Chapter 20

The Knowledge of the Distinction of Salts which we have propos'd, whereby they are discriminated into _Acid, Volatile,_ or _Salfuginous_ (if I may for Distinction sake so call the Fugitive Salts of Animal Substances) and _fix'd_ or _Alcalizate_, may possibly (by that little part which we have already deliver'd, of what we could say of its Applicableness) appear of so much Use in Natural Philosophy (especially in the Practick part of it) that I doubt not but it will be no Unwelcome Corollary of the Preceding Experiment, if by the help of it I teach you to distinguish, which of those Salts is Predominant in Chymical Liquors, as well as whether any of them be so or not. For though in our Notes upon the X. and XX. Experiments I have shown you a way by means of the Tincture of _Lignum Nephriticum_, or of Syrrup of Violets, to discover whether a propounded Salt be Acid or not, yet you can thereby only find in general that such and such Salts belong not to the Tribe of Acids, but cannot determine whether they belong to the Tribe of Urinous Salts (under which for distinction sake I comprehend all those Volatile Salts of Animal or other Substances that are contrary to Acids) or to that of Alcalies. For as well the one as the other of these Salino-Sulphurous Salts will restore the Cæruleous Colour to the Tincture of _Lignum Nephriticum_, and turn that of Syrrup of Violets into Green. Wherefore this XL. Experiment does opportunely supply the deficiency of those. For being sollicitous to find out some ready wayes of discriminating the Tribes of Chymical Salts, I found that all those I thought fit to make Tryal of, would, if they were of a Lixiviate Nature, make with Sublimate dissolv'd in Fair Water an _Orange Tawny_ Precipitate; whereas if they were of an Urinous Nature the Precipitate would be _White_ and Milky. So that having alwayes by me some Syrrup of Violets and some Solution of Sublimate, I can by the help of the first of those Liquors discover in a trice, whether the propounded Salt or Saline Body be of an Acid Nature or no, if it be I need (you know) inquire no further; but if it be not, I can very easily, and as readily distinguish between the other two kinds of Salts, by the White or Orange-Colour that is immediately produc'd, by letting fall a few Drops or Grains of the Salt to be examin'd, into a spoonfull of the cleer Solution of Sublimate. For Example, it has been suppos'd by some eminently Learned, That when Sal Armoniack being mingled with an Alcaly is forc'd from it by the Fire in close Vessels, the Volatile Salt that will thereby be obtain'd (if the Operation be skilfully perform'd,) is but a more fine and subtile sort of Sal Armoniack, which, 'tis presum'd, this Operation do's but more exquisitely purifie, than common Solutions, Filtrations, and Coagulations. But this Opinion may be easily shown to be Erroneous, as by other Arguments, so particularly by the lately deliver'd Method of distinguishing the Tribes of Salts. For the Saline Spirit of Sal Armoniack, as it is in many other manifest Qualities very like the Spirit of Urine, so like, that it will in a trice make Syrrup of Violets of a Lovely Green, turn a Solution of good Verdigrease into an Excellent Azure, and make the Solution of a Sublimate yield a White Precipitate, insomuch that in most (for I say not all of the Experiments) where I Aim onely at producing a sudden change of Colour, I scruple not to use Spirit of Sal Armoniack when it is at hand, instead of Spirit of Urine, as indeed it seems chiefly to consist (besides the flegm that helps to make it fluid) of the Volatile Urinous Salt (yet not excluding that of Soot) that abounds in the Sal Armoniack and is set at liberty from the Sea Salt wherewith it was formerly associated, and clogg'd, by the Operation of the Alcaly, that divides the Ingredients of Sal Armoniack, and retains that Sea Salt with it self. What use may be made of the like way of exploration in that inquiry which puzzles so many Modern Naturalists, whether the Rich Pigment (which we have often had occasion to mention) belongs to the Vegetable or Animal Kingdome, you may find in another place where I give you some account of what I try'd about Cocheneel. But I think it needless to exemplifie here our Method by any other Instances, many such being to be met with in divers parts of this Treatise; but I will rather advertise you, that, by this way of examining Chymical Liquors, you may not onely in most Cases conclude _Affirmatively_, but in some Cases _Negatively_. As since Spirit of Wine, and as far as I have try'd, those Chymical Oyles which Artists call Essential, did not (when I us'd them as I had us'd the several Families of Salts upon that Syrrup) turn Syrrup of Violets Red or Green, nor the Solution of Sublimate White or Yellow, I inferr'd it may thence be probably argued, that either they are destitute of Salt, or have such as belongs not to either of the three Grand families already often mention'd. When I went to examine the Spirit of Oak or of such like Concretes forced over through a Retort, I found by this means amongst others, that (as I elsewhere show) these Chymists are much mistaken in it, that account it a simple Liquor, and one of their Hypostatical Principles: for not to mention what flegm it may have, I found that with a few drops of one of this sort of Spirits mix'd with a good proportion of Syrrup of Violets, I could change the Colour and make it Purplish, by the affinity of which Colour to Redness, I conjectur'd that this Spirit had some Acid Corpuscles in it, and accordingly I found that as it would destroy the Blewness of a Tincture of _Lignum Nephriticum_, so being put upon Corals it would Corrode them, as common Spirit of Vinegar, and other Acid Liquors are wont to do. And farther to examine whether there were not a great part of the Liquor that was not of an Acid nature, having separated the Sour or Vinegar-like part from the rest, which (if I mistake not) is far the more Copious, we concluded as we had conjectured, the other or remaining part, though it had a strong taste as well as smell, to be of a nature differing from that of either of the three sorts of Salts above mention'd, since it did as little as Spirit of Wine, and Chymical Oyls, alter the Colour either of Syrrup of Violets or Solution of Sublimate, whence we also inferr'd that the change that had been made of that Syrrup into a Purple Colour, was effected by the Vinegar, that was one of the two Ingredients of the Liquor, which was wont to pass for a Simple or Uncompounded Spirit. And, upon this account, 'twas of the Spirit of Oak (and the like Concretes) freed from it's Vinegar that I elsewhere told you, that I had not then observ'd it, (and I have repeated the Tryal but very lately) to destroy the Cæruleous Tincture of _Lignum Nephriticum_. But this onely, _en passant_; for the Chief thing I had to add was this, That by the same way may be examin'd and discover'd, divers changes that are produc'd in Bodies either by Nature only, or by Art; either of them being able by changing the Texture of some Concretes I could name, to qualifie them to Operate after a New manner upon the above mention'd Syrrup, or Solution, or both. And by this means, to tell you that upon the by, I have been able to discover, that there may be made Bodies, which though they run _per Deliquium_, as readily as Salt of Tartar, belong in other respects, not to the family of Alcaliz, much less to that of Salfuginous, or that of Acid Salts. Perhaps too, I may know a way of making a highly operative Saline Body that shall neither change the Colour of Syrrup of Violets, nor Precipitate the Solution of Sublimate; And, I can likewise if I please conceal by what Liquors I perform such changes of Colour, as I have been mentioning to you, by quite altering the Texture of some ordinary Chymical productions, the Exploration of which is the main use of the fortieth Experiment, which I think teaches not a little, if it teach us to discover the nature of those things (in reference to Salt) that are obtain'd by the ordinary Chymical Analysis of mix'd Bodyes, though perhaps there may be other Bodyes prepar'd by Chymistry which may have the same Effects in the change of Colours; and yet be produc'd not from what Chymists call the Resolution of Bodies, but from their Composition. But the discoursing of things of this nature is more proper for another place. I shall now onely add, what might perhaps have been more seasonably told you before; That the Reason why the way of Exploration of Salts hitherto deliver'd, succeeds in the Solution of Sublimate, depends upon the particular Texture of that Solution, as well as upon the differing Natures of the Saline Liquors imploy'd to Precipitate it. For Gold dissolv'd in _Aqua Regia_, whether you Precipitate it with Oyl of Tartar which is an Alcaly, or with Spirit of Urine, or Sal Armoniack which belongs to the family of Volatile Salts, will either way afford a Yellow substance: though with such an Acid Liquor, as, I say not Spirit of Salt, the Body that yields it, being upon the matter an Ingredient of _Aqua Regis_, but Oyl of Vitriol it self, I did not find that I could Precipitate the Metall out of the Solution, or destroy the Colour of it, though the same Oyl of Vitriol would readily Precipitate Silver dissolv'd in _Aqua-fortis_. And if you dissolve pure Silver in _Aqua-fortis_, and suffer it to shoot into Crystals, the cleer Solution of these made in fair Water, will afford a very White Precipitate, whether it be made with an Alcaly, or an Acid Spirit, as that of Salt, whereas, which may seem somewhat strange, with Spirit of Sal Armoniack (that I us'd was made of Quicklime) I could obtain no such White Precipitate; that Volatile Spirit, nor (as I remember) that of Urine, scarce doing any more than striking down a very small quantity of Matter, which was neither White nor Whitish, so that the remaining Liquor being suffer'd to evaporate till the superfluous Moisture was gone, the greatest part of the Metalline Corpuscles with the Saline ones that had imbib'd them, concoagulated into Salt, as is usual in such Solutions, wherein the Metall has not been Precipitated.

_EXPERIMENT XLI._

Of Kin to the last or fortieth Experiment is another which I remember I have sometimes shewn to _Virtuosi_ that were pleas'd not to dislike it. I took Spirit of Urine made by Fermentation, and with a due proportion of Copper brought into small parts, I obtain'd a very lovely Azure Solution, and when I saw the Colour was such as was requisite, pouring into a clean Glass, about a spoonfull of this tincted Liquor, (of which I us'd to keep a Quantity by me,) I could by shaking into it some drops of Strong Oyl of Vitriol, deprive it in a trice of its Deep Colour, and make it look like Common-water.

_Annotation_.

This Experiment brings into my mind this other, which oftentimes succceds well enough, though not quite so well as the former; Namely, that if into about a small spoonfull of a Solution of good French Verdigrease made in fair Water, I drop't and shak'd some strong Spirit of Salt, or rather deflegm'd _Aqua Fortis_, the Greenness of the Solution would be made in a trice almost totally to disappear, & the Liquor held against the Light would scarce seeme other than Cleer or Limpid, to any but an Attentive Eye, which is therefore remarkable; because we know that _Aqua-fortis_ corroding Copper, which is it that gives the Colour to Verdigrease, is wont to reduce it to a Green Blew Solution. But if into the other altogether or almost Colourless Liquor I was speaking of, you drop a just quantity either of Oyl of Tartar or Spirit of Urine, you shall find that after the Ebullition is ceas'd, the mixture will disclose a lively Colour, though somewhat differing from that which the Solution of Verdigrease had at first.

_EXPERIMENT XLII._

That the Colour (_Pyrophilus_) of a Body may be chang'd by a Liquor which of it self is of no Colour, provided it be Saline, we have already manifested by a multitude of instances. Nor doth it seem so strange, because Saline Particles swimming up and down in Liquors, have been by many observ'd to be very operative in the Production and change of Colours. But divers of our Friends that are not acquainted with Chymical Operations have thought it very strange that a White Body, and a Dry one too, should immediately acquire a rich new Colour upon the bare affusion of Spring-Water destitute as well of adventitious Salt as of Tincture. And yet (_Pyrophilus_) the way of producing such a change of Colours may be easily enough lighted on by those that are conversant in the Solutions of Mercury. For we have try'd, that though by Evaporating a Solution of Quick-Silver in _Aqua-fortis_, and abstracting the Liquor till the remaining matter began to be well, but not too strongly dryed, fair Water pour'd on the remaining _Calx_ made it but somewhat Yellowish; yet when we took good Quick-Silver, and three or four times its weight of Oyl of Vitriol, in case we in a Glass Retort plac'd in Sand drew off the Saline _Menstruum_ from the Metalline Liquor, till there remain'd a dry _Calx_ at the bottome, though this Precipitate were a Snow White Body, yet upon pouring on it a large quantity of fair Water, we did almost in a moment perceive it to pass from a Milky Colour to one of the loveliest Light Yellows that ever we had beheld. Nor is the Turbith Mineral, that Chymists extol for its power to Salivate, and for other vertues, of a Colour much inferiour to this, though it be often made with a differing proportion of the Ingredients, a more troublesome way. For _Beguinus_,[22] who calls it _Mercurius præcipitatus optimus_, takes to one part of Quick-Silver, but two of Liquor, and that is Rectifi'd Oyl of Sulphur, which is (in _England_ at least) far more scarce and dear than Oyl of Vitriol; he also requires a previous Digestion, two or three Cohobations, and frequent Ablutions with hot Distill'd Water, with other prescriptions, which though they may conduce to the Goodness of the Medicine, which is that he aims at, are troublesome, and, our Tryals have inform'd you unneccessary to the _obtaining the Lemmon Colour_ which he regards not. But though we have very rarely seen either in Painters Shops, or elsewhere a finer Yellow than that which we have divers times this way produc'd (which is the more considerable, because durable and pleasant Yellows are very hard to be met with, as may appear by the great use which Painters are for its Colours sake fain to make of that pernicious and heavy Mineral, Orpiment) yet I fear our Yellow is too costly, to be like to be imploy'd by Painters, unless about Choice pieces of Work, nor do I know how well it will agree with every Pigment, especially, wich Oyl'd Colours. And whether this Experiment, though it have seem'd somewhat strange to most we have shown it to, be really of another Nature than those wherein Saline Liquors are imploy'd, may, as we formerly also hinted, be so plausibly doubted, that whether the Water pour'd on the _Calx_, do barely by imbibing some of its Saline parts alter its Colour by altering its Texture, or whether by dissolving the Concoagulated Salts, it does become a Saline _Menstruum_, and, as such, work upon the Mercury, I freely leave to you (_Pyrophilus_) to consider. And that I may give you some Assistance in your Enquiry, I will not only tell you, that I have several times with fair Water wash'd from this _Calx_, good store of strongly tasted Corpuscles, which by the abstraction of the _Menstruum_, I could reduce into Salt; but I will also subjoyn an Experiment, which I devis'd, to shew among other things, how much a real and permanent Colour may be as it were drawn forth by a Liquor that has neither Colour, nor so much as Saline or other Active parts, provided it can but bring the parts of the Body it imbibes to convene into clusters dispos'd after the manner requisite to the exhibiting of the emergent Colour. The Experiment was this.

[22] _Beguinus_, Tyr. Chy. Lib. 2º. Cap. 13º.

_EXPERIMENT XLIII._

We took good common Vitriol, and having beaten it to Powder, and put it into a Crucible, we kept it melted in a gentle heat, till by the Evaporation of some parts, and the shuffling of the rest, it had quite lost its former Colour, what remain'd we took out, and found it to be a friable _Calx_, of a dirty Gray. On this we pour'd fair Water, which it did not Colour Green or Blew, but only seem'd to make a muddy mixture with it, then stopping the Vial wherein the Ingredients were put, we let it stand in a quiet place for some dayes, and after many hours the water having dissolv'd a good part of the imperfectly calcin'd Body, the Vitriolate Corpuscles swiming to and fro in the Liquor, had time by their opportune Occursions to constitute many little Masses of Vitriol, which gave the water they impregnated a fair Vitriolate Colour; and this Liquor being pour'd off, the remaining dirty Powder did in process of time communicate the like Colour, but not so deep, to a second parcel of cleer Water that we pour'd on it. But this Experiment _Pyrophilus_ is, (to give you that hint by the way) of too Luciferous a Nature to be fit to be fully prosecuted, now that I am in haste, and willing to dispatch what remains. And we have already said of it, as much as is requisite to our present purpose.

_EXPERIMENT XLIV._