Experiments and Considerations Touching Colours (1664)
Chapter 6
20. Secondly, A Liquor may alter the Colour of a Body by freeing it from those things that hindred it from appearing in its Genuine Colour; and though this may be said to be rather a Restauration of a Body to its own Colour, or a Retection of its native Colour, than a Change, yet still there Intervenes in it a change of the Colour which the Body appear'd to be of before this Operation. And such a change a Liquor may work, either by Dissolving, or Corroding, or by some such way of carrying off that Matter, which either Veil'd or Disguis'd the Colour that afterwards appears. Thus we restore Old pieces of Dirty Gold to a clean and nitid Yellow, by putting them into the Fire, and into _Aqua-fortis_, which take off the adventitious Filth that made that pure Metall look of a Dirty Colour. And there is also an easie way to restore Silver Coyns to their due Lustre, by fetching off that which Discolour'd them. And I know a _Chymical_ Liquor, which I employ'd to restore pieces of Cloath spotted with Grease to their proper Colour, by Imbibing the Spotted part with this Liquor, which Incorporating with the Grease, and yet being of a very Volatile Nature, does easily carry it away with it Self. And I have sometimes try'd, that by Rubbing upon a good Touch-stone a certain _Metalline_ mixture so Compounded, that the Impression it left upon the Stone appear'd of a very differing Colour from that of Gold, yet a little of _Aqua-fortis_ would in a Trice make the Golden Colour disclose it self, by Dissolving the other _Metalline_ Corpuscles that conceal'd those of the Gold, which you know that _Menstruum_ will leave Untouch'd.
21. Thirdly, A Liquor may alter the Colour of a Body by making a Comminution of its Parts, and that principally two ways, the first by Disjoyning and Dissipating those Clusters of Particles, if I may so call them, which stuck more Loosely together, being fastned only by some more easily Dissoluble Ciment, which seems to be the Case of some of the following Experiments, where you'l find the Colour of many Corpuscles brought to cohere by having been Precipitated together, Destroy'd by the Affusion of very peircing and incisive Liquors. The other of the two ways I was speaking of, is, by Dividing the Grosser and more Solid Particles into Minute ones, which will be always Lesser, and for the most part otherwise Shap'd than the Entire Corpuscle so Divided, as it will happen in a piece of Wood reduc'd into Splinters or Chips, or as when a piece of Chrystal heated red Hot and quench'd in Cold water is crack'd into a multitude of little Fragments, which though they fall not asunder, alter the Disposition of the Body of the Chrystal, as to its manner of Reflecting the Light, as we shall have Occasion to shew hereafter.
22. There is a fourth way contrary to the third, whereby a Liquor may change the Colour of another Body, especially of another Fluid, and that is, by procuring the Coalition of several Particles that before lay too Scatter'd and Dispers'd to exhibit the Colour that afterwards appears. Thus sometimes when I have had a Solution of Gold so Dilated, that I doubted whether the Liquor had really Imbib'd any true Gold or no, by pouring in a little _Mercury_, I have been quickly able to satisfie my Self, that the Liquor contain'd Gold, that Mettall after a little while Cloathing the Surface of the _Quick-silver_, with a Thin Film of its own Livery. And chiefly, though not only by this way of bringing the Minute parts of Bodies together in such Numbers as to make them become Notorious to the Eye, many of these Colours seem to be Generated which are produc'd by Precipitations, especially by such as are wont to be made with fair Water, as when Resinous Gumms dissolv'd in Spirit of Wine, are let fall again, if the Spirit be Copiously diluted with that weakning Liquor. And so out of the Rectify'd and Transparent Butter of _Antimony_, by the bare Mixture of fair Water, there will be plentifully Precipitated that Milk-white Substance, which by having its Looser Salts well wash'd off, is turn'd into that Medicine, which Vulgar _Chymists_ are pleas'd to call _Mercurius Vitæ._
23. A fifth way, by which a Liquor may change the Colour of a Body, is, by Dislocating the Parts, and putting them out of their former Order into another, and perhaps also altering the Posture of the single Corpuscles as well as their Order or Situation in respect of one another. What certain Kinds of Commotion or Dislocation of the Parts of a Body may do towards the Changing its Colour, is not only evident in the Mutations of Colour observable in _Quick-silver_, and some other Concretes long kept by _Chymists_ in a Convenient Heat, though in close Vessels, but in the Obvious Degenerations of Colour, which every Body may take notice of in Bruis'd Cherries, and other Fruit, by comparing after a while the Colour of the Injur'd with that of the Sound part of the same Fruit. And that also such Liquors, as we have been speaking of, may greatly Discompose the Textures of many Bodies, and thereby alter the Disposition of their Superficial parts, the great Commotion made in Metalls, and several other Bodies by _Aqua-fortis_, Oyl of _Vitriol_, and other Saline _Menstruums_, may easily perswade us, and what such Vary'd Situations of Parts may do towards the Diversifying of the manner of their Reflecting the Light, may be Guess'd in some Measure by the Beating of Transparent Glass into a White Powder, but farr better by the Experiments lately Pointed at, and hereafter Deliver'd, as the Producing and Destroying Colours by the means of subtil Saline Liquors, by whose Affusion the Parts of other Liquors are manifestly both Agitated, and likewise Dispos'd after another manner than they were before such Affusion. And in some _Chymical_ Oyls, as particularly that of Lemmon Pills, by barely Shaking the Glass, that holds it, into Bubbles, that Transposition of the Parts which is consequent to the Shaking, will shew you on the Surfaces of the Bubbles exceeding Orient and Lively Colours, which when the Bubbles relapse into the rest of the Oyl, do immediately Vanish.
24. I know not, _Pyrophilus_, whether I should mention as a Distinct way, because it is of a somewhat more General Nature, that Power, whereby a Liquor may alter the Colour of another Body, by putting the Parts of it into Motion; For though possibly the Motion so produc'd, does, as such, seldome suddenly change the Colour of the Body whose Parts are Agitated, yet this seems to be one of the most General, however not Immediate causes of the Quick change of Colours in Bodies. For the Parts being put into Motion by the adventitious Liquor, divers of them that were before United, may become thereby Disjoyn'd, and when that Motion ceases or decays others of them may stick together, and that in a new Order, by which means the Motion may sometimes produce Permanent changes of Colours, as in the Experiment you will meet with hereafter, of presently turning a Snowy White Body into a Yellow, by the bare Affusion of fair Water, which probably so Dissolves the Saline Corpuscles that remain'd in the _Calx_, and sets them at Liberty to Act upon one another, and the Metall, far more Powerfully than the Water without the Assistance of such Saline Corpuscles could do. And though you rubb Blew _Vitriol_, how Venereal and Unsophisticated soever it be, upon the Whetted Blade of a Knife, it will not impart to the Iron its Latent Colour, but if you moisten the _Vitriol_ with your Spittle, or common Water, the Particles of the Liquor disjoyning those of the _Vitriol_, and thereby giving them the Various Agitation requisite to Fluid Bodies, the Metalline Corpuscles of the thus Dissolv'd _Vitriol_ will Lodge themselves in Throngs in the Small and Congruous Pores of the Iron they are Rubb'd on, and so give the Surface of it the Genuine Colour of the Copper.
25. There remains yet a way, _Pyrophilus_ to be mention'd, by which a Liquor may alter the Colour of another Body, and this seems the most Important of all, because though it be nam'd but as One, yet it may indeed comprehend Many, and that is, by Associating the Saline Corpuscles, or any other Sort of the more Rigid ones of the Liquor, with the Particles of the Body that it is employ'd to Work upon. For these Adventitious Corpuscles Associating themselves with the Protuberant Particles of the Surface of a Colour'd Body, must necessarily alter their Bigness, and will most commonly alter their Shape. And how much the Colours of Bodies depend upon the Bulk and Figure of their Superficial Particles, you may Guess by this, that eminent antient _Philosophers_ and divers _Moderns_, have thought that all Colours might in a general way be made out by these two; whose being Diversify'd, will in our Case be attended with these two Circumstances, the One, that the Protuberant Particles being Increas'd in Bulk, they will oftentimes be Vary'd as to the Closness or Laxity of their Order, fewer of them being contain'd within the same Sensible (though Minute) space than before; or else by approaching to one another, they must Straighten the Pores, and it may be too, they will by their manner of Associating themselves with the Protuberant Particles, intercept new Pores. And this invites me to consider farther, that the Adventitious Corpuscles, I have been speaking of, may likewise produce a great Change as well in the Little Cavities or Pores as in the Protuberances of a Colour'd Body; for besides what we have just now taken notice of, they may by Lodging themselves in those little Cavities, fill them up, and it may well happen, that they may not only fill the Pores they Insinuate themselves into, but likewise have their Upper Parts extant above them; and partly by these new Protuberances, partly by Increasing the Bulk of the former, these Extraneous Corpuscles may much alter the Number and Bigness of the Surfaces Pores, changing the Old and Intercepting new ones. And then 'tis Odds, but the Order of the Little Extancies, and consequently that of the Little Depressions in point of Situation will be alter'd likewise: as if you dissolve _Quick-silver_ in some kind of _Aqua-fortis_, the Saline Particles of the _Menstruum_ Associating themselves with the Mercurial Corpuscles, will make a Green Solution, which afterwards easily enough Degenerates. And Red Lead or _Minium_ being Dissolv'd in Spirit of Vinegar, yields not a Red, but a Clear Solution, the Redness of the Lead being by the Liquor Destroy'd. But a better Instance may be taken from Copper, for I have try'd, that if upon a Copper-plate you let some Drops of weak _Aqua-fortis_ rest for a while, the Corpuscles of the _Menstruum_, joyning with those of the Metall, will produce a very sensible Asperity upon the Surface of the Plate, and will Concoagulate that way into very minute Grains of a Pale Blew _Vitriol_; whereas if upon another part of the same Plate you suffer a little strong Spirit of Urine to rest a competent time, you shall find the Asperated Surface adorn'd with a Deeper and Richer Blew. And the same _Aqua-fortis_, that will quickly change the Redness of Red Lead into a Darker Colour, will, being put upon Crude Lead, produce a Whitish Substance, as with Copper it did a Blewish. And as with Iron it will produce a Reddish, and on White Quills a Yellowish, so much may the Coalition of the Parts of the same Liquor, with the differingly Figur'd Particles of Stable Bodies, divers ways Asperate the differingly Dispos'd Surfaces, and to Diversifie the Colour of those Bodies. And you'l easily believe, that in many changes of Colour, that happen upon the Dissolutions of Metalls, and Precipitations made with Oyl of _Tartar_, and the like Fix'd Salts, there may Intervene a Coalition of Saline Corpuscles with the Particles of the Body Dissolv'd or Precipitated, if you examine how much the _Vitriol_ of a Metall may be Heavier than the Metalline part of it alone, upon the Score of the Saline parts Concoagulated therewith, and, that in Several Precipitations the weight of the _Calx_ does for the same Reason much exceed that of the Metall, when it was first put in to be Dissolv'd.
26. But, _Pyrophilus_, to consider these Matters more particularly would be to forget that I declar'd against Adventuring, at least for this time, at particular Theories of Colours, and that accordingly you may justly expect from me rather Experiments than Speculations, and therefore I shall Dismiss this Subject of the Forms of Superficial Asperity in Colour'd Bodies, as soon as I shall but have nam'd to you by way of Supplement to what we have hitherto Discours'd in this Section, a Couple of Particulars, (which you'l easily grant me) The one, That there are divers other ways for the speedy Production even of True and Permanent Colours in Bodies, besides those Practicable by the help of Liquors; for proof of which Advertisement, though several Examples might be alleged, yet I shall need but Re-mind you of what I mention'd to you above, touching the change of Colours suddenly made on Temper'd Steel, and on Lead, by the Operation of Heat, without the Intervention of a Liquor. But the other particular I am to observe to you is of more Importance to our present Subject and it is, That though Nature and Art may in some cases so change the Asperity of the Superficial parts of a Body, as to change its Colour by either of the ways I have propos'd Single or Unassisted, yet for the most part 'tis by two or three, or perhaps by more of the fore-mention'd ways Associated together, that the Effect is produc'd, and if you consider how Variously those several ways and some others Ally'd unto them, which I have left unmention'd, may be Compounded and Apply'd, you will not much wonder that such fruitfull, whether Principles (or Manners of Diversification) should be fitted to Change or Generate no small store of Differing Colours.
27. Hitherto, _Pyrophilus_, we have in discoursing of the Asperity of Bodies consider'd the little Protuberances of other Superficial particles which make up that Roughness, as if we took it for granted, that they must be perfectly Opacous and Impenetrable by the Beams of Light, and so, must contribute to the Variety of Colours as they terminate more or less Light, and reflect it to the Eye mix'd with more or less of thus or thus mingl'd Shades. But to deal Ingenuously with you, _Pyrophilus_, before I proceed any further, I must not conceal from you, that I have often thought it worth a Serious Enquiry, whether or no Particles of Matter, each of them sing'y Insensible, and therefore small enough to be capable of being such Minute Particles as the _Atomists_ both of old and of late have (not absurdly) called _Corpuscula Coloris_, may not yet consist each of them of divers yet Minuter Particles, betwixt which we may conceive little Commissures where they Adhere to one another, and, however, may not be Porous enough to be, at least in some degree, Pervious to the unimaginably subtile Corpuscles that make up the Beams of Light, and consequently to be in such a degree Diaphanous. For, _Pyrophilus_, that the proposed Enquiry may be of moment to him that searches after the Nature of Colour, you'l easily grant, if you consider, that whereas Perfectly Opacous bodies can but reflect the incident Beams of Light, those that are Diaphanous are qualified to refract them too, and that Refraction has such a stroak in the Production of Colours, as you cannot but have taken notice of, and perhaps admir'd in the Colours generated by the Trajection of Light through Drops of Water that exhibit a Rain-bow, through Prismatical glasses, and through divers other Transparent bodies. But 'tis like, _Pyrophilus_, you'l more easily allow that about this matter 'tis rather Important to have a Certainty, than that 'tis Rational to entertain a Doubt; wherefore I must mention to you some of the Reasons that make me think it may need a further Enquiry, for I find that in a Darkned Room, where the Light is permitted to enter but at One hole, the little wandering Particles of Dust, that are commonly called Motes, and, unless in the Sunbeams, are not taken notice of by the unassisted Sight, I have, I say, often observ'd, that these roving Corpuscles being look'd on by an Eye plac'd on one side of the Beams that enter'd the Little hole, and by the Darkness having its Pupill much Enlarg'd, I could discern that these Motes as soon as they came within the compass of the Luminous, whether Cylinder or Inverted Cone, if I may so call it, that was made up by the Unclouded Beams of the Sun, did in certain positions appear adorn'd with very vivid Colours, like those of the Rain-bow, or rather like those of very Minute, but Sparkling fragments of Diamonds; and as soon as the Continuance of their Motion had brought them to an Inconvenient position in reference to the Light and the Eye, they were only visible without Darting any lively Colours as before, which seems to argue that these little Motes, or minute Fragments, of several sorts of bodies reputed Opacous, and only crumbled as to their Exteriour and Looser parts into Dust, did not barely Reflect the Beams that fell upon them, but remit them to the Eye Refracted too. We may also observe, that several Bodies, (as well some of a Vegetable, as others of an Animal nature) which are wont to pass for Opacous, appear in great part Transparent, when they are reduc'd into Thin parts, and held against a powerful Light. This I have not only taken notice of in pieces of Ivory reduc'd but into Thick leaves, as also in divers considerable Thick shells of Fishes, and in shaving of Wood, but I have also found that a piece of Deal, far thicker than one would easily imagine, being purposly interposed betwixt my Eye plac'd in a Room, and the clear Daylight, was not only somewhat Transparent, but (perhaps by reason of its Gummous nature) appear'd quite through of a lovely Red. And in the Darkned Room above mention'd, Bodies held against the hole at which the Light enter'd, appear'd far less Opacous then they would elsewhere have done, insomuch that I could easily and plainly see through the whole Thickness of my Hand, the Motions of a Body plac'd (at a very near distance indeed, but yet) beyond it. And even in Minerals, the Opacity is not always so great as many think, if the Body be made Thin, for White Marble though of a pretty Thickness, being within a Due distance plac'd betwixt the Eye and a Convenient Light, will Suffer the Motions of ones Finger to be well discern'd through it, and so will pieces, Thick enough, of many common Flints. But above all, that Instance is remarkable, that is afforded us by _Muscovie_ glass, (which some call _Selenites_, others _Lapis Specularis_) for though plates of this Mineral, though but of a moderate Thickness, do often appear Opacous, yet if one of these be Dextrously split into the thinnest Leaves 'tis made up of, it will yield such a number of them, as scarce any thing but Experience could have perswaded me, and these Leaves will afford the most Transparent sort of consistent Bodies, that, for ought I have observ'd, are yet known; and a single Leaf or Plate will be so far from being Opacous, that 'twill scarce be so much as Visible. And multitudes of Bodies there are, whose Fragments seem Opacous to the naked Eye, which yet, when I have included them in good _Microscopes_, appear'd Transparent; but, _Pyrophilus_, on the other side I am not yet sure that there are no Bodies, whose Minute Particles even in such a _Microscope_ as that of mine, which I was lately mentioning, will not appear Diaphanous. For having consider'd _Mercury_ Precipitated _per se_, the little Granules that made up the powder, look'd like little fragments of Coral beheld by the naked Eye at a Distance (for very Near at hand Coral will sometimes, especially if it be Good, shew some Transparency.) Filings likewise of Steel and Copper, though in an excellent _Microscope_, and a fair Day, they show'd like pretty Big Fragments of those Metalls, and had considerable Brightness on some of their Surfaces, yet I was not satisfi'd, that I perceiv'd any Reflection from the Inner parts of any of the Filings. Nay, having look'd in my best _Microscope_ upon the Red _Calx_ of Lead, (commonly call'd _Minium_) neither I, nor any I shew'd it to, could discern it to be other than Opacous, though the Day were Clear, and the Object strongly Enlightned. And the deeply Red Colour of _Vitriol_ appear'd in the same _Microscope_ (notwithstanding the great Comminution effected by the Fire) but like Grossy beaten Brick. So that, _Pyrophilus_, I shall willingly resign you the care of making some further Enquiries into the Subject we have now been considering; for I confess, as I told you before, that I think that the Matter may need a further Scrutiny, nor would I be forward to Determine how far or in what cases the Transparency or Semi-diaphaniety of the Superficial Corpuscles of Bigger Bodies, may have an Interest in the Production of their Colours, especially because that even in divers White bodies, as Beaten Glass, Snow and Froth, where it seems manifest that the Superficial parts are singly Diaphanous, (being either Water, or Air, or Glass) we see not that such Variety of Colours are produc'd as usually are by the Refraction of Light, even in those Bodies, when by their Bigness, Shape, &c. they are conveniently qualify'd to exhibit such Various and Lively Colours as those of the Rain-bow, and of Prismatical Glasses.
28. By what has been hitherto discours'd, _Pyrophilus_, we may be assisted to judge of that famous Controversie which was of Old disputed betwixt the _Epicureans_ and other _Atomists_ on the one side, and most other _Philosophers_ on the other side. The former Denying Bodies to be Colour'd in the Dark, and the Latter making Colour to be an Inherent quality, as well as Figure, Hardness; Weight, or the like. For though this Controversie be Reviv'd, and hotly Agitated among the _Moderns_, yet I doubt whether it be not in great part a Nominal dispute, and therefore let us, according to the Doctrine formerly deliver'd, Distinguish the Acceptions of the word Colour, and say, that if it be taken in the Stricter Sense, the _Epicureans_ seem to be in the Right, for if Colour be indeed, though not according to them, but Light Modify'd, how can we conceive that it can Subsist in the Dark, that is, where it must be suppos'd there is no Light; but on the other side, if Colour be consider'd as a certain Constant Disposition of the Superficial parts of the Object to Trouble the Light they Reflect after such and such a Determinate manner, this Constant, and, if I may so speak, Modifying disposition persevering in the Object, whether it be Shin'd upon or no, there seems no just reason to deny, but that in this Sense, Bodies retain their Colour as well in the Night as Day; or, to Speak a little otherwise, it may be said, that Bodies are Potentially Colour'd in the Dark, and Actually in the Light. But of this Matter discoursing more fully elsewhere, as 'tis a difficulty that concerns Qualities in general, I shall forbear to insist on it here.
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CHAP. IV