Part 47

Turned into their equivalents of sensation, the different light-waves produce different colours. Red, for example, is produced by the largest waves, violet by the smallest, while green is produced by a wave of intermediate length and amplitude. On entering from air into a more highly refracting substance, such as glass or water, or the sulphide of carbon, all the waves are retarded, but the smallest ones most. This furnishes a means of separating the different classes of waves from each other; in other words, of analysing the light.

Sent through a refracting prism, the waves of the sun are turned aside in different degrees from their direct course, the red least, the violet most. They are virtually pulled asunder, and they paint upon a white screen placed to receive them 'the solar spectrum.' Strictly speaking, the spectrum embraces an infinity of colours; but the limits of language, and of our powers of distinction, cause it to be divided into seven segments: red, orange, yellow, green, blue, indigo, violet. These are the seven primary or prismatic colours.

Separately, or mixed in various proportions, the solar waves yield all the colours observed in nature and employed in art. Collectively, they give us the impression of whiteness. Pure unsifted solar light is white; and, if all the wave-constituents of such light be reduced in the same proportion, the light, though diminished in intensity, will still be white. The whiteness of snow with the sun shining upon it, is barely tolerable to the eye. The same snow under an overcast firmament is still white. Such a firmament enfeebles the light by reflecting it upwards; and when we stand above a cloud-field--on an Alpine summit, for instance, or on the top of Snowdon--and see, in the proper direction, the sun shining on the clouds below us, they appear dazzlingly white. Ordinary clouds, in fact, divide the solar light impinging on them into two parts--a reflected part and a transmitted part, in each of which the proportions of wave-motion which produce the impression of whiteness are sensibly preserved.

It will be understood that the condition of whiteness would fail if all the waves were diminished _equally_, or by the same absolute quantity. They must be reduced _proportionately_, instead of equally. If by the act of reflection the waves of red light are split into exact halves, then, to preserve the light white, the waves of yellow, orange, green, and blue, must also be split into exact halves. In short, the reduction must take place, not by absolutely equal quantities, but by equal fractional parts. In white light the preponderance, as regards energy, of the larger over the smaller waves must always be immense. Were the case otherwise, the visual correlative, blue, of the smaller waves would have the upper hand in our sensations.

Not only are the waves of aether reflected by clouds, by solids, and by liquids, but when they pass from light air to dense, or from dense air to light, a portion of the wave-motion is always reflected. Now our atmosphere changes continually in density from top to bottom. It will help our conceptions if we regard it as made up of a series of thin concentric layers, or shells of air, each shell being of the same density throughout, a small and sudden change of density occurring in passing from shell to shell. Light would be reflected at the limiting surfaces of all these shells, and their action would be practically the same as that of the real atmosphere. And now I would ask your imagination to picture this act of reflection. What must become of the reflected light? The atmospheric layers turn their convex surfaces towards the sun; they are so many convex mirrors of feeble power; and you will immediately perceive that the light regularly reflected from these surfaces cannot reach the earth at all, but is dispersed in space. Light thus reflected cannot, therefore, be the light of the sky.

But, though the sun's light is not reflected in this fashion from the aerial layers to the earth, there is indubitable evidence to show that the light of our firmament is scattered light. Proofs of the most cogent description could be here adduced; but we need only consider that we receive light at the same time from all parts of the hemisphere of heaven. The light of the firmament comes to us across the direction of the solar rays, and even against the direction of the solar rays; and this lateral and opposing rush of wave-motion can only be due to the rebound of the waves from the air itself, or from something suspended in the air. It is also evident that, unlike the action of clouds, the solar light is not reflected by the sky in the proportions which produce white. The sky is blue, which indicates an excess of the shorter waves. In accounting for the colour of the sky, the first question suggested by analogy would undoubtedly be, Is not the air blue? The blueness of the air has, in fact, been given as a solution of the blueness of the sky. But how, if the air be blue, can the light of sunrise and sunset, which travels through vast distances of air, be yellow, orange, or even red? The passage of white solar light through a blue medium could by no possibility redden the light.

The hypothesis of a blue air is therefore untenable. In fact the agent, whatever it is, which sends us the light of the sky, exercises in so doing a dichroitic action. The light reflected is blue, the light transmitted is orange or red. A marked distinction is thus exhibited between the matter of the sky, and that of an ordinary cloud, which exercises no such dichroitic action.

By the scientific use of the imagination we may hope to penetrate this mystery. The cloud takes no note of size on the part of the waves of aether, but reflects them all alike. It exercises no selective action. Now the cause of this may be that the cloud particles are so large, in comparison with the waves of aether, as to reflect them all indifferently. A broad cliff reflects an Atlantic roller as easily as a ripple produced by a seabird's wing; and in the presence of large reflecting surfaces, the existing differences of magnitude among the waves of aether may disappear. But supposing the reflecting particles, instead of being very large, to be very small in comparison with the size of the waves. In this case, instead of the whole wave being fronted and thrown back, a small portion only is shivered off. The great mass of the wave passes over such a particle without reflection. Scatter, then, a handful of such minute foreign particles in our atmosphere, and set imagination to watch their action upon the solar waves. Waves of all sizes impinge upon the particles, and you see at every collision a portion of the impinging wave struck off; all the waves of the spectrum, from the extreme red to the extreme violet, being thus acted upon.

Remembering that the red waves stand to the blue much in the relation of billows to ripples, we have to consider whether those extremely small particles are competent to scatter all the waves in the same proportion. If they be not--and a little reflection will make it clear that they are not--the production of colour must be an incident of the scattering. Largeness is a thing of relation; and the smaller the wave, the greater is the relative size of any particle on which the wave impinges, and the greater also the ratio of the portion scattered to the total wave A pebble, placed in the way of the ring-ripples produced by heavy raindrops on a tranquil pond, will scatter a large fraction of each ripple, while the fractional part of a larger wave thrown back by the same pebble might be infinitesimal. Now we have already made it clear to our minds that to preserve the solar light white, its constituent proportions must not be altered; but in the act of division performed by these very small particles the proportions are altered; an undue fraction of the smaller waves is scattered by the particles, and, as a consequence, in the scattered light, blue will be the predominant colour. The other colours of the spectrum must, to some extent, be associated with the blue. They are not absent, but deficient. We ought, in fact, to have them all, but in diminishing proportions, from the violet to the red.

We have here presented a case to the imagination, pad, assuming the undulatory theory to be a reality, we have, I think, fairly reasoned our way to the conclusion, that were particles, small in comparison to the sizes of the aether waves, sown in our atmosphere, the light scattered by those particles would be exactly such as we observe in our azure skies. When this light is analysed, all the colours of the spectrum are found, and they are found in the proportions indicated by our conclusion. Blue is not the sole, but it is the predominant colour.

Let us now turn our attention to the light which passes unscattered among the particles. How must it be finally affected? By its successive collisions with the particles the white light is more and more robbed of its shorter waves; it therefore loses more and more of its due proportion of blue. The result may be anticipated. The transmitted light, where short distances are involved, will appear yellowish. But as the sun sinks towards the horizon the atmospheric distances increase, and consequently the number of the scattering particles. They abstract in succession the violet, the indigo, the blue, and even disturb the proportions of green. The transmitted light under such circumstances must pass from yellow through orange to red. This also is exactly what we find in nature. Thus, while the reflected light gives us at noon the deep azure of the Alpine skies, the transmitted light gives us at sunset the warm crimson of the Alpine snows. The phenomena certainly occur as if our atmosphere were a medium rendered slightly turbid by the mechanical suspension of exceedingly small foreign particles.

Here, as before, we encounter our sceptical 'as if.' It is one of the parasites of science, ever at hand, and ready to plant itself and sprout, if it can, on the weak points of our philosophy. But a strong constitution defies the parasite, and in our case, as we question the phenomena, probability grows like growing health, until in the end the malady of doubt is completely extirpated. The first question that naturally arises is this: Can small particles be really proved to act in the manner indicated? No doubt of it. Each one of you can submit the question to an experimental test. Water will not dissolve resin, but spirit will dissolve it; and when spirit holding resin in solution is dropped into water, the resin immediately separates in solid particles, which render the water milky. The coarseness of this precipitate depends on the quantity of the dissolved resin. You can cause it to separate either in thick clots or in exceedingly fine particles. Professor Bruecke has given us the proportions which produce particles particularly suited to our present purpose. One gramme of clean mastic is dissolved in eighty-seven grammes of absolute alcohol, and the transparent solution is allowed to drop into a beaker containing clear water, kept briskly stirred. An exceedingly fine precipitate is thus formed, which declares its presence by its action upon light. Placing a dark surface behind the beaker, and permitting the light to fall into it from the top or front, the medium is seen to be distinctly blue. It is not perhaps so perfect a blue as may be seen on exceptional days among the Alps, but it is a very fair sky-blue. A trace of soap in water gives a tint of blue. London, and I fear Liverpool, milk makes an approximation to the same colour, through the operation of the same cause; and Helmholtz has irreverently disclosed the fact that the deepest blue eye is simply a turbid medium.

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The action of turbid media upon light was illustrated by Goethe, who, though unacquainted with the undulatory theory, was led by his experiments to regard the firmament as an illuminated turbid medium, with the darkness of space behind it. He describes glasses showing a bright yellow by transmitted, and a beautiful blue by reflected, light. Professor Stokes, who was probably the first to discern the real nature of the action of small particles on the waves of aether, [Footnote: This is inferred from conversation. I am not aware that Professor Stokes has published anything upon the subject.] describes a glass of a similar kind. [Footnote: This glass, by reflected light, had a colour 'strongly resembling that of a decoction of horse-chestnut bark.' Curiously enough, Goethe refers to this very decoction: 'Man nehme einen Streifen frischer Rinds von der Rosskastanie, man stecke denselben in ein Glas Wasser, und in der kuerzesten Zeit werden wir das vollkommenste Himmelblau entstehen sehen.'--Goethe's Werke, B. xxix. p. 24.]

Capital specimens of such glass are to be found at Salviati's, in St. James's Street. What artists call 'chill' is no doubt an effect of this description. Through the action of minute particles, the browns of a picture often present the appearance of the bloom of a plum. By rubbing the varnish with a silk handkerchief optical continuity is established and the chill disappears. Some years ago I witnessed Mr. Hirst experimenting at Zermatt on the turbid water of the Visp. When kept still for a day or so, the grosser matter sank, but the finer particles remained suspended, and gave a distinctly blue tinge to the water. The blueness of certain Alpine lakes has been shown to be in part due to this cause. Professor Roscoe has noticed several striking cases of a similar kind. In a very remarkable paper the late Principal Forbes showed that steam issuing from the safety-valve of a locomotive, when favourably observed, exhibits at a certain stage of its condensation the colours of the sky. It is blue by reflected light, and orange or red by transmitted light. The same effect, as pointed out by Goethe, is to some extent exhibited by peat-smoke. More than ten years ago, I amused myself by observing, on a calm day at Killarney, the straight smoke-columns rising from the cabin-chimneys. It was easy to project the lower portion of a column against a dark pine, and its upper portion against a bright cloud. The smoke in the former case was blue, being seen mainly by reflected light; in the latter case it was reddish, being seen mainly by transmitted light. Such smoke was not in exactly the condition to give us the glow of the Alps, but it was a step in this direction. Bruecke's fine precipitate above referred to looks yellowish by transmitted light; but, by duly strengthening the precipitate, you may render the white light of noon as ruby-coloured as the sun, when seen through Liverpool smoke, or upon Alpine horizons. I do not, however, point to the gross smoke arising from coal as an illustration of the action of small particles, because such smoke soon absorbs and destroys the waves of blue, instead of sending them to the eyes of the observer.

These multifarious facts, and numberless others which cannot now be referred to, are explained by reference to the single principle, that, where the scattering particles are small in comparison to the aethereal waves, we have in the reflected light a greater proportion of the smaller waves, and in the transmitted light a greater proportion of the larger waves, than existed in the original white light. The consequence, as regards sensation, is that in the one ease blue is predominant, and in the other orange or red. Our best microscopes can readily reveal objects not more than 1/50000th of an inch in diameter. This is less than the length of a wave of red light. Indeed a first-rate microscope would enable us to discern objects not exceeding in diameter the length of the smallest waves of the visible spectrum. [Footnote: Dallinger and Drysdale have recently measured cilia 1/200000th of an inch in diameter. 1878.] By the microscope, therefore, we can test our particles. If they be as large as the light-waves they will infallibly be seen; and if they be not so seen, it is because they are smaller. Some months ago I placed in the hands of our President a liquid containing Bruecke's precipitate. The liquid was milky blue, and Mr. Huxley applied to it his highest microscopic power. He satisfied me that had particles of even 1/100000th of an inch in diameter existed in the liquid, they could not have escaped detection. But no particles were seen. Under the microscope the turbid liquid was not to be distinguished from distilled water. [Footnote: Like Dr. Burdon Sanderson's 'pyrogen,' the particles of mastic passed, without sensible hindrance, through filtering-paper. By such filtering no freedom from suspended particles is secured. The application of a condensed beam to the filtrate renders this at once evident.]

But we have it in our power to imitate, far more closely than we have hitherto done, the natural conditions of this problem. We can generate, in air, artificial skies, and prove their perfect identity with the natural one, as regards the exhibition of a number of wholly unexpected phenomena. By a continuous process of growth, moreover, we are able to connect sky-matter, if I may use the term, with molecular matter on the one side, and with molar matter, or matter in sensible masses, on the other. In illustration of this, I will take an experiment suggested by some of my own researches, and described by M. Morren of Marseilles at the Exeter meeting of the British Association. Sulphur and oxygen combine to form sulphurous acid gas, two atoms of oxygen and one of sulphur constituting the molecule of sulphurous acid. It has been recently shown that waves of aether issuing from a strong source, such as the sun or the electric light, are competent to shake asunder the atoms of gaseous molecules. [Footnote: See 'New Chemical Reactions produced by Light,' vol. i.] A chemist would call this, 'decomposition' by light; but it behoves us, who are examining the power and function of the imagination, to keep constantly before us the physical images which underlie our terms. Therefore I say, sharply and definitely, that the components of the molecules of sulphurous acid are shaken asunder by the aether-waves. Enclosing sulphurous acid in a suitable vessel, placing it in a dark room, and sending through it a powerful beam of light, we at first see nothing: the vessel containing the gas seems as empty as a vacuum. Soon, however, along the track of the beam a beautiful sky-blue colour is observed, which is due to light scattered by the liberated particles of sulphur. For a time the blue grows more intense; it then becomes whitish; and ends in a more or less perfect white. When the action is continued long enough, the tube is filled with a dense cloud of sulphur particles, which by the application of proper means may be rendered individually visible. [Footnote: M. Morren was mistaken in supposing that a modicum of sulphurous acid, in the drying tubes, had any share in the production of the 'actinic clouds' described by me. A beautiful case of molecular instability in the presence of light is furnished by peroxide of chlorine as proved by Professor Dewar. 1878.]

Here, then, our aether-waves untie the bond of chemical affinity, and liberate a body--sulphur--which at ordinary temperatures is a solid, and which therefore soon becomes an object of the senses. We have first of all the free atoms of sulphur, which are incompetent to stir the retina sensibly with scattered light. But these atoms gradually coalesce and form _particles_, which grow larger by continual accretion, until after a minute or two they appear as sky-matter. In this condition they are individually invisible; but collectively they send an amount of wave-motion to the retina, sufficient to produce the firmamental blue. The particles continue, or may be caused to continue, in this condition for a considerable time, during which no microscope can cope with them. But they grow slowly larger, and pass by insensible gradations into the state of _cloud_, when they can no longer elude the armed eye. Thus, without solution of continuity, we start with matter in the atom, and end with matter in the mass; sky-matter being the middle term of the series of transformations. Instead of sulphurous acid, we might choose a dozen other substances, and produce the same effect with all of them. In the case of some--probably in the case of all--it is possible to preserve matter in the firmamental condition for fifteen or twenty minutes under the continual operation of the light. During these fifteen or twenty minutes the particles constantly grow larger, without ever exceeding the size requisite to the production of the celestial blue.

Now when two vessels are placed before us, each containing sky-matter, it is possible to state with great distinctness which vessel contains the largest particles. The eye is very sensitive to differences of light, when, as in our experiments, it is placed in comparative darkness, and the wave-motion thrown against the retina is small. The larger particles declare themselves by the greater whiteness of their scattered light. Call now to mind the observation, or effort at observation, made by our President, when he failed to distinguish the particles of mastic in Bruecke's medium, and when you have done this, please follow me.

A beam of light is permitted to act upon a certain vapour. In two minutes the azure appears, but at the end of fifteen minutes it has not ceased to be azure. After fifteen minutes its colour, and some other phenomena, pronounce it to be a blue of distinctly smaller particles than those sought for in vain by Mr. Huxley. These particles, as already stated, must have been less than 1/100000th of an inch in diameter.

And now I want you to consider the following question: Here are particles which have been growing continually for fifteen minutes, and at the end of that time are demonstrably smaller than those which defied the microscope of Mr. Huxley--_What must have been the size of these particles at the beginning of their growth?_ What notion can you form of the magnitude of such particles? The distances of stellar space give us simply a bewildering sense of vastness, without leaving any distinct impression on the mind; and the magnitudes with which we have here to do, bewilder us equally in the opposite direction. We are dealing with infinitesimals, compared with which the test objects of the microscope are literally immense.