Part 60

The arrangement of metals and acid which we have described is termed a _voltaic couple_, _element_, or _cell_; and a great controversy has long been carried on among men of science as to the place at which the development of electricity has its origin. Three-quarters of a century ago, the effect was attributed by Volta to the mere contact of the two dissimilar metals. In the experiment we have described this contact, supposing the wires to be of copper, would occur at the junction of the wire and the zinc plate. Now, by joining the copper plate of such a cell to the zinc plate of another cell, the copper of that to the zinc of a third, and so on, it is evident that the number of dissimilar contacts might be indefinitely increased, and the electric power should be proportionately augmented. It is found that this is really the case, but Volta’s explanation has been opposed by another which regards the chemical action in the cells as the real origin of the electric manifestations. This last explanation, supported by many apparently conclusive experiments of Faraday and others, has been generally accepted. Galvanic batteries—as a series of cells joined together in a certain manner are termed—have been constructed, in which there is no contact of dissimilar metals; and no electric _current_ can be obtained from an apparatus in which no chemical action takes place. The contact theory in a modified form has recently been revived by Sir W. Thomson and others. In this it is now maintained that some _separation_ of electricities really does take place by contact of dissimilar _substances_, but that a _current_ can be produced only when this separation is continually renewed by chemical actions. Be the true explanation what it may, the fact is undoubted that by joining cell to cell, we can really obtain vastly more powerful effects. If we take a single cell, such as that represented in Fig. 256, and connect the plates with a long and thin wire, we shall find that the current flowing through each part of the circuit is much weaker than when we connect the plates with a short and thick wire. In other words, the action in the latter case, when the wire is stretched over a magnetic needle, will be more powerful than in the former. By using a long and thin wire the current may be so weakened that it becomes necessary to surround the needle with many coils of the wire to produce a marked deflection. Again, much depends upon the material; thus a copper wire conveys a much more powerful current than a German silver one of the same dimensions. There thus appears to be a certain analogy between the flow of electricity along conductors to that of water through pipes. The longer and narrower are the pipes, the less is the quantity of water forced through them by a given head; and similarly, the resistance to the passage of a current increases with the length and narrowness of the conducting wire. When all other circumstances are the same, the _electrical resistance_ of a conductor varies directly as its length and inversely as its sectional area. Hence the current flowing in the apparatus represented in Fig. 256 would be increased by making the wire thicker, and by making it shorter by bringing Z and C nearer together, and by making the area they expose to the liquid larger; for in the liquid also the current flows as indicated by the arrow, a fact which may be proved by the deflection of a magnetized needle suspended above the vessel. The magnitude of the current depends, then, upon two opposing forces, namely, that which continuously separates the electricities, or drives them apart to re-combine through the circuit, and that which opposes their passage. The former, which is termed the _electromotive force_, originates, according to some, from the mere contact of dissimilar materials, according to others from the chemical action. Now, we may increase the strength of the current in a given arrangement, either by increasing the electromotive force, or by diminishing the resistance. The increase of the strength of the current, produced by merely pouring more acid into the vessel, Fig. 256, is due, according to the chemical theory, to the former cause; according to the contact theory, to the latter. By multiplying the cells we increase the electromotive forces: the current receives, so to speak, an onward shove in each cell, but with each cell we introduce an additional resistance. Hence, it follows, that when the resistance of the circuit outside of the cells is extremely small, the current produced by a single cell is as powerful as that produced by a thousand. But when the external resistance is great, as when long thin wires are used, the united electromotive forces of a number of cells are needed to drive the current through the circuit. The strength of a current, C, is therefore expressible by the following simple formula, in which _r_ stands for the internal resistance, and _e_ for the electromotive force in each cell; _n_ represents the number of cells in the battery, these being supposed exactly similar in every respect; R is the sum of the resistances in the circuit outside of the battery.

_ne_ C = ———————— _nr_ + R

It is easily seen that the smaller R is made, the more nearly does the strength of the current become independent of the number of cells.

But many modifications have been made in the materials and form of the cells, by which greater power and duration of action have been attained. Our space permits a description of only two forms, and these must be described without a discussion of the principles upon which their increased efficiency depends. Daniell’s constant cell is represented in Fig. 259, where D is a battery of ten such cells, A is a cylindrical vessel of copper, C is a tube of porous earthenware, closed at the bottom, and within it is suspended the solid rod of amalgamated zinc, B. The copper vessel and the zinc rod are provided with screws by which wires may be attached. In the copper vessel is placed a saturated solution of sulphate of copper, and some crystals of the same substance are placed on the perforated shelf within the vessel. The porous tube is filled with diluted sulphuric acid. When the battery is in action the zinc is dissolved by the sulphuric acid, and metallic copper is continually deposited upon the internal surface of the copper vessel. Daniell’s battery, in some form or other, is much used for telegraphs and for electrotyping. Grove’s cell is shown in section in Fig. 260. The external vessel is made of a rectangular form in glazed earthenware or glass. It contains a thick plate of amalgamated zinc, A, A, bent upwards, and between the two portions a flat porous cell, C, C, is placed, filled with strong nitric acid, in which is immersed a thin sheet of platinum. The outside vessel is charged with water, mixed with about ⅛th of sulphuric acid. D represents a battery of four such cells, in which the mode of connecting the platinum of one to the zinc of the next may be noticed. The terminal platinum and zinc form the _poles_ of the battery, and to them the wires are attached which convey the current. The substitution of plates of coke for the platinum gives the form of battery known as Bunsen’s, which is also sometimes made with circular cells. Gover’s and Bunsen’s are much more powerful arrangements than Daniell’s, but the latter has the advantage as regards the duration and uniformity of its action.

When the current produced by a battery of a dozen or more such cells is conveyed by a wire, it is observed that this wire becomes sensibly hot, and, if the wire be thin enough, the heat may be sufficiently great to heat the wire to redness. By stretching a piece of platinum wire between two separate rods which convey the current, as represented in Fig. 261, the length of wire through which the current passes may be adjusted so as to give any required amount of light, and the wire may even be heated to the fusing-point of platinum. This property of electricity has some interesting applications, as, for example, in firing mines and other explosive charges, and in some surgical operations. A still more interesting exhibition of heating and luminous effects is observed when the terminals of a battery of many cells are connected with two rods of coke, or gas-retort carbon. When the pointed ends of the rods are brought into contact, the current passes, and the points begin to glow with an intensely bright light, and if they are then separated from each other by an interval of ⅒th of an inch or more, according to the power of the battery, a luminous arc extends between them, emitting so intense a light that the unprotected eye can hardly support it. This luminous arc is called the _voltaic arc_, and it excels all other artificial lights in brilliancy, a fact due to the extremely high temperature to which the carbon particles are heated, the temperature being, perhaps, the highest we can attain. It must not be supposed that in this brilliant light we see electricity: the light is due to the same cause as the light of a candle or gas flame, namely, incandescent particles of solid carbon. These particles are carried from one carbon point to the other, and it is found that the positive pole rapidly loses its substance, which is partly deposited on the negative pole. But in order to obtain a steady light, it is requisite to keep the pieces of carbon at one invariable distance; and therefore the transference of the material from one pole to the other, and the loss by combustion, must be compensated by a slow movement of the carbons towards each other. Several kinds of apparatus are used for this purpose, but they all depend upon the principle of regulating the motions by the action of an electro-magnet, formed by the current itself, which becomes weaker as the carbons are farther apart. The movement is communicated to the apparatus by clockwork. Duboscq’s electric lantern is shown in Fig. 262, with enlarged images of the carbon points projected on a screen. The mechanism of the regulator is contained within the cylindrical box immediately below the lantern. The supports of both carbons are moved; that which bears the positive carbon pole being advanced twice as fast as the other, and thus the light is maintained at the same level, for the positive carbon wears away twice as fast as the other. The light is more brilliant when charcoal is used instead of coke, but then it is necessary to operate in a vacuum, to avoid the combustion of the charcoal. The voltaic arc has recently been applied to illuminate lighthouses, and for other purposes, and will probably soon be more widely employed, for a cheap and convenient mode of producing a uniform current of electricity has recently been discovered and will be presently described.

The current which is maintained by the chemical action taking place in the cells of the battery can also be made to do chemical work outside of the battery. When the poles of the battery are terminated by wires or plates of platinum, and these are plunged into water acidulated with sulphuric acid, bubbles of gas are seen to rise rapidly from each wire, or _electrode_, as it is termed. Fig. 263 shows an arrangement by which these gases may be collected separately, and examined, by simply placing over each electrode an inverted glass tube, filled also with the acidulated water. The gases collect at the tops of the tubes, displacing the water, and it is found that from the wire connected with the zinc end of the battery, or negative electrode, hydrogen gas is given off, while at the positive electrode oxygen gas is liberated, in volume precisely equal to half that of the hydrogen. This being the proportion in which these two substances combine to produce water, it appears that in the passage of the current a certain quantity of water is decomposed; and the quantity thus decomposed is in reality a measure of the current, all the other effects of which are found to be proportional to this. When the electricity in a current is said to be measured, it is simply the power of the current to deflect a magnet, or the quantity of gas it can liberate, or some other such effect, which is in fact measured. The discharge of a Leyden jar through such an apparatus as that represented in Fig. 263 would present no perceptible decomposition of the water; yet such a discharge passed through the arms and body produces, as everybody knows, a painful shock, and is accompanied by a bright spark and a noise, while the simultaneous contact of the fingers with the positive and negative poles of the galvanic battery occasions neither shock nor spark. Thousands of discharges from large jars must be passed through acidulated water to liberate the amount of gas which a battery current of a second’s duration will produce. The electricity of the jar is often spoken about as having a higher _tension_ than that of the battery, but the latter sets an immensely greater quantity of electricity in motion. The idea may be illustrated thus: Suppose we have a small cistern of water placed at a great height, and that this water could fall to the ground in one mass. The fall of the small quantity from a great height would be capable of producing very marked instantaneous effects, such as smashing, as with a blow, any structure upon which it might fall. This would correspond with the small quantity of electricity which passes in the discharge of a Leyden jar. Contrast this with the case in which we allow a very large quantity of water to descend from a very small height—as when the water of a reservoir is flowing down a gently inclined channel. It is plain that a different kind of effect might be produced in this case; the current might be made, for instance, to turn a water-wheel, which the more forcible impact of the small quantity of water in the case first supposed would have broken into pieces.

It is probable that the apparent decomposition of water by the electric current is in reality a secondary effect, and that it is the sulphuric acid which is decomposed. When, instead of acidulated water, we place in the apparatus a solution of sulphate of copper, it is found that metallic copper is deposited on the negative electrode, and sulphuric acid collects at the positive electrode. The metal is deposited in a firm and coherent state, and the useful applications of this deposition of metals are of great interest and importance. For, in a similar manner, gold, silver, lead, zinc, and other metals may be made to form thin uniform layers over any properly prepared surface. The immense advantages which the arts have derived from electro-plating illustrate in a convincing manner the benefits which physical science can confer on society at large.

The process of electro-plating may be practised by the aid of apparatus of very simple character. Fig. 264 shows all that is necessary for obtaining perfect casts in copper of seals, small medals, &c. A A is a section of a common tumbler; B B is a tube, made by rolling some brown paper round a ruler, uniting the edge with sealing-wax, and closing the bottom by a plug of cork, round which the paper may be tied by a string, or in any other convenient manner. The tumbler contains a solution of sulphate of copper, and the tube is filled with water, to which about one-twentieth of its bulk of sulphuric acid has been added. A strip of _amalgamated_ zinc, or a piece of thick amalgamated zinc wire, is placed in the tube, and a piece of copper bell-wire is twisted round the top of it, and has attached to its other extremity, and immersed in the copper solution, the article which is to be covered with copper. We may suppose that this is to be a cast in white wax or in plaster of one side of a medal. The cast is carefully covered with black lead by means of a soft brush, and the copper wire is inserted in such a manner as to be in contact with the black lead at some part. When the apparatus has been left for some hours in the position represented, a deposit of copper will be found over the blackleaded surface, and it will be a perfect impression of the wax cast.

Such a copper cast, or any article in copper having a perfectly clean surface, can be readily covered by a film of silver by means of a similar arrangement, where a solution of cyanide of potassium, in which some chloride of silver has been dissolved, is made to take the place of the sulphate of copper. Electro-plating with the precious metals has become a commercial industry of great importance; and this process has completely superseded the old plan of covering the metallic article to be plated with an amalgam of silver or of gold, and then exposing it to heat, which volatized the mercury, leaving a thin film of gold or of silver adhering to the baser metal. On the large scale a battery of several cells is used for electro-plating, and the articles are immersed in the metallic solutions as the negative poles of the battery; any required thickness of deposit being given according to the length of the time they remain. At the works of Messrs. Elkington, of Birmingham, these operations are conducted on a grand scale. The liquid there employed for silvering is a solution of cyanide of silver in cyanide of potassium, and the positive pole is formed of a plate of silver, which dissolves in proportion as the metal is deposited on the negative pole. As the charging of batteries is a troublesome operation, and their action is liable to variations which affect the strength of the currents, the more uniform, more convenient, and more economical mode of producing currents by magneto-electricity, which will presently be described, has been to a great extent substituted for the voltaic battery.

The wire conveying a current not only affects a magnetic needle in the manner already described, but itself possesses magnetic properties, of which, indeed, its action on the needle is the result and the indication. If such a wire be plunged into iron filings, it will be found that the filings are attracted by it: they cling in a layer of uniform thickness round its whole circumference and along its whole length, and the moment the connection with the battery is broken they drop off. This experiment shows that every part of the wire conveying a current is magnetic, and it may be proved that the action is not intercepted by the interposition of any non-magnetic material. Thus the action of the wire upon the magnetic needle takes place equally well through glass, copper, lead, or wood. Consequently, if we cover the wire with a layer of gutta-percha, or over-spin it with silk or cotton, we shall obtain like results on our filings, and if we coil the covered wire round a bar of iron, while the non-conducting covering of the wire will compel the current to circulate through all the turns of the coil, it will not interfere with the magnetic action on each particle of the bar. Whenever this is done it is found that the iron is converted into a powerful magnet so long as the current passes. Fig. 265 represents in a striking manner the result when the current is made to circulate through numerous convolutions of the wire; and as each turn adds its effect to that of the rest, magnets of enormous strength may be formed by sufficiently increasing the number of the turns. The end of the iron bar is shown projecting from the axis of the coil, and below it is placed a shallow wooden bowl, containing a number of small iron nails. The instant the battery connection is completed these nails leap up to the magnetic pole, and group themselves round it in the manner shown in the cut; and again, when the current is interrupted, the iron reverts to its ordinary condition, the magnetism vanishes, and the nails drop down in an instant. These effects may be produced again and again, as often as the current flows and is broken. A magnet so produced is called an _electro-magnet_, to distinguish it from the ordinary permanent steel magnets. By coiling the conducting wire round a bar of iron which has been bent into the form of a horse-shoe, very powerful magnets may be produced, and enormous weights may be supported by the force of the magnetic attraction so evoked. Fig. 266 represents the apparatus for experiments of this kind, in which weights exceeding a ton can be sustained.

Here, then, we have a striking instance of the subtile agent electricity, evoked by the contact of a few pieces of zinc with dilute acid, showing itself capable of exerting an enormous mechanical force. Engines have been constructed in which this force is turned to account to produce rotatory motion as a source of power. Such engines have certain advantages for special purposes; but the money cost for expenditure of material for power so obtained is, at least, sixty times greater than in the case of the steam engine. It is, however, in producing mechanical effects at a distance that the electric current finds the most interesting practical application of its magnetic properties. These are the actions which are so extensively utilized in the construction of telegraphic instruments, of clocks regulated by electric communication with a standard time-keeper, and of many ingenious self-registering instruments. The telegraph will be described in the next article, and we shall also have occasion in subsequent articles to describe some of the other applications of electro-magnetic and electro-chemical force.

_INDUCED CURRENTS._

These very remarkable phenomena were discovered by the illustrious Faraday, in 1830, and this discovery, and that of magneto-electricity, may be ranked among the most memorable of his many brilliant contributions to electric science. Let two wires be stretched parallel and very near to each other, but not in contact. Let the extremities of one wire, which we shall term A, be connected with a galvanometer (page 415), so that the existence of any current through the wire may be instantly indicated. Let the two extremities of the other wire, B, be put into connection with the poles of a battery. The moment the connection is complete, and the battery current _begins_ to rush through B, a deflection of the galvanometer needle will be observed, indicating a current of very short duration through A in the opposite direction to the battery current through B. This induced current, which is called the _secondary_ current, does not continue to flow through A: it occurs merely at the time the _primary_ or battery current is established; and though the latter continues to flow through the wire, B, no further effect is produced in the other wire. When, however, the battery connection is broken, and the primary current ceases to flow, at that instant there is set up in the wire, A, another momentary secondary current, but this one is in the _same_ direction as the battery current. This is termed the _direct secondary_ current, in opposition to the former, which is called the _inverse_ current.