Buffon's Natural History. Volume 10 (of 10) Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &c

Part 12

Chapter 124,089 wordsPublic domain

This mirror of three feet diameter burnt strong enough to melt gold, and I was desirous to see how much I should gain by reducing its action to the burning of wood. For this purpose I used circular zones of paper on the mirrors to diminish the diameter, and I found that there was no longer power enough to inflame dry wood when its diameter was reduced to little more than four inches; therefore, taking five inches, or sixty lines, for the diameter necessary to burn with a focus of four lines, it appeared, that to burn equally at 210 feet, where the focus should necessarily have two feet diameter, I should require a mirror of 30 feet diameter, which appeared still as impossible, or at least impracticable.

To such positive conclusions, and which others would have regarded as demonstrations of the impossibility of the mirror, I had only a supposition to oppose; but an old supposition, on which the more I reflected the more I was persuaded that it was not without foundation; namely, that the effects of heat might possibly not be in proportion to the quantity of light, or, what amounts to the same, that at an equal intensity of light large focuses must burn brisker than the small.

By estimating heat mathematically, it is not to be doubted but that the power of a focus of the same length is in proportion to the surface of the mirror. A mirror whose surface is double that of another, must have the same sized focus, and this focus must contain double the quantity of light which the first contained; and in the supposition, that effects are always in proportion to their causes, it might be presumed that the heat of this second focus should be double that of the first.

So likewise, and by the same mathematical estimation, it has always been thought, that at an equal intensity of light, a small focus ought to burn as much as a large one, and that the effect of the heat ought to be in proportion to this intensity of light: _insomuch_ (says Descartes) _that glasses, or extremely small mirrors, may be made, which will burn with as much violence as the large_. I at first thought that this conclusion, drawn from mathematical theory, might be found false in practice, because heat being a physical quality, of the action and propagation of which we know not the laws, it seemed to me, that there was some kind of temerity in thus estimating its effects by a simple speculation.

I had, therefore, once more, recourse to experiments. I took metal mirrors of different focuses and different degrees of polish, and by comparing the different actions on the same fusible or combustible matters, I found, that at an equal intensity of light, large focuses constantly have more effect than small, and I discovered the same to be the case with refracting mirrors.

It is easy to assign the reason of this difference, if we consider that heat communicates nearer and nearer, and disperses, if I may so speak, when it is even applied on the same point: for example, if we let the focus of a burning glass fall on the centre of a crown piece, and that this focus was only a line in diameter, the heat produced on the centre disperses and extends over and throughout the whole piece: thus all the heat, although used at first to the centre of the crown, does not stop there, and consequently cannot produce so great an effect as if it did. But if, instead of a focus of a line which falls upon the centre of the crown, we let fall a focus of equal intensity on the whole crown, every part being alike heated, then instead of experiencing the less heat, it acquires an augmentation; for the middle profiting of the heat with the other points which surround it, the crown piece will be melted in this latter case, while in the first, it will only be slightly heated.

After these experiments and reflections, I began to entertain sanguine hopes of making mirrors to burn at a great distance; for I no longer dreaded as before, the great extent of the focus; I was persuaded, on the contrary, that a focus of a considerable breadth, as two feet, and which in the intensity of the light would not be near so great as in a small focus of four lines, might, nevertheless, produce inflammation, and with more power; and that, consequently, this mirror, which, by mathematical theory, ought to have at least thirty feet diameter, would be reduced to one of eight or ten feet at most, which was not only a possible, but even a very practicable thing.

I then thought seriously of executing my project: I had at first a design of trying to burn at 200 or 300 feet distance with circular or hexagonal glasses of a square foot in surface, and I was desirous of having four iron carriages for them, with screws to each to move them, and a spring to adjust them; but the considerable expense that this required made me quit that idea, and I took two common glasses of six inches by eight, and a wooden adjustment, which, in fact, was less solid and precise, but the expence was more consistent with a mere experiment: the mechanism of which was executed by M. Passement.

It is sufficient to say, that it was at first composed of 168 glasses of six inches by eight each, about four lines distant from each other; these glasses moved in all directions, and the four lines of space between them not only served for the freedom of this motion, but also to let the operator see the place where he was to conduct his images. By means of this construction, 168 images could be thrown on one point, and, consequently, burn at several distances, as at 20, 30, and to 150 feet. By increasing the size of the mirror, or by making other mirrors like the first, we are certain of throwing fire to still greater distances, or to increase as much as we please the force or activity of those first distances.

It is only to be observed, that the motion here spoken of is not very easy to be executed, and that also there is a very great choice to be made in the glasses; for they are not all equally good, though they appear so at the first inspection. I was obliged to pick out of more than 500 the 168 I made use of. The method of trying them is to receive at 150 feet distance the reflected image of the sun, as a vertical plane; we must select those which give a round and terminated image, and reject those, whose thicknesses being unequal in different parts, or the surface a little concave or convex, have images badly terminated, double, treble, oblong, &c. according to the different defects found in the glasses.

By the first experiment which I made the 23d of March, 1747, at noon, I set fire to a plank of fir at 66 feet distance, with 40 glasses only, about a quarter of the mirror. It must be observed that not being yet mounted, it was very disadvantageously placed, forming an angle with the sun of twenty degrees declination, and another of more than ten degrees inclination.

The same day I set fire to a pitchy and sulphureous plank at 126 feet distance, with eighty-eight glasses, the mirror being still placed disadvantageously. It is well known, that to burn with the greatest advantage the mirror should be directly opposed to the sun, as well as the matters to be inflamed; so that, by supposing a perpendicular plane on the plane of the mirror, it must pass by the sun, and, at the same time, through the midst of combustible matters.

The 3d of April, at four o'clock in the afternoon, the mirror being mounted, produced a slight inflammation on a plank covered with pitch at 138 feet distance, although the sun was weak and the light pale. Great care must be taken, when we approach the spot where the combustible matters are, not to look on the mirror; for if, unfortunately, the eyes should meet the focus, inevitable blindness will ensue.

The 4th of April, at eleven in the morning, although the sun appeared watery, and the sky cloudy, yet it produced, with 154 glasses, so considerable a heat at 158 feet, that in less than two minutes it made a deal plank smoke, and which would certainly have flamed, if the sun had not suddenly disappeared.

The ensuing day, the 5th of April, at three o'clock in the afternoon, we set fire, in a minute and a half, at 150 feet distance, to a plank sulphured and mixed with coals, with 154 glasses. When the sun is powerful, only a few seconds is required to produce inflammation.

The 10th of April in the afternoon, the sun being bright, we set fire to a fir plank at 150 feet distance, with only 128 glasses: the inflammation was very sudden, and made in all the extent of the focus, which was about sixteen inches diameter at this distance.

The same day, at half past two o'clock, we threw the fire on another plank, partly pitched and covered with sulphur in some places: the inflammation was made very suddenly; it began by the parts of the wood which were uncovered, and the fire was so violent, that the plank was obliged to be dipt in water to extinguish it: there were 148 glasses at 150 feet distance.

The eleventh of April, the focus being only 20 feet distant from the mirror, it only required 12 glasses to inflame small combustible matters; with 21 glasses we set fire to another plank which had already been partly burnt; with 45 glasses we melted a block of tin of 6lb. weight; and with 117 glasses we melted thin pieces of silver, and reddened an iron plate; and I am also persuaded, that by using all the glasses of the mirror we should have been enabled to have melted metals at 50 feet distance; and as the focus at this distance was six or seven inches broad, we should be able to make trials on all metals, which it was not possible to do with common mirrors, whose focus is either very weak or 100 times smaller than that of mine. I have remarked, that metals, and especially silver, smoke much before they melt; the smoke was so striking that it shaded the ground, and it was there I looked on it attentively, for it is not possible to look a moment on the focus when it falls on the metal, the lustre being much more dazzling than that of the sun.

The experiments which I have here related, and which were made immediately after the invention of the mirrors, have been followed by a great number of others, which confirm them. I have set fire to wood at 210 feet distance with this mirror, by the sun in summer; and I am certain, that with four similar mirrors I could burn at 400 feet, and, perhaps, at a greater distance. I have likewise, melted all metals, and metallic minerals, at 25, 30, and 40 feet. We shall find, in the course of this article, the uses to which these mirrors can be applied, and the limits that must be assigned to their power for calcination, combustion, fusion, &c.[F]

[F] It requires about half an hour to mount the mirror and to make all the images fall on the same point; but when this is once adjusted, it may be used at all times by simply drawing a curtain.

This mirror burns according to the different inclination given it, and what gave it this advantage over the common reflecting mirrors was that its focus was very distant, and had so little curvature, that it was almost imperceptible: it was seven feet broad by eight feet high, which makes about the 150th part of the circumference of the sphere, when we burn at 150 feet distance.

The reason that determined me to prefer glasses of six inches broad by eight inches high to square glasses of six or eight inches, was, that it is much more commodious to make experiments upon a horizontal and level ground than otherwise, and that with this figure, the height of which exceeded the breadth, the images were rounder; whereas with square glasses they would be shortened, especially at small distances, in a horizontal situation.

This discovery furnishes us with many useful hints for physic, and perhaps for the arts. We know that what renders common reflecting mirrors most useless for experiments is, that they burn almost always upwards, and that we are greatly embarrassed to find means to suspend or support to their focus matters to be melted or calcined. By means of my mirror we burn concave mirrors downwards, and with so great an advantage that we have what degree of heat we please; for example, by opposing to my mirror a concave one of a foot square in the surface, the heat produced to this last mirror, by using 154 glasses only, will be upwards of 12 times greater than that generally produced, and the effect will be the same as if 12 suns existed instead of one, or rather as if the sun had 12 times more heat.

Secondly, By means of my mirror we shall have the true scale of the augmentation of heat, and make a real thermometer, whose divisions will be no longer arbitrary, from the temperature of the air to what degree of heat we chuse, by letting fall, successively, the images of the sun one on the other, and by graduating the intervals, whether by means of an expansive liquor, or a machine of dilatation, and from that we shall know, in fact, what a double, treble, quadruple, &c. augmentation of heat is, and shall find out matters whose expansion, or other effects, will be the most suitable to measure the augmentations of heat.

Thirdly, We shall exactly know how many times is required for the heat of the sun to burn, melt, or calcine different matters, which was hitherto only known in a vague and very indefinite manner; and shall be in a state to make precise comparisons of the activity of our fires with that of the sun, and have exact relations and fixed and invariable measures. In short, those who examine my theory, and shall have seen the effect of my mirror, I think will be convinced the mode I have used was the only one possible to succeed to burn far off, for, independant of the physical difficulty of making large concave, spherical, parybolical mirrors, or of any other curvature whatsoever, regular enough to burn at 150 feet distance, we shall easily be convinced that they would not produce but nearly as much effect as mine, because the focus would be almost as broad; that besides, these curved mirrors, if even it should be possible to make them, would have the very great disadvantage to burn only at a nigh distance, whereas mine burns at all distances; and, consequently, we shall abandon the scheme of making mirrors to burn at a great distance by means of curves, which has uselessly employed a great number of mathematicians and artists, who were always deceived, because they considered the rays of the sun as parallel, whereas they should be considered as they are, namely, as forming angles of all sizes, from 0 to 32 minutes, which makes it impossible, whatsoever curve is given to a mirror, to render the diameter of the focus smaller than the chord, which measures 32 minutes. Thus, even if we could make a concave mirror to burn at a great distance; for example, at 150 feet, by employing all its points on a sphere of 600 feet diameter, and by employing an uncommon mass of glass or metal, it is evident that we shall have a little more advantage than by using, as I have done, only small plane mirrors.

On the whole, although this mirror is susceptible of a very great perfection, both for the adjustment, and many other particulars, and though I think I shall be able to make another, whose effects will be superior, yet, as every thing has its limits, it must not be expected that every one can be formed to burn at extreme distances; to burn, for example, at the distance of half a mile, a mirror 200 times larger would be required; and I am of opinion that more will never be effected than to burn at the distance of 8 or 900 feet. The focus, whose motion is always correspondent to that of the sun, moves so much the quicker as it is farther distant from the mirror; and at 90 feet it would move about six feet a minute.

However, as I have given an account of my discovery, and the success of my experiments, I should render to Archimedes, and the ancients, the glory that is their due. It is certain that Archimedes could perform with metal mirrors what I have done with glass, and that, consequently, I cannot refuse him the title of the first inventor of these mirrors, and the opportunity he had of using them rendered him, without doubt, more celebrated than the merit of the thing itself.

Many advantages may be derived from the use of these mirrors; by an assemblage of small mirrors, with hexagonal planes, and polished steel, which will have more solidity than glasses, and which would not be subject to the alterations which the light of the sun may cause, we may produce very useful effects, and which would amply repay the expences of the construction of the mirror.

"For all evaporations of salt waters, where great quantities of wood and coal are consumed, or structures raised for the purpose of carrying the waters off, which cost more than the construction of many mirrors, such as I mention; for the evaporation of salt waters, only an assemblage of twelve plane mirrors of a square foot each is necessary. The heat reflected by their focuses, although directed below their level, and at fifteen or sixteen feet distance, will be still great enough to boil water, and consequently produce a quick evaporation: for the heat of boiling water is only treble the heat of the sun in summer; and as the reflection of a well polished plane surface only diminishes the heat one half, only six mirrors are required to produce at the focus a heat equal to boiling water; but I shall double the number to make the heat communicate quicker; and likewise by reason of the loss occasioned by the obliquity, under which the light falls on the surface of the water to be evaporated, and because salt water heats slower than fresh. This mirror, whose assemblage would form only a square four feet broad by three high, would be easy to be managed; and if it were required to double or treble the effects in the same time, it would be better to make so many similar mirrors, than to augment the scale of them; for water can only receive a certain quantity of heat, and we should not gain any thing by increasing this degree; whereas, by making two focuses with two equal mirrors, we should double the effect of the evaporation, and treble it by three mirrors, whose focuses would fall separately one from the other on the surface of the water to be evaporated. We cannot avoid the loss caused by the obliquity; nor can it be remedied but by suffering a still greater, that is, by receiving the rays of the sun on a large glass, which would reflect them broken on the mirror; for then it would burn at bottom instead of the top, but it would lose half the heat by the first reflection, and half of the remainder by the second; so that instead of six small mirrors, it would require a dozen to obtain a heat equal to boiling water. For the evaporation to be made with more success, we ought to diminish the thickness of the water as much as possible; a mass of water a foot deep will not evaporate nearly so quick as the same mass reduced to six inches, and increased to double the superfices. Besides, the bottom being nearer the surface, it heats quicker, and this heat, which the bottom of the vessel receives, contributes still more to the celerity of the evaporation.

2. These mirrors may be used with advantage to calcine plaisters, and even calcareous stones, but they would require to be larger, and the matters placed in an elevated situation, that nothing might be lost by the obliquity of the light. It has already been observed that gypsum heats as soon again as soft calcareous stone, and nearly twice as quick as marble, or hard calcareous stone; their calcination, therefore, must be in a respective ratio. I have found by an experiment repeated three times, that very little more heat is required to calcine white gypsum, called alabaster, than to melt lead. Now the heat necessary to melt lead is, according to the experiments of Newton, eight times stronger than the heat of the summer sun; it therefore would require at least sixteen small mirrors to calcine gypsum; and because of the losses thereby occasioned, as well by the obliquity of the light as by the inequality of the focus, which is not removed above fifteen feet, I presume it would require twenty, and perhaps twenty-four mirrors of a foot square each, to calcine gypsum in a short time, consequently it would require an assemblage of forty-eight small mirrors to calcine the softest calcareous stone, and seventy-two of a foot square to calcine hard calcareous stones. Now a mirror twelve feet broad by six feet high, would be a large and cumbersome machine; yet we might conquer these difficulties if the product of the calcination were considerable enough to surpass the expense of the consumption of wood. To ascertain this, we ought to begin by calcining plaister with a mirror of twenty-four pieces, and if that succeeded, to make two other similar mirrors, instead of making a large one of seventy-two pieces; for by coinciding the focuses of these three mirrors of twenty-four pieces, we should produce an equal heat, strong enough to calcine marble or hard stone.

But a very essential matter remains doubtful, that is, to know how much time would be requisite, for example, to calcine a cubical foot of matter, especially if that foot were struck with the heat only in one part. Some time would pass before the heat penetrated its thickness; during this time, a great part of the heat would be lost, and which would issue from this piece of matter after it had entered it. I fear, therefore, much that the stone not being touched by the heat on every side at once, the calcination would be slower, and the produce less. Experience alone can decide this, but it would be at least necessary to attempt it on gypsous matters, whose calcination is as quick again as calcareous stone.

By concentrating this heat of the sun in a kiln, which has no other opening than what admits the light, a great part of the heat would be prevented from flying off, and by mixing with calcareous stone a small quantity of coal dust, which is the cheapest of all combustible matters, this slight supply of food would suffice to feed and augment the quantity of heat, which would produce a more ample and quick calcination, and at very little expense.

3. These mirrors of Archimedes might be, in fact, used to set fire to the sails of vessels, and even to pitched wood at more than 150 feet distance; they might also be used against the enemy, by burning the grain and other productions of the earth; this effect would be no less sudden than destructive; but we will not dwell on the means of doing mischief, conceiving it to be more our duty to think on those which may do some real service to mankind.