Discoveries and Inventions of the Nineteenth Century

Part 75

Chapter 753,182 wordsPublic domain

The “wet collodion” process, that has been described on the preceding page, maintained an almost undisputed hold for more than twenty years in the practice of photography in all branches, and it was not until after the publication of the first edition of the present work that a new era in the art was commenced by the introduction of what is known as the _dry plate gelatino-bromide process_, to which the present enormous popularity of photography as a recreative art is due. The difficulties of manipulation, the necessity for extensive experience, and for special and cumbersome appliances were obstacles it at once removed. And not only so, but the whole scope of the art was extended; for work that was before supposed impracticable, even to the most expert professional photographer, became the amusement of the amateur. Here, we may remark in passing, that photography is greatly indebted for this, and many other improvements, to the enthusiasm of the amateur, which has accelerated the development of the art to a remarkable extent. The collodion process itself admitted of being modified as a dry plate method, by coating the film with a preservative solution of tannin, gum, albumen, or other substance, and then drying the plates, of course in a dark place. This plan made it possible to practise out-door photography with ease, and such plates were, at one time, much used for landscape photography, but they have now been almost superseded by the gelatine plates. It was Mr. Bennet, who, in 1874, first introduced the use of sensitive emulsions of gelatine, and the advantages offered by their use, caused them to be soon adopted by landscape and amateur photographers. In 1878, Mr. Bennet showed, that these plates could be made wonderfully rapid in their action, so that portraits, etc., could be taken by them in an unprecedentedly short time. The preparation of the dry gelatine plates was then commenced on a large scale, and these were found so convenient, and reliable in use, that they were adopted by the professional photographers, who had hitherto adhered to the wet collodion and silver bath, from long habit and established associations. The collodion processes are, however, still much used, and are preferred by many to the gelatine plates; indeed, it is admitted, that only by the former can certain desirable qualities of negatives be obtained, which are of great importance in some applications of the art.

There are, it need hardly be said, many modifications of the processes recommended for preparing gelatino-bromide dry plates, and each manufacturer of the various kinds offered for sale has, no doubt, his own special plan and formula. In all, a very fine and carefully selected quality of gelatine is the medium in which the sensitive salts are embedded. An “emulsion” is prepared by adding to warm gelatine solution exactly determined quantities of solutions of certain compounds, of which a bromide (usually bromide of potassium) and silver nitrate are the essential ones, together with a small proportion of iodide of potassium. Minute quantities of iodine, hydrochloric acid, etc., are also often prescribed as additions. The mixture has to be heated, at the boiling temperature, for three quarters of an hour, then cooled, and mixed with more gelatine solution, or, instead of using acid and iodine and boiling, a little ammonia is added. When cold and set, the gelatine is washed with cold water, while squeezed through canvas, or after it has been cut into thin strips. It is then drained, dissolved at a gentle heat, and filtered warm. The clean glass plates are coated over with it, at the temperature of 120° F., and are set aside in a perfectly horizontal position until the gelatine has set, when they are placed for twenty-four hours in a drying cupboard, maintained at 80° F. It will be understood that these operations are conducted in a room where no light enters, except through a frame of ruby-coloured glass, and the plates, when dry, are carefully packed and stored in light-tight boxes. They are marvellously sensitive, and receive the photographic impression in about one-sixtieth (1/60th) of the time required for wet collodion plates. Half a second exposure in the camera may be sufficient to impress the image of a well lighted landscape, even when a very small stop is used, and it is not unusual to employ for extra sensitive plates, a so-called “instantaneous shutter,” when the exposure may be no more than 1/80th to 1/100th of a second, and yet obtain a perfectly strong image. Dry plates are manufactured in vast numbers in many large establishments, and the operations are carried on to a great extent by the aid of machinery, by which the plates are uniformly coated and automatically carried into drying chambers, etc.

If photography were popular before the introduction of the dry gelatino-bromide plates, it has since become a hundred-fold more so. Indeed, the camera is now seen everywhere, and few are the family circles in which at least one amateur practitioner of the art is not to be found; indeed, the technical terms of the art have become “Familiar in their mouths as household words.” The daguerrotype, notwithstanding its cost, had no sooner become a practicable process for taking likenesses, than it began to supersede miniature painting, and how rapidly it rose into general favour may be inferred from the fact that, in 1850, ten years after its introduction, it was estimated that in the United States of America, at least ten thousand persons had made it their profession, and, probably half as many more were occupied in making and selling chemicals, plates, cameras, lenses, mounting cases, and other apparatus connected with its practice. Such being the demand for photographic portraits, at the period when the sitter had, as we have already seen, to remain motionless for two whole minutes in sunlight, we can hardly be surprised at the increased popularity the art has acquired in the last decade, when a picture can be produced with one-hundredth the length of sitting, and at about the same reduction of cost. It may here be mentioned, that Daguerre’s process is still occasionally used for special purposes; it was, for instance, the method selected for obtaining the photographic records in the expedition sent out by the French Government, in 1874, to observe the transit of Venus.

The dry plate processes have given an immense impulse to landscape photography, and travellers have been able to bring back authentic representations of the scenery and inhabitants from every part of the globe. This advantage arises from the fact that having the camera, and its appurtenances, the tourist or traveller is not obliged to carry anything about with him except his plates, and when these have once been exposed in the camera, and stowed away in light-tight boxes, the latent images may be developed months, or even years, afterwards. But glass plates are heavy, and are liable to accidental breakage. Inventive ingenuity has been actively at work for the past few years, to find a means of obviating these remaining inconveniences. The first method adopted was to employ paper instead of glass, as a support for the sensitive gelatine film. The paper, having been cut to the proper size, is placed on a _film-carrier_, which is usually a thin plate of ebonite, by which the paper is kept flat. These carriers take the place of the glass plates in the ordinary dark slide, and after exposure in the usual way, the papers are removed in the dark room and made up into light-tight packages, where, of course, a large number will occupy but a small space, and the weight of them be wholly negligible. Many persons make use of this arrangement, which has the advantages of simplicity and of requiring no special apparatus. But an improvement was soon brought out, which consists in substituting for the carriers and pieces of sensitive paper a continuous roll of the material. For this purpose a special piece of apparatus, called the roll-holder, is made to take the place of the dark slide at the back of the camera. The arrangement will be readily understood from Fig. 311_a_. The figure shows the apparatus in section, but only the disposition of the principal parts, most of the mechanical details being omitted. R R´ are two metallic or wooden rollers, which admit of being readily put in their places and taken out. Upon one of these, R, the full length of the material is previously wound, and the free end is passed over another roller, _r´_, and across the opening at E O, where the exposure is made. There is in front of this a dark slide (not here shown) to be drawn up when everything is ready for uncovering the lens. Immediately behind the paper is a flat plate of ebonite, E, or a smooth black board, the object of which is to keep the material quite flat as it passes over the opening to the roller, _r´_, which guides it to the roll, R´, on which it is wound as required. S S´ are two small rollers always pressed by springs against the rolls to prevent the turns working loose. There is a registering apparatus outside in connection with one of the rollers, _r_, or _r´_, to show when the proper length of material has been wound across the opening for a new exposure; and at the same time a mark is automatically made on the paper to indicate where the negatives are to be separated for development by cutting the paper. Some forms of the apparatus also call the operator’s attention to the sufficient winding of the roll by an audible signal, a stroke on a little bell tells that everything is ready for a new exposure. In some cases the number of exposures already made is registered by figures that appear on the outside. The paper in these processes is used only as a temporary support; for after the negative has been developed in the ordinary way, the sensitive gelatine film is removed from it and made to adhere firmly on a plate of clear glass, from which prints are taken as usual. The operations required for the transferring require considerable dexterity of manipulation, and to both the paper and the glass special preparations have to be applied, before and after the transference of the film. This plan, therefore, of “stripping films” involves so great a number of delicate and somewhat troublesome operations that very many photographers have preferred to encounter the labour and risks of carrying about with them the more easily manageable glass plates. But what if some grainless, transparent substance could replace the paper in these rolls so that the negatives might be ready for printing from when merely developed and fixed? Many trials have been made to find this desideratum. A material sufficiently translucent, even, and of tenacity enough to bear the stretching strain between the rollers has, it is believed, been discovered in a very singular substance previously used for other purposes. The reader is no doubt familiar with it as the substitute for ivory in combs, knife handles, and other small articles. It is called _celluloid_, and is a composition the principal ingredients of which would never be guessed from its appearance—namely gun-cotton and camphor! This material is prepared in a plastic condition that enables it to be shaped into any required form. It can be drawn into threads or rolled out into very thin films. Thin plates of it have been used in photography as a substitute for glass, for the sake of lightness, before its employment as a transparent film in the roll-holders. We have now at length the equipment of the travelling photographer reduced to the utmost conceivable limits of lightness and compactness. Thus the complete apparatus required for taking hundreds of pictures of a good size need not be more than a few pounds in weight, and can easily be carried in the hand. But even quite small negatives can now be very readily printed in a few seconds on paper, with an enlargement of many times the original dimensions. The resources of the photographic art appear indeed to be endless; but a mere statement of even the more interesting of these would lead us beyond our limits, and descriptions of the details of manipulation are out of our province altogether. But a few of the more recent applications and developments of the art scarcely or not at all alluded to in the foregoing pages should receive some attention.

The extraordinary sensitiveness of the gelatine-bromide film which makes it possible to impress on it a photographic image in the merest fraction of a second of time, enables us to take pictures of objects in rapid motion. Express trains at their highest speed have been successfully photographed, and so has almost every moving object in nature. The photographs that have been taken of men, of birds, horses, and other animals in every phase of their most rapid actions, have solved many disputed and perplexing problems as to the nature of their movements, and sometimes the solutions have been of a very unexpected kind. Taking a photographic “shot” at a bird has become almost more than a figure of speech; for there are contrivances by which a bird on the wing may be aimed at with the lens, and hit off on the sensitive plate with a certainty surpassing that of the fowling-piece. There are also photographic repeaters by which six or more successive photographs of the bird, etc., can be taken in a single second. Mr. Muybridge has published a number of such photographs of the horse, and by projection of the different images on a screen from a magic lantern, in rapid succession, he has been able to reproduce the visual appearance of horses trotting, leaping, galloping, etc., on the principle of the zoetrope (page 399). Photography has afforded wonderfully delicate observations in many departments of science, by recording phenomena too rapid for the eye to seize, or too recondite for direct perception. A few examples may be mentioned. First, the advantage of photographing the lines of spectra, such as those described in our article on the spectroscope, will at once suggest themselves, and accordingly this method of recording spectra has been largely used, and in the hands of Mr. Lockyer, Dr. Draper, and others has been successfully applied to the study of the solar and stellar spectra. But more than this, it is the sensitive photographic plate that has enabled us to explore the region of the solar spectrum lying far beyond its visible limits in the red and in the violet rays. The ultra-violet portion of the spectrum is shown photographically to be occupied by multitudes of the thin insensitive spaces—breaks in the continuity of the active rays—which are impressed on the photographic print as black lines, similar in every respect to the lines mapped out in the visible spectrum by Fraunhofer. It is known by these that the ultra-violet spectrum, produced by glass prisms, extends to a distance beyond the last visible rays of nearly double the space occupied by the colour spectrum. The principal lines, or rather the greater groups of lines in the invisible spectrum, are distinguished by the capital letters of the alphabet, in continuation of Fraunhofer’s method, beginning from H and nearly exhausting the letters of the alphabet to designate them. These are photographed _in the dark_; for all the solar beams that are allowed to enter the stereoscope are first passed through blue glass of such a depth that every kind of emanation capable of affecting the human eye is intercepted.

Another extremely interesting example of the application of the art to scientific research is celestial photography. An image of the sun may be impressed on a sensitive plate in an ordinary camera, in an amazingly short space of time, but such image is much too small to show any of the markings on the disc of our luminary, even when the image is magnified, for its diameter is only about ⅒th of an inch for each 12 inches of the focal length of the lens. In order to obtain an image of 4 inches diameter, a lens of 40 feet focal length must therefore be used. The first attempts in solar photography appear to have been made in France, in 1845, and the solar prominences were daguerrotyped in 1851; but it was not until 1860, that Mr. De La Rue succeeded in obtaining some beautiful negatives of the phenomena presented in an eclipse of the sun, and was thus enabled to determine a great astronomical problem, by showing that the red flames, or prominences, really belonged to the sun itself. At the present time, photographs of parts of the sun’s disc are regularly taken at Kew, and other observatories, without the very long and heavy telescopes, which introduced many mechanical difficulties into the operation; for, by means of Foucault’s siderostat, the great lens and the photographic apparatus can be used in one fixed position. The siderostat is an instrument on which a flat mirror, made of glass worked to a perfect plane and silvered externally, is caused by clockwork to follow the motion of the sun, so that the reflected beams can be projected in any required direction unchangeably, and, therefore the image of the sun (or other heavenly bodies) viewed in the mirror, is absolutely stationary. The lens, carried in a short tube, has its axis directed to this image, just as it would be pointed at the luminary itself. In solar photography, the exposure is made through a very narrow slit in an opaque screen, which is caused to move rapidly in front of the image. Very fair photographic images of the sun, of several inches diameter, can, however, be obtained with an ordinary telescope of five feet or so focal length, by substituting a small photographic lens and camera in the eye-piece, and by enlarging the image in printing.

As early as 1840, Dr. Draper succeeded in daguerrotyping the moon, but it was not until 1851, that lunar photographs, obtained by Professor Bond, another American astronomer, were first exhibited in England. Many other distinguished experimenters have since successfully turned their attention to this subject, such as Dancer, of Manchester, Secchi, Crookes, Huggins, Phillips, and De La Rue. The latter, and also Mr. Fry, by photographing the moon, at different periods of her libration, have obtained very beautiful and interesting _stereoscopic_ prints of our satellite, in which she presents to the eye the roundness and solidity of a cannon ball. Mr. Rutherford, in America, had an object glass of 11¼ inches diameter, made expressly with correction for the chemical rays, and with this instrument he has produced some of the finest photographs of the moon that have yet been taken. Reflecting telescopes, which have the advantage of uniting all the rays in one focus, have been used with excellent results, and it is said that some taken with the great reflector at Melbourne, where also the atmospheric conditions are very favourable, are almost perfect.