Experiments and Considerations Touching Colours (1664)

Chapter 14

Chapter 143,781 wordsPublic domain

We took a Leaf of Such Foliated Gold as Apothecaries are wont to Gild their Pills with; and with the Edge of a Knife, (lightly moysten'd by drawing it over the Surface of the Tongue, and afterwards) laid upon the edge of the Gold Leaf; we so fasten'd it to the Knife, that being held against the light, it conctinu'd extended like a little Flagg. This Leaf being held very near the Eye, and obverted to the Light, appear'd so full of Pores, that it seem'd to have such a kind of Transparency as that of a Sive, or a piece of Cyprus, or a Love-Hood; but the Light that pass'd by these Pores was in its Passages So Temper'd with Shadow, and Modify'd, that the Eye discern'd no more a Golden Colour, but a Greenish Blew. And for other's satisfaction, we did in the Night look upon a Candle through such a Leaf of Gold; and by trying the Effect of Several Proportions of Distance betwixt the Leaf, the Eye and the Light, we quickly hit upon such a Position for the Leaf of Gold, as that the flame, look'd on through it, appear'd of a Greenish Blew, as we have seen in the Day time. The like Experiment try'd with a Leaf of Silver succeeded not well.

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_EXPERIMENT X._

We have sometimes found in the Shops of our Druggists, a certain Wood, which is there called _Lignum Nephriticum_, because the Inhabitants of the Country where it grows, are wont to use the Infusion of it made in fair Water against the Stone of the Kidneys, and indeed an Eminent Physician of our Acquaintance, who has very Particularly enquir'd into that Disease, assures me, that he has found such an Infusion one of the most effectual Remedyes, which he has ever tried against that formidable Disease. The ancientest Account I have met with of this Simple, is given us by the Experienc'd _Monardes_ in these Words. _Nobis,_ says he,[16] _Nova Hispania mittit quoddam ligni genus crassum & enode, cujus usus jam diu receptus fuit in his Regionibus ad Renum vitia & urinæ difficultates ac arenulas pellendas. Fit autem hac ratione, Lignum assulatim & minutim concisum in limpidissima aqua fontana maceratur, inque ea relinquitur, donec aqua à bibentibus absumpta sit, dimidia hora post injectum lignum aqua cæruleum colorem contrabit, qui sensim intenditur pro temporis diuturnitate, tametsi lignum candidum fit_. This Wood, _Pyrophilus_, may afford us an Experiment, which besides the singularity of it, may give no small assistance to an attentive Considerer towards the detection of the Nature of Colours. The Experiment as we made it is this. Take _Lignum Nephriticum_, and with a Knife cut it into thin Slices, put about a handfull of these Slices into two three or four pound of the purest Spring-water, let them infuse there a night, but if you be in hast, a much shorter time may suffice; _decant_ this Impregnated Water into a clear Glass Vial, and if you hold it directly between the Light and your Eye, you shall see it wholly Tincted (excepting the very top of the Liquor, wherein you will some times discern a Sky-colour'd Circle) with an almost Golden Colour, unless your Infusion have been made too Strong of the Wood, for in that case it will against the Light appear somewhat Dark and Reddish, and requires to be diluted by the addition of a convenient quantity of fair Water. But if you hold this Vial from the Light, so that your Eye be plac'd betwixt the Window and the Vial, the Liquor will appear of a deep and lovely Cæruleous Colour, of which also the drops, if any be lying on the outside of the Glass, will seem to be very perfectly; And thus far we have try'd the Experiment, and found it to Succeed even by the Light of Candles of the larger size. If you so hold the Vial over against your Eyes, that it may have a Window on one side of it, and a Dark part of the Room both before it and on the other side, you shall see the Liquor partly of a Blewish and partly of a Golden Colour. If turning your back to the Window, you powr out some of the Liquor towards the Light and towards your Eyes, it will seem at the comming out of the Glass to be perfectly Cæruleous, but when it is fallen down a little way, the drops may seem Particolour'd, according as the Beams of Light do more or less fully Penetrate and Illustrate them. If you take a Bason about half full of Water, and having plac'd it so in the Sun-beams Shining into a Room, that one part of the Water may be freely illustrated by the Beams of Light, and the other part of it Darkned by the shadow of the Brim of the Bason, if then I say you drop of our Tincture, made somewhat strong, both into the Shaded and Illuminated parts of the Water, you may by looking upon it from several places, and by a little Agitation of the water, observe divers pleasing Phænomena which were tedious to particularize. If you powr a little of this Tincture upon a sheet of White Paper, so as the Liquor may remain of some depth upon it, you may perceive the Neighbouring drops to be partly of one Colour, and partly of the other, according to the position of your Eye in reference to the Light when it looks upon them, but if you powr off all the Liquor, the Paper will seem Dy'd of an almost Yellow Colour. And if a sheet of Paper with some of this Liquor in it be plac'd in a window where the Sunbeams may shine freely on it, then if you turn your back to the Sun and take a Pen or some such slender Body, and hold it over-thwart betwixt the Sun and the Liquor, you may perceive that the Shadow projected by the Pen upon the Liquor, will not all of it be a vulgar and Dark, but in part a curiously Colour'd shadow, that edge of it, which is next the Body that makes it, being almost of a lively Golden Colour, and the remoter verge of a Cæruleous one.

[16] _Nicolaus Monardes_ lib _simplic. ex India allatis_, cap. 27.

These and other Phænomena, which I have observ'd in this delightfull Experiment, divers of my friends have look'd upon not without some wonder, and I remember an excellent Oculist finding by accident in a friends Chamber a fine Vial full of this Liquor, which I had given that friend, and having never heard any thing of the Experiment, nor having any Body near him that could tell him what this strange Liquor might be, was a great while apprehensive, as he presently after told me, that some strange new distemper was invading his Eyes. And I confess that the unusualness of the Phænomena made me very sollicitous to find out the Cause of this Experiment, and though I am far from pretending to have found it, yet my enquiries have, I suppose, enabled me to give such hints, as may lead your greater sagacity to the discovery of the Cause of this wonder. And first finding that this Tincture, if it were too copious in the water, Kept the Colours from being so lively, and their Change from being so discernable, and finding also that the Impregnating Virtue of this Wood did by its being frequently Infus'd in New Water by degrees Decay, I Conjectur'd that the Tincture afforded by the Wood must proceed from some Subtiler parts of it drawn forth by the Water, which swimming too and fro in it did so Modifie the Light, as to exhibit such and such Colours; and because these Subtile parts were so easily Soluble even in Cold water, I concluded that they must abound with Salts, and perhaps contain much of the Essential Salt, as the _Chymists_ call it, of the Wood. And to try whether these Subtile parts were Volatile enough to be Distill'd, without the Dissolution of their Texture, I carefully Distill'd some of the Tincted Liquor in very low Vessels, and the gentle heat of a Lamp Furnace; but found all that came over to be as Limpid and Colourless as Rock-water, and the Liquor remaining in the Vessel to be so deeply Cæruleous, that it requir'd to be oppos'd to a very strong Light to appear of any other Colour. I took likewise a Vial with Spirit of Wine, and a little Salt of Harts-horn, and found that there was a certain proportion to be met with betwixt the Liquor and the Salt, which made the Mixture fit to exhibit some little Variety of Colours not Observable in ordinary Liquors, as it was variously directed in reference to the Light and the Eye, but this Change of Colour was very far short from that which we had admir'd in our Tincture. But however, I suspected that the Tinging Particles did abound with such Salts, whose Texture, and the Colour springing from it, would probably be alter'd by peircing Acid Salts, which would in likelihood either make some Dissipation of their Parts, or Associate themselves to the like Bodies, and either way alter the Colour exhibited by them; whereupon Pouring into a small Vial full of Impregnated Water, a very little Spirit of Vinegar, I found that according to my Expectation, the Cæruleous Colour immediately vanish'd, but was deceiv'd in the Expectation I had, that the Golden Colour would do so too; for, which way soever I turned the Vial, either to or from the Light, I found the Liquor to appear always of a Yellowish Colour and no other: Upon this I imagin'd that the Acid Salts of the Vinegar having been able to deprive the Liquor of its Cæruleous Colour, a Sulphureous Salt being of a contrary Nature, would be able to Mortifie the Saline Particles of Vinegar, and Destroy their Effects; And accordingly having plac'd my Self betwixt the Window, and the Vial, and into the Same Liquor dropt a few drops of Oyl of Tartar _per Deliquium_, (as _Chymists_ call it) I observ'd with pleasure, that immediately upon the Diffusion of this Liquor, the Impregnated Water was restor'd to its former Cæruleous Colour; And this Liquor of _Tartar_ being very Ponderous, and falling at first to the Bottom of the Vial, it was easie to observe that for a little while the Lower part of the Liquor appear'd deeply Cæruleous; whilst all the Upper part retain'd its former Yellowness, which it immediately lost as soon as either Agitation or Time had made a competent Diffusion of the Liquor of _Tartar_ through the Body of the former Tincture; and this restored Liquor did, as it was Look'd upon against or from the Light, exhibit the Same _Phænomena_ as the Tincted Water did, before either of the Adventitious Liquors was pour'd into it.

Having made, _Pyrophilus_, divers Tryals upon this Nephritick Wood, we found mention made of it by the Industrious Jesuit _Kircherus_, who having received a Cup Turned of it from the _Mexican_ Procurator of his Society, has probably receiv'd also from him the Information he gives us concerning that _Exotick_ Plant, and therefore partly for that Reason, and partly because what he Writes concerning it, does not perfectly agree with what we have deliver'd, we shall not Scruple to acquaint you in his own Words, with as much of what he writes concerning our Wood, as is requisite to our present purpose. _Hoc loco_ (says he)[17] _neutiquam omittendum duximus quoddam ligni candidi Mexicani genus, quod Indigenæ Coalle & Tlapazatli vocant, quod etsi experientia hucusque non nisi Cæruleo aquam colore tingere docuerit, nos tamen continua experientia invenimus id aquam in omne Colorum genus transformare, quod merito cuipiam Paradoxum videri posset; Ligni frutex grandis, ut aiunt, non rarò in molem arboris excrescit, truncus illius eft crassus, enodis, instar piri arboris, folia ciceris foliis, aut rutæ haud absimilia, flores exigui, oblongi, lutei & spicatim digesti; est frigida & humida planta, licet parum recedat à medio temperamento. Hujus itaque descriptæ arboris lignum in poculum efformatum, aquam eidem infusam primo in aquam intense Cæruleam, colore floris Buglossæ; tingit, & quo diutius in eo steterit, tanto intensiorem colorem acquirit. Hanc igitur aquam si Vitreæ Sphæræ infuderis, lucique exposueris, ne ullum quidem Cærulei coloris vestigium apparebit, sed instar aquæ puræ putæ fontanæ limpidam claramque aspicientibus se præbebit. Porro si hanc phialam vitream versus locum magis umbrosum direxeris, totus humor gratissimum virorem referet; si adhuc umbrosioribus locis, subrubrum, & sic pro rerum objectarum conditione, mirum dictu, colorem mutabit; in tenebris verò vel in vase opaco posita, Cæruleum colorem suum resumet._

[17] Kircher. Art. Mag. lucis & umbræ, _lib. 1. part. 3._

In this passage we may take notice of the following Particulars. And first, he calls it a White _Mexican_ Wood, whereas (not to mention that _Mornardes_ informs us that it is brought out of _Nova Hispania_) the Wood that we have met with in several places, and employ'd as _Lignum Nephriticum_, was not White, but for the most part of a much Darker Colour, not unlike that of the Sadder Colour'd Wood of Juniper. 'Tis true, that _Monardes_ himself also says, that the Wood is White; and it is affirm'd, that the Wood which is of a Sadder Colour is Adulterated by being Imbu'd with the Tincture of a Vegetable, in whose Decoction it is steep'd. But having purposely enquir'd of the Eminentest of our _English_ Druggists, he peremptorily deny'd it. And indeed, having consider'd some of the fairest Round pieces of this Wood that I could meet with in these Parts, I had Opportunity to take notice that in one or two of them it was the External part of the Wood that was White, and the more Inward part that was of the other Colour, the contrary of which would probably have appear'd, if the Wood had been Adulterated after the afore-mention'd manner. And I have at present by me a piece of such Wood, which for about an Inch next the Bark is White, and then as it were abruptly passes to the above-mention'd Colour, and yet this Wood by the Tincture, it afforded us in Water, appears to have its Colour'd part Genuine enough; for as for the White part, it appears upon tryal of both at once, much less enrich'd with the tingent Property.

Next, whereas our Author tells us, that the Infusion of this Wood expos'd in a Vial to the Light, looks like Spring-water, in which he afterwards adds, that there is no Tincture to be seen in it, our Observation and his agree not, for the Liquor, which opposed to the Darker part of a Room exhibits a Sky-colour, did constantly, when held against the Light, appear Yellowish or Reddish, according as its Tincture was more Dilute or Deep; and then, whereas it has been already said, that the Cæruleous Colour was by Acid Salts abolished, this Yellowish one surviv'd without any considerable Alteration, so that unless our Author's Words be taken in a very Limited Sense, we must conclude, that either his Memory mis-inform'd him, or that his White _Nephritick_ Wood, and the Sadder Colour'd one which we employ'd, were not altogether of the same Nature: What he mentions of the Cup made of _Lignum Nephriticum_, we have not had Opportunity to try, not having been able to procure pieces of that Wood great enough, and otherwise fit to be turned into Cups; but as for what he says in the Title of his Experiment, that this Wood tinges the Water with all Sorts of Colours, that is much more than any of those pieces of Nephritick Wood that we have hitherto employ'd, was able to make good; The change of Colours discernable in a Vial full of Water, Impregnated by any of them, as it is directed towards a place more Lightsome or Obscure, being far from affording a Variety answerable to so promising a Title. And as for what he tells us, that in the Dark the Infusion of our Wood will resume a Cæruleous Colour, I wish he had Inform'd us how he Try'd it.

But this brings into my mind, that having sometimes for Curiosity sake, brought a round Vial with a long Neck fill'd with the Tincture of _Lignum Nephriticum_ into the Darken'd Room already often mention'd, and holding it sometimes in, sometimes near the Sun-beams that enter'd at the hole, and sometimes partly in them, and partly out of them, the Glass being held in several postures, and look'd upon from several Neighbouring parts of the Room, disclos'd a much greater Variety of Colours than in ordinary inlightn'd Rooms it is wont to do; exhibiting, besides the usual Colours, a Red in some parts, and a Green in others, besides Intermediate Colours produc'd by the differing Degrees, and odd mixtures of Light and Shade.

By all this You may see, _Pyrophilus_, the reasonableness of what we elsewhere had occasion to mention, when we have divers times told you, that it is usefull to have New Experiments try'd over again, though they were, at first, made by Knowing and Candid Men, such Reiterations of Experiments commonly exhibiting some New Phænomena, detecting some Mistake or hinting some Truth, in reference to them, that was not formerly taken notice of. And some of our friends have been pleas'd to think, that we have made no unusefull addition to this Experiment, by shewing a way, how in a moment our Liquor may be depriv'd of its Blewness, and restor'd to it again by the affusion of a very few drops of Liquors, which have neither of them any Colour at all of their own. And that which deserves some particular wonder, is, that the Cæruleous Tincture of our Wood is subject by the former Method to be Destroy'd or Restor'd, the Yellowish or Reddish Tincture continuing what it was. And that you may see, that Salts are of a considerable use in the striking of Colours, let me add to the many Experiments which may be afforded us to this purpose by the Dyers Trade, this Observation; That as far as we have hitherto try'd, those Liquors in general that are strong of Acid Salts have the Power of Destroying the Blewness of the Infusion of our Wood, and those Liquors indiscriminatly that abound with Sulphureous Salts, (under which I comprehend the Urinous and Volatile Salts of Animal Substances, and the Alcalisate or fixed Salts that are made by Incineration) have the vertue of Restoring it.

_A Corollary of the Tenth Experiment._

That this Experiment, _Pyrophilus_, may be as well Usefull as Delightfull to You, I must mind You, _Pyrophilus_, that in the newly mention'd Observation, I have hinted to You a New and Easie way of Discovering in many Liquors (for I dare not say in all) whether it be an Acid or Sulphureous Salt, that is Predominant; and that such a Discovery is oftentimes of great Difficulty, and may frequently be of great Use, he that is not a Stranger to the various Properties and Effects of Salts, and of how great moment it is to be able to distinguish their Tribes, may readily conceive. But to proceed to the way of trying other Liquors by an Infusion of our Wood, take it briefly thus. Suppose I have a mind to try whether I conjecture aright, when I imagine that Allom, though it be plainly a Mixt Body, does abound rather with Acid than Sulphureous Salt. To satisfie my self herein, I turn my back to the Light, and holding a small Vial full of the Tincture of _Lignum Nephriticum_, which look'd upon in that Position, appears Cæruleous, I drop into it a little of a strong Solution of Allom made in Fair Water, and finding upon the Affusion and shaking of this New liquor, that the Blewness formerly conspicuous in our Tincture does presently vanish, I am thereby incited to suppose, that the Salt Prædominant in Allom belongs to the Family of Sour Salts; but if on the other side I have a mind to examine whether or no I rightly conceive that Salt of Urine, or of Harts-horn is rather of a Saline Sulphureous (if I may so speak) than of an Acid Nature, I drop a little of the Saline Spirit of either into the Nephritick Tincture, and finding that the Cæruleous Colour is rather thereby Deepned than Destroy'd, I collect that the Salts, which constitute these Spirits, are rather Sulphureous than Acid. And to satisfie my self yet farther in this particular, I take a small Vial of fresh Tincture, and placing both it and my self in reference to the Light as formerly, I drop into the Infusion just as much Distill'd Vinegar, or other Acid liquor as will serve to Deprive it of its Blewness (which a few drops, if the Sour Liquor be strong, and the Vial small will suffice to do) then without changing my Posture, I drop and shake into the same Vial a small proportion of Spirit of Hartshorn or Urine, and finding that upon this affusion, the Tincture immediately recovers its Cæruleous Colour, I am thereby confirm'd firm'd in my former Opinion, of the Sulphureous Nature of these Salts. And so, whereas it is much doubted by Some Modern Chymists to what sort of Salt, that which is Prædominant in Quick-lime belongs, we have been perswaded to referr it rather to Lixiviate than Acid Salts, by having observ'd, that though an Evaporated Infusion of it will scarce yield such a Salt, as Ashes and other Alcalizate Bodyes are wont to do, yet if we deprive our Nephritick Tincture of its Blewness by just so much Distill'd Vinegar as is requisite to make that Colour Vanish, the _Lixivium_ of Quick-lime will immediately upon its Affusion recall the Banished Colour; but not so Powerfully as either of the Sulphureous Liquors formerly mention'd. And therefore I allow my self to guess at the _Strength_ of the Liquors examin'd by this Experiment, by the _Quantity_ of them which is sufficient to Destroy or Restore the Cæruleous Colour of our Tincture. But whether concerning Liquors, wherein neither Acid nor Alcalisate Salts are Eminently Prædominant, our Tincture will enable us to conjecture any thing more than that such Salts are not Prædominant in them, I take not upon me to determine here, but leave to further Tryal; For I find not that Spirit of Wine, Spirit of Tartar freed from Acidity, or Chymical Oyl of Turpentine, (although Liquors which must be conceiv'd very Saline, if Chymists have, which is here no place to Dispute, rightly ascrib'd tasts to the Saline Principle of Bodyes,) have any Remarkable Power either to deprive our Tincture of its Cæruleous Colour, or restore it, when upon the Affusion of Spirit of Vinegar it has disappear'd.

_EXPERIMENT XI._