Part 53

This fact remained without explanation from 1814 to 1859, when Kirchhoff accidentally found, to his surprise, that the dark D line could be produced artificially. He says: “In order to test in the most direct manner possible the frequently asserted fact of the coincidence of the sodium lines with the D lines, I obtained a tolerably bright solar spectrum, and brought a flame coloured by sodium vapour in front of the slit. I then saw the dark lines D, change into bright ones. The flame of a Bunsen’s lamp threw the bright sodium lines upon the solar spectrum with unexpected brilliancy. In order to find out the extent to which the intensity of the solar spectrum could be increased without impairing the distinctness of the sodium lines, I allowed the full sunlight to shine through the sodium flame, and, to my astonishment, I saw that the _dark lines_, D, _appeared with an extraordinary_ degree of clearness. I then exchanged the sunlight for the Drummond’s or oxy-hydrogen lime-light, which, like that of all incandescent solid or liquid bodies, gives a spectrum containing no dark lines. When this light was allowed to fall through a suitable flame, coloured by common salt, _dark_ lines were seen in the spectrum in the position of the sodium lines. The same phenomenon was observed if, instead of the incandescent lime, a platinum wire was used, which, being heated in the flame, was brought to a temperature near its melting point, by passing an electric current through it. The phenomenon in question is easily explained, upon the supposition that the sodium flame absorbs rays of the same degree of refrangibility as those it emits, whilst it is perfectly transparent for all other rays.” (Quoted in Roscoe’s Lectures on “Spectrum Analysis.”) When the light of ignited lime was similarly made to pass through flames containing the incandescent vapours of potassium, barium, strontium, &c., the bright lines which these substances would have produced had the lime-light not been present were found to be in every case changed into dark lines, occupying the very same positions in the spectrum. In such experiments the flames containing the metals in the vapourized state do all the time really give off those rays which are peculiar to each substance; but when a more intense illumination—such as the lime-light, the electric arc, or direct sunlight—passes through them, the rays of the spectrum produced by the intense light overpower those given off by the relatively feebly coloured flames, and hence the portions of the spectrum which are occupied by these, appear black. But as the intense light would give a perfectly continuous spectrum if the incandescent metallic vapour allowed the rays corresponding to its lines to pass through it, the inference is obvious that each vapour absorbs those particular rays which it has itself the power of emitting, but allows all others to pass freely through it. Besides the experimental proofs of this fact which have been already adduced, many others might be named. The flame of a spirit-lamp with a salted wick appears opaque and smoky when we look through it at a large flame of burning hydrogen, also coloured by sodium; for the rays emitted by the latter do not penetrate the former, which, in consequence of its feebler light, appears dark by comparison. Again, if an exhausted tube containing metallic sodium be heated so as to convert the sodium into vapour, the tube viewed by the light of a sodium flame appear to contain a black smoke, and the light from the flame will no more pass through it than through a solid object; yet the tube appears perfectly transparent when viewed by ordinary light, and the light from a lithium or other coloured flame would also pass freely. Kirchhoff was led by purely theoretical reasoning to conclude that all luminous bodies have precisely the same power of absorbing certain rays of light as they have of emitting them at the same temperature, and he thus brought luminous rays under the same general law which had previously been established for radiant heat by Prevost, Dessains, Balfour Stewart, and others. Here, then, a law was arrived at, and, abundantly confirmed by direct experiment as regards the more volatile metals, it was ready to supply the most satisfactory explanation of the coincidences which were everywhere discovered to exist between the Fraunhofer lines and those which belong to terrestrial substances. For Kirchhoff also found, when mapping the very numerous lines seen in the spark spectrum of iron, that for each of the 90 bright lines of iron which he then observed, there was a dark line in the solar spectrum exactly corresponding in position. The number of observed bright lines in the iron spectrum has been since extended to 460, and yet each is found to have its exact counterpart in a solar dark line.

So many coincidences as these made it certain that these dark lines and the bright lines of iron must have a common cause, for the chances against the supposition that the agreement was merely accidental are enormous. Kirchhoff actually calculated, by the theory of probabilities, the odds against the supposition. He found it represented by 1,000,000,000,000,000,000 to 1. The result arrived at in the case of sodium at once suggested the explanation that these lines were produced by an absorptive effect of the vapour of iron. Now, the existence of such a vapour in our atmosphere could not be admitted, while the temperature of the sun was known to be exceedingly high, far higher, indeed, than any temperature we can produce by electricity, or any other means. Hence, Kirchhoff concluded that his observations proved the presence of the vapour of iron in the sun’s atmosphere with as much certainty as if the iron had been actually submitted to chemical tests. By the same reasoning, Kirchhoff also demonstrated the existence in the solar atmosphere of calcium, chromium, magnesium, nickel, barium, copper, and zinc. To these, other observers have added strontium, cadmium, cobalt, manganese, lead, potassium, aluminium, titanium, uranium, and hydrogen. It has also been demonstrated that a considerable number of the Fraunhofer lines are due to absorption in our atmosphere by its gases and aqueous vapour. This demonstration of the existence of iron and nickel in the sun is an interesting pendent to the known composition of many meteorites which reach us from interplanetary space.

Kirchhoff was led to believe that the central part of the sun is formed of an incandescent solid or liquid, giving out rays of all refrangibility, just as white-hot carbon does; that round this there is an immense atmosphere, in which sodium, iron, aluminium, &c., exist in the state of gas, where they have the power of absorbing certain rays; that the solar atmosphere extends far beyond the sun, and forms the corona; and that the dark sunspots, which astronomers have supposed to be cavities, are a kind of cloud, floating in the vaporous atmosphere.

During total eclipses of the sun, certain red-coloured prominences have been noticed projecting from the sun’s limb, and visible only when the glare of its disc is entirely intercepted by the moon. Fig. 228 represents a total eclipse, and will give a rude notion of the appearance of the red prominences seen against the fainter light of the _corona_, which extends to a considerable distance beyond the sun’s disc. Now, two distinguished men of science simultaneously and independently made the discovery of a mode of seeing these red prominences, even when the sun was unobscured. M. Janssen was observing a total eclipse of the sun in India, and the examination by the spectroscope of the light emitted from the red prominences showed him that they were due to immense columns of incandescent hydrogen, for he recognised the red line and blue lines which belong to the spectrum of this gas (see No. 12, Plate XVII.). Mr. Norman Lockyer at the same time also succeeded in viewing the solar prominences in London without an eclipse. He found a red line perfectly coinciding in position with Fraunhofer’s C line and that of hydrogen, another nearly coinciding with F, and a third yellow line near D. Soon after this, Dr. Huggins discovered a mode of observing the shape of the red prominences at any time, by using a powerful train of prisms and a wide slit, so that the changes in the forms of the red flames can be followed. Now, since the red prominences give off only a few rays of particular refrangibility, it is not difficult to understand that the light of the sun might be, as it were, so diluted by stretching out the spectrum, by means of a train of many prisms, that almost only the red rays, C, should enter the telescope, and occupy the field with sufficient intensity to overpower all others, and produce an image of the object from which they originated. The nature of this action may be illustrated thus: If we hold vertically a prism, and look through it at a candle-flame, we may perceive a lengthened-out image of the flame, showing the succession of prismatic colours, and formed, as it were, of a red image of the flame close to a yellow one, and so on, but presenting no defined form. If, still viewing this spectrum, we introduce into the flame on a platinum wire a piece of common salt, we shall perceive a well-defined yellow image of the candle start out, because the rays which are emitted by the incandescent sodium, being all of one refrangibility, the prism simply refracts without dispersing them. The dispersion which weakens the light of the continuous spectrum by lengthening it out, does not sensibly detract from the brilliancy of the bright lines, as their breadth is scarcely increased—they are refracted but not dispersed. Hence, when a sufficient number of prisms is employed, the bright lines of the solar _chromosphere_ may be seen in full sunshine, in spite of the greater intensity of the light emanating from the _photosphere_, which produces the continuous spectrum. The bright C line is, of course, a virtual image of the slit produced by rays of that particular refrangibility; but by using a very high dispersive power, the slit may be opened so wide that the C rays form in the telescope a red image of the prominence from which they issue, since their light will predominate over that of any rays belonging to the continuous spectrum.

In the hands of Mr. Norman Lockyer the science of the physical and chemical constitution of the sun has made rapid progress, and new facts are continually being observed, which serve to furnish more and more definite views. Mr. Lockyer considers that, extending to a great distance around the sun is an atmosphere of comparatively cooler hydrogen, or perhaps of some still lighter substance which is unknown to us. It is this which forms what is termed the _corona_, or circle of light which is seen surrounding the sun in a total eclipse. Immersed in this, and extending to a much smaller distance from the nucleus of the sun, is another envelope, termed the _chromosphere_, consisting of incandescent hydrogen and some glowing vapours of magnesium and calcium. The brightest part of this envelope, which lies nearest the sun, is that which gives off the red rays by which the prominences may be observed without an eclipse. These prominences have been shown to be tremendous outbursts of glowing hydrogen, belched up with sometimes an enormous velocity from below, since they have been observed to spring up 90,000 miles in a few minutes. Beneath the chromosphere, and nearer to the body of the sun, are enormous quantities of the vapours of the different elements—sodium, iron, &c.—to which the dark lines of the solar spectrum are due. This stratum Mr. Lockyer calls the _reversing layer_, because it reverses (turns to dark) the lines which would otherwise have appeared bright, just as Kirchhoff’s sodium vapour did in the experiment described on page 437. Beneath the reversing layer is the _photosphere_, from which emanates the light that is absorbed in part by the reversing layer, and which there is good reason to believe is either intensely heated solid or liquid matter.

In 1861 Dr. Huggins devoted himself, with an ardour which has since known no remission, to the extension of prismatic analysis to the other heavenly bodies. The difficulties of the investigations were great. There was first the small quantity of light which a star sends to the spectator; this was obviated by the use of a telescope of large aperture, which admitted and brought to a focus many more rays from the star, and therefore the brightness of the image was proportionately increased. Not so the size of the image: the case of the fixed stars for this always remains a mere point. It was, of course, necessary to drive the telescope by clockwork, so that the light of the star might be stationary on the field of the spectroscope. As the spectrum of the image of the star formed by the object-glass would be a mere line, without sufficient breadth for an observation of the dark or light lines by which it might be crossed, it is necessary to spread out the image so that the whole of the light may be drawn out into a very narrow line, having a length no greater than will produce a spectrum broad enough for the eye to distinguish the lines in it. This is accomplished by means of a cylindrical lens placed in the focus of the object-glass, and immediately in front of the slit. Covering one-half of the slit is a right-angled prism by which the light to be compared with that of the star is reflected into the slit. The light is usually that produced by taking electric sparks between wires of the metal in the manner already described. The dispersive power of the spectroscope was furnished by two prisms of very dense glass, and the spectrum was viewed through a telescope of short focal length. Dr. Huggins’s observations lead him to the conclusion that the planets Mars, Jupiter, and Saturn possess atmospheres, as does also the beautiful ring by which Saturn is surrounded; for he noticed in the spectrum of each different dark lines not belonging to the solar spectrum.

Passing to the results obtained in the case of the fixed stars, we may remind the reader of the enormous distance of the bodies which are submitted to the new method of analysis. Sir John Herschel gives the following illustration of the remoteness of Sirius—supposed to be one of the nearest of the fixed stars: Take a globe, 2 ft. in diameter, to represent the sun, and at a distance of 215 ft. place a pea, to give the proportionate size and distance of the earth. If you wish to represent the distance of Sirius _on the same scale_, you must suppose something placed _forty thousand miles_ away from the little models of sun and earth. But not only do we know with certainty some of the substances contained in Sirius, but the star spectroscope has taught us a great deal about orbs so remote, that their distance is absolutely unmeasurable. About Aldebaran we know that there are hydrogen gas and vapours of magnesium, iron, calcium, sodium, and some four or five other elements. Generally the lines indicate the presence of hydrogen in these distant suns; but there is, at least, one remarkable exception in α _Orionis_, the spectrum of which yields no trace of the hydrogen lines, although it is evident that magnesium, sodium, calcium, &c., are present. The spectra of celestial bodies are of several kinds. Many of the stars have, like our sun, a continuous spectrum crossed by dark lines. Such is that of Sirius, No. 10, Plate XVII. Others have, however, both dark and bright lines, and some are marked by only three bright spaces. Of the spectra of the nebulæ some have three bright lines (see No. 11, Plate XVII.), and the bodies producing them are, therefore, to be considered as masses of incandescent gas, while some give continuous spectra. One of the bright lines in the spectra of the nebulæ coincides with one of the hydrogen lines, and another—the brightest of the three—with one of the brightest nitrogen lines; but the third does not agree with any with which it has as yet been compared. The inference from these appearances is that the nebulæ contain hydrogen and nitrogen, but the absence of the other lines of these substances has not been fully explained; although the observation of Dr. Huggins, that when the light of incandescent nitrogen and hydrogen is gradually obscured by interposing layers of neutral tinted glass, the lines corresponding with those in the nebular spectra are the last to disappear, seems to suggest a probable solution of the difficulty.

There is another very interesting line of spectroscopic research in the power the prism gives us of estimating the velocity with which the distances of the stars from our system are increasing or diminishing. On closely examining the hydrogen lines of Sirius, and comparing them with the bright lines of hydrogen rendered incandescent by electric discharges in a Geissler tube, the spectrum of which his instrument enabled him to place side by side with that of the star, Mr. Huggins was surprised to find that the lines in the latter did not exactly coincide in position with those of the former, but appeared slightly nearer the red end of the spectrum. This indicated a longer wave-length, or increased period of vibration, according to the theory of light, which would be accounted for by a receding motion between Sirius and the earth, just as the crest of successive waves of the sea would overtake a boat going in the same direction at longer intervals of time than those at which they would pass a fixed point, while, if the boat were meeting the waves, these intervals would, on the other hand, be shorter. Hence if the position of the lines in the spectrum depends on the periods of vibration, that position will be shifted towards the red end when the luminous body is receding from the earth with a velocity comparable to that of light, and towards the violet end when the motion is one of approach. The change in refrangibility observed by Mr. Huggins corresponded with a receding velocity of 41·4 miles per second, and when from this was subtracted the known speed with which the earth’s motion round the sun was carrying us from the star at the time, the remainder expressed a motion of recession amounting to about twenty miles a second, which motion, there is reason to believe, is chiefly due to a proper movement of Sirius. These deductions from prismatic observations are of the highest value astronomically, since they will eventually enable the real motions of the stars to be determined, for ordinary observation could only show us that component of the motion which is at right angles to the visual ray, while this gives the component along the visual ray. In the same manner, it is inferred that Arcturus, a bright star in the constellation _Boötes_, is approaching us with a velocity of fifty-five miles per second.

When the solar spots are examined with the spectroscope, the dark image of the slit produced by the hydrogen line, F, is observed to show a strange crookedness when it is formed by rays from different parts of the spot. This distortion is due to the same cause as the displacement of the stellar lines, namely, motions of approach or recession of the masses of glowing hydrogen. Mr. Norman Lockyer, to whom we are indebted for the most elaborate investigations of the solar surface, has calculated, from the position of the lines, the velocities with which masses of heated hydrogen are seen bursting upwards, and those which belong to the down-rushes of cooler gas. Velocities as great as 100 miles per second were, in this way, inferred to occur in some of the storms which agitate the solar surface. Two drawings of a solar storm, given by Mr. Lockyer, are shown in Figs. 230 and 231. These are representations of one of the so-called red prominences, the first giving its appearance at five minutes past eleven on the morning of March 14th, 1869, and the last showing the same _ten minutes afterwards_. The enormous velocity which these rapid changes imply will be understood when it is stated that this prominence was 27,000 miles high. “This will give you some idea,” says Mr. Lockyer, “of the indications which the spectroscope reveals to us, of the enormous forces at work in the sun, merely as representing the stars, for everything we have to say about the sun the prism tells us—and it was the first to tell us—we must assume to be said about the stars. I have little doubt that, as time rolls on, the spectroscope will become, in fact, almost the pocket companion of every one amongst us; and it is utterly impossible to foresee what depths of space will not in time be gauged and completely investigated by this new method of research.”

The light of comets has also been examined by the spectroscope, and many interesting results arrived at. Our limits do not, however, permit us to enter into a discussion of these interesting subjects.

Fig. 232 is a section of another of Mr. Browning’s popular instruments, which is named by him the “Amateur’s Star Spectroscope.” It exhibits very distinctly the different spectra of the various stars, nebulæ, comets, &c.

The reader who is desirous of learning more of this fascinating subject is referred to Dr. Roscoe’s elegant volume, entitled, “Lectures on Spectrum Analysis.” This work, which is embellished with handsome engravings and illustrated by coloured maps and spectra, gives a clear and full account of every department of the subject, and in the form of appendices, abstracts of the more important original papers are supplied, while a complete list is given of all the memoirs and publications relating to the spectroscope which have been published.