Buffon's Natural History. Volume 10 (of 10) Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &c

Part 3

Chapter 34,169 wordsPublic domain

All matter will become light, for if all coherence were destroyed it would be divided into molecules sufficiently minute, and these molecules, being at liberty, will be determined by their mutual attraction to rush one against the other. In the moment of the shock the repulsive force will be exercised, the molecules will fly in all directions with an almost infinite volatility, which, nevertheless, is not equal to their velocity acquired in the moment of contact, for the law of attraction being augmented as the space diminishes, it is evident, that at the contact the space is always proportionable till the square of the distance becomes nil, and, consequently, the velocity acquired by virtue of the attraction must at this point become almost infinite: and it would be perfectly so if the contact were immediate, and, consequently, the distance between the two bodies void; but there is nothing in nature entirely nil, and nothing truly infinite; and all that I have observed of the _infinite_ minuteness of the atoms which constitute light, of their _perfect_ spring, and of the _nil_ distance in the moment of contact, must be understood only relatively. If this metaphysical truth were doubted, a physical demonstration may be given. It is pretty generally known that light employs seven minutes and a half to come from the sun to the earth; supposing, therefore, the sun at thirty-six millions of miles, light darts through this enormous distance in that short space, that is (supposing its motion uniform), 80,000 miles in one second. But this velocity, although prodigious, is yet far from being infinite, since it is determinable by numbers. It will even cease to appear so prodigious, when we reflect on the celerity of the motion of the comets to their perihelia, or even that of the planets, and by computing that, we shall find that the velocity of those immense masses may pretty nearly be compared to that of the atoms of light.

So, likewise, as all matter can be converted into light by the division and expulsion of its parts, when they feel a shock one against another, we shall find that all the elements are convertible; and if it have been doubted whether light, which appears to be the most simple element, may be converted into a solid substance, it is because we have not paid sufficient attention to every phenomena, and were infected with the prejudice, that being essentially volatile it can never become fixed. But it is plain that the fixity and volatility depend on the same attractive force in the first case, and become repulsive in the second; and from thence are we led to think that this change of matter into light, and from light into matter, is one of the most frequent operations of Nature.

Having shewn that impulsion depends on attraction; that the expansive force, like the attractive, becomes negative; that light, heat, and fire, are only modes of the common existing matter; in one word, that there exists but one sole force, and one sole matter, ever ready to attract or repel, according to circumstances; let us see how, with this single spring, and this single subject, Nature can vary her works, _ad infinitum_. In a general point of view, light, heat, and fire, only make one object, but in a particular point of view they are three distinct objects, which, although resembling in a great number of properties, differ nevertheless in a few others, sufficiently essential for us to consider them as three distinct things.

Light, and elementary fire, compose, it is said, only one and the same thing. This may be, but as we have not yet a clear idea of elementary fire we shall desist from pronouncing on this first point. Light and fire, such as we are acquainted with, are two distinct substances, differently composed. Fire is, in fact, very often luminous, but it sometimes also exists without any appearance of light. Fire, whether luminous or obscure, never exists without a great heat, whereas light often burns with a noise without the least sensible heat. Light appears to be the work of nature while fire is only the produce of the industry of man. Light subsists of itself, and is found diffused in the immense space of the whole universe. Fire cannot subsist without food, and is only found in some parts of this space where man preserves it, and in some parts of the profundity of the earth, where it is also supported by suitable food. Light when condensed and united by the art of man, may produce fire, but it is only as much as it lets fall on combustible matters. Light is therefore no more, and in this single instance, only the principle of fire and not the fire itself: even this principle is not immediate, for it supposes the intermediate one of heat, and which appears to appertain more than light to the essence of fire. Now heat exists as often without light as light exists without heat: these two principles might, therefore, appear not to bind them necessarily together; their effects are not contemporary, since in certain circumstances we feel heat long before light appears, and in others we see light long before we feel any heat. Hence is not heat a mode of being, a modification of matter, which, in fact, differs less than all the rest from that of light, but which can be considered apart, and still more easily conceived? It is, nevertheless, certain, that much fewer discoveries have been made on the nature of heat than on that of light; whether man better catches what he sees than what he feels; whether light, presenting itself generally as a distinct and different substance from all the rest, has appeared worthy of a particular consideration; whereas heat, the effect of which is the most obscure, and presents itself as a less detached and less simple object, has not been regarded as a distinct substance but as an attribute of light and fire.

The first thing worthy of remark, is, that the seat of heat is quite different from that of light: the latter occupies and runs through the void space of the universe; heat, on the contrary, is diffused through all solid matter. The globe of the earth, and the whole matter of which it is composed, have a considerable degree of heat. Water has its degree of heat which it does not lose but by losing its fluidity. The air has also heat, which we call its temperature, and which varies much, but is never entirely lost, since its springs subsist even in the greatest cold. Fire has also its different degrees of heat, which appear to depend less on its own nature, than on that of the aliments which feed it. Thus all known matter possesses warmth; and, hence, heat is a much more general affection than that of light.

Heat penetrates every body without exception which is exposed to it, while light passes through transparent bodies only, and is stopped and in part repelled, by every opaque one. Heat, therefore acts in a much more general and palpable manner than light, and although the molecules of heat are excessively minute, since they penetrate the most compact bodies, it seems, however, demonstrable, that they are much more gross than those of light; for we make heat with light, by collecting it in a great quantity. Besides, heat acting on the sense of feeling, it is nececssary that its action be proportionate to the grossness of this sense, the same as the delicacy of the organs of sight appears to be to the extreme fineness of the parts of light; these parts move with the greatest velocity, and act in the instant at immense distances, whereas those of heat have but a slow progressive motion, and only extend to small intervals from the bodies whence they emanate.

The principle of all heat seems to be the attrition of bodies; all friction, that is, all contrary motion between solid matters produces heat; and if the same effect do not happen to fluids, it is because their parts do not touch close enough to rub one against the other; and that, having little adherence between them, their resistance to the shock of other bodies is too weak for the heat to be produced to a sensible degree; but we often see light produced by an attrition of a fluid, without feeling any heat. All bodies whether great or little become heated as soon as they meet in a contrary direction; heat is, therefore, produced by the motion of all palpable matter; while the production of light, which is also made by motion, but in a contrary direction, supposes also the division of matter into very minute parts: and as this operation of Nature is the same with respect to both, we must conclude, that the atoms of light are solid of themselves, and are hot at the moment of their birth. But we cannot be equally certain, that they preserve their heat in the same degree as their light, nor that they cease to be hot before they cease to be luminous.

It is well known, that heat grows less, or cold becomes greater, the higher we ascend on the mountains. It is true that the heat which proceeds from the terrestrial globe, is of course sensibly less on those advanced points, than it is on the plains; but this cause is not proportionable to the effect; the action of heat, which emanates from the terrestrial globe, not being able to diminish but by the square of the distance, it does not appear that at the height of half a mile, which is only the three thousandth part of the semi-diameter of the globe, whose centre must be taken for the focus of heat, that this difference, which in this supposition is only a unit and nine millions, can produce a diminution of heat nearly so considerable; for the thermometer lowers at that height, at all times of the year, to the freezing point. It is not probable, that this great difference of heat simply proceeds from the difference of the earth; and of that we must be fully convinced, if we consider, that at the mouth of the volcanos, where the earth is hotter than in any other part on the surface of the globe, the air is nearly as cold as on other mountains of the same height.

It may then be supposed that the atoms of light, though very hot at the moment of quitting the sun, are greatly cooled during the seven minutes and a half in which they pass from that body to the earth; and this in fact would be the case if they were detached; but, as they almost immediately succeed each other, and are the more confined as they are nearer the place of their origin, the heat lost by each atom falls on the neighbouring ones; and this reciprocal communication supports the general heat of light a longer time; and as their constant direction is in divergent rays, their distance from each other increases according to the space they run over; and as the heat which flies from each atom, as a centre, diminishes also in the same ratio, it follows, that the light of the solar rays, decreasing in an inverted ratio from the square of the distance, that of their heat decreases in an inverted ratio of the square of the same distance.

Taking therefore the semi-diameter of the sun for a unit, and supposing the action of light to be as 1000 to the distance of a demi-diameter of the surface of this planet, it will not be more than as 1000/4 to the distance of two demi-diameters; as 1000/9 to that of three demi-diameters, as 1000/16 to the distance of four demi-diameters; and finally, when it arrives at us, who are distant from the sun thirty-six millions of leagues, that is about two hundred and twenty-four of its demi-diameters, the action of light will be no more than as 1000/50625, that is, more than 50,000 times weaker than at its issuing from the sun; and the heat of each atom of light being also supposed 1000 at its issuing from the sun, will not be more than as 1000/16 1000/81 1000/256 to the successive of 1, 2, 3, demi-diameters, and, when arrived at us, as 1000/2562890625 that is, more than two thousand five hundred millions of times weaker than at issuing from the sun.

If even this diminution of the heat of light should not be admitted by reason of the squared square of the distance to the sun, it will still be evident that heat, in its propagation, diminishes more than light. If we excite a very strong heat, by kindling a large fire, we shall only feel it at a moderate distance but we shall see the light at a very great one. If we bring our hands by degrees nearer and nearer a body excessively hot, we shall perceive that the heat increases much more in proportion than as the space diminishes; for we may warm ourselves with pleasure at a distance which differs only by a few inches from that at which we should be burnt. Every thing, therefore, appears to indicate, that heat diminishes in a greater ratio than light, in proportion as both are removed from the focus whence they issued.

This might lead us to imagine, that the atoms of light would be very cold when they came to the surface of our atmosphere; but that by traversing the great extent of this transparent mass, they receive a new heat by friction. The infinite velocity with which the particles of light rub against those of the air, must produce a heat so much the stronger as the friction is more multiplied: and it is, probably, for this reason, that the heat of the solar rays is found much stronger in the lower parts of the atmosphere, and that the coldness of the air appears to augment as we are elevated. Perhaps, likewise, as light receives heat only by uniting, a great number of atoms of light is required to constitute a single atom of heat, and this may be the cause why the feeble light of the moon, although in the atmosphere, like that of the sun, does not receive any sensible degree of heat. If, as M. Bouguer says, the intensity of the light of the sun to the surface of the earth is 300,000 times stronger than that of the moon, the latter must be almost insensible, even by uniting it in the focus of the most powerful burning glasses, which cannot condense it more than 2000 times; subtracting the half of which for the loss by reflexion or refraction, there remains only a 300dth part intensity to the focus of the glass.

Thus, we must not infer that light can exist without any heat, but only that the degrees of this heat are very different, according to different circumstances, and always insensible when light is very weak. Heat, on the contrary, seems to exist habitually, and even to cause itself to be strongly felt without light; for in general it is only when it becomes excessive, that light accompanies it. But the very essential difference between these two modifications of matter is, that heat, which penetrates all bodies, does not appear to fix in any one, whereas light incorporates and extinguishes in all those which do not reflect, or permit it to pass freely; heat bodies of all kinds to any degree, in a very short time they will lose the acquired heat, and return to the general temperature. If we receive light on black or white bodies, rude or polished, it will easily be perceived, that some admit, and others repel it; and that instead of being affected in a uniform manner as they are by heat, they are only so relatively to their nature, colour, and polish. Black will absorb more light than white, and the rough more than the smooth. Light once absorbed remains fixed in the body which received it, nor quits it like heat; whence we must conclude, that atoms of light may become constituent parts of bodies by uniting with the matter which composes them; whereas heat not fixing at all, seems to prevent the union of every part of matter, and only acts to keep them separate. Nevertheless, there are instances where heat remains fixed in bodies, and others where the light they have absorbed re-appears, and goes out like heat.

After all there appear to be two kinds of heat, the one luminous, of which the sun is the focus; the other obscure, of which the grand reservoir is the terrestrial globe. Our body, as making part of the globe, participates of this obscure heat; and it is for this reason, that it is still obscure to us, because we do not perceive it by any one of our senses. It is with respect to this heat of the globe, as with its motion, we are subject to and participate thereof without feeling or doubting of it: from hence it happened that physicians at first carried all their views and enquiries on the heat of the sun, without suspecting that it makes but a very small part of what we really feel; but having made instruments to discover the difference of the immediate heat of the rays of the sun, they with astonishment found that the heat of them was sixty-six times stronger in summer than in winter, notwithstanding the strongest heat of our summer differs only a seventh from the strongest cold of our winter; from whence they have concluded, that, independent of the heat we receive from the sun, there emanates another, even from this terrestrial globe, which is much more considerable; insomuch, that it is at present demonstrable, that this heat, which escapes from the bowels of the earth, is in our climate at least twenty-nine times in summer, and four hundred times in winter, stronger than the heat which comes to us from the sun.

This strong heat which resides in the interior part of the globe, and which, without ceasing to emanate externally, must, like an element, enter into the combination of all the other elements. If the sun is the parent of Nature, the heat of the earth must be the mother; they both unite to produce, support, and animate organized beings, and to assimilate and compose inanimate substances. This internal heat of the globe, which tends always from the centre to the circumference, is, in my opinion, a great agent in nature. We can scarcely doubt but it is the principal influence on the perpendicularity of the trunks of trees, on the phenomena of electricity, on the effects of magnetism, &c. But as I do not pretend to make a physical treatise here, I shall confine myself to the effects of this heat on the other elements. It is alone sufficient to maintain the rarefaction of the air to the degree that we breathe in: it is more than sufficient to keep water in its state of fluidity, for we have lowered the thermometers to the depth of 120 fathoms, and have found the temperature of the water was there nearly the same as at the like depth in the earth, namely, ten degrees two thirds. We must not, therefore, be surprized, especially as salt acts as a prevention, that the sea in general does not freeze, that fresh water freezes but to a certain thickness, and that the water at bottom always remains liquid, even in the most intense frosts.

But of all the elements the earth is that on which this internal heat must necessarily have produced, and still produces the greatest effects. This heat originally was doubtless much greater than it is at present; therefore we must refer to it, as to the first cause, all the sublimations, precipitations, aggregations, and separations, which have been, and still continue to be made in the internal part of the globe, especially in the external layer which we have penetrated, and the matter of which has been removed by the convulsions of Nature, or by the hands of man. The whole mass of the globe having been melted, or liquefied, by fire, the internal is only a concrete or discreet glass, whose simple substance cannot receive any alteration by heat alone; there is, therefore, only an upper and superficial layer, which being exposed to the action of external causes united to that of the internal heat, will have undergone all the modifications, differences, and forms, in one word, of Mineral Substances, which their combined actions were enabled to produce.

Fire, which at first sight appears to be only a compound of heat and light, might also be a modification of the matter, though it does not essentially differ from either, and still less from both taken together. Fire never exists without heat, but it can exist without light. Heat alone, deprived of all appearance of light, can produce the same effects as the most violent fire; so can also light, when it is united. Light seems to carry a substance in itself which has no need of fuel; but fire cannot subsist without absorbing the air, and it becomes more violent in proportion to the quantity it absorbs; whereas light, concentrated and received into a vessel exhausted of air, acts as fire in air; and heat, confined and retained in a narrow space, subsists and even augments with a very small quantity of food. The most general difference between fire, heat, and light, appears, therefore, to consist in the quantity, and perhaps quality, of their food.

Air is the first food of fire; combustible matters are only the second. It has been demonstrated, by experiments, that a little spark of fire, placed in a vessel well closed, in a short time absorbs a great quantity of air, and becomes extinguished as soon as the quantity or quality, of this food becomes deficient. By other experiments it is proved, that the most combustible matters will not consume in vessels well closed, although exposed to the action of the greatest fire. Air is, therefore, the first and true food of fire, and combustible matters would not be able to supply it without the assistance and mediation of this element.

We have observed that heat is the cause of all fluidity, and we find, by comparing some fluids together, that more heat is requisite to keep iron in fusion than gold; and more to keep gold than tin; much less is necessary for wax, for water less than that, and still less for spirits of wine, and a mere trifle is sufficient for mercury, since the latter goes 187 degrees below what water can without losing its fluidity; mercury, therefore, is the most fluid of all matter, air excepted. Now this superior fluidity in air indicates the least degree of adherence possible between its constituting parts, and supposes them of such a figure as only to be touched at one point. It may be also imagined, that, being endowed with so little apparent energy and mutual attraction, they are, for that reason, less massive, and more light, than those of every other body; but that conclusion appears unfounded, from the comparison of mercury, the next fluid body, but of which the constituting parts appear to be more massive and heavy than those of any other matter, excepting gold. The greater or lesser fluidity, does not, therefore, indicate that the parts of the fluid are more or less weighty, but only that their adherence is so much the less, and their separation so much the easier.

Air, therefore, of all known matter, is that which heat divides the easiest, and is very near the nature of fire, whose property consists in the expansive motions of its parts; and it is from this similarity that air so strongly augments the activity of fire, to which it is the most powerful assistant, and the most intimate and necessary food. Even combustible matters will not keep it alive if deprived of air, for under this privation the most intense fire will not burn; but a single spark of air is sufficient to kindle them, and in proportion as it is supplied with that element the fire becomes strong, extended, and devouring.

Artificial phosphorus, and gunpowder, seem, at first, to be an exception, for they have no need of the assistance of renewed air to inflame and wholly consume them: their combustion may be performed in the closest vessels, but that is because those matters, which are also the most combustible, contain the necessary quantity of air in their substance, therefore they have no need of the assistance of foreign air.