Experiments and Considerations Touching Colours (1664)
Chapter 9
11. But to return to our Experiments. We may take notice, That the White of an Egg, though in part Transparent, yet by its power of Reflecting some Incident Rays of Light, is in some measure a Natural _Speculum_, being long agitated with a Whisk or Spoon, loses its Transparency, and becomes very White, by being turn'd into Froth, that is into an Aggregate of Numerous small Bubbles, whose Convex Superficies fits them to Reflect the Light every way Outwards. And 'tis worth Noting, that when Water, for instance, is Agitated into Froth, if the Bubbles be Great and Few, the Whiteness will be but Faint, because the number of _Specula_ within a Narrow compass is but Small, and they are not Thick set enough to Reflect so Many Little Images or Beams of the Lucid Body, as are requisite to produce a Vigorous sensation of Whiteness: And partly least it should be said, that the Whiteness of such Globulous Particles proceeds from the Air Included in the Froth; (which to make good, it should be prov'd that the Air it self is White) and partly to illustrate the better the Notion we have propos'd of Whiteness, I shall add, that I purposely made this Experiment, I took a quantity Fair water, & put to it in a clear Glass phial, a convenient quantity of Oyl or Spirit of Turpentine, because that Liquor will not incorporate with Water, and yet is almost as Clear and Colourless as it; these being Gently Shaken together, the Agitation breaks the Oyl (which as I said, is Indispos'd to Mix like Wine or Milk _per minima_ with the Water) into a Multitude of Little Globes, which each of them Reflecting Outwards a Lucid Image, make the Imperfect Mixture of the two Liquors appear Whitish; but if by Vehemently Shaking the Glass for a competent time you make a further Comminution of the Oyl into far more Numerous and Smaller _Globuli_, and thereby confound it also better with the Water, the Mixture will appear of a Much greater Whiteness, and almost like Milk; whereas if the Glass be a while let alone, the Colour will by degrees Impair, as the Oyly globes grow Fewer and Bigger, and at length will quite Vanish, leaving both the Liquors Distinct and Diaphanous as before. And such a Tryal hath not ill succeeded, when insteed of the Colourless Oyl of Turpentine I took a Yellow Mixture made of a good Proportion of Crude Turpentine dissolv'd in that Liquor; and (if I mis-remember not) it also Succeeded better than one would expect, when I employ'd an Oyl brought by Filings of Copper infused in it, to a deep Green. And this (by the way) may be the Reason, why often times when the Oyls of some Spices and of Anniseeds &c. are Distilled in a Limbec with Water, the Water (as I have several times observ'd) comes over Whitish, and will perhaps continue so for a good while, because if the Fire be made too Strong, the subtile Chymical Oyl is thereby much Agitated and Broken, and Blended with the Water in such Numerous and Minute Globules, as cannot easily in a short time Emerge to the Top of the Water, and whilst they Remain in it, make it, for the Reason newly intimated, look Whitish; and perhaps upon the same Ground a cause may be rendred, why Hot water is observ'd to be usually more Opacous and Whitish, than the same Water Cold, the Agitation turning the more Spirituous or otherwise Conveniently Dispos'd Particles of the Water into Vapours, thereby Producing in the Body of the Liquor a Multitude of Small Bubbles, which interrupt the Free passage, that the Beams of Light would else have Every way, and from the Innermost parts of the Water Reflect many of them Outwards. These and the like Examples, _Pyrophilus_, have induc'd me to Suspect, that the Superficial Particles of White bodies, may for the Most part be as well Convex as Smooth; I content my self to say _Suspect_ and _for the most part_, because it seems not Easie to prove, that when Diaphanous bodies, as we shall see by and by, are reduc'd into White Powders, each Corpuscle must needs be of a Convex Superficies, since perhaps it may Suffice that Specular Surfaces look severally ways. For (as we have seen) when a Diaphanous Body comes to be reduc'd to very Minute parts, it thereby requires a Multitude of Little Surfaces within a Narrow compass. And though each of these should not be of a Figure Convenient to Reflect a Round Image of the Sun, yet even from such an Inconveniently Figur'd body, there may be Reflected some (either Streight or Crooked) Physical Line of Light, which Line I call Physical, because it has some Breadth in it, and in which Line in many cases some Refraction of the Light falling upon the Body it depends on, may contribute to the Brightness, as if a Slender Wire, or Solid Cylinder of Glass be expos'd to the Light, you shall see in some part of it a vivid Line of Light, and if we were able to draw out and lay together a Multitude of these Little Wires or Thrids of Glass, so Slender, that the Eye could not discern a Distance betwixt the Luminous Lines, there is little doubt (as far as I can guess by a Tryal purposely made with very Slender, but far less Slender Thrids of Glass, whose Aggregate was Look'd upon one way White) but the whole Physical Superficies compos'd of them, would to the Eye appear White, and if so, it will not be always necessary that the Figure of those Corpuscles, that make a Body appear White, should be _Globulous_. And as for Snow it self, though the Learned _Gassendus_ (as we have seen above) makes it to seem nothing else but a pure Frozen Froth, consisting of exceedingly Minute and Thickset Bubbles; yet I see no necessity of Admitting that, since not only by the Variously and Curiously Figur'd Snow, that I have divers times had the Opportunity with Pleasure to observe, but also by the Common Snow, it rather doth appear both to the Naked Eye, and in a _Microscope_, often, if not most commonly, to consist principally of Little Slender Icicles of several Shapes, which afford such Numerous Lines of Light, as we have been newly Speaking of.
12. Sixthly, If you take a Diaphanous Body, as for instance a Piece of Glass, and reduce it to Powder, the same Body, which when it was Entire, freely Transmitted the Beams of Light, acquiring by Contusion a multitude of Minute Surfaces, each of which is as it were a Little, but Imperfect _Speculum_, is qualify'd to Reflect in a Confus'd manner, so many either Beams, or Little and Singly Unobservable Images of the Lucid Body, that from a Diaphanous it Degenerates into a White Body. And I remember, I have for Trials sake taken Lumps of Rock Crystal, and Heating them Red hot in a Crucible, I found according to my Expectation, that being Quench'd in Fair water, even those that remain'd in seemingly entire Lumps exchang'd their Translucency for Whiteness, the Ignition and Extinction having as it were Crack'd each Lump into a multitude of Minute Bodies, and thereby given it a great multitude of new Surfaces. And ev'n with Diaphanous Bodies, that are Colour'd, there may be this way a Greater Degree of Whiteness produced, than one would lightly think; as I remember, I have by Contusion obtain'd Whitish Powders of _Granates_, Glass of _Antimony_, and _Emeralds_ finely Beaten, and you may more easily make the Experiment, by taking Good Venereal _Vitriol_ of a Deep Blew, and comparing with some of the Entire Crystalls purposely reserv'd, some of the Subtile Powder of the same Salt, which will Comparatively exhibit a very considerable degree of Whitishness.
13. Seventhly, And as by a Change of Position in the Parts, a Body that is not White, may be made White, so by a Slight change of the Texture of its Surface, a White Body may be Depriv'd of its Whiteness. For if, (as I have try'd in Gold-smiths Shops) you take a piece of Silver that has been freshly Boyl'd, as the Artificers call it, (which is done by, first Brushing, and then Decocting it with Salt and Tartar, and perhaps some other Ingredients) you shall find it to be of a Lovely White. But if you take a piece of Smooth Steel, and therewith Burnish a part of it, which may be presently done, you shall find that Part will Lose its Whiteness, and turn a _Speculum_, looking almost every where Dark, as other Looking-glasses do, which may not a little confirm our Doctrine. For by this we may guess, what it is chiefly that made the Body White before, by considering that all that was done to deprive it of that Whiteness, was only to Depress the Little Protuberances that were before on the Surface of the Silver into one Continu'd Superficies, and thereby effect this, that now the Image of the Lucid Body, and consequently a Kind of Whiteness shall appear to your Eye, but in some place of the greater Silver Looking-glass (whence the Beams reflected at an Angle Equal to that wherewith they fall on it, may reach your Eye) whilst the Asperity remain'd Undestroy'd, the Light falling on innumerable Little _Specula_ Obverted some one way, and some another, did from all Sensibly Distinguishable parts of the Superficies reflect confus'd Beams or Representations of Light to the Beholders Eye, from whence soever he chance to Look upon it. And among the Experiments annex'd to this Discourse, you will find One, wherein by the Change of Texture in Bodies, Whiteness is in a Trice both Generated and Destroy'd.
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CHAP. II.
1. What we have Discours'd of Whiteness, may somewhat Assist us to form a Notion of Blackness, those two Qualities being Contrary enough to Illustrate each other. Yet among the Antient _Philosophers_ I find less Assistance to form a Notion of Blackness than of Whiteness, only _Democritus_ in the passage above Recited out of _Aristotle_ has given a General Hint of the Cause of this Colour, by referring the Blackness of Bodies to their Asperity. But this I call but a General Hint, because those Bodies that are Green, and Purple, and Blew, seem to be so as well as Black ones, upon the Account of their Superficial Asperity. But among the _Moderns_, the formerly mention'd _Gassendus_, perhaps invited by this Hint of _Democritus_, has Incidentally in another Epistle given us, though a very Short, yet a somewhat Clearer account of the Nature of Blackness in these words: _Existimare par est corpora suâpte Naturâ nigra constare ex particulis, quarum Superficieculæ scabræ sint, nec facilè lucem extrorsum reflectant._ I wish this Ingenious Man had enlarg'd himself upon this Subject; For indeed it seems, that as that which makes a Body White, is chiefly such a Disposition of its Parts, that it Reflects (I mean without much Interruption) more of the Light that falls on it, than Bodies of any other Colour do, so that which makes a Body Black is principally a Peculiar kind of Texture, chiefly of its Superficial Particle, whereby it does as it were Dead the Light that falls on it, so that very little is Reflected Outwards to the Eye.
2. And this Texture may be Explicated two, and perhaps more than two several ways, whereof the first is by Supposing in the Superficies of the Black Body a Particular kind of Asperity, whereby the Superficial Particles reflect but Few of the Incident Beams Outwards, and the rest Inwards towards the Body it self. As if for Instance, we should conceive the Surface of a Black Body to be Asperated by an almost Numberless throng of Little Cylinders, Pyramids, Cones, and other such Corpuscles, which by their being Thick Set and _Erected_, reflect the Beams of Light from one to another Inwards, and send them too and fro so often, that at length they are Lost before they can come to Rebound out again to the Eye. And this is the first of the two mention'd ways of Explicating Blackness. The other way is by Supposing the Texture of Black Bodies to be such, that either by their Yielding to the Beams of Light, or upon some other Account, they do as it were Dead the Beams of Light, and keep them from being Reflected in any Plenty, or with any Considerable Vigour of Motion, Outwards. According to this Notion it may be said, that the Corpuscles that make up the Beams of Light, whether they be Solary _Effluviums_, or Minute Particles of some Ætherial Substance, Thrusting on one another from the Lucid Body, do, falling on Black Bodies, meet with such a Texture, that such Bodies receive Into themselves, and Retain almost all the Motion communicated to them by the Corpuscles that make up the Beams of Light, and consequently Reflect but Few of them, or those but Languidly, towards the Eye, it happening here almost in like manner as to a ball, which thrown against a Stone or Floor, would Rebound a great way Upwards, but Rebounds very Little or not at all, when it is thrown against Water, or Mud, or a Loose Net, because the Parts yield, and receive into themselves the Motion, on whose Account the Ball should be Reflected Outwards. But this Last way of Explicating Blackness, I shall content my Self to have Propos'd, without either Adopting it, or absolutely Rejecting it. For the Hardness of Touchstones, Black Marble and other Bodies, that being Black are Solid, seem to make it somewhat Improbable, that such Bodies should be of so Yielding a Texture, unless we should say, that some Bodies may be more Dispos'd to Yield to the Impulses of the Corpuscles of Light by reason of a Peculiar Texture, than other Bodies, that in other Tryals appear to be Softer than they. But though the Former of these two Explications of Blackness be that, by which we shall Endeavour to give an Account of it, yet as we said, we shall not Absolutely Reject this Latter, partly because they both Agree in this, that Black Bodies Reflect but Little of the Light that falls on them, and partly because it is not Impossible, that in some Cases both the Disposition of the Superficial particles, as to Figure and Position, and the Yielding of the Body, or some of its Parts, may joyntly, though not in an Equal measure concurr to the rendring of a Body Black. The Considerations that induc'd me to propose this Notion of Blackness, as I Explan'd it, are principally these:
3. First, That as I lately said, Whiteness and Blackness being generally reputed to be Contrary Qualities, Whiteness depending as I said upon the Disposition of the Parts of a Body to Reflect much Light, it seems likely, that Blackness may depend upon a Contrary Disposition of the Black Bodies Surface; But upon this I shall not Insist.
4. Next then we see, that if a Body of One and the same Colour be plac'd, part in the Sun-beams, and part in the Shade, that part which is not Shin'd on will appear more of Kin to Blackness than the other, from which more Light Rebounds to the Eye; And Dark Colours seem the Blacker, the less Light they are Look'd upon in, and we think all Things Black in the Dark, when they send no Beams to make Impressions on our Organs of Sight, so that Shadows and Darkness are near of Kin, and Shaddow we know is but a Privation of Light; and accordingly Blackness seems to proceed from the Paucity of Beams Reflected from the Black Body to the Eye, I say the Paucity of Beams, because those Bodies that we call Black, as Marble, Jeat, &c. are Short of being perfectly so, else we should not See them at all. But though the Beams that fall on the Sides of those Erected Particles that we have been mentioning, do Few of them return Outwards, yet those that fall upon the Points of those Cylinders, Cones, or Pyramids, may thence Rebound to the Eye, though they make there but a Faint Impression, because they Arrive not there, but Mingl'd with a great Proportion of Little Shades. This may be Confirm'd by my having procur'd a Large piece of Black Marble well Polish'd, and brought to the Form of a Large Sphærical and Concave _Speculum_; For on the Inside this Marble being well Polish'd, was a kind of Dark Looking-glass, wherein I could plainly see a Little Image of the Sun, when that Shin'd upon it. But this Image was very far from Offending and Dazling my Eyes, as it would have done from another _Speculum_; Nor, though the _Speculum_ were Large, could I in a Long time, or in a Hot Sun set a piece of Wood on Fire, though a far less _Speculum_ of the same Form, and of a more Reflecting Matter, would have made it Flame in a Trice.
5. And on this Occasion we may as well in Reference to something formerly deliver'd concerning Whiteness, as in Reference to what has been newly said, Subjoyn what we further observ'd touching the Differing Reflections of Light from White and Black Marble, namely, that having taking a pretty Large Mortar of White Marble, New and Polish'd in the Inside, and Expos'd it to the Sun, we found that it Reflected a great deal of Glaring Light, but so Dispers'd, that we could not make the Reflected Beams concurr in any such Conspicuous _Focus_, as that newly taken notice of in the Black Marble, though perhaps there may enough of them be made to meet near the Bottom, to make some Kind of _Focus_, especially since by holding in the Night-time a Candle at a convenient Distance, we were able to procure a Concourse of some, though not many of the Reflected Beams, at about two Inches distant from the Bottom of the Mortar: But we found the Heat even of the Sunbeams so Dispersedly Reflected to be very Languid, even in Comparison of the Black Marbles _Focus_. And the Little Picture of the Sun, that appear'd upon the White Marble as a _Speculum_, was but very Faint and exceeding ill Defin'd. Secondly, That taking two pieces of Plain and Polish'd Surfaces, and casting on them Successively the Beams of the Same Candle, In such manner, as that the Neighbouring Superficies being Shaded by an Opacous and Perforated Body, the Incident Beams were permitted to pass but through a Round Hole of about Half an Inch Diameter, the Circle of Light that appear'd on the White Marble was in Comparison very Bright, but very ill Defin'd; whereas that on the Black Marble was far less Luminous, but much more precisely Defin'd.
6. Thirdly, When you Look upon a piece of Linnen that has Small Holes in it, those Holes appear very Black, and Men are often deceiv'd in taking Holes for Spots of Ink; And Painters to represent Holes, make use of Black, the Reason of which seems to be, that the Beams that fall on those Holes, fall into them So Deep, that none of them is Reflected back to the Eye. And in narrow Wells part of the Mouth seems Black, because the Incident Beams are Reflected Downwards from one side to another, till they can no more Rebound to the Eye.
We may consider too, that if Differing parts of the same piece of Black Velvet be stroak'd Opposite ways, the piece of Velvet will appear of two Distinct kinds of Blackness, the one far Darker than the other, of which Disparity the Reason Seems to be, that in the Less obscure part of the Velvet, the Little Silken Piles whereof 'tis made up, being Inclin'd, there is a Greater part of each of them Obverted to the Eye, whereas in the other part the Piles of Silk being more Erected, there are far Fewer Beams Reflected Outwards from the Lateral parts of each Pile, So that most of those that Rebound to the Eye, come from the Tops of the Piles, which make but a small part of the whole Superficies, that may be cover'd by the piece of Velvet. Which Explication I propose, not that I think the Blackness of the Velvet proceeds from the Cause assign'd, since each Single Pile of Silk is Black by reason of its Texture, in what Position soever you Look upon it; But that the Greater Blackness of one of these Tuffts seems to proceed from the Greater Paucity of Beams Reflected from it, and that from the Fewness of those Parts of a Surface that Reflect Beams, and the Multitude of those Shaded Parts that Reflect none. And I remember, that I have oftentimes observ'd, that the Position of Particular Bodies far greater than Piles of Silk in reference to the Eye, may notwithstanding their having each of them a Colour of its own, make one part of their Aggregate appear far Darker than the other; For I have near Great Towns often taken notice, that a Cart-load of Carrots pack'd up, appear'd of a much Darker Colour when Look'd upon, where the Points of the Carrots were Obverted to the Eye, than where the Sides of them were so.
7. Fourthly, In a Darkned Room, I purposely observ'd, that if the Sun-beams, which came in at the Hole were receiv'd upon White or any other Colour, and directed to a Convenient place of the Room, they would Manifestly, though not all Equally, Encrease the Light of that Part; whereas if we Substituted, either a piece of Black Cloth or Black Velvet, it would so Dead the Incident Beams, that the place (newly mention'd) whereto I Obverted the Black Body, would be Less Enlightned than it was before, when it received its Light but from the Weak and Oblique Reflections of the Floor and Walls of a pretty Large Room, through which the Beams that came in at the Hole were Confusedly and Brokenly Dispers'd.