Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2

Part 37

Chapter 374,008 wordsPublic domain

This is the simple and natural account, given subsequently by Mayer himself, of the course of thought started by his observation in Java. But the conviction once formed, that an unalterable relation subsists between work and heat, it was: inevitable that Mayer should seek to express it numerically. It was also inevitable that a mind like his, having raised itself to clearness on this important point, should push forward to consider the relationship of natural forces generally. At the beginning of 1842 his work had made considerable progress; but he had become physician to the town of Heilbronn, and the duties of his profession limited the time which he could devote to purely scientific enquiry. He thought it wise, therefore, to secure himself against accident, and in the spring of 1842 wrote to Liebig, asking him to publish in his 'Annalen' a brief preliminary notice of the work then accomplished. Liebig did so, and Dr. Mayer's first paper is contained in the May number of the 'Annalen' for 1842.

Mayer had reached his conclusions by reflecting on the complex processes of the living body; but his first step in public was to state definitely the physical principles on which his physiological deductions were to rest. He begins, therefore, with the forces of inorganic nature. He finds in the universe two systems of causes which are not mutually convertible;--the different kinds of matter and the different forms of force. The first quality of both he affirms to be indestructibility. A force cannot become nothing, nor can it arise from nothing. Forces are convertible but not destructible. In the terminology of his time, he then gives clear expression to the ideas of potential and dynamic energy, illustrating his point by a weight resting upon the earth, suspended at a height above the earth, and actually falling to the earth. He next fixes his attention on cases where motion is apparently destroyed, without producing other motion; on the shock of inelastic bodies, for example. Under what form does the vanished motion maintain itself? Experiment alone, says Mayer, can help us here. He warms water by stirring it; he refers to the force expended in overcoming friction. Motion in both cases disappears; but heat is generated, and the quantity generated is the equivalent of the motion destroyed. 'Our locomotives,' he observes with extraordinary sagacity, 'may be compared to distilling apparatus: the heat beneath the boiler passes into the motion of the train, and is again deposited as heat in the axles and wheels.

A numerical solution of the relation between heat and work was what Mayer aimed at, and towards the end of his first paper he makes the attempt. It was known that a definite amount of air, in rising one degree in temperature, can take up two different amounts of heat. If its volume be kept constant, it takes up one amount: if its pressure be kept constant it takes up a different amount. These two amounts are called the specific heat under constant volume and under constant pressure. The ratio of the first to the second is as 1: 1.421. No man, to my knowledge, prior to Dr. Mayer, penetrated the significance of these two numbers. He first saw that the excess 0.421 was not, as then universally supposed, heat actually lodged in the gas, but heat which had been actually consumed by the gas in expanding against pressure. The amount of work here performed was accurately known, the amount of heat consumed was also accurately known, and from these data Mayer determined the mechanical equivalent of heat. Even in this first paper he is able to direct attention to the enormous discrepancy between the theoretic power of the fuel consumed in steam-engines, and their useful effect.

Though this paper contains but the germ of his further labours, I think it may be safely assumed that, as regards the mechanical theory of heat, this obscure Heilbronn physician, in the year 1842, was in advance of all the scientific men of the time.

Having, by the publication of this paper, secured himself against what he calls 'Eventualitaeten,' he devoted every hour of his spare time to his studies, and in 1845 published a memoir which far transcends his first one in weight and fulness, and, indeed, marks an epoch in the history of science. The title of Mayer's first paper was, 'Remarks on the Forces of Inorganic Nature.' The title of his second great essay was, 'Organic Motion in its Connection with Nutrition.' In it he expands and illustrates the physical principles laid down in his first brief paper.

He goes fully through the calculation of the mechanical equivalent of heat. He calculates the performances of steam-engines, and finds that 100 lbs. of coal, in a good working engine, produce only the same amount of heat as 95 lbs. in an unworking one; the 5 missing lbs. having been converted into work. He determines the useful effect of gunpowder, and finds nine per cent. of the force of the consumed charcoal invested on the moving ball. He records observations on the heat generated in water agitated by the pulping engine of a paper manufactory, and calculates the equivalent of that heat in horse-power. He compares chemical combination with mechanical combination--the union of atoms with the union of falling bodies with the earth. He calculates the velocity with which a body starting at an infinite distance would strike the earth's surface, and finds that the heat generated by its collision would raise an equal weight of water 17,356' C. in temperature. He then determines the thermal effect which would be produced by the earth itself falling into the sun. So that here, in 1845, we have the germ of that meteoric theory of the sun's heat which Mayer developed with such extraordinary ability three years afterwards. He also points to the almost exclusive efficacy of the sun's heat in producing mechanical motions upon the earth, winding up with the profound remark, that the heat developed by friction in the wheels of our wind and water mills comes from the sun in the form of vibratory motion; while the heat produced by mills driven by tidal action is generated at the expense of the earth's axial rotation.

Having thus, with firm step, passed through the powers of inorganic nature, his next object is to bring his principles to bear upon the phenomena of vegetable and animal life. Wood and coal can burn; whence come their heat, and the work producible by that heat? From the immeasurable reservoir of the sun. Nature has proposed to herself the task of storing up the light which streams earthward from the sun, and of casting into a permanent form the most fugitive of all powers. To this end she has overspread the earth with organisms which, while living, take in the solar light, and by its consumption generate forces of another kind. These organisms are plants. The vegetable world, indeed, constitutes the instrument whereby the wave-motion of the sun is changed into the rigid form of chemical tension, and thus prepared for future use. With this prevision, as shall subsequently be shown, the existence of the human race itself is inseparably connected. It is to be observed that Mayer's utterances are far from being anticipated by vague statements regarding the 'stimulus' of light, or regarding coal as 'bottled sunlight.' He first saw the full meaning of De Saussure's observation as to the reducing power of the solar rays, and gave that observation its proper place in the doctrine of conservation. In the leaves of a tree, the carbon and oxygen of carbonic acid, and the hydrogen and oxygen of water, are forced asunder at the expense of the sun, and the amount of power thus sacrificed is accurately restored by the combustion of the tree. The heat and work potential in our coal strata are so much strength withdrawn from the sun of former ages. Mayer lays the axe to the root of the notions regarding 'vital force' which were prevalent when he wrote. With the plain fact before us that in the absence of the solar rays plants cannot perform the work of reduction, or generate chemical tensions, it is, he contends, incredible that these tensions should be caused by the mystic play of the vital force. Such an hypothesis would cut off all investigation; it would land us in a chaos of unbridled phantasy.

'I count,' he says, 'therefore, upon your agreement with me when I state, as an axiomatic truth, that during vital processes the conversion only, and never the creation of matter or force occurs.'

Having cleared his way through the vegetable world, as he had previously done through inorganic nature, Mayer passes on to the other organic kingdom. The physical forces collected by plants become the property of animals. Animals consume vegetables, and cause them to reunite with the atmospheric oxygen. Animal heat is thus produced; and not only animal heat, but animal motion. There is no indistinctness about Mayer here; he grasps his subject in all its details, and reduces to figures the concomitants of muscular action. A bowler who imparts to an 8-lb. ball a velocity of 30 feet, consumes in the act one tenth of a grain of carbon. A man weighing 150 lbs, who lifts his own body to a height of 8 feet, consumes in the act 1 grain of carbon. In climbing a mountain 10,000 feet high, the consumption of the same man would be 2 oz. 4 drs. 50 grs. of carbon. Boussingault had determined experimentally the addition to be made to the food of horses when actively working, and Liebig had determined the addition to be made to the food of men. Employing the mechanical equivalent of heat, which he had previously calculated, Mayer proves the additional food to be amply sufficient to cover the increased oxidation.

But he does not content himself with showing, in a general way, that the human body burns according to definite laws, when it performs mechanical work. He seeks to determine the particular portion of the body consumed, and in doing so executes some noteworthy calculations. The muscles of a labourer 150 lbs. in weight weigh 64 lbs; but when perfectly desiccated they fall to 15 lbs. Were the oxidation corresponding to that labourer's work exerted on the muscles alone, they would be utterly consumed in 80 days. The heart furnishes a still more striking example. Were the oxidation necessary to sustain the heart's action exerted upon its own tissue, it would be utterly consumed in 8 days. And if we confine our attention to the two ventricles, their action would be sufficient to consume the associated muscular tissue in 3.5 days. Here, in his own words, emphasised in his own way, is Mayer's pregnant conclusion from these calculations: 'The muscle is only the apparatus by means of which the conversion of the force is effected; but it is not the substance consumed in the production of the mechanical effect.' He calls the blood 'the oil of the lamp of life;' it is the slow-burning fluid whose chemical force, in the furnace of the capillaries, is sacrificed to produce animal motion. This was Mayer's conclusion twenty-six years ago. It was in complete opposition to the scientific conclusions of his time; but eminent investigators have since amply verified it.

Thus, in baldest outline, I have sought to give some notion of the first half of this marvellous essay. The second half is so exclusively physiological that I do not wish to meddle with it. I will only add the illustration employed by Mayer to explain the action of the nerves upon the muscles. As an engineer, by the motion of his finger in opening a valve or loosing a detent, can liberate an amount of mechanical motion almost infinite compared with its exciting cause, so the nerves, acting upon the muscles, can unlock an amount of activity, wholly out of proportion to the work done by the nerves themselves.

As regards these questions of weightiest import to the science of physiology, Dr. Mayer, in 1845, was assuredly far in advance of all living men.

Mayer grasped the mechanical theory of heat with commanding power, illustrating it and applying it in the most diverse domains. He began, as we have seen, with physical principles; he determined the numerical relation between heat and work; he revealed the source of the energies of the vegetable world, and showed the relationship of the heat of our fires to solar heat. He followed the energies which were potential in the vegetable, up to their local exhaustion in the animal. But in 1845 a new thought was forced upon him by his calculations. He then, for the first time, drew attention to the astounding amount of heat generated by gravity where the force has sufficient distance to act through. He proved, as I have before stated, the heat of collision of a body falling from an infinite distance to the earth, to be sufficient to raise the temperature of a quantity of water, equal to the falling body in weight, 17,356°C. He also found, in 1845, that the gravitating force between the earth and sun was competent to generate an amount of heat equal to that obtainable from the combustion of 6,000 times the weight of the earth of solid coal. With the quickness of genius he saw that we had here a power sufficient to produce the enormous temperature of the sun, and also to account for the primal molten condition of our own planet. Mayer shows the utter inadequacy of chemical forces, as we know them, to produce or maintain the solar temperature. He shows that were the sun a lump of coal it would be utterly consumed in 5,000 years. He shows the difficulties attending the assumption that the sun is a cooling body; for, supposing it to possess even the high specific heat of water, its temperature would fall 15,000' in 5,000 years. He finally concludes that the light and heat of the sun are maintained by the constant impact of meteoric matter. I never ventured an opinion as to the truth of this theory; that is a question which may still have to be fought out. But I refer to it as an illustration of the force of genius with which Mayer followed the mechanical theory of heat through all its applications. Whether the meteoric theory be a matter of fact or not, with him abides the honour of proving to demonstration that the light and heat of suns and stars may be originated and maintained by the collisions of cold planetary matter.

It is the man who with the scantiest data could accomplish all this in six short years, and in, the hours snatched from the duties of an arduous profession, that the Royal Society, in 1871, crowned with its highest honour.

Comparing this brief history with that of the Copley Medalist of 1870, the differentiating influence of 'environment,' on two minds of similar natural cast and endowment, comes out in an instructive manner. Withdrawn from mechanical appliances, Mayer fell back upon reflection, selecting with marvellous sagacity, from existing physical data, the single result on which could be founded a calculation of the mechanical equivalent of heat. In the midst of mechanical appliances, Joule resorted to experiment, and laid the broad and firm foundation which has secured for the mechanical theory the acceptance it now enjoys. A great portion of Joule's time was occupied in actual manipulation; freed from this, Mayer had time to follow the theory into its most abstruse and impressive applications. With their places reversed, however, Joule might have become Mayer, and Mayer might have become Joule.

It does not lie within the scope of these brief articles to enter upon the developments of the Dynamical Theory accomplished since Joule and Mayer executed their memorable labours.

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XXI. DEATH BY LIGHTNING.

PEOPLE in general imagine, when they think at all about the matter, that an impression upon the nerves--a blow, for example, or the prick of a pin--is felt at the moment it is inflicted. But this is not the case. The seat of sensation being the brain, to it the intelligence of any impression made upon the nerves has to be transmitted before this impression can become manifest as consciousness. The transmission, moreover, requires time, and the consequence is, that a wound inflicted on a portion of the body distant from the brain is more tardily appreciated than one inflicted adjacent to the brain. By an extremely ingenious experimental arrangement, Helmholtz has determined the velocity of this nervous transmission, and finds it to be about eighty feet a second, or less than one-thirteenth of the velocity of sound in air. If therefore, a whale forty feet long were wounded in the tail, it would not be conscious of the injury till half a second after the wound had been inflicted. [Footnote: A most admirable lecture on the velocity of nervous transmission has been published by Dr. Du Bois Reymond in the 'Proceedings of the Royal Institution' for 1866, vol. iv. p. 575.] But this is not the only ingredient in the delay. There can scarcely be a doubt that to every act of consciousness belongs a determinate molecular arrangement of the brain--that every thought or feeling has its physical correlative in that organ; and nothing can be more certain than that every physical change, whether molecular or mechanical, requires time for its accomplishment. So that, besides the interval of transmission, a still further time is necessary for the brain to put itself in order--for its molecules to take up the motions or positions necessary to the completion of consciousness. Helmholtz considers that one-tenth of a second is demanded for this purpose. Thus, in the case of the whale above supposed, we have first half a second consumed in the transmission of the intelligence through the sensor nerves to the head, one-tenth of a second consumed by the brain in completing the arrangements necessary to consciousness, and, if the velocity of transmission through the motor be the same as that through the sensor nerves, half a second in sending a command to the tail to defend itself. Thus one second and a tenth would elapse before an impression made upon its caudal nerves could be responded to by a whale forty feet long.

Now, it is quite conceivable that an injury might be inflicted so rapidly that within the time required by the brain to complete the arrangements necessary to consciousness, its power of arrangement might be destroyed. In such a case, though the injury might be of a nature to cause death, this would occur without pain, Death in this case would be simply the sudden negation of life, without any intervention of consciousness whatever.

The time required for a rifle-bullet to pass clean through a man's head may be roughly estimated at a thousandth of a second. Here, therefore, we should have no room for sensation, and death would be painless. But there are other actions which far transcend in rapidity that of the rifle-bullet. A flash of lightning cleaves a cloud, appearing and disappearing in less than a hundred-thousandth of a second, and the velocity of electricity is such as would carry it in a single second over a distance almost equal to that which separates the earth and moon. It is well known that a luminous impression once made upon the retina endures for about one-sixth of a second, and that this is the reason why we see a continuous band of light when a glowing coal is caused to pass rapidly through the air. A body illuminated by an instantaneous flash continues to be seen for the sixth of a second after the flash has become extinct; and if the body thus illuminated be in motion, it appears at rest at the place where the flash falls upon it. When a colour-top with differently-coloured sectors is caused to spin rapidly the colours blend together. Such a top, rotating in a dark room and illuminated by an electric spark, appears motionless, each distinct colour being clearly seen. Professor Dove has found that a flash of lightning produces the same effect. During a thunderstorm he put a colour-top in exceedingly rapid motion, and found that every flash revealed the top as a motionless object with its colours distinct. If illuminated solely by a flash of lightning, the motion of all bodies on the earth's surface would, as Dove has remarked, appear suspended. A cannon-ball, for example, would have its flight apparently arrested, and would seem to hang motionless in space as long as the luminous impression which revealed the ball remained upon the eye.

If, then, a rifle-bullet move with sufficient rapidity to destroy life without the interposition of sensation, much more is a flash of lightning competent to produce this effect. Accordingly, we have well-authenticated cases of people being struck senseless by lightning who, on recovery, had no memory of pain. The following circumstantial case is described by Hemmer:

On June 30, 1788, a soldier in the neighbourhood of Mannheim, being overtaken by rain, placed himself under a tree, beneath which a woman had previously taken shelter. He looked upwards to see whether the branches were thick enough to afford the required protection, and, in doing so, was struck by lightning, and fell senseless to the earth. The woman at his side experienced the shock in her foot, but was not struck down. Some hours afterwards the man revived, but remembered nothing about what had occurred, save the fact of his looking up at the branches. This was his last act of consciousness, and he passed from the conscious to the unconscious condition without pain. The visible marks of a lightning stroke are usually insignificant: the hair is sometimes burnt; slight wounds are observed; while, in some instances, a red streak marks the track of the discharge over the skin.

Under ordinary circumstances, the discharge from a small Leyden jar is exceedingly unpleasant to me. Some time ago I happened to stand in the presence of a numerous audience, with a battery of fifteen large Leyden jars charged beside me. Through some awkwardness on my part, I touched a wire leading from the battery, and the discharge went through my body. Life was absolutely blotted out for a very sensible interval, without a trace of pain. In a second or so consciousness returned; I vaguely discerned the audience and apparatus, and, by the help of these external appearances, immediately concluded that I had received the battery discharge. The intellectual consciousness of my position was restored with exceeding rapidity, but not so the optical consciousness. To prevent the audience from being alarmed, I observed that it had often been my desire to receive accidentally such a shock, and that my wish had at length been fulfilled. But, while making this remark, the appearance which my body presented to my eyes was that of a number of separate pieces. The arms, for example, were detached from the trunk, and seemed suspended in the air. In fact, memory and the power of reasoning appeared to be complete long before the optic nerve was restored to healthy action. But what I wish chiefly to dwell upon here is, the absolute painlessness of the shock; and there cannot, I think, be a doubt that, to a person struck dead by lightning, the passage from life to death occurs without consciousness being in the least degree implicated. It is an abrupt stoppage of sensation, unaccompanied by a pang.

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XXII. SCIENCE AND THE 'SPIRITS.'

THEIR refusal to investigate 'spiritual phenomena' is often urged as a reproach against scientific men. I here propose to give a sketch of an attempt to apply to the 'phenomena' those methods of enquiry which are found available in dealing with natural truth.