Chapter 22

That Gold dissolv'd in _Aqua Regia_ ennobles the _Menstruum_ with its own Colour, is a thing that you cannot (_Pyrophilus_,) but have often seen. The Solutions of Mercury in _Aqua-fortis_ are not generally taken notice of, to give any notable Tincture to the _Menstruum_; but sometimes when the Liquor first falls upon the Quick Silver, I have observ'd a very remarkable, though not durable, Greenness, or Blewness to be produc'd, which is a _Phænomenon_ not unfit for you to consider, though I have not now the leisure to discourse upon it. Tin Corroded by _Aqua-fortis_ till the _Menstruum_ will work no farther on it, becomes exceeding White, but as we elsewhere note, does very easily of it self acquire the consistence, not of a Metalline _Calx_, but of a Coagulated matter, which we have observ'd with pleasure to look so like, either to curdled Milk, or curdled Whites of Eggs, that a person unacquainted with such Solutions may easily be mistaken in it. But when I purposely prepar'd a _Menstruum_ that would dissolve it as _Aqua-fortis_ dissolves Silver, and not barely Corrode it, and quickly let it fall again, I remember not that I took notice of any particular Colour in the Solution, as if the more Whitish Metalls did not much Tinge their _Menstruums_, though the conspicuously Colour'd Metalls as Gold, and Copper, do. For Lead dissolv'd in Spirit of Vinegar or _Aqua-fortis_ gives a Solution cleer enough, and if the _Menstruum_ be abstracted appears either Diaphanous or White. Of the Colour of Iron we have elsewhere said something: And 'tis worth noting, that though if that Metall be dissolv'd in oyl of Vitriol diluted with water, it affords a Salt or Magistery so like in colour, as well as some other Qualities, to other green Vitriol, that Chymists do not improperly call it _Vitriolum Martis_; yet I have purposely try'd, that, by changing the _Menstruum_, and pouring upon the filings of Steel, instead of oyl of Vitriol, _Aqua Fortis_, (whereof as I remember, I us'd 4 parts to one of the Metall) I obtain'd not a Green, but a Saffron Colour Solution; or rather a thick Liquor of a deep but yellowish Red. Common Silver, such as is to be met with in Coines, being dissolv'd in _Aqua fortis_, yields a Solution tincted like that of Copper, which is not to be wondred at, because in the coining of Silver, they are wont (as we elsewhere particularly inform you) to give it an Allay of Copper, and that which is sold in shops for refined silver, is not (so far as we have tryed) so perfectly free from that ignobler Metall, but that a Solution of It in _Aqua fortis_, will give a Venereal Tincture to the _Menstruum_. But we could not observe upon the solution of some Silver, which was perfectly refin'd, (such as some that we have, from which 8 or 10 times its weight of Lead has been blown off) that the _Menstruum_ though held against the Light in a Crystal Vial did manifestly disclose any Tincture, only it seem'd sometimes not to be quite destitute of a little, but very faint Blewishness.

But here I must take notice, that of all the Metalls, there is not any which doth so easily and constantly disclose its unobvious colour as Copper doth. For not only in acid _Menstruums_ as _Aqua Fortis_ and Spirit of Vinegar, it gives a Blewish green solution, but if it be almost any way corroded, it _appears of one of those_ two colours, as may be observ'd in Verdigreese made several wayes, in that odd preparation of _Venus_, which we elsewhere teach you to make with Sublimate, and in the common Vitriols of _Venus_ deliver'd by Chymists; and so constant is the disposition of Copper, notwithstanding the disguise Artists put upon it, to disclose the colour we have been mentioning, that we have by forcing it up with _Sal Armoniack_ obtain'd a Sublimate of a Blewish Colour. Nay a famous Spagyrist affirms, that the very Mercury of it is green, but till he teach us an intelligible way of making such a Mercury, we must content ourselves to inform you, that we have had a Cupreous Body, that was Præcipitated out of a distill'd Liquor, that seem'd to be the the Sulphur of _Venus_, and seem'd even when flaming, of a Greenish Colour. And indeed Copper is a Metall so easily wrought upon by Liquors of several kinds, that I should tell you, I know not any Mineral, that will concurr to the production of such a variety of Colours as Copper dissol'd in several _Menstruums_, as Spirit of Vinegar, _Aqua fortis_, _Aqua Regis_, Spirit of Nitre, of Urine, of Soot, Oyls of several kinds, and I know not how many other Liquors, if the variety of somewhat differing colours (that Copper will be made to assume, as it is wrought upon by several Liquors) were not comprehended within the Limits of Greenish Blew, or Blewish Green.

And yet I must advertise you (_Pyrophilus_) that being desirous to try if I could not make with crude Copper a Green Solution without the Blewishness that is wont to accompany its Vulgar Solutions, I bethought my self of using two _Menstruums_, which I had not known imploy'd to work on this Metall, and which I had certain Reasons to make Tryal of, as I successfully did. The one of these Liquors (if I much misremember not) was Spirit of Sugar distill'd in a Retort, which must be warily done, (if you will avoid breaking your glasses) and the other, Oyl or Spirit of Turpentine, which affords a fine Green Solution that is useful to me on several occasions. And yet to shew that the adventitious colour may result, as well from the true and permanent Copper it self, as the Salts wherewith 'tis corroded, I shall add, that if you take a piece of good _Dantzick_ Copperis, or any other Vitriol wherein _Venus_ is prædominant, and having moistened it in your Mouth, or with fair water, rubb it upon a whetted knife, or any other bright piece of Steel or Iron, it will (as we have formerly told you) present'y stain the Steel with a Reddish colour, like that of Copper, the reason of which, we must not now stay to inquire.

_Annotation I._

I presume you may have taken notice (_Pyrophilus_) that I have borrowed some of the Instances mention'd in this 47th Experiment, from the Laboratories of Chymists, and because in some (though very few) other passages of this Essay, I have likewise made use of Experiments mention'd also by some Spagyrical Writers, I think it not amiss to represent to you on this Occasion once for all, some things besides those which I intimated in the præamble of this present Experiment; For besides, that 'tis very allowable for a Writer to repeat an Experiment which he invented not, in case he improve it; And besides that many Experiments familiar to Chymists are unknown to the generality of Learned Men, who either never read Chymical processes, or never understood their meaning, or never durst believe them; besides these things, I say, I shall represent, That, as to the few Experiments I have borrowed from the Chymists, if they be very Vulgar, 'twould perhaps be difficult to ascribe each of them its own Author, and 'tis more than the generality of Chymists themselves can do: and if they be not of very known and familiar practise among them, unless the Authors wherein I found them had given me cause to believe, themselves had try'd them, I know not why I might not set them down, as a part of the _Phænomena_ of Colours which I present you; Many things unanimously enough deliver'd as matters of fact by (I know not how many Chymical Writers) being not to be rely'd on, upon the single Authority of such Authors: For Instance, as some Spagyrists deliver (perhaps amongst several deceitful processes) that _Saccarum Saturni_ with Spirit of Turpentine will afford a Balsom, so _Beguinus_ and many more tell us, that the same Concrete (_Saccarum Saturni_) will yield an incomparably fragrant Spirit, and a pretty Quantity of two several Oyles, and yet since many have complain'd, as well as I have done, that they could find no such odoriferous, but rather an ill-sented Liquor, and scarce any oyl in their Distillation of that sweet Vitriol, a wary person would as little build any thing on what they say of the former Experiment, as upon what they averr of the later, and therefore I scrupled not to mention this Red Balsom of which I have not seen any, (but what I made) among my other experiments about redness.

_Annot. II._

We have sometimes had the Curiosity to try what Colours Minerals, as Tinglass, Antimony, Spelter, &c. would yield in several _Menstruums_, nor have we forborn to try the Colours of stones, of which that famous one, (which _Helmont_ calls _Paracelsus's Ludus_) though it be digg'd out of the Earth and seem a true stone, has afforded in _Menstruums_ capable to dissolve so solid a stone, sometimes a Yellowish, sometimes a Red solution of both which I can show you. But though I have from Minerals obtain'd with several _Menstruums_ very differing Colours, and some such as perhaps you would be surpriz'd to see drawn from such Bodies: yet I must now pass by the particulars, being desirous to put an End to this Treatise, before I put an end to your Patience and my own.

_Annotation III._

And yet before I pass to the next Experiment, I must put you in mind, that the Colours of Metals may in many cases be further alter'd by imploying, either præcipitating Salts, or other convenient Substances to act upon their Solutions. Of this you may remember, that I have given you several Instances already, to which may be added such as these, That if Quicksilver be dissolv'd in _Aqua fortis_, and Præcipitated out of the Solution, either with water impregnated with Sea salt, or with the spirit of that Concrete, it falls to the Bottom in the form of a white powder, whereas if it be Præcipitated with an Alcaly, it will afford a Yellowish or tawny powder, and if there be no Præcipitation made, and the _Menstruum_ be drawn off with a convenient fire, the corroded Mercury will remain in the bottom, in the form of a substance that may be made to appear of differing Colours by differing degrees of Heat; As I remember that lately having purposely abstracted _Aqua fortis_ from some Quicksilver that we had dissolv'd in it, so that there remain'd a white _Calx_, exposing that to several degrees of Fire, and afterwards to a naked one, we obtain'd some new Colours, and at length the greatest part of the _Calx_ lying at the Bottome of the Vial, and being brought partly to a Deep Yellow, and partly to a Red Colour, the rest appear'd elevated to the upper part and neck of the Vial, some in the form of a Reddish, and some of an Ash-Colour Sublimate. But of the differing Colours which by differing wayes and working of Quick Silver with Fire, and Saline Bodies, may be produc'd in Precipitates, I may elsewhere have occasion to take further notice. I also told you not long since, that if you corrode Quick-silver with Oyl of Vitriol instead of _Aqua-fortis_, and abstract the _Menstruum_, there will remain a White _Calx_ which by the Affusion of Fair Water presently turns into a Lemmon Colour. And ev'n the _Succedaneum_ to a _Menstruum_ may sometimes serve the turn to change the Colours of a Metal. The lovely Red which Painters call Vermillion, is made of Mercury, which is of the Colour of Silver, and of Brimstone which is of Kin to that of Gold, Sublim'd up together in a certain proportion, as is vulgarly known to Spagyrists.

_EXPERIMENT XLVIII._

The third chief sort of the Adventitious Colours of Metals, is, that which is produc'd by associating them (especially when Calcin'd) with other fusible Bodies, and Principally Venice, and other fine Glass devoid of Colour.

I have formerly given you an Example, whereby it may appear, that a Metal may impart to Glass a Colour much differing from its own, when I told you, how with Silver, I had given Glass a lovely Golden Colour. And I shall now add, that I have Learn'd from one of the Chief Artificers that sells Painted Glass, that those of his Trade Colour it Yellow with a preparation of the _Calx_ of Silver. Though having lately had occasion among other Tryals to mingle a few grains of Shell-silver (such as is imploy'd with the Pensil and Pen) with a convenient proportion of powder'd Crystal Glass, having kept them two or three hours in fusion, I was surpriz'd to find the Colliquated Mass to appear upon breaking the Crucible of a lovely Saphirine Blew, which made me suspect my Servant might have brought me a wrong Crucible, but he constantly affirm'd it to be the same wherein the Silver was put, and considerable Circumstances countenanc'd his Assertion, so that till I have opportunity to make farther Tryal, I cannot but suspect, either that Silver which is not (which is not very probable) brought to a perfect Fusion and Colliquation with Glass, may impart to it other Colours than when Neal'd upon it, or else (which is less unlikely) that though Silver Beaters usually chuse the finest Coyn they can get, as that which is most extensive under the Hammer, yet the Silver-leaves of which this Shel-silver was made, might retain so much Copper as to enable it to give the predominant tincture to the Glass.

For, I must proceed to tell you (_Pyrophilus_) as another instance of the Adventitious Colours of Metals, that which is something strange, Namely, That though Copper Calcin'd _per se_ affords but a Dark and basely Colour'd _Calx_, yet the Glassmen do with it, as themselves inform me, Tinge their Glass green. And I remember, that when once we took some crude Copper, and by frequent Ignition quenching it in Water had reduc'd it to a Dark and Ill-colour'd Powder, and afterward kept it in Fusion in about a 100. times its weight of fine Glass, we had, though not a Green, yet a Blew colour'd Mass, which would perhaps have been Green, if we had hit right upon the Proportion of the Materials, and the Degree of Fire, and the Time wherein it ought to be kept in Fusion, so plentifully does that Metal abound in a Venerial Tincture, as Artists call it, and in so many wayes does it disclose that Richness. But though Copper do as we have said give somewhat near the like Colour to Glass, which it does to _Aqua-fortis_, yet it seems worth inquiry, whether those new Colours which Mineral Bodies disclose in melted Glass, proceed from the Coalition of the Corpuscles of the Mineral with the Particles of the Glass as such, or from the Action (excited or actuated by fire) of the Alcalizate Salt (which is a main Ingredient of Glass,) upon the Mineral Body, or from the concurrence of both these Causes, or else from any other. But to return to that which we were saying, we may observe that _Putty_ made by calcining together a proportion of Tin and Lead, as it is it self a White _Calx_, so does it turn the _Pitta di Crystallo_ (as the Glassmen call the matter of the Purer sort of Glass, wherewith it is Colliquated into a White Mass, which if it be opacous enough is employ'd, as we elsewhere declare, for White Amel. But of the Colours which the other Metals may be made to produce in Colourless Glass, and other Vitrifiable Bodies, that have native Colours of their own, I must leave you to inform your self upon Tryal, or at least must forbear to do it till another time, considering how many Annotations are to follow, upon what has in this and the two former Experiments been said already.

_Annotation I._

When the Materials of Glass being melted with Calcin'd Tin, have compos'd a Mass Undiaphanous and White, this White Amel is as it were the Basis of all those fine Concretes that Goldsmiths and several Artificers imploy in the curious Art of Enamelling. For this White and Fusible substance will receive into it self, without spoyling them, the Colours of divers other Mineral substances, which like it will indure the fire.

_Annotation II._

So that as by the present (XLVIII.) Experiment it appears, that divers Minerals will impart to fusible Masses, Colours differing from their own; so by the making and compounding of Amels, it may appear, that divers Bodies will both retain their Colour in the fire, and impart the _same_ to some others wherewith they were vitrifi'd, and in such Tryals as that mention'd in the 17. Experiment, where I told you, that ev'n in Amels a Blew and Yellow will compound a Green. 'Tis pretty to behold, not only that some Colours are of so fix'd a Nature, as to be capable of mixture without receiving any detriment by the fire, that do's so easily destroy or spoyl those of other Bodies; but Mineral Pigments may be mingled by fire little less regularly and successfully, than in ordinary Dyeing Fatts, the vulgar Colours are wont to be mingled by the help of Water.

_Annotation III._

'Tis not only Metalline, but other Mineral Bodies, that may be imploy'd, to give Tinctures unto Glass (and 'tis worth noting how small a quantity of some Mineral substances, will Tinge a Comparatively vast proportion of Glass, and we have sometimes attempted to Colour Glass, ev'n with Pretious Stones, and had cause to think the Experiment not cast away. And 'tis known by them that have look'd into the Art of Glass, that the Artificers use to tinge their Glass Blew, with that Dark Mineral _Zaffora_, (some of my Tryals on which I elsewhere acquaint you) which some would have to be a Mineral Earth, others a Stone, and others neither the one, nor the other, but which is confessedly of a Dark, but not a Blew Colour, though it be not agreed of what particular Colour it is. 'Tis likewise though a familiar yet a remarkable practise among those that Deal in the making of Glass, to imploy (as some of themselves have inform'd me) what they call Manganess, and some Authors call _Magnesia_ (of which I make particular mention in another Treatise) to exhibit in Glass not only other Colours than its own, (which is so like in Darkness or blackishness to the Load stone, that 'tis given by Mineralists, for one of the Reasons of its Latine Name) but Colours differing from one another. For though they use it, (which is somewhat strange) to Clarifye their Glass, and free it from that Blewish Greenish Colour, which else it would too often be subject to, yet they also imploy it in certain proportions, to tinge their Glass both with a Red colour, and with a Purplish or Murry, and putting in a greater Quantity, they also make with it that deep obscure Glass which is wont to pass for Black, which agrees very well with, and may serve to confirm what we noted near the beginning of the 44th Experiment, of the seeming Blackness of those Bodies that are overcharg'd with the Corpuscles of such Colours, as Red, or Blew, or Green, &c. And as by several Metals and other Minerals we can give various Colours to Glass, so on the other side, by the differing Colours that Mineral Oars, or other Mineral Powders being melted with Glass disclose in it, a good Conjecture may be oftentimes made of the Metall or known Mineral, that the Oar propos'd, either holds, or is most of kin to. And this easie way of examining Oars, may be in some cases of good use, and is not ill deliver'd by _Glauber_, to whom I shall at present refer you, for a more particular account of it: unless your Curiosity command also what I have observ'd about these matters; only I must here advertise you, that great circumspection is requisite to keep this way from proving fallacious, upon the account of the variations of Colour that may be produc'd by the differing proportions that may be us'd betwixt the Oar and the Glass, by the Richness or Poorness of the Oar it self, by the Degree of Fire, and (especially) by the Length of Time, during which the matter is kept in fusion; as you will easily gather from what you will quickly meet with in the following Annotation upon this present 48th Experiment.

_Annotation IV._

There is another way and differing enough from those already mention'd, by which Metalls may be brought to exhibit adventitious Colours: For by This, the Metall do's not so much impart a Colour to another Body, as receive a Colour from it, or rather both Bodies do by the new Texture resulting from their mistion produce a new Colour. I will not insist to this purpose upon the Examples afforded us by yellow Orpiment, and common Sea Salt, from which, sublim'd together, Chymists unanimously affirm their White or Crystalline Arsenick to be made: But 'tis not unworthy our noting, That though Yellow Orpiment be acknowledg'd to be the Copiousest by far of the two Ingredients of Arsenick, yet this last nam'd Body being duely added to the highest Colour'd Metall Copper, when 'tis in fusion, gives it a whiteness both within and without. Thus _Lapis Calaminaris_ changes and improves the Colour of Copper by turning it into Brass. And I have sometimes by the help of Zinck duely mix'd after a certain manner, given Copper one of the Richest Golden Colours that ever I have seen the Best true Gold Ennobled with. But pray have a care that such Hints fall not into any hands that may mis-imploy them.

_Annotation V._

Upon the Knowledge of the differing wayes of making Minerals and Metalls produce their adventitious Colours in Bodies capable of Vitrification, depends the pretty Art of making what Chymists by a Barbarous Word are pleas'd to call _Amanses_, that is counterfeit, or factitious Gemms, as Emeralds, Rubies, Saphires, Topazes, and the like. For in the making of these, though pure Sand or Calcin'd Crystal give the Body, yet 'tis for the most part some Metalline or Mineral _Calx_, mingled in a small proportion that gives the Colour. But though I have many years since taken delight, to divert my self with this pleasing Art, and have seen very pretty Productions of it, yet besides that I fear I have now forgot most of the little Skill I had in it, this is no place to entertain you with what would rather take up an intire Discourse, than be comprehended in an Annotation; wherefore the few things which I shall here take notice of to you, are only what belong to the present Argument, Namely,

First, That I have often observ'd that Calcin'd Lead Colliquated with fine White Sand or Crystal, reduc'd by ignitions and subsequent extinctions in Water to a subtile Powder, will of it self be brought by a due Decoction to give a cleer Mass Colour'd like a _German_ Amethyst. For though this glass of Lead, is look'd upon by them that know no better way of making _Amanses_, as the grand Work of them all, yet which is an inconvenience that much blemishes this way, the Calcin'd Lead it self does not only afford matter to the _Amanses_, but has also as well as other Metals a Colour of its own, which as I was saying, I have often found to be like that of _German_ (as many call them) not Eastern Amethysts.

Secondly, That nevertheless this Colour may be easily over-powr'd by those of divers other Mineral Pigments (if I may so call them) so that with a glass of Lead, you may Emulate (for Instance) the fresh and lovely Greenness of an Emerald, though in divers cases the Colour which the Lead it self upon Vitrification tends to, may vitiate that of the Pigment, which you would introduce into the Mass.

Thirdly, That so much ev'n these Colours depend upon Texture, that in the Glass of Lead it self made of about three parts of _Lytharge_ or _Minium_ Colliquated with one of very finely Powder'd Crystal or Sand, we have taken pleasure to make the mixture pass through differing Colours, as we kept it more or less in the Fusion. For it was not usually till after a pretty long Decoction that the Mass attain'd to the Amethystin Colour.

Fourthly and lastly, That the degrees of Coction and other Circumstances may so vary the Colour produc'd in the same mass, that in a Crucible that was not great I have had fragments of the same Mass, in some of which perhaps not so big as a Hazel-Nut, you may discern four distinct Colours.

_Annotation VI._