Part 4

This seems to indicate that the most essential difference between combustible matters and those which are not so, consists in the latter containing only a few or none of the light, ethereal, and oily matters susceptible of an expansive motion, or, at least, if they contain them, that they are fixed, so that they cannot exercise their volatility whenever the force of the fire is not strong enough to surmount the force of adhesion which retains them united to the fixed parts of matter. It may be said that this induction is confirmed by a number of observations well known to chemists; but what appears to be less so, and which, nevertheless, is a necessary consequence of it, is, that all matter may become volatile when the expansive force of the fire can be rendered superior to the attractive force which holds the parts of matter united; for though to produce a fire sufficiently strong it may require better constructed mirrors than any at present known, yet we are certain that fixity is only a relative quality, and that there is no matter absolutely so, since heat dilates the most fixed bodies. Now is not this dilation the index of a beginning separation, that may be augmented with a degree of heat to fusion, and with a still greater heat to volatilisation?

Combustion supposes something more than volatilisation; it is not sufficient that the parts of matter be sufficiently separated to be carried off by those of heat; they must also be of an analogous nature to fire; without that, mercury, being the most fluid next to air, would also be the most combustible, whereas experience demonstrates, that though very volatile it is not combustible. Matter is, in general, composed of four principal substances, called _elements_, that is, earth, water, air, and fire. Those in which earth and water predominate will be fixed, and will only become volatile by the action of heat; and those which contain most air and fire will be the only real combustibles. The great difficulty here is clearly to conceive how air and fire, both so volatile, can fix and become constituent parts of all bodies.

Fire, by absorbing air, destroys the spring. Now there are but two methods of destroying a spring, either by compressing it till it breaks, or extending it till it loses its effect. It is plain that fire cannot destroy air by compression, since the least degree of heat rarefies it; on the contrary, by a very strong heat the rarefaction of the air will be so great that it will occupy a space thirteen times more extended than that of its general volume; and by this means the spring becomes weakened, and it is in this state that it can become fixed, and unite with other bodies.

Light, which falls on bodies, is not merely reflected, but remains in quantities on the small thickness of the surface which it strikes; consequently it loses its motion, extends, is fixed, and becomes a constituent part of all that it penetrates. Let us add this light, transformed and fixed in bodies, to the above air, and to both, the constant and actual heat of the terrestrial globe, whose sum is much greater than that which comes from the sun, and then it will appear to be not only one of the greatest springs of the mechanism of Nature, but an element with which the whole matter of the globe is penetrated.

If we consider more particularly the nature of combustible matters, we shall find, that they all proceed originally from vegetables and animals; in a word, from bodies placed on the surface of the globe, which the sun enlightens, heats, and vivifies. Wood, bitumen, resins, coals, fat and oil, by expression, wax, and suet, are substances proceeding immediately from animals and vegetables. Turf, fossil, coal, amber, liquid, or concrete bitumens, are the productions of their mixture, and their decomposition, whose ulterior waste forms sulphurs, and the combustible parts of iron, tin, pyrites, and every inflammable mineral. I know, that this last assertion will be rejected by those who have studied nature only by the mode of chemistry; but I must request them to consider, that their method is not that of nature, and that it cannot even approach it without banishing all those precarious principles, those fictitious beings which they play upon, without being acquainted with them.

But, without pressing longer on those general considerations, let us pursue in a more direct and particular manner the examination of fire and its effects. The action of fire depends much on the manner in which it is applied; and the effects of its motion, on similar substances, will appear different according to the mode in which it is administered. I conceive that fire should be considered in three different states, first relative to its velocity; secondly, as to its volume; and thirdly, as to its mass. Under each of these points of view, this element, so simple, and so uniform to all appearance, will appear extremely different. The velocity of fire is augmented without the apparent volume being increased, every time that in a given space and filled with combustible matters, its action and expansion is pressed by augmenting the velocity of the air by bellows, caverns, ventilators, aspirative tubes, &c. all of which accelerate more or less the rapidity of the air directed on the fire. The action of fire is augmented by its volume, when a great quantity of combustible matters is accumulated, and the heat and fire are driven into the reverberatory furnaces, which comprehend those of our glass, porcelain, and pottery manufactories, and all those wherein metals and minerals are melted, iron excepted. Fire acts here by its volume, and has only its own velocity, since the rapidity is not augmented by the bellows, or other instruments which carry air to the fire.

There are many modes of augmenting the action of fire by its velocity or volume; but there is only one way of augmenting its mass; namely, by uniting it in the focus of a burning glass. When we receive on the refracting, or reflecting mirror, the rays of the sun, or even those of a well-kindled fire, we unite them in so much the less space, as the mirror is longer, and the focus shorter; for example, by a mirror of four feet diameter, and one inch focus, it is clear, that the quantity of light, or fire, which falls on the four-feet mirror, will be united in the space of one inch, that is, it will be 2304 times denser than it was, if all the incident matter arrived to this focus without any loss, and when even the loss is two thirds or three fourths, the mass of fire concentrated in the focus of this mirror, will always be six or seven hundred times denser than on the surface. In this, as in all other cases, the mass goes by the contraction of the volume; and the fire which we thus augment the density of, has all the properties of a mass of matter; for, independently of the action of heat, by which it penetrates bodies, it impels and displaces them as a solid moving body which strikes another would do.

Each of these modes of administering fire, and increasing either the velocity, volume, or mass, often produce very different effects on the same substances; insomuch, that no reliance is to be placed on any thing that cannot be worked at the same time, or successively, by all three. In the like manner, as I divide into three general proceedings the administration of this element, I divide every matter that can be submitted to its action into three classes. Passing over for the present those which are purely combustible, and which immediately proceed from animals and vegetables; we proceed to minerals, in the first class of which we reckon those mineral matters, which this action, continued for a long time, renders lighter, as iron; in the second, such as it renders heavier, as lead; and in the third class, are those matters on which, as gold, this action of fire does not appear to produce any sensible effect, since it does not at all alter their weight. All existing matters, that is, all substances simple and compounded, will necessarily be comprized under one of these three classes; and experiments on them by the three proceedings, which are not difficult to be made, and only require exactness and time, might develope many useful discoveries, and prove very necessary to build on real principles the theory of chemistry, which has hitherto been carried on by a precarious nomenclatura, and on words the more vague as they are the more general.

Fire is the lightest of all bodies, notwithstanding which it has weight, and it may be demonstrated, that even in a small volume it is really heavy, as it obeys, like all other matters, the general law of gravity, and consequently must have connections or affinities with other bodies. All matters it renders more weighty will be those with which it has the greatest affinity. One of the effects of this affinity in the matters is to retain the substance even of fire, with which it is incorporated, and this incorporation supposes that fire not only loses its heat and elasticity, but even all its motion, since it fixes itself in these bodies, and becomes a constituent part. From which it may be imagined that there is fire under a fixed and concrete form in almost every body.

It is evident, that all matters, whose weight increases by the action of fire, are endowed with an attractive force superior to the expansive, the fiery particles of which are animated; this being extinguished the motion ceases, and the elastic and fugitive particles become fixed, and take a concrete form. Thus matters, whose weight is increased by fire, as tin, lead, &c. are substances which, by their affinity with fire, attract and incorporate. All matters, on the contrary, which, like iron, copper, &c. become lighter in proportion as they are calcined, are substances whose attractive forces, relative to the igneous particles, is less than the expansive force of fire; and hence the fire, instead of fixing in these matters, carries off and drives away the least adherent parts which cannot resist its impulsion. Those which, like gold, platina, silver, &c. neither lose nor acquire by the application of fire, are substances which, having no affinity with fire, and not being able to unite, cannot, consequently, either retain or accompany it when it is carried off. It is evident that the matters of the two first classes have a certain degree of affinity with fire, since those of the second class are loaded with fire, which they retain; and the fire loads itself with those of the first class, which it carries off; whereas the matters of the third class, to which it neither lends nor borrows, have not any affinity or attraction with it, but are indifferent to its action, which can neither unnaturalize nor even change them.

This division of every matter into three classes, relative to the action of fire, does not exclude the more particular and less absolute division of all matters into two other classes, hitherto regarded as relative to their own nature, which is said to be always vitrifiable, or calcareous. Our new division is only a more elevated point of view, under which we must consider them, to endeavour to deduce therefrom even the agent that is used by the relations fire can have with every substance to which it is applied.

We might say, with naturalists, that all is vitrifiable in Nature, excepting that which is calcareous: that quartz, chrystals, precious stones, flints, granites, porphyries, agates, gypsums, clays, lava, pumice stone, with all metals and other minerals, are vitrifiable either by the fire of our furnaces, or that of mirrors; whereas marble, alabaster, stones, chalk, marl, and other substances which proceed from the residue of shells and madrepores, cannot be reduced into fusion by these means. Nevertheless I am persuaded, that if the power of our furnaces and mirrors were further increased, we should be enabled to put these calcareous matters in fusion; since there are a multiplicity of reasons to conclude, that at the bottom their substance is the same, and that glass is the common basis of all terrestrial matter.

By my own experiments I have found, that the most powerful glass furnaces is only a weak fire, compared with that of bellows furnaces; and that fire produced in the focus of a good mirror, is stronger than that of the most glowing fire of a furnace. I have kept iron ore for thirty-six hours in the hottest part of the glass furnace of Rouelle, in Burgundy, without its being melted, agglutinated, or even in any manner changed; whereas, in less than twelve hours this ore runs in a forge furnace. I have also melted, or volatilized, by a mirror many matters which neither the fire, nor reverberatory furnace, nor the most powerful bellows furnace could cause to run.

It is commonly supposed, that flame is the hottest part of fire, yet nothing is more erroneous than this opinion; the contrary may be demonstrated by the most simple and familiar experiments. Offer to a straw fire, or even to the flame of a lighted faggot, a cloth to dry or heat, and treble the time will be required to what would be necessary if presented to a brasier without flame. Newton very accurately defines flame to be a burning smoke, and this smoke, or vapour, has never the same quantity or intensity of heat as the combustible body from which it escapes. By being carried upwards and extending, it has the property of communicating fire, and carrying it further than the heat of the brasier, which alone might not be sufficient to communicate it when even very near.

The communication of fire merits a particular attention. I found, after repeated reflections that besides the assistance of facts which appear to have a relation to it, that experiments were necessary to understand the manner in which this operation of Nature is made. Let us receive two or three thousand weight of iron in a mould at its issuing from the furnace; this metal in a short time loses its incandescence, and ceases from its redness, according to the thickness of the ingot. If at the moment its redness leaves it, it is drawn from the mold, the under parts will be still red, but this colour will fly off. Now so long as the redness subsists, we can light combustible matters by applying them to the ingot; but as soon as it has lost its incandescent state, there are numbers of matters which it will not set fire to, although the heat which it diffuses is, perhaps a hundred times stronger than that of a straw fire, which would inflame them. This made me think that flame being necessary to the communication of fire, there is therefore a flame in all incandescence. The red colour seems, in fact, to indicate it; and indeed I am convinced, that combustible, and even the most fixed matters, such as gold and silver, when in an incandescent state, are surrounded with a dense flame which extends only to a very short distance, and which is attached to their surface; and I can easily conceive, that when flame becomes dense to a certain degree, it ceases from obeying the fluctuation of the air. This white or red body, which issues from all bodies in incandescence, and which strikes our eyes, is the evaporation of this dense flame which surrounds the body by renewing itself incessantly on its surface; and even the light of the sun, which emits such an amazing brightness, I presume to be only an evaporation of the dense state that constantly plays on its surface; and which we must regard as a true flame, more pure and dense than any proceeding from our combustible matters.

It is, therefore, by light that fire communicates, and heat alone cannot produce the same effect as when it becomes very strong to be luminous. Even water, that destructive element to fire, by which alone we can prevent its progress, nevertheless communicates when in a well-closed vessel, such as Papin's digester, where it is penetrated with a sufficient quantity of fire to render it luminous, and capable of melting lead and tin, whereas when it is only boiling, far from communicating fire, it extinguishes it immediately. It is true, that heat alone is sufficient to prepare and dispose combustible bodies for inflammation, by driving off the humid parts from bodies; and what is very remarkable, this heat, which dilates all bodies, does not desist from hardening them by drying. I have an hundred times discovered, by examining the stones of my great furnaces, especially the calcareous, they increased in hardness in proportion to the time they had undergone the heat, and they also at the same time became specifically heavier. From this circumstance, I think an induction may be drawn, which would prove, and fully confirm, that heat, although in appearance always fugitive and never stable in the bodies which it penetrates, nevertheless deposits in a positive manner many parts which fixes there even in greater quantities than the aqueous and other parts which it has driven off. But what appears very difficult to be reconciled, this same calcareous stone, which becomes specifically heavier by the action of a moderate heat a long time continued, becomes near a half lighter, when submitted to a fire sufficient for its calcination, and, at the same time, not only loses all the hardness it had acquired by the action of heat, but even the natural adherence of its constituting parts.

Calcination generally received, is, with respect to fixed and incombustible bodies, what combustion is to volatile and inflammable. Calcination, like combustion, needs the assistance of air; it operates so much the quicker, as it is furnished with a greater quantity of that element, without which the fiercest fire cannot calcine nor inflame any thing, except such matters as contain in themselves all the air necessary for those purposes. This necessity for the concurrence of air in calcination, as in combustion, indicates, that there are more things common between them than has been suspected. The application of fire is the principle of both; that of air is the second cause, and almost as necessary as the first; but these two causes are equally combined, according as they act in more or less time, and with more or less power on different substances.

Combustion operates almost instantaneously; calcination is sometimes so long, as to be thought impossible; for in proportion as matters are more incombustible, the calcination is there more slowly made; and when the constituent parts of a substance, such as gold, are not only incombustible, but appear so fixed as not to be volatilized, calcination produces no effect. They must both, therefore, be considered as effects of the same cause, whose two extremes are delineated to us by phosphorus, which is the most inflammable of all bodies, and by gold, which is the most fixed and least combustible. All substances comprized between these two extremes, will be more or less subjected to the effects of combustion and calcination, according as they approach either of them; insomuch, that in the middle points there will be found substances that endure an almost equal degree of both; from which we may conclude, that all calcination is always accopmanied with a little combustion, and all combustion with a little calcination. Cinders and other residue of the most combustible matters, demonstrate that fire has calcined all the parts it has not burned, and consequently, a little calcination is found here with combustion. The small flame which rises from most matters, that are calcined, demonstrates also that a slight combustion is made. Thus, we must not separate these two effects, if we would find out the results of the action of fire on the different substances to which it is applied.

But it may be said, that combustion always diminishes the volume or mass, on account of the quantity of matter it consumes; and that, on the contrary, calcination increases the weight of many substances. Ought we then to consider these two effects whose results are so contrary, as effects of the same nature? Such an objection appears well-founded, and deserves an answer, especially as this is the most difficult point of the question. For that purpose let us consider a matter in which we shall suppose one half to be fixed parts, and the other volatile or combustible. By the application of fire to this, all the volatile or combustible parts will be raised up or burnt, and consequently separated from the whole mass; from hence this mass or quantity of matter will be found diminished one half, as we see it in calcareous stones, which lose near half their weight in the fire. But if we continue to apply the fire for a very long time to the other half, composed of fixed parts, all combustion and volatilization being ceased, that matter, instead of continuing to lose its mass, must increase at the expense of the air and fire with which it is penetrated; and those are matters already calcined, and prepared by Nature to the degree where combustion ceases, and consequently susceptible of increasing the weight from the first moment of the application. We have seen, that light extinguishes on the surface of all bodies which do not reflect; and that heat, by long residence, fixes partly in the matters which it penetrates; we know also that air is necessary for calcination, or combustion, and the more so for calcination as having more fixity in the external parts of bodies, and becomes a constituent part: hence, it is natural to imagine, that this augmentation of weight proceeds only from the addition of the particles of light, heat, and air, which are at length fixed and united to one matter, against which they have made so many efforts, without being able either to raise or burn them. This appears clearly to be the fact, for if we afterwards present a combustible substance to them they will quit the fixed matter, to which they were only attached through force, retake their natural motion, elasticity, and volatility, and all depart with it; from hence, metal, or calcinized matter, to which these volatile parts has been rendered, retakes its pristine form, and its weight is found diminished by the whole quantity of fiery and airy particles which were fixed in it, and which had been just raised by this new combustion. All this is performed by the sole law of affinities; and there seems to be no more difficulty to conceive how the lime of a metal is reduced, than to understand how it is precipitated in dissolution; the cause is the same, and the effects are similar. A metal dissolved by an acid, will precipitate when to this acid another substance is offered with which it has more affinity than metal, the acid then quits it and falls to the bottom. So, likewise, this metal calcines, that is, loaded with parts of air, heat, and fire, which being fixed, keeps it under the form of a lime, and will precipitate, or be reduced, when presented to this fire and fixed air, from the combustible matters with which they have more affinity than with the metal; the latter will retake its first form as soon as it is disembarrassed from this superfluous air and fire, at the expence of the combustible matters offered to it, and the volatile parts it had lost.