Chapter 4

Take a bottle (_a_) or Florence flask, adapt to the mouth of it a cork furnished with a glass tube (_b_), bent at right angles; let one leg of the tube be immersed in the vial (_c_) containing the water to be examined; as shewn in the following sketch. Then take one part of sulphuret of antimony of commerce, break it into pieces of half the size of split pease, put it into the flask, and pour upon it four parts of common concentrated muriatic acid (spirit of salt of commerce). Sulphuretted hydrogen gas will become disengaged from the materials in abundance, and pass through the water in the vial (_c_). Let the extrication of the gas be continued for about five minutes; and if the minutest quantity of lead be present, the water will acquire a dark-brown or blackish tinge. The extrication of the gas is facilitated by the application of a gentle heat.

The action of the sulphuretted hydrogen test, when applied in this manner, is astonishingly great; for one part of acetate of lead may be detected by means of it, in 20000 parts of water.[24]

Another test for readily detecting lead in water, is sulphuretted chyazate of potash, first pointed out as such by Mr. Porret. A few drops of this re-agent, added to water containing lead, occasion a white precipitate, consisting of small brilliant scales of a considerable lustre.

Sulphate of potash, or sulphate of soda, is likewise a very delicate test for detecting minute portions of lead. Dr. Thomson[25] discovered, by means of it, one part of lead in 100000 parts of water; and this acute Philosopher considers it as the most unequivocal test of lead that we possess. Dr. Thomson remarks that "no other precipitate can well be confounded with it, except sulphate of barytes; and there is no probability of the presence of barytes existing in common water."

Carbonate of potash, or carbonate of soda, may also be used as agents to detect the presence of lead. By means of these salts Dr. Thomson was enabled to detect the presence of a smaller quantity of lead in distilled water, than by the action of sulphuretted hydrogen. But the reader must here be told, that the use of these tests cannot be entrusted to an unskilful hand; because the alkaline carbonates throw down also lime and magnesia, two substances which are frequently found in common water; the former tests, namely, water impregnated with sulphuretted hydrogen gas, and nascent sulphuretted hydrogen, are therefore preferable.

It is absolutely essential that the water impregnated with sulphuretted hydrogen, when employed as a test for detecting very minute quantities of lead, be fresh prepared; and if sulphate of potash, or sulphate of soda, be used as tests, they should be perfectly pure. Sulphate of potash is preferable to sulphate of soda. It is likewise advisable to act with these tests upon water concentrated by boiling. The water to which the test has been added does sometimes appear not to undergo any change, at first; it is therefore necessary to suffer the mixture to stand for a few hours; after which time the action of the test will be more evident. Mr. Silvester[26] has proposed gallic acid as a delicate test for detecting lead.

FOOTNOTES:

[11] Dalton, Manchester Memoirs, vol. iv. p. 55.

[12] Marsden's History of Sumatra.

[13] Manchester Memoirs vol. x. 1819.

[14] Observations on the Water with which Tunbridge Wells is chiefly supplied for Domestic Purposes, by Dr. Thomson; forming an Appendix to an Analysis of the Mineral Waters of Tunbridge Wells, by Dr. Scudamore.

[15] It is absolutely essential that the tests should be pure.

[16] Philosophical Magazine, vol. xv. p. 252.

[17] Transactions of the Royal Society of Edinburgh, vol. viii. p. 259.

[18] Sir G. Baker, Med. Trans. vol. i. p. 280.

[19] Lamb on Spring Water.

[20] Medical Trans. vol. i. p. 420.

[21] Van Swieten ad Boerhaave, Aphorisms, 1060. Comment.

[22] Medical Comment. Dec. 2, 1794.

[23] Lambe on Spring Water.

[24] See An Analysis of the Mineral Waters of Tunbridge Wells, by Dr. Scudamore, p. 55.

The application of the sulphuretted hydrogen test requires some precautions in those cases where other metals besides lead may be expected; because silver, quicksilver, tin, copper, and several other metals, are affected by it, as well as lead; but there is no chance of these metals being met with in common water.--See _Chemical Tests_, third edition, p. 207.

[25] Analysis of Tunbridge Wells Water, by Dr. Scudamore, p. 55.

[26] Nicholson's Journal, p. 33, 310.

_Adulteration of Wine._

It is sufficiently obvious, that few of those commodities, which are the objects of commerce, are adulterated to a greater extent than wine. All persons moderately conversant with the subject, are aware, that a portion of alum is added to young and meagre red wines, for the purpose of brightening their colour; that Brazil wood, or the husks of elderberries and bilberries,[27] are employed to impart a deep rich purple tint to red Port of a pale, faint colour; that gypsum is used to render cloudy white wines transparent;[28] that an additional astringency is imparted to immature red wines by means of oak-wood sawdust,[29] and the husks of filberts; and that a mixture of spoiled foreign and home-made wines is converted into the wretched compound frequently sold in this town by the name of _genuine old Port_.

Various expedients are resorted to for the purpose of communicating particular flavours to insipid wines. Thus a _nutty_ flavour is produced by bitter almonds; factitious Port wine is flavoured with a tincture drawn from the seeds of raisins; and the ingredients employed to form the _bouquet_ of high-flavoured wines, are sweet-brier, oris-root, clary, cherry laurel water, and elder-flowers.

The flavouring ingredients used by manufacturers, may all be purchased by those dealers in wine who are initiated in the mysteries of the trade; and even a manuscript recipe book for preparing them, and the whole mystery of managing all sorts of wines, may be obtained on payment of a considerable fee.

The sophistication of wine with substances not absolutely noxious to health, is carried to an enormous extent in this metropolis. Many thousand pipes of spoiled cyder are annually brought hither from the country, for the purpose of being converted into factitious Port wine. The art of manufacturing spurious wine is a regular trade of great extent in this metropolis.

"There is, in this city, a certain fraternity of chemical operators, who work underground in holes, caverns, and dark retirements, to conceal their mysteries from the eyes and observation of mankind. These subterraneous philosophers are daily employed in the transmutation of liquors; and by the power of magical drugs and incantations, raising under the streets of London the choicest products of the hills and valleys of France. They can squeeze Bourdeaux out of the sloe, and draw Champagne from an apple. Virgil, in that remarkable prophecy,

_Incultisque ruhens pendebit sentibus uva._

Virg. Ecl. iv. 29.

The ripening grape shall hang on every thorn.

seems to have hinted at this art, which can turn a plantation of northern hedges into a vineyard. These adepts are known among one another by the name of _Wine-brewers_; and, I am afraid, do great injury, not only to her Majesty's customs, but to the bodies of many of her good subjects."[30]

The following are a few of the recipes employed in the manufacture of spurious wine:

To make _British Port Wine_.[31]--"Take of British grape wine, or good cyder, 4 gallons; of the juice of red beet root two quarts; brandy, two quarts; logwood 4 ounces; rhatany root, bruised, half a pound: first infuse the logwood and rhatany root in brandy, and a gallon of grape wine or cyder for one week; then strain off the liquor, and mix it with the other ingredients; keep it in a cask for a month, when it will be fit to bottle."

_British Champagne._--"Take of white sugar, 8 pounds; the whitest brown sugar, 7 pounds, crystalline lemon acid, or tartaric acid, 1 ounce and a quarter, pure water, 8 gallons; white grape wine, two quarts, or perry, 4 quarts; of French brandy, 3 pints."

"Put the sugar in the water, skimming it occasionally for two hours, then pour it into a tub and dissolve in it the acid; before it is cold, add some yeast and ferment. Put it into a clean cask and add the other ingredients. The cask is then to be well bunged, and kept in a cool place for two or three months; then bottle it and keep it cool for a month longer, when it will be fit for use. If it should not be perfectly clear after standing in the cask two or three months, it should be rendered so by the use of isinglass. By adding 1 lb. of fresh or preserved strawberries, and 2 ounces of powdered cochineal, the PINK _Champagne may be made_."

_Southampton Port._[32]--"Take cyder, 36 gallons; elder wine, 11 gallons; brandy, 5 gallons; damson wine, 11 gallons; mix."

The particular and separate department in this factitious wine trade, called _crusting_, consists in lining the interior surface of empty wine-bottles, in part, with a red crust of super-tartrate of potash, by suffering a saturated hot solution of this salt, coloured red with a decoction of Brazil-wood, to crystallize within them; and after this simulation of maturity is perfected, they are filled with the compound called Port wine.

Other artisans are regularly employed in staining the lower extremities of bottle-corks with a fine red colour, to appear, on being drawn, as if they had been long in contact with the wine.

The preparation of an astringent extract, to produce, from spoiled home-made and foreign wines, a "genuine old Port," by mere admixture; or to impart to a weak wine a rough austere taste, a fine colour, and a peculiar flavour; forms one branch of the business of particular wine-coopers: while the mellowing and restoring of spoiled white wines, is the sole occupation of men who are called _refiners of wine_.

We have stated that a crystalline crust is formed on the interior surface of bottles, for the purpose of misleading the unwary into a belief that the wine contained in them is of a certain age. A correspondent operation is performed on the wooden cask; the whole interior of which is stained artificially with a crystalline crust of super-tartrate of potash, artfully affixed in a manner precisely similar to that before stated. Thus the wine-merchant, after bottling off a pipe of wine, is enabled to impose on the understanding of his customers, by taking to pieces the cask, and exhibiting the beautiful dark coloured and fine crystalline crust, as an indubitable proof of the age of the wine; a practice by no means uncommon, to flatter the vanity of those who pride themselves in their acute discrimination of wines.

These and many other sophistications, which have long been practised with impunity, are considered as legitimate by those who pride themselves for their skill in the art of _managing_, or, according to the familiar phrase, _doctoring_ wines. The plea alleged in exculpation of them, is, that, though deceptive, they are harmless: but even admitting this as a palliation, yet they form only one department of an art which includes other processes of a tendency absolutely criminal.

Several well-authenticated facts have convinced me that the adulteration of wine with substances deleterious to health, is certainly practised oftener than is, perhaps, suspected; and it would be easy to give some instances of very serious effects having arisen from wines contaminated with deleterious substances, were this a subject on which I meant to speak. The following statement is copied from the Monthly Magazine for March 1811, p. 188.

"On the 17th of January, the passengers by the Highflyer coach, from the north, dined, as usual, at Newark. A bottle of Port wine was ordered; on tasting which, one of the passengers observed that it had an unpleasant flavour, and begged that it might be changed. The waiter took away the bottle, poured into a fresh decanter half the wine which had been objected to, and filled it up from another bottle. This he took into the room, and the greater part was drank by the passengers, who, after the coach had set out towards Grantham, were seized with extreme sickness; one gentleman in particular, who had taken more of the wine than the others, it was thought would have died, but has since recovered. The half of the bottle of wine sent out of the passengers' room, was put aside for the purpose of mixing negus. In the evening, Mr. Bland, of Newark, went into the hotel, and drank a glass or two of wine and water. He returned home at his usual hour, and went to bed; in the middle of the night he was taken so ill, as to induce Mrs. Bland to send for his brother, an apothecary in the town; but before that gentleman arrived, he was dead. An inquest was held, and the jury, after the fullest enquiry, and the examination of the surgeons by whom the body was opened, returned a verdict of--_Died by Poison._"

The most dangerous adulteration of wine is by some preparations of lead, which possess the property of stopping the progress of acescence of wine, and also of rendering white wines, when muddy, transparent. I have good reason to state that lead is certainly employed for this purpose. The effect is very rapid; and there appears to be no other method known, of rapidly recovering ropy wines. Wine merchants persuade themselves that the minute quantity of lead employed for that purpose is perfectly harmless, and that no atom of lead remains in the wine. Chemical analysis proves the contrary; and the practice of clarifying spoiled white wines by means of lead, must be pronounced as highly deleterious.

Lead, in whatever state it be taken into the stomach, occasions terrible diseases; and wine, adulterated with the minutest quantity of it, becomes a slow poison. The merchant or dealer who practises this dangerous sophistication, adds the crime of murder to that of fraud, and deliberately scatters the seeds of disease and death among those consumers who contribute to his emolument. If to debase the current coin of the realm be denounced as a capital offence, what punishment should be awarded against a practice which converts into poison a liquor used for sacred purposes.

Dr. Watson[33] relates, that the method of adulterating wine with lead, was at one time a common practice in Paris.

Dr. Warren[34] states an instance of thirty-two persons having become severely ill, after drinking white wine that had been adulterated with lead. One of them died, and one became paralytic.

In Graham's Treatise on Wine-Making,[35] under the article of _Secrets_, belonging to the mysteries of vintners, p. 31, lead is recommended to prevent wine from becoming acid. The following lines are copied from Mr. Graham's work:

"_To hinder Wine from turning._

"Put a pound of melted lead, in fair water, into your cask, pretty warm, and stop it close."

"_To soften Grey Wine._

"Put in a little vinegar wherein litharge has been well steeped, and boil some honey, to draw out the wax. Strain it through a cloth, and put a quart of it into a tierce of wine, and this will mend it."

* * * * *

The ancients knew that lead rendered harsh wines milder, and preserved it from acidity, without being aware that it was pernicious: it was therefore long used with confidence; and when its effects were discovered, they were not ascribed to that metal, but to some other cause.[36] When the Greek and Roman wine merchants wished to try whether their wine was spoiled, they immersed in it a plate of lead;[37] if the colour of the lead were corroded, they concluded that their wine was spoiled. Wine may become accidentally impregnated with lead.

It is well known that bottles in which wine has been kept, are usually cleaned by means of shot, which by its rolling motion detaches the super-tartrate of potash from the sides of the bottles. This practice, which is generally pursued by wine-merchants, may give rise to serious consequences, as will become evident from the following case:[38]

"A gentleman who had never in his life experienced a day's illness, and who was constantly in the habit of drinking half a bottle of Madeira wine after his dinner, was taken ill, three hours after dinner, with a severe pain in the stomach and violent bowel colic, which gradually yielded within twelve hours to the remedies prescribed by his medical adviser. The day following he drank the remainder of the same bottle of wine which was left the preceding day, and within two hours afterwards he was again seized with the most violent colliquative pains, headach, shiverings, and great pain over the whole body. His apothecary becoming suspicious that the wine he had drank might be the cause of the disease, ordered the bottle from which the wine had been decanted to be brought to him, with a view that he might examine the dregs, if any were left. The bottle happening to slip out of the hand of the servant, disclosed a row of shot wedged forcibly into the angular bent-up circumference of it. On examining the beads of shot, they crumbled into dust, the outer crust (defended by a coat of black lead with which the shot is glazed) being alone left unacted on, whilst the remainder of the metal was dissolved. The wine, therefore, had become contaminated with _lead and arsenic_, the shot being a compound of these metals, which no doubt had produced the mischief."

TEST FOR DETECTING THE DELETERIOUS ADULTERATIONS OF WINE.

A ready re-agent for detecting the presence of lead, or any other deleterious metal in wine, is known by the name of the _wine test_. It consists of water saturated with sulphuretted hydrogen gas, acidulated with muriatic acid. By adding one part of it, to two of wine, or any other liquid suspected to contain lead, a dark coloured or black precipitate will fall down, which does not disappear by an addition of muriatic acid; and this precipitate, dried and fused before the blowpipe on a piece of charcoal, yields a globule of metallic lead. This test does not precipitate iron; the muriatic acid retains iron in solution when combined with sulphuretted hydrogen; and any acid in the wine has no effect in precipitating any of the sulphur of the test liquor. Or a still more efficacious method is, to pass a current of sulphuretted hydrogen gas through the wine, in the manner described, p. 70, having previously acidulated the wine with muriatic acid.

The wine test sometimes employed is prepared in the following manner:--Mix equal parts of finely powdered sulphur and of slacked quick-lime, and expose it to a red heat for twenty minutes. To thirty-six grains of this sulphuret of lime, add twenty-six grains of super-tartrate of potassa; put the mixture into an ounce bottle, and fill up the bottle with water that has been previously boiled, and suffered to cool. The liquor, after having been repeatedly shaken, and allowed to become clear, by the subsidence of the undissolved matter, may then be poured into another phial, into which about twenty drops of muriatic acid have been previously put. It is then ready for use. This test, when mingled with wine containing lead or copper, turns the wine of a dark-brown or black colour. But the mere application of sulphuretted hydrogen gas to wine, acidulated by muriatic acid, is a far more preferable mode of detecting lead in wine.

M. Vogel[39] has lately recommended acetate of lead as a test for detecting extraneous colours in red wine. He remarks, that none of the substances that can be employed for colouring wine, such as the berries of the Vaccinium Mirtillus (bilberries), elderberries, and Campeach wood, produce with genuine red wine, a greenish grey precipitate, which is the colour that is procured by this test by means of genuine red wines.

Wine coloured with the juice of the bilberries, or elderberries, or Campeach wood, produces, with acetate of lead, a deep blue precipitate; and Brazil-wood, red saunders, and the red beet, produce a colour which is precipitated red by acetate of lead. Wine coloured by beet root is also rendered colourless by lime water; but the weakest acid brings back the colour. As the colouring matter of red wines resides in the skin of the grape, M. Vogel prepared a quantity of skins, and reduced them to powder. In this state he found that they communicated to alcohol a deep red colour: a paper stained with this colour was rendered red by acids and green by alkalies.

M. Vogel made a quantity of red wine from black grapes, for the purpose of his experiments; and this produced the genuine greyish green precipitate with acetate of lead. He also found the same coloured precipitate in two specimens of red wine, the genuineness of which could not be suspected; the one from Chateau-Marguaux, and the other from the neighbourhood of Coblentz.

SPECIFIC DIFFERENCES, AND COMPONENT PARTS OF WINE.

Every body knows that no product of the arts varies so much as wine; that different countries, and sometimes the different provinces of the same country, produce different wines. These differences, no doubt, must be attributed chiefly to the climate in which the vineyard is situated--to its culture--the quantity of sugar contained in the grape juice--the manufacture of the wine; or the mode of suffering its fermentation to be accomplished. If the grapes be gathered unripe, the wine abounds with acid; but if the fruit be gathered ripe, the wine will be rich. When the proportion of sugar in the grape is sufficient, and the fermentation complete, the wine is perfect and generous. If the quantity of sugar be too large, part of it remains undecomposed, as the fermentation is languid, and the wine is sweet and luscious; if, on the contrary, it contains, even when full ripe, only a small portion of sugar, the wine is thin and weak; and if it be bottled before the fermentation be completed, part of the sugar remains undecomposed, the fermentation will go on slowly in the bottle, and, on drawing the cork, the wine sparkles in the glass; as, for example, Champagne. Such wines are not sufficiently mature. When the must is separated from the husk of the red grape before it is fermented, the wine has little or no colour: these are called _white_ wines. If, on the contrary, the husks are allowed to remain in the must while the fermentation is going on, the alcohol dissolves the colouring matter of the husks, and the wine is coloured: such are called _red_ wines. Hence white wines are often prepared from red grapes, the liquor being drawn off before it has acquired the red colour; for the skin of the grape only gives the colour. Besides in these principal circumstances, wines vary much in flavour.

All wines contain one common and identical principle, from which their similar effects are produced; namely, _brandy_ or _alcohol_. It is especially by the different proportions of brandy contained in wines, that they differ most from one another. When wine is distilled, the alcohol readily separates. The spirit thus obtained is well known under the name of _brandy_.

All wines contain also a free acid; hence they turn blue tincture of cabbage, red. The acid found in the greatest abundance in grape wines, is tartaric acid. Every wine contains likewise a portion of super-tartrate of potash, and extractive matter, derived from the juice of the grape. These substances deposit slowly in the vessel in which they are kept. To this is owing the improvement of wine from age. Those wines which effervesce or froth, when poured into a glass, contain also carbonic acid, to which their briskness is owing. The peculiar flavour and odour of different kinds of wines probably depend upon the presence of a _volatile oil_, so small in quantity that it cannot be separated.