Part 30

The position of these bright bands never varies, and each metal has its own system. Hence the competent observer can infer from the bands of the spectrum the metals which produce it. It is a language addressed to the eye instead of the ear; and the certainty would not be augmented if each metal possessed the power of audibly calling out, 'I am here!' Nor is this language affected by distance. If we find that the sun or the stars give us the bands of our terrestrial metals, it is a declaration on the part of these orbs that such metals enter into their composition. Does the sun give us any such intimation? Does the solar spectrum exhibit bright lines which we might compare with those produced by our terrestrial metals, and prove either their identity or difference? No. The solar spectrum, when closely examined, gives us a multitude of fine dark lines instead of bright ones. They were first noticed by Dr. Wollaston, but were multiplied and investigated with profound skill by Fraunhofer, and named after him Fraunhofer's lines. They had been long a standing puzzle to philosophers. The bright lines yielded by metallic vapours had been also known to us for years; but the connection between both classes of phenomena was wholly unknown, until Kirchhoff, with admirable acuteness, revealed the secret, and placed it at the same time in our power to chemically analyse the sun.

We have now some difficult work before us. Hitherto we have been delighted by objects which addressed themselves as much to our aesthetic taste as to our scientific faculty; we have ridden pleasantly to the base of the final cone of Etna, and must now dismount and march through ashes and lava, if we would enjoy the prospect from the summit. Our problem is to connect the dark lines of Fraunhofer with the bright ones of the metals. The white beam of the lamp is refracted in passing through our two prisms, but its different components are refracted in different degrees, and thus its colours are drawn apart.

Now the colour depends solely upon the rate of oscillation of the atoms of the luminous body; red light being produced by one rate, blue light by a much quicker rate, and the colours between red and blue by the intermediate rates. The solid incandescent coal-points give us a continuous spectrum; or in other words they emit rays of all possible periods between the two extremes of the spectrum. Colour, as many of you know, is to light what _pitch_ is to sound. When a violin-player presses his finger on a string he makes it shorter and tighter, and thus, causing it to vibrate more speedily, heightens the pitch. Imagine such a player to move his fingers slowly along the string, shortening it gradually as he draws his bow, the note would rise in pitch by a regular gradation; there would be no gap intervening between note and note. Here we have the analogue to the continuous spectrum, whose colours insensibly blend together without gap or interruption, from the red of the lowest pitch to the violet of the highest. But suppose the player, instead of gradually shortening his string, to press his finger on a certain point, and to sound the corresponding note; then to pass on to another point more or less distant, and sound its note; then to another, and so on, thus sounding particular notes separated from each other by gaps which correspond to the intervals of the string passed over; we should then have the exact analogue of a spectrum composed of separate bright bands with intervals of darkness between them. But this, though a perfectly true and intelligible analogy, is not sufficient for our purpose; we must look with the mind's eye at the oscillating atoms of the volatilised metal.

Figure these atoms as connected together by springs of a certain tension, which, if the atoms are squeezed together, push them again asunder, and if the atoms are drawn apart, pull them again together, causing them, before coming to rest, to quiver for a certain time at a certain definite rate determined by the strength of the spring. Now the volatilised metal which gives us one bright band is to be figured as having its atoms united by springs all of the same tension, its vibrations are all of one kind. The metal which gives us two bands may be figured as having some of its atoms united by springs of one tension, and others by springs of a different tension. Its vibrations are of two distinct kinds; so also when we have three or more bands we are to figure as many distinct sets of springs, each capable of vibrating in its own particular time and at a different rate from the others. If we seize this idea definitely, we shall have no difficulty in dropping the metaphor of springs, and substituting for it mentally the forces by which the atoms act upon each other. Having thus far cleared our way, let us make another effort to advance.

A heavy ivory ball is here suspended from a string. I blow against this ball; a single puff of my breath moves it a little way from its position of rest; it swings back towards me, and when it reaches the limit of its swing I puff again. It now swings further; and thus by timing the puffs I can so accumulate their action as to produce oscillations of large amplitude. The ivory ball here has absorbed the motion which my breath communicated to the air. I now bring the ball to rest. Suppose, instead of the breath, a wave of air to strike against it, and that this wave is followed by a series of others which succeed each other exactly in the same intervals as my puffs; it is obvious that these waves would communicate their motion to the ball and cause it to swing as the puffs did. And it is equally manifest that this would not be the case if the impulses of the waves were not properly timed; for then the motion imparted to the pendulum by one wave would be neutralised by another, and there could not be the accumulation of effect obtained when the periods of the waves correspond with the periods of the pendulum. So much for the particular impulses absorbed by the pendulum. But if such a pendulum set oscillating in air could produce waves in the air, it is evident that the waves it would produce would be of the same period as those whose motions it would take up or absorb most completely, if they struck against it. Perhaps the most curious effect of these timed impulses ever described was that observed by a watchmaker, named Ellicott, in the year 1741. He left two clocks leaning against the same rail; one of them, which we may call A, was set going; the other, B, not. Some time afterwards he found, to his surprise, that B was ticking also. The pendulums being of the same length, the shocks imparted by the ticking of A to the rail against which both clocks rested were propagated to B, and were so timed as to set B going. Other curious effects were at the same time observed. When, the pendulums differed from each other a certain amount, set B going, but the reaction of B stopped A. Then B set A going, and the re-action of A stopped B. When the periods of oscillation were close to each other, but still not quite alike, the clocks mutually controlled each other, and by a kind of compromise they ticked in perfect unison.

But what has all this to do with our present subject? The varied actions of the universe are all modes of motion; and the vibration of a ray claims strict brotherhood with the vibrations of our pendulum. Suppose aethereal waves striking upon atoms which oscillate in the same periods as the waves, the motion of the waves will be absorbed by the atoms; suppose we send our beam of white light through a sodium flame, the atoms of that flame will be chiefly affected by those undulations which are synchronous with their own periods of vibration. There will be on the part of those particular rays a transference of motion from the agitated aether to the atoms of the volatilised metal, which, as already defined, is absorption.

The experiment justifying this conclusion is now for the first time to be made before a public audience. I pass a beam through our two prisms, and the spectrum spreads its colours upon the screen. Between the lamp and the prism I interpose a snapdragon light. Alcohol and water are here mixed with common salt, and the metal dish that holds them is heated by a spirit-lamp. The vapour from the mixture ignites and we have a monochromatic flame. Through this flame the beam from the lamp is now passing; and observe the result upon the spectrum. You see a shady band cut out of the yellow,--not very dark, but sufficiently so to be seen by everybody present.

But let me exalt this effect. Placing in front of the electric lamp the intense flame of a large Bunsen's burner, a platinum capsule containing a bit of sodium less than a pea in magnitude is plunged into the flame. The sodium soon volatilises and burns with brilliant incandescence. The beam crosses the flame, and at the same time the yellow band of the spectrum is clearly and sharply cut out, a band of intense darkness occupying its place. On withdrawing the sodium, the brilliant yellow of the spectrum takes its proper place, while the reintroduction of the flame causes the band to reappear.

Let me be more precise: The yellow colour of the spectrum extends over a sensible space, blending on one side with the orange and on the other with the green. The term 'yellow band' is therefore somewhat indefinite. This vagueness may be entirely removed. By dipping the carbon-point used for the positive electrode into a solution of common salt, and replacing it in the lamp, the bright yellow band produced by the sodium vapour stands out from the spectrum. When the sodium flame is caused to act upon the beam it is that particular yellow band that is obliterated, an intensely black streak occupying its place.

An additional step of reasoning leads to the conclusion that if, instead of the flame of sodium alone, we were to introduce into the path of the beam a flame in which lithium, strontium, magnesium, calcium, &c, are in a state of volatilisation, each metallic vapour would cut out a system of bands, corresponding exactly in position with the bright bands of the same metallic vapour. The light of our electric lamp shining through such a composite flame would give us a spectrum cut up by dark lines, exactly as the solar spectrum is cut up by the lines of Fraunhofer.

Thus by the combination of the strictest reasoning with the most conclusive experiment, we reach the solution of one of the grandest of scientific problems--the constitution of the sun. The sun consists of a nucleus surrounded by a flaming atmosphere. The light of the nucleus would give us a continuous spectrum, like that of our common carbon-points; but having to pass through the photosphere, as our beam had to pass through the flame, those rays of the nucleus which the photosphere can itself emit are absorbed, and shaded spaces, corresponding to the particular rays absorbed, occur in the spectrum. Abolish the solar nucleus, and we should have a spectrum showing a bright line in the place of every dark line of Fraunhofer. These lines are therefore not absolutely dark, but dark by an amount corresponding to the difference between the light of the nucleus intercepted by the photosphere, and the light which issues from the latter.

The man to whom we owe this noble generalisation is Kirchhoff, Professor of Natural Philosophy in the University of Heidelberg; [Footnote: Now Professor in the University of Berlin.] but, like every other great discovery, it is compounded of various elements. Mr. Talbot observed the bright lines in the spectra of coloured flames. Sixteen years ago Dr. Miller gave drawings and descriptions of the spectra of various coloured flames. Wheatstone, with his accustomed ingenuity, analysed the light of the electric spark, and showed that the metals between which the spark passed determined the bright bands in the spectrum of the spark. Masson published a prize essay on these bands; Van der Willigen, and more recently Plucker, have given us beautiful drawings of the spectra, obtained from the discharge of Ruhmkorff's coil. But none of these distinguished men betrayed the least knowledge of the connection between the bright bands of the metals and the dark lines of the solar spectrum. The man who came nearest to the philosophy of the subject was Angstrom. In a paper translated from Poggendorff's 'Annalen' by myself, and published in the 'Philosophical Magazine' for 1855, he indicates that the rays which a body absorbs are precisely those which it can emit when rendered luminous. In another place, he speaks of one of his spectra giving the general impression of a reversal of the solar spectrum. Foucault, Stokes, and Thomson, have all been very close to the discovery; and, for my own part, the examination of the radiation and absorption of heat by gases and vapours, some of the results of which I placed before you at the commencement of this discourse, would have led me in 1859 to the law on which all Kirchhoff's speculations are founded, had not an accident withdrawn me from the investigation. But Kirchhoff's claims are unaffected by these circumstances. True, much that I have referred to formed the necessary basis of his discovery; so did the laws of Kepler furnish to Newton the basis of the theory of gravitation. But what Kirchhoff has done carries us far beyond all that had before been accomplished. He has introduced the order of law amid a vast assemblage of empirical observations, and has ennobled our previous knowledge by showing its relationship to some of the most sublime of natural phenomena.

********************

XV. ELEMENTARY MAGNETISM.

A LECTURE TO SCHOOLMASTERS.

WE have no reason to believe that the sheep or the dog, or indeed any of the lower animals, feel an interest in the laws by which natural phenomena are regulated. A herd may be terrified by a thunderstorm; birds may go to roost, and cattle return to their stalls, during a solar eclipse; but neither birds nor cattle, as far as we know, ever think of enquiring into the causes of these things. It is otherwise with Man. The presence of natural objects, the occurrence of natural events, the varied appearances of the universe in which he dwells penetrate beyond his organs of sense, and appeal to an inner power of which the senses are the mere instruments and excitants. No fact is to him either original or final. He cannot limit himself to the contemplation of it alone, but endeavours to ascertain its position in a series to which uniform experience assures him it must belong. He regards all that he witnesses in the present as the efflux and sequence of something that has gone before, and as the source of a system of events which is to follow. The notion of spontaneity, by which in his ruder state he accounted for natural events, is abandoned; the idea that nature is an aggregate of independent parts also disappears, as the connection and mutual dependence of physical powers become more and more manifest: until he is finally led to regard Nature as an organic whole--as a body each of whose members sympathises with the rest, changing, it is true, from age to age, but changing without break of continuity in the relation of cause and effect.

The system of things which we call Nature is, however, too vast and various to be studied first-hand by any single mind. As knowledge extends there is always a tendency to subdivide the field of investigation. Its various parts are taken up by different minds, and thus receive a greater amount of attention than could possibly be bestowed on them if each investigator aimed at the mastery of the whole. The centrifugal form in which knowledge, as a whole, advances, spreading ever wider on all sides, is due in reality to the exertions of individuals, each of whom directs his efforts, more or less, along a single line. Accepting, in many respects, his culture from his fellow-men--taking it from spoken words or from written books--in some one direction, the student of Nature ought actually to touch his work. He may otherwise be a distributor of knowledge, but not a creator, and he fails to attain that vitality of thought, and correctness of judgment, which direct and habitual contact with natural truth can alone impart.

One large department of the system of Nature which forms the chief subject of my own studies, and to which it is my duty to call your attention this evening, is that of physics, or natural philosophy. This term is large enough to cover the study of Nature generally, but it is usually restricted to a department which, perhaps, lies closer to our perceptions than any other. It deals with the phenomena and laws of light and heat--with the phenomena and laws of magnetism and electricity--with those of sound--with the pressures and motions of liquids and gases, whether at rest or in a state of translation or of undulation. The science of mechanics is a portion of natural philosophy, though at present so large as to need the exclusive attention of him who would cultivate it profoundly. Astronomy is the application of physics to the motions of the heavenly bodies, the vastness of the field causing it, however, to bed regarded as a department in itself. In chemistry physical agents play important parts. By heat and light we cause atoms and molecules to unite or to fall asunder. Electricity exerts a similar power. Through their ability to separate nutritive compounds into their constituents, the solar beams build up the whole vegetable world, and by it the animal world. The touch of the self-same beams causes hydrogen and chlorine to; unite with sudden explosion, and to form by their combination a powerful acid. Thus physics and chemistry intermingle. Physical agents are, however, employed by the chemist as a means to an end; while in physics proper the laws and phenomena of the agents themselves, both qualitative and quantitative, are the primary objects of attention.

My duty here to-night is to spend an hour in telling how this subject is to be studied, and how a knowledge of it is to be imparted to others. From the domain of physics, which would be unmanageable as a whole, I select as a sample the subject of magnetism. I might readily entertain you on the present occasion with an account of what natural philosophy has accomplished. I might point to those applications of science of which we hear so much in the newspapers, and which are so often mistaken for science itself. I might, of course, ring changes on the steam-engine and the telegraph, the electrotype and the photograph, the medical applications of physics, and the various other inlets by which scientific thought filters into practical life. That would be easy compared with the task of informing you how you are to make the study of physics the instrument of your pupil's culture; how you are to possess its facts and make them living seeds which shall take root and grow in the mind, and not lie like dead lumber in the storehouse of memory. This is a task much heavier than the mere recounting of scientific achievements; and it is one which, feeling my own want of time to execute it aright, I might well hesitate to accept.

But let me sink excuses, and attack the work before me. First and foremost, then, I would advise you to get a knowledge of facts from actual observation. Facts looked at directly are vital; when they pass into words half the sap is taken out of them. You wish, for example, to get a knowledge of magnetism; well, provide yourself with a good book on the subject, if you can, but do not be content with what the book tells you; do not be satisfied with its descriptive woodcuts; see the operations of the force yourself. Half of our book writers describe experiments which they never made, and their descriptions often lack both force and truth; but, no matter how clever or conscientious they may be, their written words cannot supply the place of actual observation. Every fact has numerous radiations, which are shorn off by the man who describes it.

Go, then, to a philosophical instrument maker, and give a shilling or half a crown for a straight bar-magnet, or, if you can afford it, purchase a pair of them; or get a smith to cut a length of ten inches from a bar of steel an inch wide and half an inch thick; file its ends smoothly, harden it, and get somebody like myself to magnetise it. Procure some darning needles, and also a little unspun silk, which will give you a suspending fibre void of torsion. Make little loop of paper, or of wire, and attach your fibre to it. Do it neatly. In the loop place a darning-needle, and bring the two ends or poles, as they are called, of your bar-magnet successively up to the ends of the needle. Both the poles, you find, attract both ends of the needle. Replace the needle by a bit of annealed iron wire; the same effects ensue. Suspend successively little rods of lead, copper, silver, brass, wood, glass, ivory, or whalebone; the magnet produces no sensible effect upon any of the substances. You thence infer a special property in the case of steel and iron. Multiply your experiments, However, and you will find that some other substances, besides iron and steel, are acted upon by your magnet. A rod of the metal nickel, or of the metal cobalt, from which the blue colour used by painters is derived, exhibits powers similar to those observed with the iron and steel.

In studying the character of the force you may, however, confine yourself to iron and steel, which are always at hand. Make your experiments with the darning-needle over and over again; operate on both ends of the needle; try both ends of the magnet. Do not think the work dull; you are conversing with Nature, and must acquire over her language a certain grace and mastery, which practice can alone impart. Let every movement be made with care, and avoid slovenliness, from the outset. Experiment, as I have said, is the language by which we address Nature, and through which she sends her replies; in the use of this language a lack of straightforwardness is as possible, and as prejudicial, as in the spoken language of the tongue. If, therefore, you wish to become acquainted with the truth of Nature, you must from the first resolve to deal with her sincerely.

Now remove your needle from its loop, and draw it from eye to point along one of the ends of the magnet; resuspend it, and repeat your former experiment. You now find that each extremity of the magnet attracts one end of the needle, and repels the other. The simple attraction observed in the first instance, is now replaced by a _dual_ force. Repeat the experiment till you have thoroughly observed the ends which attract and those which repel each other.

Withdraw the magnet entirely from the vicinity of your needle, and leave the latter freely suspended by its fibre. Shelter it as well as you can from currents of air, and if you have iron buttons on your coat, or a steel penknife in your pocket, beware of their action. If you work at night, beware of iron candlesticks, or of brass ones with iron rods inside. Freed from such disturbances, the needle takes up a certain determinate position. It sets its length nearly north and south. Draw it aside and let it go. After several oscillations it will again come to the same position. If you have obtained your magnet from a philosophical instrument maker, you will see a mark on one of its ends. Supposing, then, that you drew your needle along the end thus marked, and that the point of your needle was the last to quit the magnet, you will find that the point turns to the south, the eye of the needle turning towards the north. Make sure of this, and do not take the statement on my authority.