Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2
Part 36
'Et vous, monsieur,' he writes to Faraday, 'qui appartenez à une société à laquelle je n'avais rien offert, vous qui me connaissiez à peine de nom; vous n'avez pas demandé si j'avais des ennemis faibles ou puissants, ni calculé quel en était le nombre; mais vous avez parlé pour l'opprimé étranger, pour celui qui n'avait pas le moindre droit à tant de bienveillance, et vos paroles ont été accueillies favorablement par des collègues consciencieux! Je reconnais bien là des hommes dignes de leur noble mission, les véritable représentants de la science d'un pays libre et généreux.'
Within the prescribed limits of this article it would be impossible to give even the slenderest summary of Faraday's correspondence, or to carve from it more than the merest fragments of his character. His letters, written to Lord Melbourne and others in 1836, regarding his pension, illustrate his uncompromising independence. The Prime Minister had offended him, but assuredly the apology demanded and given was complete. I think 'it certain that, notwithstanding the very full account of this transaction given by Dr. Bence Jones, motives and influences were at work which even now are not entirely revealed. The minister was bitterly attacked, but he bore the censure of the press with great dignity. Faraday, while he disavowed having either directly or indirectly furnished the matter of those attacks, did not publicly exonerate the Premier. The Hon. Caroline Fox had proved herself Faraday's ardent friend, and it was she who had healed the breach between the philosopher and the minister. She manifestly thought that Faraday ought to have come forward in Lord Melbourne's defence, and there is a flavour of resentment in one of her letters to him on the subject. No doubt Faraday had good grounds for his reticence, but they are to me unknown.
In 1841 his health broke down utterly, and he went to Switzerland with his wife and brother-in-law. His bodily vigour soon revived, and he accomplished feats of walking respectable even for a trained mountaineer. The published extracts from his Swiss journal contain many beautiful and touching allusions. Amid references to the tints of the Jungfrau, the blue rifts of the glaciers, and the noble Niesen towering over the Lake of Thun, we come upon the charming little scrap which I have elsewhere quoted: 'Clout-nail making goes on here rather considerably, and is a very neat and pretty operation to observe. I love a smith's shop and anything relating to smithery. My father was a smith.' This is from his journal; but he is unconsciously speaking to somebody--perhaps to the world.
His description of the Staubbach, Giessbach, and of the scenic effects of sky and mountain, are all fine and sympathetic. But amid it all, and in reference to it all, he tells his sister that 'true enjoyment is from within, not from without.' In those days Agassiz was living under a slab of gneiss on the glacier of the Aar. Faraday met Forbes at the Grimsel, and arranged with him an excursion to the 'Hôtel des Neufchâtelois'; but indisposition put the project out.
From the Fort of Ham, in 1843, Faraday received a letter addressed to him by Prince Louis Napoleon Bonaparte. He read this letter to me many years ago, and the desire, shown in various ways by the French Emperor, to turn modern science to account, has often reminded me of it since. At the age of thirty-five the prisoner of Ham speaks of 'rendering his captivity less sad by studying the great discoveries' which science owes to Faraday; and he asks a question which reveals his cast of thought at the time: 'What is the most simple combination to give to a voltaic battery, in order to produce a spark capable of setting fire to powder under water or under ground?' Should the necessity arise, the French Emperor will not lack at the outset the best appliances of modern science; while we, I fear, shall have to learn the magnitude of the resources we are now neglecting amid the pangs of actual war.' [Footnote: The 'science' has since been applied, with astonishing effect, by those who had studied it far more thoroughly than the Emperor of the French. We also, I am happy to think, have improved the time since the above words were written [1878].]
One turns with renewed pleasure to Faraday's letters to his wife, published in the second volume. Here surely the loving essence of the man appears more distinctly than anywhere else. From the house of Dr. Percy, in Birmingham, he writes thus:
'Here--even here the moment I leave the table, I wish I were with you IN QUIET. Oh, what happiness is ours! My runs into the world in this way only serve to make me esteem that happiness the more.'
And again:
'We have been to a grand conversazione in the town-hall, and I have now returned to my room to talk with you, as the pleasantest and happiest thing that I can do. Nothing rests me so much as communion with you. I feel it even now as I write, and catch myself saying the words aloud as I write them.'
Take this, moreover, as indicative of his love for Nature:
'After writing, I walk out in the evening hand in hand with my dear wife to enjoy the sunset; for to me who love scenery, of all that I have seen or can see, there is none surpasses that of heaven. A glorious sunset brings with it a thousand thoughts that delight me.'
Of the numberless lights thrown upon him by the Life and Letters,' some fall upon his religion. In a letter to Lady Lovelace, he describes himself as belonging to 'a very small and despised sect of Christians, known, if known at all, as _Sandemanians_, and our hope is founded on the faith that is in Christ.' He adds: 'I do not think it at all necessary to tie the study of the natural sciences and religion together, and in my intercourse with my fellow-creatures, that which is religious, and that which is philosophical, have ever been two distinct things.' He saw clearly the danger of quitting his moorings, and his science acted indirectly as the safeguard of his faith. For his investigations so filled his mind as to leave no room for sceptical questionings, thus shielding from the assaults of philosophy, the creed of his youth. His religion was constitutional and hereditary. It was implied in the eddies of his blood and in the tremors of his brain; and, however its outward and visible form might have changed, Faraday would still have possessed its elemental constituents--awe, reverence, truth, and love.
It is worth enquiring how so profoundly religious a mind, and so great a teacher, would be likely to regard our present discussions on the subject of education. Faraday would be a 'secularist' were he now alive. He had no sympathy with those who contemn knowledge unless it be accompanied by dogma. A lecture delivered before the City Philosophical Society in 1818, when he was twenty-six years of age, expresses the views regarding education which he entertained to the end of his life. 'First, then,' he says, 'all theological considerations are banished from the society, and of course from my remarks; and whatever I may say has no reference to a future state, or to the means which are to be adopted in this world in anticipation of it. Next, I have no intention of substituting anything for religion, but I wish to take that part of human nature which is independent of it. Morality, philosophy, commerce, the various institutions and habits of society, are independent of religion, and may exist either with or without it. They are always the same, and can dwell alike in the breasts of those who, from opinion, are entirely opposed in the set of principles they include in the term religion, or in those who have none.
'To discriminate more closely, if possible, I will observe that we have no right to judge religious opinions; but the human nature of this evening is that part of man which we have a right to judge. And I think it will be found on examination, that this humanity--as it may perhaps be called--will accord with what I have before described as being in our own hands so improvable and perfectible.'
In an old journal I find the following remarks on one of my earliest dinners with Faraday: 'At two o'clock he came down for me. He, his niece, and myself, formed the party, "I never give dinners," he said. "I don't know how to give dinners, and I never dine out. But I should not like my friends to attribute this to a wrong cause. I act thus for the sake of securing time for work, and not through religious motives, as some imagine." He said grace. I am almost ashamed to call his prayer a "saying Of grace." In the language of Scripture, it might be described as the petition of a son, into whose heart God had sent the Spirit of His Son, and who with absolute trust asked a blessing from his father. We dined on roast beef, Yorkshire pudding, and potatoes; drank sherry, talked of research and its requirements, and of his habit of keeping himself free from the distractions of society. He was bright and joyful--boy-like, in fact, though he is now sixty-two. His work excites admiration, but contact with him warms and elevates the heart. Here, surely, is a strong man. I love strength; but let me not forget the example of its union with modesty, tenderness, and sweetness, in the character of Faraday.'
Faraday's progress in discovery, and the salient points of his character, are well brought out by the wise choice of letters and extracts published in the volumes before us. I will not call the labours of the biographer final. So great a character will challenge reconstruction. In the coming time some sympathetic spirit, with the requisite strength, knowledge, and solvent power, will, I doubt not, render these materials plastic, give them more perfect organic form, and send through them, with less of interruption, the currents of Faraday's life. 'He was too good a man,' writes his present biographer, 'for me to estimate rightly, and too great a philosopher for me to understand thoroughly.' That may be: but the reverent affection to which we owe the discovery, selection, and arrangement of the materials here placed before us, is probably a surer guide than mere literary skill. The task of the artist who may wish in future times to reproduce the real though unobtrusive grandeur, the purity, beauty, and childlike simplicity of him whom we have lost, will find his chief treasury already provided for him by Dr. Bence Jones's labour of love.
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XIX. THE COPLEY MEDALIST OF 1870.
THIRTY years ago Electro-magnetism was looked to as a motive power, which might possibly compete with steam. In centres of industry, such as Manchester, attempts to investigate and apply this power were numerous. This is shown by the scientific literature of the time. Among others Mr. James Prescot Joule, a resident of Manchester, took up the subject, and, in a series of papers published in Sturgeon's 'Annals of Electricity' between 1839 and 1841, described various attempts at the construction and perfection of electro-magnetic engines. The spirit in which Mr. Joule pursued these enquiries is revealed in the following extract: 'I am particularly anxious,' he says, 'to communicate any new arrangement in order, if possible, to forestall the monopolising designs of those who seem to regard this most interesting subject merely in the light of pecuniary speculation.' He was naturally led to investigate the laws of electro-magnetic attractions, and in 1840 he announced the important principle that the attractive force exerted by two electromagnets, or by an electro-magnet and a mass of annealed iron, is directly proportional to the square of the strength of the magnetising current; while the attraction exerted between, an electro-magnet and the pole of a permanent steel magnet, varies simply as the strength of the current. These investigations were conducted independently of, though a little subsequently to, the celebrated enquiries of Henry, Jacobi, and Lenz and Jacobi, on the same subject.
On December 17, 1840, Mr. Joule communicated to the Royal Society a paper on the production of heat by Voltaic electricity. In it he announced the law that the calorific effects of equal quantities of transmitted electricity are proportional to the resistance overcome by the current, whatever may be the length, thickness, shape, or character of the metal which closes the circuit; and also proportional to the square of the quantity of transmitted electricity. This is a law of primary importance. In another paper, presented to, but declined by, the Royal Society, he confirmed this law by new experiments, and materially extended it. He also executed experiments on the heat consequent on the passage of Voltaic electricity through electrolytes, and found, in all cases, that the heat evolved by the proper action of any Voltaic current is proportional to the square of the intensity of that current, multiplied by the resistance to conduction which it experiences. From this law he deduced a number of conclusions of the highest importance to electrochemistry.
It was during these enquiries, which are marked throughout by rare sagacity and originality, that the great idea of establishing quantitative relations between Mechanical Energy and Heat arose and assumed definite form in his mind. In 1843 Mr. Joule read before the meeting of the British Association at Cork a. paper' On the Calorific Effects of Magneto-Electricity, and on the Mechanical Value of Heat.' Even at the present day this memoir is tough reading, and at the time it was written it must have appeared hopelessly entangled. This, I should think, was the reason why Faraday advised Mr. Joule not to submit the paper to the Royal Society. But its drift and results are summed up in these memorable words by its author, written some time subsequently: 'In that paper it was demonstrated experimentally, that the mechanical power exerted in turning a magneto-electric machine is converted into the heat evolved by the passage of the currents of induction through its coils; and, on the other hand, that the motive power of the electromagnetic engine is obtained at the expense of the heat due to the chemical reaction of the battery by which it is worked.' [Footnote: Phil. Mag. May, 1845.] It is needless to dwell upon the weight and importance of this statement.
Considering the imperfections incidental to a first determination, it is not surprising that the 'mechanical values of heat,' deduced from the different series of experiments published in 1843, varied widely from each other. The lowest limit was 587, and the highest 1,026 foot-pounds, for 1 degree Fahr. of temperature.
One noteworthy result of his enquiries, which was pointed out at the time by Mr. Joule, had reference to the exceedingly small fraction of the heat actually converted into useful effect in the steam-engine. The thoughts of the celebrated Julius Robert Mayer, who was then engaged in Germany upon the same question, had moved independently in the same groove; but to his labours due reference will be made on a future occasion. [Footnote: See the next Fragment.] In the memoir now referred to, Mr. Joule also announced that he had proved heat to be evolved during the passage of water through narrow tubes; and he deduced from these experiments an equivalent of 770 foot-pounds, a figure remarkably near the one now accepted. A detached statement regarding the origin and convertibility of animal heat strikingly illustrates the penetration of Mr. Joule, and his mastery of principles, at the period now referred to. A friend had mentioned to him Haller's hypothesis, that animal heat might arise from the friction of the blood in the veins and arteries. 'It is unquestionable,' writes Mr. Joule,' that heat is produced by such friction; but it must be understood that the mechanical force expended in the friction is a part of the force of affinity which causes the venous blood to unite with oxygen, so that the whole heat of the system must still be referred to the chemical changes. But if the animal were engaged in turning a piece of machinery, or in ascending a mountain, I apprehend that in proportion to the muscular effort put forth for the purpose, a _diminution_ of the heat evolved in the system by a given chemical action would be experienced.' The italics in this memorable passage, written, it is to be remembered, in 1843, are Mr. Joule's own.
The concluding paragraph of this British Association paper equally illustrates his insight and precision, regarding the nature of chemical and latent heat. 'I had,' he writes, 'endeavoured to prove that when two atoms combine together, the heat evolved is exactly that which would have been evolved by the electrical current due to the chemical action taking place, and is therefore proportional to the intensity of the chemical force causing the atoms to combine. I now venture to state more explicitly, that it is not precisely the attraction of affinity, but rather the mechanical force expended by the atoms in falling towards one another, which determines the intensity of the current, and, consequently, the quantity of heat evolved; so that we have a simple hypothesis by which we may explain why heat is evolved so freely in the combination of gases, and by which indeed we may account "latent heat" as a mechanical power, prepared for action, as a watch-spring is when wound up. Suppose, for the sake of illustration, that 8 lbs. of oxygen and 1 lb. of hydrogen were presented to one another in the gaseous state, and then exploded; the heat evolved would be about 1 degree Fahr. in 60,000 lbs. of water, indicating a mechanical force, expended in the combination, equal to a weight of about 50,000,000 lbs. raised to the height of one foot. Now if the oxygen and hydrogen could be presented to each other in a liquid state, the heat of combination would be less than before, because the atoms in combining would fall through less space.' No words of mine are needed to point out the commanding grasp of molecular physics, in their relation to the mechanical theory of heat, implied by this statement.
Perfectly assured of the importance of the principle which his experiments aimed at establishing, Mr. Joule did not rest content with results presenting such discrepancies as those above referred to. He resorted in 1844 to entirely new methods, and made elaborate experiments on the thermal changes produced in air during its expansion: firstly, against a pressure, and therefore performing work; secondly, against no pressure, and therefore performing no work. He thus established anew the relation between the heat consumed and the work done. From five different series of experiments he deduced five different mechanical equivalents, the agreement between them being far greater than that attained in his first experiments. The mean of them was 802 foot-pounds. From experiments with water agitated by a paddle-wheel, he deduced, in 1845, an equivalent of 890 foot-pounds. In 1847 he again operated upon water and sperm-oil, agitated them by a paddle-wheel, determined their elevation of temperature, and the mechanical power which produced it. From the one he derived an equivalent of 781.6 foot-pounds; from the other an equivalent of 782.1 foot-pounds. The mean of these two very close determinations is 781.8 foot-pounds.
By this time the labours of the previous ten years had made Mr. Joule completely master of the conditions essential to accuracy and success. Bringing his ripened experience to bear upon the subject, he executed in 1849 a series of 40 experiments on the friction of water, 50 experiments on the friction of mercury, and 20 experiments on the friction of plates of cast-iron. He deduced from these experiments our present mechanical equivalent of heat, justly recognised all over the world as 'Joule's equivalent.'
There are labours so great and so pregnant in consequences, that they are most highly praised when they are most simply stated. Such are the labours of Mr. Joule. They constitute the experimental foundation of a principle of incalculable moment, not only to the practice, but still more to the philosophy of Science. Since the days of Newton, nothing more important than the theory, of which Mr. Joule is the experimental demonstrator, has been enunciated.
I have omitted all reference to the numerous minor papers with which Mr. Joule has enriched scientific literature. Nor have I alluded to the important investigations which he has conducted jointly with Sir William Thomson. But sufficient, I think, has been here said to show that, in conferring upon Mr. Joule the highest honour of the Royal Society, the Council paid to genius not only a well-won tribute, but one which had been fairly earned twenty years previously. [Footnote: Lord Beaconsfield has recently honoured himself and England by bestowing an annual pension of 200 pounds on Dr. Joule.]
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XX. THE COPLEY MEDALIST OF 1871.
DR. JULIUS ROBERT MAYER was educated for D the medical profession. In the summer of 1840, as he himself informs us, he was at Java, and there observed that the venous blood of some of his patients had a singularly bright red colour. The observation riveted his attention; he reasoned upon it, and came to the conclusion that the brightness of the colour was due to the fact that a less amount of oxidation sufficed to keep up the temperature of the body in a hot climate than in a cold one. The darkness of the venous blood he regarded as the visible sign of the energy of the oxidation.
It would be trivial to remark that accidents such as this, appealing to minds prepared for them, have often led to great discoveries. Mayer's attention was thereby drawn to the whole question of animal heat. Lavoisier had ascribed this heat to the oxidation of the food. 'One great principle,' says Mayer, 'of the physiological theory of combustion, is that under all circumstances the same amount of fuel yields, by its perfect combustion, the same amount of heat; that this law holds good even for vital processes; and that hence the living body, notwithstanding all its enigmas and wonders, is incompetent to generate heat out of nothing.'
But beyond the power of generating internal heat, the animal organism can also generate heat outside of itself. A blacksmith, for example, by hammering can heat a nail, and a savage by friction can warm wood to its point of ignition. Now, unless we give up the physiological axiom that the living body cannot create heat out of nothing, 'we are driven,' says Mayer, 'to the conclusion that it is the total heat generated within and without that is to be regarded as the true calorific effect of the matter oxidised in the body.'
From this, again, he inferred that the heat generated externally must stand in a fixed relation to the work expended in its production. For, supposing the organic processes to remain the same; if it were possible, by the mere alteration of the apparatus, to generate different amounts of heat by the same amount of work, it would follow that the oxidation of the same amount of material would sometimes yield a less, sometimes a greater, quantity of heat. 'Hence,' says Mayer, 'that a fixed relation subsists between heat and work, is a postulate of the physiological theory of combustion.'