Discoveries and Inventions of the Nineteenth Century
Part 77
It is the statement as to the futility of assigning limits to scientific discovery that has been justified by facts. The preceding edition of this work was not long in the hands of its readers before the solution of the problem of photography in colours was announced from Paris, where, at the close of 1890, the physicist M. Lippmann had succeeded in photographing the solar spectrum in its natural colours, and at the beginning of 1891, he was able to exhibit at the Academy of Science untouched photographs of a stained glass window in three colours, of a dish of oranges and red flowers, and of a gorgeously coloured parrot, all in their natural tints. The method employed had no apparent relation to that of Becquerel, but was of the simplest, and, moreover, one which any reader who has followed the first few pages of our section on the “Causes of Light and Colours” will have little difficulty in completely understanding, if he has devoted a little attention to Fresnel’s interference experiment. M. Lippmann took a photographic plate, coated to a greater depth than usual with a gelatine film containing the sensitive salts of silver, and in the camera this plate was exposed with the glass towards the lens, while at the other side of the film was a metallic reflecting surface, namely, quicksilver. Supposing a ray of red light to enter the glass and traverse the film, it would be reflected from the metallic surface, and would meet the direct ray within the substance of the film, with a difference of length of path that would produce the interferences already described, and so give rise to alternate lines or bands of darkness and brightness. It would, of course, be in the lines of maximum brightness that the silver would be first deposited by the photographic action, and these microscopically fine lines or striæ of silver would give back, from ordinary light, a colour corresponding to the waves of red light that produced them. Similarly with the other colours. Anyone may observe the production of colour from ordinary white light in the iridescent tints of mother-of-pearl, where the effects are due to the varying distances of fine edges of the layers of the substance. If an impression is taken from a piece of mother-of-pearl by solid paraffin, or by white wax, or even by common red sealing-wax, the colours will seem to be adhering to the impression, but the operation may be repeated times without number. It is the distance apart of the lines or striæ that determinates the colour, and this is always some definite multiple of the wave lengths, given on p. 411, for the various colours. M. Lippmann’s products are true colour photographs, and they form a new and elegant experimental demonstration of the doctrine of luminiferous undulations.
The colour effects of nature have also been reproduced by taking photographs of the same scene through coloured glass. Thus a screen of yellow glass will intercept the blue and the red rays, and the sensitive film will be impressed with images of objects containing yellow rays only, and that in proportion to the quantity of these rays that enter into any given tint. Similarly with images taken through red and blue glasses. The positives from these partial images being projected by three optical lanterns on the same space on a screen, and each being coloured by passing through tinted glasses like the original, the superposed images thus combined give a very lively impression of the natural colours in all their gradations.
Among the many processes for reproducing photographs by non-photographic processes, some have been more or less successfully combined with colour printing. Some of these productions are very effective, and are more attractive to many persons than the monochromatic tints of ordinary photographs.
PRINTING PROCESSES.
As it is beyond contradiction that printing is one of those inventions which have most influenced the progress of mankind, so it will be admitted that certain modern processes, by greatly facilitating the operations, and vastly extending the resources, of the art, possess an interest and importance surpassed by few of the subjects we have discussed. In a former article the reader has been made acquainted with the steam printing-press and other applications of machinery by which the impressions of a form of type, or of a pattern, can be rapidly multiplied. Here we have to describe some ingenious methods of preparing the forms or originals for letterpress and other printing, and certain beautiful processes for multiplying drawings, engravings, and pictures.
_STEREOTYPING._
This term is applied to the process of obtaining the impression of a form of movable types, or of a woodcut, on a plate of metal which can be printed from. These plates, after the required number of copies have been printed, can be stored away; and they are ready for use whenever another issue of the work is required. When the pages that are to be stereotyped have been set up in ordinary type, there are several methods by which the stereotype plates may be obtained from them; or rather, there are several materials used to form the matrix or mould in which the metal is cast. When plaster of Paris is used, the form is first slightly oiled, to prevent adhesion of the plaster; a thin mixture of plaster and water is then poured upon the form, which is surrounded by a raised rim, to retain the plaster. The thin plaster is carefully led into all the recesses of the type, and then some thicker material is poured on. The plaster soon sets, and is lifted off the type, and, after drying, is ready to receive the molten metal of which the stereotype plate is formed. This metal is an easily fusible alloy of lead, antimony, and other metals, which takes the form of the mould with great accuracy, and is, when solid, sufficiently hard to print from.
Another plan is to make use of prepared clay, spread upon an iron plate, for the formation of the mould. The face of the type is brushed with benzine, the plate with the clay is laid upon it, and pressure is applied. The whole is then dried in a slow oven, and the clay, when detached from the type, is ready to form the mould. The advantages of the clay process are that the type does not require to be afterwards cleaned from oil, and that the material does not fill up the deeper spaces of the form, so that a thinner stratum of metal suffices to form the stereotype plate.
A third mode of obtaining the mould has been already mentioned in connection with the Walter Printing Press (page 313), in the working of which the _papier maché_ process is ingeniously made to supply the curved stereotype plates for the cylinders. This process is also largely used for other newspaper presses, and sometimes for bookwork, as it forms an invaluable means of expeditiously obtaining a number of stereotype plates from the movable types. This production of a number of similar forms makes it possible to strike off a very large number of copies in a short time, for many presses can be employed simultaneously. For the paper process a number of sheets of tissue-paper are pasted together, and the moist paper is laid upon the form; then the operator, by light strokes of a brush, beats down the paper into the hollows of the type, beginning at the centre of the page, and going towards the margins. A sheet of stout unsized paper, called “plate paper,” constitutes the upper layer; and when the whole has been well beaten down upon the type, pressure is applied by means of a screw acting upon a plate of iron covering the whole. In this condition a gentle heat, produced by steam, is made to completely dry and harden the paper matrix, which is very soon fit to be used for casting the metal. The apparatus for this purpose consists of a hollow iron table, within which steam is made to circulate. On this the form is placed, and the platen is pressed down upon it by means of a screw. In many cases the platen also is heated by steam, to accelerate still further the drying of the matrix, which is effected in about four or five minutes. One paper matrix, by careful use, will serve for the production of a series of casts without receiving any damage from the molten metal, as this is fusible at a low temperature.
The mould for casting flat stereotype plates from the paper matrix is made of iron, and has parallel surfaces, which admit of being so adjusted that the thickness required in the plates may be obtained very nearly. The paper matrix is laid on the horizontal iron bed of the mould; gauge-bars are adjusted, which retain it in its position; and then the second plate is folded down—the distance between that and the paper being determined by the gauge-bars. The cover is secured by clamping-screws, and then the mould is turned upright to receive the metal, which is removed, when solid, after the mould has been turned back into its horizontal position.
However the stereotype plates have been produced, it is necessary accurately to adjust their thickness by planing off some of the material from the back. The edges have also to be cut and trimmed to the exact dimensions required by the press. Various machines have been devised for effecting all these operations with accuracy and dispatch. The plates are afterwards mounted on wooden or metal blocks to bring them to the height of ordinary type.
A fourth method of producing plates for the same purpose as the stereotype plates already described is by _electrotyping_. This method appears to have been introduced as early as 1840, but the first results were not without imperfections. Now, however, this plan is almost universally applied to bookwork and woodcut illustrations. Many of our popular illustrated periodicals have so large a circulation that the wooden blocks would necessarily be spoiled by being used in steam presses long before they had yielded the required number of impressions; and the method has also the great advantage of securing the original engraving from the chance of accidental damage, by which a block is sometimes irretrievably injured. Hence woodcut illustrations are now always printed from electrotype copies of the engraved blocks, whether the work itself be printed from movable type or not. But the electrotype or stereotype process is always resorted to in the case of a work, whether illustrated or not, when it is foreseen that a re-issue will be demanded. These processes are also of great advantage to the practical printer, because when the pages set up in type have received their final corrections, he can take the casts, and then the type may be distributed—that is, returned to the cases ready for the compositors to use for other work.
The electrotype process is almost as simple as those for producing stereotype plates by casting, and its productions excel these by their great durability and extreme exactness of reproduction. We may take it for granted that the reader is familiar with the fact that ordinary letterpress characters and woodcuts are printed from forms, in which the black portions are in _relief_. For woodcuts the artist makes the drawing, in reversed position, on a block of finely-grained boxwood, in which the fibres of the wood are perpendicular to the surface. The engraver hollows out all the parts which in the impression remain white, while all the parts which are to receive the ink and produce the black parts of the impression must be left at the original level. The wooden blocks thus engraved would serve to produce a certain number of impressions, which could be taken off by careful hand-printing without perceptible damage to the block. But the pressure necessary for printing inevitably crushes the projecting parts of the block; and the impressions, after a certain number, lose their sharpness. This is especially the case in machine printing; but not only does the electrotype cast present a surface capable of bearing hard usage much better than those of the hardest wood, but even if the number of impressions required should wear out the metal plate, it can easily be replaced by another cast from the original block.
The mould which serves to give the electrotype cast may be made either of gutta-percha softened by a gentle heat and applied to the wood, or of wax. In either case a powerful pressure is applied, in order to force the yielding substance to take the forms of the engraved block or of the metal type. Wax is now generally preferred; the yellow wax used for this purpose is melted, and poured into a shallow pan; when it has become solid, it is sprinkled over with finely-powdered pure blacklead, which is brushed over the surface, and then the excess is removed by blowing with bellows made for the purpose. Thus prepared, the wax is placed over the type-form or wooden block in a powerful press, sometimes worked by hydraulic power; but more frequently a _toggle_ press is employed, in which the pressure is given by a screw and crank-wheel acting on two _elbow joints_, or _toggles_. For the information of non-mechanical readers it may be stated that a “toggle” consists of two bars jointed together, and placed _nearly_ in a straight line: when a pressure is applied to the joint, tending to bring the rods still more nearly into a straight line, their extremities are thrust apart with a great force, which increases indefinitely as the rectilinear position is approached. In the electrotyper’s press there are two toggles constructed of very broad bars, or rather thick plates, for they have nearly the width of the bed of the press. With this machine a very powerful and regular pressure is applied; and the wax in a few minutes takes a sharp impression, embracing all the most delicate details of the work, and becomes at the same time very hard. The impression, of course, has hollows corresponding to the projections of the wooden block or type-form, and _vice versâ_. The face of the wax mould is now very carefully and completely blackleaded, a soft brush being used in the process. It is then placed in the solution of sulphate of copper, and the blacklead receives a deposit of copper, in the manner explained in a former page (498). In about forty or fifty hours a firm, compact deposit, about as thick as the finger-nail, covers the blackleaded surface, forming a perfect reproduction of even the most minute details of the engraved block or letterpress form.
The next operation has for its object the removal of the thin shell of copper from the wax. This is effected by exposing the mould to a gentle heat by immersing it in hot water, or by placing it on a hollow iron table which is heated by steam. The wax is run off into a proper receptacle for future use, and any portion adhering to the copper is removed by the action of naphtha or of a solution of potash. The thin copper shell is then tinned on the back, and an alloy of lead with some tin and antimony, forming the _backing metal_, is poured on it, to the depth of about one-eighth of an inch. When this has become solid the backing is planed, so that the compound plate may have a certain regular thickness, and that the back surface may be parallel to the face. The edges are cut by a circular saw and trimmed by machine-tools, and the plate is rendered perfectly even, and adjusted with the greatest possible exactness to the required thickness. It is prepared for the press by being screwed down upon a block of wood of a certain thickness, so that the face of the plate may have the same height as common type, the screws passing through the margin or other hollow parts of the face of the cast. No more enduring surface than the copper of these electrotype casts, backed up by the hard alloy, has yet been discovered.
_LITHOGRAPHY._
To Aloysius Senefelder, a musician attached to one of the theatres in Munich, whose portrait appears at the head of this article, is due the invention of the art of lithography. It is said he used to arrange his musical compositions on a kind of slates, formed of flakes of the limestone which is found in the neighbourhood of Munich. One day a memorandum which he had made in this manner happened to fall into a slop-bucket full of greasy water; on withdrawing the piece of stone, he noticed with surprise that the grease had attached itself to the characters, while the rest of the stone remained quite clean. Such an incident might have happened to each one of a thousand men, and its significance might not be perceived; but it suggested great possibilities to Senefelder, who, applying himself for some years with ingenuity and perseverance to experiments with the Munich limestone, became, in the year 1800, the inventor of a new art. Though he was no chemist, and was unskilled in mechanics and in drawing, yet within four years from his first observation he had succeeded in finding the proper materials for his crayons and the appropriate acids for acting on the stone, in contriving a suitable press for taking the impressions, and in producing samples of lithographic work in various styles of art. He endeavoured to keep his processes secret, and having obtained the exclusive right of exercising his invention in his own country, he attempted to carry on all the operations himself. Little by little, however, the general nature of the process became known, and although the details were jealously concealed, ingenious persons in France and elsewhere, by force of experiment, succeeded in re-inventing the art for themselves, and Senefelder never profited by his invention as he should have done.
The first lithographic press in London was established by Mr. Hullmandel in 1810. The value of lithography as a means of multiplying works of art was soon afterwards proved by the publication of a magnificent series of picturesque delineations of the quaint architecture of the old towns of Flanders and Germany, drawn on the stone by Samuel Prout. The late Mr. J. D. Harding largely contributed to the popularity of lithography by the landscapes which he drew on the stone, and thus placed in the hands of every one, prints in which all the freedom and force of the artist’s work were secured. The French designers excel in fine-art lithography, and many beautiful productions of their crayons have been published in every department of pictorial illustration.
The best lithographic stones come from Germany; but for some kinds of work stones from other localities are used, on account of their less cost. Thus, in England, a stone yielded by the white lias formation near Bath has been found to possess the requisite qualities. The stones for lithography are prepared in much the same way as slabs of marble are polished; that is to say, by rubbing one slab against another with sand and water. When the stones have thus been brought to a plane surface, they are finished according to the purpose for which they are intended. If they are intended to receive written characters, they are polished to a very smooth surface by means of pumice-stone. But if they are to take drawings, then a certain uniform grain is given by means of finely-sifted sand, the operation being performed in a similar manner to that in which the stones are dressed, only pressure is not applied to the upper stone. The stones, after being washed and dried, are carefully covered on their prepared surfaces with thin paper, and are sent out for use.
When the stone is employed to reproduce written characters, or drawings imitating those done with a pen, _lithographic ink_ is made use of with an ordinary pen, a ruling-pen, a fine brush, or a pen which the lithographer makes for the occasion out of thin metallic plates. The composition of the ink varies much: the usual ingredients are wax, gum-mastic, gum-lac, soap, and lampblack. This composition forms a solid, which is rubbed down with water to a thick liquid when required for use. The characters have, of course, to be written on the stone in a reversed position, and the lithographer acquires the habit of doing this with neatness and dexterity. He is provided with a looking-glass for viewing his work, in order to see the effect which will be given by the impression, for the looking-glass shows the characters in their usual position, just as the image of ordinary writing seen in it is reversed, showing, in fact, the very appearance the characters present on the stone. For a drawing, a _lithographic crayon_ is used, made of wax, soap, grease, lampblack, and other ingredients. With this the drawing is made on the stone exactly as on paper, save the necessary reversals.
When the design has been placed on the stone, a liquid containing nitric acid and gum is poured over it. This liquid acts on all the parts of the stone not protected by the ink or crayon: they are thus rendered incapable of receiving printing-ink, while the protected parts have the impression more strongly fixed; for when the stone has been well washed with water, and turpentine has afterwards been applied, so that all the matter used in marking the design is dissolved away, the seemingly obliterated characters reappear when—after the stone has been lightly wiped with a damp sponge—the roller charged with printer’s ink is applied. The ink is taken up by the stone only at those places which have not been acted on by the acid. The impression is obtained by laying a sheet of damp paper on the inked stone and applying pressure by means of a roller, under which the stone passes. The stone is moistened with water after each impression before the inking-roller is again applied.
The lithographic stone, like other originals used in printing, is liable to deteriorate when large numbers of impressions are taken from it. This would be a serious drawback in lithography, but for a method of renewing the impression, which renders it unnecessary for the artist to retouch his work. This is the process of _transferring_, which is practised by the aid of a certain kind of paper specially prepared by a coating of paste. On this a proof is taken from the original drawing on the stone, and the still moist sheet is then applied to another stone, with the face downwards, and passed under the press. The effect of the pressure is to cause the adherence of the layer of paste to the stone; and when the paper has been thoroughly wetted at the back, it may be removed, leaving the paste still adhering to the stone, with the impression beneath it. When water is applied, the paste is washed off, while the ink of the impression remains attached to the stone, there reproducing the design drawn on the first stone. The transferred design is treated in exactly the same manner as the original drawing, acid being poured over the stone, &c., and the impressions obtained by the same method of successively sponging, inking, and pressing. The transferred drawing may be made to yield another transfer, and so on indefinitely; but when a large number of impressions from one design are required, it is usual to make at once from the original as many transfers to separate stones as will yield the required number of impressions without deterioration. In this way as many as 70,000 copies have been taken from a single drawing without their showing any marked difference in the character of the impressions.