture for 1 hour; they are then generally well bleached, and only require to be thoroughly rinsed and worked. For bleaching straw it is best to soak the goods in caustic soda, and afterwards to make use of chloride of lime or Javelle water. The excess of {121} chlorine is afterwards removed by hyposulphite of soda.
«Feathers.»—Place the feathers from 3 to 4 hours in a tepid dilute solution of bichromate of potassa, to which, cautiously, some nitric acid has been added (a small quantity only). To remove a greenish hue induced by this solution, place them in a dilute solution of sulphuric acid, in water, whereby the feathers become perfectly white and bleached.
«Bleaching Solution.»—Aluminum hypochloride, or Wilson’s bleaching liquid, is produced by adding to a clear solution of lime chloride a solution of aluminum sulphate (alumina, alum) as long as a precipitate keeps forming. By mutual decomposition aluminum chloride results, which remains in solution, and lime sulphate (gypsum), which separates out in the form of an insoluble salt.
«BLIGHT REMEDIES.»
I.—Soft soap 40 parts Amyl alcohol 50 parts Methylated spirit 20 parts Water 1,000 parts II.—Soft soap 30 parts Sulphureted potash 2 parts Amyl alcohol 32 parts Water 1,000 parts III.—Soft soap 15 parts Sulphureted potash 29 parts Water 1,000 parts
BLEACHING SOLUTIONS FOR THE LAUNDRY: See Laundry Preparations.
BLEACHING SOLUTION FOR PHOTOGRAPHS: See Photography.
BLEEDING, LOCAL: See Styptics.
BLISTER CURE: See Turpentine.
BLISTERS, FOR HORSES: See Veterinary Formulas.
BLOCK, HOLLOW CONCRETE BUILDING: See Stone, Artificial.
BLOCK FOR SOLDERING: See Soldering.
BLOTTING PAPER: See Paper.
«BLUE FROM GREEN AT NIGHT, TO DISTINGUISH:»
To distinguish blue from green at night, use either the light of a magnesium wire for this purpose or take a number of Swedish (parlor) matches, light them, and as soon as they flash up, observe the 2 colors, when the difference can be easily told.
BLUE (BALL): See Dyes.
BLUING: See Laundry Preparations.
BLUING OF STEEL: See Steel.
«BLUE PRINTS, TO MAKE CHANGES AND CORRECTIONS ON:»
Use a solution of sodium carbonate and water, with a little red ink mixed in. This gives a very pleasing pink color to the changes which, at the same time, is very noticeable. The amount of sodium carbonate used depends upon the surface of the blue-print paper, as some coarse-grained papers will look better if less soda is used and _vice versa_. However, the amount of powdered soda held on a small coin dissolved in a bottle of water gives good results.
BLUE-PRINT PAPER MAKING: See Photography.
BLUE PRINTS, TO TURN BROWN: See Photography, under Toning.
«BOIL REMEDY.»
Take a piece of soft linen or borated gauze, rub some vaseline upon one side of it, quickly pour upon it some chloroform, apply it to the unopened boil or carbuncle, and place a bandage over all. It smarts a little at first, but this is soon succeeded by a pleasing, cool sensation. The patient is given a bottle of the remedy, and directed to change the cloth often. In from 2 hours to 1 day the boil (no matter how indurated) softens and opens.
«Boiler Compounds»
There are three chemicals which are known to attack boiler scale. These are caustic soda, soda ash, and tannic-acid compounds, the last being derived from sumac, catechu, and the exhausted bark liquor from tanneries.
Caustic soda in large excess is injurious to boiler fittings, gaskets, valves, {122} etc. That it is injurious, in reasonable excess, to the boiler tubes themselves is yet to be proved. Foaming and priming may be caused through excess of caustic soda or soda ash, as is well known by every practical engineer. Tannic acid is to be condemned and the use of its salts is not to be recommended. It may unite with the organic matter, present in the form of albuminoids, and with calcium and magnesium carbonates. That it removes scale is an assured fact; that it removes iron with the scale is also assured, as tannic acid corrodes an iron surface rapidly.
Compounds of vegetable origin are widely advertised, but they often contain dextrine and gum, both of which are dangerous, as they coat the tubes with a compact scale, not permitting the water to reach the iron. Molasses is acid and should not be used in the boiler. Starch substances generally should be avoided. Kerosene must be dangerous, as it is very volatile and must soon leave the boiler and pass over and through the engine.
There are two materials the use of which in boilers is not prohibited through action upon the metal itself or on account of price. These are soda ash and caustic soda. Sodium triphosphate and sodium fluoride have both been used with success, but their cost is several hundred per cent greater than soda ash. If prescribed as per analysis, in slight excess, there should be no injurious results through the use of caustic soda and soda ash. It would be practicable to manufacture an intimate mixture of caustic soda and carbonate of soda, containing enough of each to soften the average water of a given district.
There is a great deal of fraud in connection with boiler compounds generally. The better class of venders advertise to prepare a special compound for special water. This is expensive, save on a large scale, in reference to a particular water, for it would mean a score or more of tanks with men to make up the mixtures. The less honest of the boiler-compound guild consign each sample of water to the sewer and send the regular goods. Others have a stock analysis which is sent to customers of a given locality, whether it contains iron, lime, or magnesium sulphates or carbonates.
Any expense for softening water in excess of 3 cents per 1,000 gallons is for the privilege of using a ready-made softener. Every superintendent in charge of a plant should insist that the compound used be pronounced by competent authority free from injurious materials, and that it be adapted to the water in use.
Boiler compounds should contain only such ingredients as will neutralize the scale-forming salts present. They should be used only by prescription, so many gallons per 1,000 gallons of feed water. A properly proportioned mixture of soda ought to answer the demands of all plants depending upon that method of softening water in limestone and shale regions.
The honest boiler compounds are, however, useful for small isolated plants, because of the simplicity of their action. For plants of from 75 to 150 horse power two 24-hour settling tanks will answer the purpose of a softening system. Each of these, capable of holding a day’s supply, provided with a soda tank in common, and with sludge valves, has paddles for stirring the contents. Large plants are operated on this principle, serving boilers of many thousand horse power. Such a system has an advantage over a continuous system, in that the exact amount of chemical solutions required for softening the particular water can be applied. For some variations of such a system, several companies have secured patents. The fundamental principles, however, have been used for many years and are not patentable.
«Prevention of Boiler Scale.»—The lime contained in the feed water, either as bicarbonate or as sulphate, is precipitated in the shape of a light mud, but the walls of the boiler remain perfectly bright without being attacked in any manner. While under ordinary atmospheric pressure calcium chromate in solution is precipitated by soda or Glauber’s salt as calcium carbonate or as calcium sulphate; the latter is separated under higher pressure by chromates as calcium chromate. An excess of chromates or chromic acid does not exercise any deleterious action upon the metal, nor upon the materials used for packing. By the slight admixture of chromates, two pounds are sufficient for a small boiler for weeks; no injurious ingredients are carried in by the wet steam, the injection water, on the contrary, having been found to be chemically pure.
«Protecting Boiler Plates from Scale.»—
I.—For a 5-horse-power boiler, fed with water which contains calcic sulphate, take catechu, 2 pounds; dextrine, 1 pound; crystallized soda, 2 pounds; potash, 1/2 pound; cane sugar, 1/2 pound; alum, 1/2 pound; gum arabic, 1/2 pound. {123}
II.—For a boiler of the same size, fed with water which contains lime: Turmeric, 2 pounds; dextrine, 1 pound; sodium bicarbonate, 2 pounds; potash, 1/2 pound; alum, 1/2 pound; molasses, 1/2 pound.
III.—For a boiler of the same size, fed with water which contains iron: Gamboge, 2 pounds; soda, 2 pounds; dextrine, 1 pound; potash, 1/2 pound; sugar, 1/2 pound; alum, 1/2 pound; gum arabic, 1/2 pound.
IV.—For a boiler of the same size, fed with sea water: Catechu, 2 pounds; Glauber’s salt, 2 pounds; dextrine, 2 pounds; alum, 1/2 pound; gum arabic, 1/2 pound.
When these preparations are used add 1 quart of water, and in ordinary cases charge the boiler every month; but if the incrustation is very bad, charge every two weeks.
V.—Place within the boiler of 100 horse power 1 bucketful of washing soda; put in 2 gallons of kerosene oil (after closing the blow-off cock), and fill the boiler with water. Feed in at least 1 quart of kerosene oil every day through a sight-feed oil cup attached to the feed pipe near the boiler—i. e., between the heater and the boiler—so that the oil is not entrapped within the heater. If it is inconvenient to open the boiler, then dissolve the washing soda in hot water and feed it in with the pump or through a tallow cock (attached between the ejector and the valve in the suction pipe) when the ejector is working.
VI.—A paint for protecting boiler plates from scale, and patented in Germany, is composed of 10 pounds each of train oil, horse fat, paraffine, and of finely ground zinc white. To this mixture is added 40 pounds of graphite and 10 pounds of soot made together into a paste with 1 1/2 gallons of water, and about a pound of carbolic acid. The horse fat and the zinc oxide make a soap difficult to fuse, which adheres strongly to the plates, and binds the graphite and the soot. The paraffine prevents the water from penetrating the coats. The scale which forms on this application can be detached, it is said, with a wooden mallet, without injuring the paint.
VII.—M. E. Asselin, of Paris, recommends the use of glycerine as a preventive. It increases the solubility of combinations of lime, and especially of the sulphate. It forms with these combinations soluble compounds. When the quantity of lime becomes so great that it can no longer be dissolved, nor form soluble combinations, it is deposited in a gelatinous substance, which never adheres to the surface of the iron plates. The gelatinous substances thus formed are not carried with the steam into the cylinder of the engine. M. Asselin advises the employment of 1 pound of glycerine for every 300 pounds or 400 pounds of coal burnt.
«Prevention of Electrolysis.»—In order to prevent the eating away of the sheets and tubes by electrolytic action, it has long been the practice of marine engineers to suspend slabs of zinc in their boilers. The zinc, being more susceptible to the electrolytic action than the iron, is eaten away, while the iron remains unimpaired. The use of zinc in this way has been found also to reduce the trouble from boiler scale. Whether it be due to the formation of hydrogen bubbles between the heating surfaces and incipient scale, to the presence in the water of the zinc salts resulting from the dissolution of the zinc, or to whatever cause, it appears to be a general conclusion among those who have used it that the zinc helps the scale, as well as the corrosion. Nobody has ever claimed for it that it prevented the attachment of scale altogether, but the consensus of opinion is that it “helps some.”
«BOILER PRESSURE.»
It hardly pays to reduce pressure on boilers, except in very extreme cases, but if it can be done by throttling before the steam reaches the cylinder of the engine it would be an advantage, because this retains the heat units due to the higher pressure in the steam, and the throttling has a slight superheating effect. As a matter of fact, tests go to show that for light loads and high pressure a throttling engine may do better than an automatic cut-off. The ideal arrangement is to throttle the steam for light loads; for heavier loads, allow the variable cut-off to come into play. This practice has been carried into effect by the design of Mr. E. J. Armstrong, in which he arranges the shaft governor so that there is negative lead up to nearly one-quarter cut-off, after which the lead becomes positive, and this has the effect of throttling the steam for the earlier loads and undoubtedly gives better economy, in addition to making the engine run more quietly.
«BONE BLACK:»
«Bone or Ivory Black.»—All bones (and ivory is bone in a sense) consist of a framework of crystallized matter or bone earth, in the interstices of which organic matter is embedded. Hence if {124} bones are heated red-hot in a closed vessel, the organic matter is destroyed, leaving carbon, in a finely divided state, lodged in the bony framework. If the heat is applied gradually the bone retains its shape, but is quite black and of much less weight than at first. This bone black or animal charcoal is a substance which has great power of absorbing coloring matter from liquids, so that it is largely used for bleaching such liquids. For example, in the vast industry of beet-sugar manufacture the solutions first made are very dark in color, but after filtration through animal charcoal will give colorless crystals on evaporation. Chemical trades require such large quantities of bone charcoal that its production is a large industry in itself. As in breaking up the charred bones a considerable amount of waste is produced, in the form of dust and small grains which cannot be used for bleaching purposes, this waste should be worked up into a pigment. This is done by dissolving out the mineral with hydrochloric acid, and then rinsing and drying the carbon.
The mineral basis of bones consists mainly of the phosphates of lime and magnesia, salts soluble in not too dilute hydrochloric acid. A vat is half filled with the above-mentioned waste, which is then just covered with a mixture of equal volumes of commercial hydrochloric acid and water. As the mineral matter also contains carbonates, a lively effervescence at once ensues, and small quantities of hydrofluoric acid are also formed from the decomposition of calcium fluoride in the bones. Now hydrofluoric acid is a very dangerous substance, as air containing even traces of it is very injurious to the lungs. Hence the addition of hydrochloric acid should be done in the open air, and the vat should be left by itself until the evolution of fumes ceases. A plug is then pulled out at the bottom and the carbon is thoroughly drained. It is then stirred up with water and again drained, when it has fully settled to the bottom. This rinsing with clear water is repeated till all the hydrochloric acid is washed away and only pure carbon remains in the vat. As for pigment-making purposes it is essential that the carbon should be as finely divided as possible, it is as well to grind the washed carbon in an ordinary color mill. Very little power is required for this purpose, as when once the bone earth is removed the carbon particles have little cohesion. The properly ground mass forms a deep-black mud, which can be left to dry or be dried by artificial heat. When dry, the purified bone black is of a pure black and makes a most excellent pigment.
Bone black is put upon the market under all sorts of names, such as ivory black, _ebur ustum_, Frankfort black, neutral black, etc. All these consist of finely ground bone black purified from mineral matter. If leather scraps or dried blood are to be worked up, iron tubes are employed, closed at one end, and with a well-fitting lid with a small hole in it at the other. As these bodies give off large volumes of combustible gas during the charring, it is a good plan to lead the vapors from the hole by a bent tube so that they can be burnt and help to supply the heat required and so save fuel. Leather or blood gives a charcoal which hardly requires treatment with hydrochloric acid, for the amount of mineral salts present is so small that its removal appears superfluous.
«BONES, A TEST FOR BROKEN.»
Place a stethoscope on one side of the supposed fracture, and a tuning fork on the other. When the latter is vibrated, and there is no breakage, the sound will be heard distinctly through bone and stethoscope. Should any doubt exist, comparison should be made with the same bone on the other side of the body. This test shows the difference in the power of conducting sound possessed by bone and soft tissue.
BONE BLEACHES: See Ivory.
BONE FAT: See Fats.
BONE FAT, PURIFICATION AND BLEACHING OF: See Soap.
BONE POLISHES: See Polishes.
BONE FERTILIZERS: See Fertilizers.
BONES, TREATMENT OF, IN MANUFACTURING GLUE: See Adhesives.
BONE, UNITING GLASS WITH: See Adhesives.
«BOOKS, THEIR HANDLING AND PRESERVATION:»
«The Preservation of Books in Hot Climates.»—Books in hot climates quickly deteriorate unless carefully guarded. There are three destructive agencies: (1) damp, (2) a small black insect, (3) cockroaches. {125}
(1) Books which are kept in a damp atmosphere deteriorate on account of molds and fungi that grow rapidly when the conditions are favorable. Books are best kept on open, airy, well-lighted shelves. When there has been a prolonged spell of moist weather their covers should be wiped, and they should be placed in the sun or before a fire for a few hours. Damp also causes the bindings and leaves of some books to separate.
(2) A small black insect, one-eighth of an inch long and a sixteenth of an inch broad, somewhat resembling a beetle, is very destructive, and books will be found, if left untouched, after a few months to have numerous holes in the covers and leaves. If this insect be allowed plenty of time for its ravages it will make so many holes that bindings originally strong can be easily torn to pieces. All damage may be prevented by coating the covers of books with the varnish described under (3). When books are found to contain the insects they should be well wrapped and placed in the sun before varnishing.
(3) The appearance of a fine binding may be destroyed in a single night by cockroaches. The lettering of the binding may, in two or three days, be completely obliterated.
The following varnishes have been found to prevent effectually the ravages of cockroaches and of all insects that feed upon books:
I.—Dammar resin 2 ounces Mastic 2 ounces Canada balsam 1 ounce Creosote 1/2 ounce Spirit of wine 20 fl. ounces
Macerate with occasional shaking for a few days if wanted at once, but for a longer time when possible, as a better varnish will result after a maceration of several months.