Part II.

INITIATORY ANALYSIS.

Qualitative analysis refers to those examinations which relate simply to the presence or the absence of certain substances, irrespective of their quantities. But before we take cognizance of special examinations, it would facilitate the progress of the student to pass through a course of Initiatory Exercises. These at once lead into the special analysis of all those substances susceptible of examination by the blowpipe. The Initiatory Analysis is best studied by adopting the following arrangement:

1. EXAMINATIONS WITH THE GLASS BULB.

The glass of which the bulb is made should be entirely free from lead, otherwise fictitious results will ensue. If the bulb be of flint glass, then by heating it, there is a slightly iridescent film caused upon the surface of the glass, which may easily be mistaken for arsenic. Besides, this kind of glass is easily fusible in the oxidating flame of the blowpipe, while, in the reducing flame, its ready decomposition would preclude its use entirely. The tube should be composed of the potash or hard Bohemian glass, should be perfectly white, and very thin, or the heat will crack it.

The tube should be perfectly clean, which can be easily attained by wrapping a clean cotton rag around a small stick, and inserting it in the tube. Before using the tube, see also that it is perfectly dry.

The quantity of the substance put into the tube for examination should be small. From one to three grains is quite sufficient, as a general rule, but circumstances vary the quantity. The sides of the tube should not catch any of the substance as it is being placed at the bottom of the tube, or into the bulb. If any of the powder, however, should adhere, it should be pushed down with a roll of clean paper, or the clean cotton rag referred to above.

In submitting the tube to the flame, it should be heated at first very gently, the heat being increased until the glass begins to soften, when the observations of what is ensuing within it may be made.

If the substance be of an organic nature, a peculiar empyreumatic odor will be given off. If the substance chars, then it may be inferred that it is of an organic nature. The matters which are given off and cause the empyreumatic odor, are a peculiar oil, ammonia, carbonic acid, acetic acid, water, cyanogen, and frequently other compounds. If a piece of paper is heated in the bulb, a dark colored oil condenses upon the sides of the tube, which has a strong empyreumatic odor. A piece of litmus paper indicates that this oil is acid, as it is quickly changed to red by contact with it. A black residue is now left in the tube, and upon examination we will find that it is charcoal. If, instead of the paper, a piece of animal substance is placed in the bulb, the reddened litmus paper will be converted into its original blue color, while charcoal will be left at the bottom of the tube.

A changing of the substance, however, to a dark color, should not be accepted as an invariable indication of charcoal, as some inorganic bodies thus change color, but the dark substance will not be likely to be mistaken for charcoal. By igniting the suspected substance with nitrate of potassa, it can quickly be ascertained whether it is organic or not, for if the latter, the vivid deflagration will indicate it.

If the substance contains water, it will condense upon the cold portion of the tube, and may be there examined as to whether it is acid or alkaline. If the former, the matter under examination is, perhaps, vegetable; if the latter, it is of an animal nature. The water may be that fluid absorbed, or it may form a portion of its constitution,

If the substance contain _sulphur_, the sublimate upon the cold part of the tube may be recognized by its characteristic appearance, especially if the substance should be a sulphide of tin, copper, antimony, or iron. The hyposulphites, and several other sulphides, also give off sulphur when heated. The volatile metals, mercury and arsenic, will, however, sublime without undergoing decomposition. As the sulphide of arsenic may be mistaken, from its color and appearance, for sulphur, it must be examined especially for the purpose of determining that point.

_Selenium_ will likewise sublime by heat as does sulphur. This is the case if selenides are present. Selenium gives off the smell of decayed horse-radish.

When the persalts are heated they are reduced to protosalts, with the elimination of a part of their acid. This will be indicated by the blue litmus paper.

If some of the neutral salts containing a volatile acid be present, they will become decomposed. For instance, the red nitrous acid water of the nitrates will indicate the decomposition of the salt, especially if it be the nitrate of a metallic oxide.

If there is an odor of sulphur, then it is quite probable, if no free sulphur be present, that a hyposulphite is decomposed.

If an oxalate be present, it is decomposed with the evolution of carbonic oxide, which may be inflamed at the mouth of the tube; but there are oxalates that give off carbonic acid gas, which, of course, will not burn. A cyanide will become decomposed and eliminate nitrogen gas, while the residue is charred. Some cyanides are, however, not thus decomposed, as the dry cyanides of the earths and alkalies.

There are several oxides of metals which will sublime, and may be thus examined in the tube. _Arsenious acid_ sublimes with great ease in minute octohedral crystals. The oxides of tellurium and antimony will sublime, the latter in minute glittering needles.

There are several metals which will sublime, and may be examined in the cold portion of the tube. _Mercury_ condenses upon the tube in minute globules. These often do not present the metallic appearance until they are disturbed with a glass rod, when they attract each other, and adhere as small globules. Place in the tube about a grain of red precipitate of the drug stores and apply heat, when the oxide will become decomposed, its oxygen will escape while the vaporized mercury will condense upon the cold portion of the tube, and may there be examined with a magnifying glass.

_Arsenic_, when vaporized, may be known by its peculiar alliaceous odor. Arsenic is vaporized from its metallic state, and likewise from its alloys. Several compounds which contain arsenic will also sublime, such as the arsenical cobalt. Place in the bulb a small piece of arsenical cobalt or "fly-stone," and apply heat. The sulphide of arsenic will first rise, but soon the arsenic will adhere to the sides of the tube.

The metals tellurium and cadmium are susceptible of solution, but the heat required is a high one. This is best done upon charcoal.

The _perchloride of mercury_ sublimes undecomposed in the bulb, previously undergoing fusion.

The _protochloride of mercury_ likewise sublimes, but it does not undergo fusion first, as is the case with the corrosive sublimate.

The _ammoniacal salts_ all are susceptible of sublimation, which they do without leaving a residue. There are, however, several which contain fixed acids, which latter are left in the bulb. This is particularly the case with the phosphates and borates. A piece of red litmus paper will readily detect the escaping ammonia, while its odor will indicate its presence with great certainty. The halogen compounds of mercury, we should have mentioned, also sublime, the red iodide giving a yellow sublimate.

The bulb is also a convenient little instrument for the purpose of heating those substances which phosphoresce, and likewise those salts that decrepitate.

Should the above reactions not be readily discerned, it should not be considered as an indication that the substances are not present, for they are frequently expelled in such combinations that the above reactions will not take place. This is often the case with sulphur, selenium, arsenic, and tellurium. It frequently happens, likewise, that these substances are in such combinations that heat alone will not sublime them; or else two or more of them may arise together, and thus complicate the sublimate, so that the eye cannot readily detect either substance. Sometimes sulphur and arsenic will coat the tube with a metal-like appearance, which is deceptive. This coating presents a metallic lustre at its lower portion, but changing, as it progresses upward, to a dark brown, light brown, orange or yellow; this sublimate being due to combinations of arsenic and sulphur, which compounds are volatilized at a lower temperature than metallic arsenic.

If certain reagents are mixed with many substances, changes are effected which would not ensue with heat alone. _Formiate of soda_ possesses the property of readily reducing metallic oxides. When this salt is heated, it gives off a quantity of carbonic oxide gas. This gas, when in the presence of a metallic oxide, easily reduces the metal, by withdrawing its oxygen from it, and being changed into carbonic oxide. If a little fly-stone is mixed with some formiate of soda, and heated in the bulb, the arsenic is reduced, volatilized, and condenses in the cool portion of the tube. By this method, the smallest portion of a grain of the arsenical compound may be thus examined with the greatest readiness. If the residue is now washed, by which the soda is got rid of, the metallic arsenic may be obtained in small spangles. If the compound examined be the sulphide of antimony, the one-thousandth part can be readily detected, and hence this method is admirably adapted to the examination of medicinal antimonial compounds. The arsenites of silver and copper are reduced by the formiate of soda to their metals, mixed with metallic arsenic. The mercurial salts are all reduced with the metal plainly visible as a bright silvery ring on the cool portion of the tube. The chloride and nitrate of silver are completely reduced, and may be obtained after working out the soda, as bright metallic spangles. The salts of antimony and zinc are thus reduced; also the sulphate of cadmium. The sublimate of the latter, although in appearance not unlike that of arsenic, can easily be distinguished by its brighter color. It is, in fact, the rich yellow of this sublimate which has led artists to adopt it as one of their most valued pigments.

2. EXAMINATIONS IN THE OPEN TUBE.

The substance to be operated upon should be placed in the tube, about half an inch from the end, and the flame applied at first very cautiously, increasing gradually to the required temperature. The tube, in all these _roasting_ operations, as they are termed, should be held in an inclined position. The nearer perpendicular the tube is held, the stronger is the draught of air that passes through it. If but little heat is required in the open tube operation, the spirit-lamp is the best method of applying the heat. But if a greater temperature is required, then recourse must be had to the blowpipe. Upon the angle of inclination of the tube depends the amount of air that passes through it, and therefore, the rapidity of the draught may be easily regulated at the will of the operator. The inclination of the tube may, as a general rule, be about the angle represented in Fig. 14.

The length of the tube must be about six inches, so that the portion upon which the substance rested in a previous examination may be cut off. The portion of the tube left will answer for several similar operations.

When the substance is under examination, we should devote our attention to the nature of the sublimates, and to that of the _odors_ of the gases. If sulphur be in the substance experimented upon, the characteristic odor of sulphurous acid gas will readily indicate the sulphur. If metallic sulphides, for instance, are experimented upon, the sulphurous acid gas eliminated will readily reveal their presence. As it is a property of this gas to bleach, a piece of Brazil-wood test paper should be held in the mouth of the tube, when its loss of color will indicate the presence of the sulphurous acid. It often happens, too, that a slight deposition of sulphur will be observed upon the cool portion of the tube. This is particularly the case with those sulphides, which yield sublimates of sulphur when heated in the bulb.

_Selenium_ undergoes but slight oxidation, but it becomes readily volatilized, and may be observed on the cool portion of the tube. At the same time the nose, if applied close to the end of the tube, will detect the characteristic odor of rotten horse-radish. Arsenic also gives its peculiar alliaceous odor, which is so characteristic that it can be easily detected. A few of the arsenides produce this odor. The _sublimates_ should be carefully observed, as they indicate often with great certainty the presence of certain substances; for instance, that of arsenic. The sublimate, in this case, presents itself as the arsenious acid, or the metallic arsenic itself. If it be the former, it may be discerned by aid of the magnifying glass as beautiful glittering octohedral crystals. If the latter, the metallic lustre will reveal it.

But it will be observed that while some of the arsenides are sublimed at a comparatively low temperature, others require a very high one.

_Antimony_ gives a white sublimate when its salts are roasted, as the sulphide, or the antimonides themselves, or the oxide of this metal. This white sublimate is not antimonious acid, but there is mixed with it the oxide of antimony with which the acid is sublimed. As is the case with arsenious acid, the antimonious acid may, by dexterous heating, be driven from one portion of the tube to another.

_Tellurium_, or its acid and oxide, may be got as a sublimate in the tube. The tellurious acid, unlike the arsenious and antimonious acids, cannot be driven from one portion of the tube to another, but, on the contrary, it fuses into small clear globules, visible to the naked eye sometimes, but quite so with the aid of the magnifying glass.

_Lead_, or its chloride, sublimes like tellurium, and, like that substance, fuses into globules or drops.

_Bismuth_, or its sulphide, sublimes into an orange or brownish globules, when it is melted, as directed above, for tellurium. The color of the bismuth and lead oxides are somewhat similar, although that of the latter is paler.

If any mineral containing _fluorine_, is fused, first with the microcosmic salt bead, then put into the tube, and the flame of the blowpipe be directed _into_ the tube upon the bead, hydrofluoric acid is disengaged and attacks the inside of the tube. The fluoride of calcium, or fluorspar, may be used for this experiment.

During the roasting, a brisk current of air should be allowed to pass through the tube, whereby unoxidized matter may be prevented from volatilization, and the clogging up of the substance under examination be prevented.

3. EXAMINATIONS UPON CHARCOAL.

In making examinations upon charcoal, it is quite necessary that the student should make himself familiar with the different and characteristic appearances of the deposits upon the charcoal. In this case I have found the advice given by Dr. Sherer to be the best; that is, to begin with the examination of the pure materials first, until the eye becomes familiarized with the appearances of their incrustations upon charcoal.

The greater part of the metals fuse when submitted to the heat of the blowpipe, and if exposed to the outer flame, they oxidize. These metals, termed the noble metals, do not oxidize, but they fuse. The metals platinum, iridium, rhodium, osmium and palladium do not fuse. The metal osmium, if exposed to the flame of oxidation, fuses and is finally dissipated as osmic acid. In the latter flame, the salts of the noble metals are reduced to the metallic state, and the charcoal is covered with the bright metal.

We shall give a brief description of the appearance of the principal elementary bodies upon being fused with charcoal. This plan is that deemed the most conducive to the progress of the student, by Berzelius, Plattner, and Sherer. Experience has taught us that this method is the most efficient that could have been devised as an initiatory exercise for the student, ere he commences a more concise and methodical method of analysis. In these reactions upon charcoal, we shall follow nearly the language of Plattner and Sherer.

SELENIUM is not difficult of fusion, and gives off brown fumes in either the oxidation or reduction flame. The deposit upon the charcoal is of a steel-grey color, with a slightly metallic lustre. The deposit however that fuses outside of this steel-grey one is of a dull violet color, shading off to a light brown. Under the flame of oxidation this deposit is easily driven from one portion of the charcoal to another, while the application of the reducing flame volatilizes it with the evolution of a beautiful blue light. The characteristic odor of decayed horse-radish distinguishes the volatilization of this metal.

TELLURIUM.--This metal fuses with the greatest readiness, and is reduced to vapor under both flames with fumes, and coats the charcoal with a deposit of tellurous acid. This deposit is white near the centre, and is of a dark yellow near the edges. It may be driven from place to place by the flame of oxidation, while that of reduction volatilizes it with a green flame. If there be a mixture of selenium present, then the color of the flame is bluish-green.

ARSENIC.--This metal is volatilized without fusing, and covers the charcoal both in the oxidizing and reducing flames with a deposit of arsenious acid. This coating is white in the centre, and grey towards the edges, and is found some distance from the assay. By the most gentle application of the flame, it is immediately volatilized, and if touched for a moment with the reducing flame, it disappears, tinging the flame pale blue. During volatilization a strong garlic odor is distinctly perceptible, very characteristic of arsenic, and by which its presence in any compound may be immediately recognized.

ANTIMONY.--This metal fuses readily, and coats the charcoal under both flames with antimonious acid. This incrustation is of a white color where thick, but of a bluish tint where it is thin, and is found nearer to the assay than that of arsenic. When greatly heated by the flame of oxidation, it is driven from place to place without coloring the flame, but when volatilized by the flame of reduction, it tinges the flame blue. As antimonious acid is not so volatile as arsenious acid, they may thus be easily distinguished from one another.

When metallic antimony is fused upon charcoal, and the metallic bead raised to a red heat, if the blast be suspended, the fluid bead remains for some time at this temperature, giving off opaque white fumes, which are at first deposited on the surrounding charcoal, and then upon the bead itself, covering it with white, pearly crystals. The phenomenon is dependent upon the fact, that the heated button of antimony, in absorbing oxygen from the air, developes sufficient heat to maintain the metal in a fluid state, until it becomes entirely covered with crystals of antimonious acid so formed.

BISMUTH.--This metal fuses with ease, and under both flames covers the charcoal with a coating of oxide, which, while hot, is of an orange-yellow color, and after cooling, of a lemon-yellow color, passing, at the edges, into a bluish white. This white coating consists of the carbonate of bismuth. The sublimate from bismuth is formed at a less distance from the assay than is the case with antimony. It may be driven from place to place by the application of either flame; but in so doing, the oxide is first reduced by the heated charcoal, and the metallic bismuth so formed is volatilized and reoxidized. The flame is uncolored.

LEAD.--This metal readily fuses under either flame, and incrusts the charcoal with oxide at about the same distance from the assay as is the case with bismuth. The oxide is, while hot, of a dark lemon-yellow color, but upon cooling, becomes of a sulphur yellow. The carbonate which is formed upon the charcoal, beyond the oxide, is of a bluish-white color. If the yellow incrustation of the oxide be heated with the flame of oxidation, it disappears, undergoing changes similar to those of bismuth above mentioned. Under the flame of reduction, it, however, disappears, tinging the flame blue.

CADMIUM.--This metal fuses with ease, and, in the flame of oxidation, takes fire, and burns with a deep yellow color, giving off brown fumes, which coat the charcoal, to within a small distance of the assay, with oxide of cadmium. This coating exhibits its characteristic reddish-brown color most clearly when cold. Where the coating is very thin, it passes to an orange color. As oxide of cadmium is easily reduced, and the metal very volatile, the coating of oxide may be driven from place to place by the application of either flame, to neither of which does it impart any color. Around the deposit of oxide, the charcoal has occasionally a variegated tarnish.

ZINC.--This metal fuses with ease, and takes fire in the flame of oxidation, burning with a brilliant greenish-white light, and forming thick white fumes of oxide of zinc, which coat the charcoal round the assay. This coating is yellow while hot, but when perfectly cooled, becomes white. If heated with the flame of oxidation, it shines brilliantly, but is not volatilized, since the heated charcoal is, under these circumstances, insufficient to effect its reduction. Even under the reducing flame, it disappears very slowly.

TIN.--This metal fuses readily, and, in the flame of oxidation, becomes covered with oxide, which, by a strong blast, may be easily blown off. In the reducing flame, the fused metal assumes a white surface, and the charcoal becomes covered with oxide. This oxide is of a pale yellow color while hot, and is quite brilliant when the flame of oxidation is directed upon it. After cooling, it becomes white. It is found immediately around the assay, and cannot be volatilized by the application of either flame.

MOLYBDENUM.--This metal, in powder, is infusible before the blowpipe. If heated in the outer flame, it becomes gradually oxidized, and incrusts the charcoal, at a small distance from the assay, with molybdic acid, which, near the assay, forms transparent crystalline scales, and is elsewhere deposited as a fine powder. The incrustation, while hot, is of a yellow color, but becomes white after cooling. It may be volatilized by heating with either flame, and leaves the surface of the charcoal, when perfectly cooled, of a dark-red copper color, with a metallic lustre, due to the oxide of molybdenum, which has been formed by the reducing action of the charcoal upon the molybdic acid. In the reducing flame, metallic molybdenum remains unchanged.

SILVER.--This metal, when fused alone, and kept in this state for some time, under a strong oxidizing flame, covers the charcoal with a thin film of dark reddish-brown oxide. If the silver be alloyed with lead, a yellow incrustation of the oxide of that metal is first formed, and afterwards, as the silver becomes more pure, a dark red deposit is formed on the charcoal beyond. If the silver contains a small quantity of antimony, a white incrustation of antimonious acid is formed, which becomes red on the surface if the blast be continued. And if lead and antimony are both present in the silver, after the greater part of these metals have been volatilized, a beautiful crimson incrustation is produced upon the charcoal. This result is sometimes obtained in fusing rich silver ores on charcoal.

SULPHIDES, CHLORIDES, IODIDES, AND BROMIDES.

In blowpipe experiments, it rarely occurs that we have to deal with pure metals, which, if not absolutely non-volatile, are recognized by the incrustation they form upon charcoal. Some compound substances, when heated upon charcoal, form white incrustations, resembling that formed by antimony, and which, when heated, may, in like manner, be driven from place to place. Among these are certain sulphides, as sulphide of potassium, and sulphide of sodium, which are formed by the action of the reducing flame upon the sulphates of potassa and soda, and are, when volatilized, reconverted into those sulphates, and as such deposited on the charcoal. No incrustation is, however, formed, until the whole of the alkaline sulphate has been absorbed into the charcoal, and has parted with its oxygen. As sulphide of potassium is more volatile than sulphide of sodium, an incrustation is formed from the former sooner than from the latter of these salts, and is considerably thicker in the former case. If the potash incrustation be touched with the reducing flame, it disappears with a violet-colored flame; and if a soda incrustation be treated in like manner, an orange-yellow flame is produced.

Sulphide of lithium, formed by heating the sulphate in the reducing flame, is volatilized in similar manner by a strong blast, although less readily than the sulphide of sodium. It affords a greyish white film, which disappears with a crimson flame when submitted to the reducing flame.

Besides the above, the sulphides of bismuth and lead give, when heated in either flame, two different incrustations, of which the more volatile is of a white color, and consists in the one case of sulphate of lead, and in the other of sulphate of bismuth. If either of these be heated under the reducing flame, it disappears in the former case with a bluish flame, in the latter unaccompanied by any visible flame. The incrustation formed nearest to the assay consists of the oxide of lead or bismuth, and is easily recognized by its color when hot and after cooling. There are many other metallic sulphides, which, when heated by the blowpipe flame, cover the charcoal with a white incrustation, as sulphide of antimony, sulphide of zinc, and sulphide of tin. In all these cases, however, the incrustation consists of the metallic oxide alone, and either volatilizes or remains unchanged, when submitted to the oxidizing flame.

Of the metallic chlorides there are many which, when heated on charcoal with the blowpipe flame, are volatilized and redeposited as a white incrustation. Among these are the chlorides of potassium, sodium, and lithium, which volatilize and cover the charcoal immediately around the assay with a thin white film, after they have been fused and absorbed into the charcoal, chloride of potassium forms the thickest deposit, and chloride of lithium the thinnest, the latter being moreover of a greyish-white color. The chlorides of ammonium, mercury, and antimony volatilize without fusing.

The chlorides of zinc, cadmium, lead, bismuth, and tin first fuse and then cover the charcoal with two different incrustations, one of which is a white volatile chloride, and the other a less volatile oxide of the metal.

Some of the incrustations formed by metallic chlorides disappear with a colored flame when heated with the reducing flame; thus chloride of potassium affords a violet flame, chloride of sodium an orange one, chloride of lithium a crimson flame, and chloride of lead a blue one. The other metals mentioned above volatilize without coloring the flame.

The chloride of copper fuses and colors the flame of a beautiful blue. Moreover, if a continuous blast be directed upon the salt, a part of it is driven off in the form of white fumes which smell strongly of chlorine, and the charcoal is covered with incrustations of three different colors. That which is formed nearest to the assay is of a dark grey color, the next, a dark yellow passing into brown, and the most distant of a bluish white color. If this incrustation be heated under the reducing flame, it disappears with a blue flame.

Metallic iodides and bromides behave upon charcoal in a similar manner to the chlorides. Those principally deserving of mention are the bromides and iodides of potassium and sodium. These fuse upon charcoal, are absorbed into its pores, and volatilize in the form of white fumes, which are deposited upon the charcoal at some distance from the assay. When the saline films so formed are submitted to the reducing flame, they disappear, coloring the flame in the same manner as the corresponding chlorides.

4. EXAMINATIONS IN THE PLATINUM FORCEPS.

Before the student attempts to make an examination in the platinum forceps or tongs, he should first ascertain whether or not it will act upon the platinum. If the substance to be examined shall act chemically upon the platinum, then it should be examined on the charcoal, and the color of the flame ascertained as rigidly as possible. The following list of substances produce the color attached to them.

A. VIOLET.

Potash, and all its compounds, with the exception of the phosphate and the borate, tinge the color of the flame violet.

B. BLUE.

Chloride of copper, Intense blue. Lead, Pale clear blue. Bromide of copper, Bluish green. Antimony, Bluish green. Selenium, Blue. Arsenic, English green.

C. GREEN.

Ammonia, Dark green. Boracic acid, Dark green. Copper, Dark green. Tellurium, Dark green. Zinc, Light green. Baryta Apple green. Phosphoric acid, Pale green. Molybdic acid, Apple green. Telluric acid, Light green.

D. YELLOW.

Soda, Intense yellow. Water, Feeble yellow.

E. RED.

Strontia, Intense crimson. Lithia, Purplish red. Potash, Violet red. Lime, Purplish red.

The student may often be deceived in regard to the colors: for instance, if a small splinter of almost any mineral be held at the point of the flame of oxidation, it will impart a very slight yellow to the flame. This is caused, doubtless, by the water contained in the mineral. If the piece of platinum wire is used, and it should be wet with the saliva, as is frequently done by the student, then the small quantity of soda existing in that fluid will color the flame of a light yellow hue.

A. THE VIOLET COLOR.

The salts of potash, with the exception of the borate and the phosphate, color the flame of a rich violet hue. This color is best discovered in the outer flame of the blowpipe, as is the case with all the other colors. The flame should be a small one, with a lamp having a small wick, while the orifice of the blowpipe must be quite small. These experiments should likewise be made in a dark room, so that the colors may be discerned with the greatest ease. In investigating with potash for the discernment of color, it should be borne in mind that the least quantity of soda will entirely destroy the violet color of the potash, by the substitution of its own strong yellow color. If there be not more than the two hundredth part of soda, the violet reaction of the potash will be destroyed. This is likewise the case with the presence of lithia, for its peculiar red color will destroy the violet of the potash. Therefore in making investigations with the silicates which contain potash, the violet color of the latter can only be discerned when they are free from soda and lithia.

B. THE BLUE COLOR.

(_a._) _The Chloride of Copper._--Any of the chlorides produce a blue color in the blowpipe flame, or any salt which contains chlorine will show the blue tint, as the color in this case is referable to the chlorine itself. There are, however, some chlorides which, in consequence of the peculiar reactions of their bases, will not produce the blue color, although in these cases the blue of the chlorine will be very likely to blend itself with the color produced by the base. The chloride of copper communicates an intense blue to the flame, when fused on the platinum wire. If the heat be continued until the chlorine is driven off, then the greenish hue of the oxide of copper will be discerned.

(_b._) _Lead._--Metallic lead communicates to the flame a pale blue color. The oxide reacts in the same manner. The lead-salts, whose acids do not interfere with the color, impart also a fine blue to the flame, either in the platina forceps, or the crooked wire.

(_c._) _Bromide of Copper._--This salt colors the flame of a bluish-green color, but when the bromine is driven off, then we have the green of the oxide of copper.

(_d._) _Antimony._--This metal imparts a blue color to the blowpipe flame, but if the metal is in too small a quantity, then the color is a brilliant white. If antimony is fused on charcoal, the fused metal gives a blue color. The white sublimate which surrounds the fused metal, being subjected to the flame of oxidation, disappears from the charcoal with a bluish-green color.

(_e._) _Selenium._--If fused in the flame of oxidation, it imparts to the flame a deep blue color. The incrustation upon charcoal gives to the flame the same rich color.

(_f._) _Arsenic._--The arseniates and metallic arsenic itself impart to the blowpipe flame a fine blue color, provided that there is no other body present which may have a tendency to color the flame with its characteristic hue. The sublimate of arsenious acid which surrounds the assay, will give the same blue flame, when dissipated by the oxidation flame. The platinum forceps will answer for the exhibition of the color of arsenic, even though the salts be arseniates, whose bases possess the property of imparting their peculiar color to the flame, such as the arseniate of lime.

C. THE GREEN COLOR.

(_a._) _Ammonia._--The salts of ammonia, when heated before the blowpipe, and just upon the point of disappearing, impart to the flame a feeble though dark green color. This color, however, can only be discerned in a dark room.

(_b._) _Boracic Acid._--If any one of the borates is mixed with two parts of a flux composed of one part of pulverized fluorspar, and four and a half parts of bisulphate of potash, and after being melted, is put upon the coil of a platinum wire, and held at the point of the blue flame, soon after fusion takes place a dark green color is discerned, but it is not of long duration. The above process is that recommended by Dr. Turner. The green color of the borates may be readily seen by dipping them, previously moistened with sulphuric acid, into the upper part of the blue flame, when the color can be readily discerned. If soda be present, then the rich green of the boracic acid is marred by the yellow of the soda. Borax, or the biborate of soda (NaO, 2BO_{3}) may be used for this latter reaction, but if it be moistened with sulphuric acid, the green of the boracic acid can then be seen. If the borates, or minerals which contain boracic acid, are fused on charcoal with carbonate of potash, then moistened with sulphuric acid and alcohol, then the bright green of the boracic acid is produced, even if the mineral contains but a minute portion of the boracic acid.

(_c._) _Copper_. Nearly all the ores of copper and its salts, give a bright green color to the blowpipe flame. Metallic copper likewise colors the flame green, being first oxidized. If iodine, chlorine, and bromine are present, the flame is considerably modified, but the former at least intensifies the color. Many ores containing copper also color the flame green, but the internal portion is of a bright blue color if the compound contains lead, the latter color being due to the lead. The native sulphide and carbonate of copper should be moistened with sulphuric acid, while the former should be previously roasted. If hydrochloric acid is used for moistening the salts, then the rich green given by that moistened with the sulphuric acid is changed to a blue, being thus modified by the chlorine of the acid. Silicates containing copper, if heated in the flame in the platinum forceps, impart a rich green color to the outer flame. In fact, if any substance containing copper be submitted to the blowpipe flame, it will tinge it green, provided there be no other substance present to impart its own color to the flame, and thus modify or mar that of the copper.

(_d._) _Tellurium._--If the flame of reduction is directed upon the oxide of tellurium placed upon charcoal, a green color is imparted to it. If the telluric acid be placed upon platinum wire in the reduction flame, the oxidation flame is colored green. Or if the sublimate be dissipated by the flame of oxidation, it gives a green color. If selenium be present, the green color is changed to a blue.

(_e._) _Zinc._--The oxide of zinc, when strongly heated, gives a blue flame. This is especially the case in the reducing flame. The flame is a small one, however, and not very characteristic, as with certain preparations of zinc the blue color is changed to a bright white. The soluble salts of zinc give no blue color.

(_f._) _Baryta._--The soluble salts of baryta, moistened, and then submitted to the reduction flame, produce a green color. The salt should be moistened, when the color will be strongly marked in the outer flame. The insoluble salts do not produce so vivid a color as the soluble salts, and they are brighter when they have previously been moistened. The carbonate does not give a strong color, but the acetate does, so long as it is not allowed to turn to a carbonate. The chloride, when fused on the platinum wire, in the point of the reduction flame, imparts a fine green color to the oxidation flame. This tint changes finally to a faint dirty green color. The sulphate of baryta colors the flame green when heated at the point of the reduction flame. But neither the sulphate, carbonate, nor, in fact, any other salt of baryta, gives such a fine green color as the chloride. The presence of lime does interfere with the reaction of baryta, but still does not destroy its color.

(_g._) _Phosphoric Acid._--The phosphates give a green color to the oxidation flame, especially when they are moistened with sulphuric acid. This is best shown with the platinum forceps. The green of phosphoric, or the phosphates, is much less intense than that of the borates or boracic acid, but yet the reaction is a certain one, and is susceptible of considerable delicacy, either with the forceps, or still better upon platinum wire. Sulphuric acid is a great aid to the development of the color, especially if other salts be present which would be liable to hide the color of the phosphoric acid. In this reaction with phosphates, the water should be expelled from them previous to melting them with sulphuric acid. They should likewise be pulverized. Should soda be present it will only exhibit its peculiar color after the phosphoric acid shall have been expelled; therefore, the green color of the phosphoric acid should be looked for immediately upon submitting the phosphate to heat.

(_h._) _Molybdic Acid._--If this acid or the oxide of molybdenum be exposed upon a platinum wire to the point of the reduction flame, a bright green color is communicated to the flame of oxidation. Take a small piece of the native sulphide of molybdenum, and expose it in the platinum tongs to the flame referred to above, when the green color characteristic of this metal will be exhibited.

(_i._) _Telluric Acid._--If the flame of reduction is directed upon a small piece of the oxide of tellurium placed upon charcoal, a bright green color is produced. Or if telluric acid be submitted to the reduction flame upon the loop of a platinum wire, it communicates to the outer flame the bright green of tellurium. If the sublimate found upon the charcoal in the first experiment be submitted to the blowpipe flame, the green color of tellurium is produced while the sublimate is volatilized. If selenium be present the green color is changed to a deep blue one.

D. YELLOW.

The salts of soda all give a bright yellow color when heated in the platinum loop in the reduction flame. This color is very persistent, and will destroy the color of almost any other substance. Every mineral of which soda is a constituent, give this bright orange-yellow reaction. Even the silicate of soda itself imparts to the flame of oxidation the characteristic yellow of soda.

E. RED.

(_a._) _Strontia._--Moisten a small piece of the chloride of strontium, put it in the platinum forceps and submit it to the flame of reduction, when the outer flame will become colored of an intense red. If the salt of strontia should be a soluble one, the reaction is of a deeper color than if an insoluble salt is used, while the color is of a deeper crimson if the salt is moistened. If the salt be a soluble one, it should be moistened and dipped into the flame, while if it be an insoluble salt, it should be kept dry and exposed beyond the point of the flame. The carbonate of strontia should be moistened with hydrochloric acid instead of water, by which its color similates that of the chloride of strontium when moistened with water. In consequence of the decided red color which strontia communicates to flame, it is used by pyrotechnists for the purpose of making their "crimson fire."

(_b._) _Lithia._--The color of the flame of lithia is slightly inclined to purple. The chloride, when placed in the platinum loop, gives to the outer flame a bright red color, sometimes with a slight tinge of purple. Potash does not prevent this reaction, although it may modify it to violet; but the decided color of soda changes the red of lithia to an orange color. If much soda be present, the color of the lithia is lost entirely. The color of the chloride of lithium may be distinctly produced before the point of the blue flame, and its durability may be the means of determining it from that of lithium, as the latter, under the same conditions, is quite evanescent. The minerals which contain lithia, frequently contain soda, and thus the latter destroys the color of the former.

(_c._) _Potash._--The salts of potash, if the acid does not interfere, give a purplish-red color before the blowpipe; but as the color is more discernibly a purple, we have classed it under that color.

(_d._) _Lime._--The color of the flame of lime does not greatly differ from that of strontia, with the exception that it is not so decided. Arragonite and calcareous spar, moistened with hydrochloric acid, and tried as directed for strontia, produce a red light, not unlike that of strontia. The chloride of calcium gives a red tinge, but not nearly so decided as the chloride of strontium. The carbonate of lime will produce a yellowish flame for a while, until the carbonic acid is driven off, when the red color of the lime may be discerned.

If the borate or phosphate of lime be used, the green color of the acids predominates over the red of the lime. Baryta also destroys the red color of the lime, by mixing its green color with it. There is but one silicate of lime which colors the flame red, it is the variety termed tabular spar.

5. EXAMINATIONS IN THE BORAX BEAD.

In order to examine a substance in borax, the loop of the platinum wire should, after being thoroughly cleaned, and heated to redness, be quickly dipped into the powdered borax, and then quickly transferred to the flame of oxidation, and there fused. If the bead is not large enough to fill the loop of the wire, it must be subjected again to the same process. By examining the bead, both when hot and cold, by holding it up against the light, it can be soon ascertained whether it is free from dirt by the transparency, or the want of it, of the bead.

In order to make the examination of a substance, the bead should be melted and pressed against it, when enough will adhere to answer the purpose. This powder should then be fused in the oxidation flame until it mixes with, and is thoroughly dissolved by the borax bead.

The principal objects to be determined now are: the color of the borax bead, both when heated and when cooled; also the rapidity with which the substance dissolves in the bead, and if any gas is eliminated.

If the color of the bead is the object desired, the quantity of the substance employed must be very small, else the bead will be so deeply colored, as in some cases to appear almost opaque, as, for instance, in that of cobalt. Should this be the case, then, while the bead is still red hot, it should be pressed flat with the forceps; or it may, while soft, be pulled out to a thin thread, whereby the color can be distinctly discovered.

Some bodies, when heated in the borax bead, present a clear bead both while hot and cold; but if the bead be heated with the intermittent flame, or in the flame of reduction, it becomes opalescent, opaque or milk-white. The alkaline earths are instances of this kind of reaction, also glucina oxide of cerium, tantalic and titanic acids, yttria and zirconia. But if a small portion of silica should be present, then the bead becomes clear. This is likewise the case with some silicates, provided there be not too large a quantity present, that is: over the quantity necessary to saturate the borax, for, in that case, the bead will be opaque when cool.

If the bead be heated on charcoal, a small tube or cavity must be scooped out of the charcoal, the bead placed in it, and the flame of reduction played upon it. When the bead is perfectly fused, it is taken up between the platinum forceps and pressed flat, so that the color may be the more readily discerned. This quick cooling also prevents the protoxides, if there be any present, from passing into a higher degree of oxidation.

The bead should first be submitted to the oxidation flame, and any reaction carefully observed. Then the bead should be submitted to the flame of reduction. It must be observed that the platinum forceps should not be used when there is danger of a metallic oxide being reduced, as in this case the metal would alloy with the platinum and spoil the forceps. In this case charcoal should be used for the support. If, however, there be oxides present which are not reduced by the borax, then the platinum loop may be used. Tin is frequently used for the purpose of enabling the bead to acquire a color for an oxide in the reducing flame, by its affinity for oxygen. The oxide, thus being reduced to a lower degree of oxidation, imparts its peculiar tinge to the bead as it cools.

The arsenides and sulphides, before being examined, should be roasted, and then heated with the borax bead. The arsenic of the former, it should be observed, will act on the glass tube in which the sublimation is proceeding, if the glass should contain lead.

It should be recollected that earths, metallic oxides, and metallic acids are soluble in borax, except those of the easily reducible metals, such as platinum or gold, or of mercury, which too readily vaporize. Also the metallic sulphides, after the sulphur has been driven off. Also the salts of metals, after their acids are driven off by heat. Also the nitrates and carbonates, after their acids are driven off during the fusion. Also the salts of the halogens, such as the chlorides, iodides, bromides, etc., of the metals. Also the silicates, but with great tardiness. Also the phosphates and borates that fuse in the bead without suffering decomposition. The metallic sulphides are insoluble in borax, and many of the metals in the pure state.

There are many substances which give clear beads with borax both while hot and cold, but which, upon being heated with the intermittent oxidation flame, become enamelled and opaque. The intermittent flame may be readily attained, not by varying the force of the air from the mouth, but by raising and depressing the bead before the point of the steady oxidating flame. The addition of a little nitrate of potash will often greatly facilitate the production of a color, as it oxidizes the metal. The hot bead should be pressed upon a small crystal of the nitrate, when the bead swells, intumesces, and the color is manifested in the surface of the bead,

6. EXAMINATIONS IN MICROCOSMIC SALT.

Microcosmic salt is a better flux for many metallic oxides than borax, as the colors are exhibited in it with more strength and character. Microcosmic salt is the phosphate of soda and ammonia. When it is ignited it passes into the biphosphate of soda, the ammonia being driven off. This biphosphate of soda possesses an excess of phosphoric acid, and thus has the property of dissolving a great number of substances, in fact almost any one, with the exception of silica. If the substances treated with this salt consist of sulphides or arsenides, the bead must be heated on charcoal. But if the substance experimented upon consists of earthly ingredients or metallic oxides, the platinum wire is the best. If the latter is used a few additional turns should be given to the wire in consequence of the greater fluidity of the bead over that of borax. The microcosmic salt bead possesses the advantage over that of borax, that the colors of many substances are better discerned in it, and that it separates the acids, the more volatile ones being dissipated, while the fixed ones combine with a portion of the base equally with the phosphoric acid, or else do not combine at all, but float about in the bead, as is the case particularly with silicic acid. Many of the silicates give with borax a clear bead, while they form with microcosmic salt an opalescent one.

It frequently happens, that if a metallic oxide will not give its peculiar color in one of the flames, that it will in the other, as the difference in degree with which the metal is oxidized often determines the color. If the bead is heated in the reducing flame, it is well that it should be cooled rapidly to prevent a reoxidation. Reduction is much facilitated by the employment of metallic tin, whereby the protoxide or the reduced metal may be obtained in a comparatively brief time.

The following tables, taken from Plattner and Sherer, will present the reactions of the metallic oxides, and some of the metallic acids, in such a clear light, that the student cannot very easily be led astray, if he gives the least attention to them. It frequently happens that a tabular statement of reactions will impress facts upon the memory when long detailed descriptions will fail to do so. It is for this purpose that we subjoin the following excellent tables.

* * * * *

TABLE I.

A. BORAX. 1. Oxydizing flame. 2. Reducing "

B. MICROCOSMIC SALT. 1. Oxydizing flame. 2. Reducing "

A. BORAX

1. Oxydizing flame

Color of Bead. --+----------------------------------------------------------------------- | Substances which produce this color +--------------------------------------+-------------------------------- | in the hot bead. | in the cold bead. --+--------------------------------------+-------------------------------- Colorless -----------------------------------------+-------------------------------- | Silica \ | Silica | Alumina \ | Alumina _ | Oxide of Tin | | Oxide of Tin \ | Telluric Acid | | Telluric Acid \ | Baryta | | Baryta \ | Strontia | | Strontia | | Lime | | Lime | | Magnesia | | Magnesia | | Glucina | In all | Glucina | | Yttria } proportions. | Yttria | | Zirconia | | Zirconia | | Thoria | | Thoria |With | Oxide of Lanthanum | | Oxide of Lanthanum |intermittent | | | " " Silver }flame | Tantalic Acid | | Tantalic Acid |opaque | Niobic " | | Niobic " |white. | Pelopic " / | Pelopic " | | Titanic " _/ | Titanic " | | _ | | | Tungstic " \ In small | Tungstic " | | Molybdic " \ quantity | Molybdic " | | Oxide of Zinc | only. | Oxide of Zinc / | " " Cadmium } | " " Cadmium_/ | " " Lead | In large | " " Lead | " " Bismuth / quantity | " " Bismuth | " " Antimony / yellow. | " " Antimony --+-----------+--------------------------+-------------------------------- Yellow, orange-red and reddish-brown. --+-----------+--------------------------+-------------------------------- | _ | | Titanic Acid, yellow \ | | Tungstic Acid, yellow \ | | Molybdic Acid, dark yellow|when in | | Oxide of Zinc, pale-yellow|large | | Oxide of Cadmium, }quantity. | | pale-yellow |Otherwise | | Oxide of Lead, yellow |colorless.| | Oxide of Bismuth, orange / | | Oxide of Antimony, yellow/ | | Oxide of Cerium, red | Oxide of Cerium with interm. | Oxide of Iron, dark red | flame opaque white. | Oxide of Uranium, red | Oxide of Iron, yellow | Oxide of Silver | Oxide of Uranium with interm. | | flame opaque yellow. | | Oxide of Silver in large | | proportion, with interm. | | flame yellow. | Vanadic Acid, yellow | Vanadic Acid, yellow. | Oxide of Chromium, dark-red | Oxide of Nickel, | | reddish-brown. | | Oxide of Manganese, red to | | violet. --+--------------------------------------+-------------------------------- Violet or Amethyst. --+--------------------------------------+-------------------------------- | Oxide of Nickel | | " " Manganese | Oxide of Didymium. | " " Didymium | --+--------------------------------------+-------------------------------- Blue. --+--------------------------------------+-------------------------------- | Oxide of Cobalt | Oxide of Cobalt. | | " Copper, blue to | | greenish-blue. --+--------------------------------------+-------------------------------- Green. --+--------------------------------------+-------------------------------- | Oxide of Copper | Oxide of Chromium, with | | yellowish tinge. --+--------------------------------------+--------------------------------

A. BORAX

2. Reducing flame

--+--------------------------------------+-------------------------------- Color of Bead. --+----------------------------------------------------------------------- | Substances which produce this color +--------------------------------------+-------------------------------- | in the hot bead. | in the cold bead. --+--------------------------------------+-------------------------------- Colorless --+--------------------------------------+-------------------------------- | Silica | Silica | Alumina | Alumina | Oxide of Tin | Oxide of Tin _ | Baryta | Baryta \ | Strontia | Strontia \ | Lime | Lime | | Magnesia | Magnesia |With | Glucina | Glucina |intermittent | Yttria | Yttria }flame | Zirconia | Zirconia |opaque-white. | Thoria | Thoria only when | | | saturated | | Oxide of Lanthanum | Oxide of Lanthanum | | " " Cerium | " " Cerium / | Tantalic Acid | Tantalic Acid _/ | Oxide of Didymium | Oxide of Didymium | " " Manganese | " " Manganese | _ | _ | Niobic Acid \ In small | Niobic Acid \ In small | Pelopic " } proportions. | Pelopic " } proportions. | _/ | _/ | _ | _ | Oxide of Silver \ | Oxide of Silver \ After | " " Zinc \ After long | " " Zinc \ long | " " Cadmium | continued | " " Cadmium | continued | " " Lead } blowing. | " " Lead } blowing. | " " Bismuth | Otherwise | " " Bismuth | Otherwise | " " Antimony| grey. | " " Antimony | grey. | " " Nickel / | " " Nickel / | Telluric Acid _/ | Telluric Acid _/ --+--------------------------------------+-------------------------------- Yellow to brown. --+--------------------------------------+-------------------------------- | Titanic Acid | Titanic Acid. | Tungstic " | Tungstic " | Molybdic " | Molybdic " | Vanadic " | --+--------------------------------------+-------------------------------- Blue. --+--------------------------------------+-------------------------------- | Oxide of Cobalt. | Oxide of Cobalt. | | Titanic Acid with intermittent | | flame opaque-blue. --+--------------------------------------+-------------------------------- Green. --+--------------------------------------+-------------------------------- | Oxide of Iron | Oxide of Iron, bottle-green. | " " Uranium | Oxide of Uranium, bottle- | " " Chromium | green. | | Oxide of Chromium, emerald- | | green. | | Vanadic Acid, emerald-green. --+--------------------------------------+-------------------------------- Opaque-grey. (The opacity generally becomes distinct during cooling.) --+--------------------------------------+-------------------------------- | _ | | Oxide of Silver \ | Oxide of Silver._ | " " Zinc \ After | " " Zinc \ After | " " Cadmium | short | " " Cadmium \short | " " Lead } blowing. | " " Lead |blowing. | " " Bismuth | Otherwise | " " Bismuth }Otherwise | " " Antimony| colorless. | " " Antimony |colorless. | " " Nickel / | " " Nickel / | Telluric Acid _/ | Telluric Acid _/ | _ | _ | Niobic Acid \ After long | Niobic Acid\ After long | Pelopic " | continued blowing | Pelopic " | continued | } and in | } blowing and | | considerable | | in considerable | _/ proportion. | _/ proportion. | | --+--------------------------------------+-------------------------------- Opaque red and reddish-brown. --+--------------------------------------+-------------------------------- | Oxide of Copper | Oxide of Copper. --+--------------------------------------+--------------------------------

B. MICROCOSMIC SALT.

1. Oxydizing flame.

--+--------------------------------------+-------------------------------- Color of Bead. --+----------------------------------------------------------------------- | Substances which produce this color +--------------------------------------+-------------------------------- | in the hot bead. | in the cold bead. --+--------------------------------------+-------------------------------- Colorless --+--------------------------------------+-------------------------------- | _ | | Silica (only \ | Silica | slightly soluble)\ | | Alumina | | Alumina | Oxide of Tin | | Oxide of Tin _ | Telluric Acid | | Telluric Acid \ | Baryta | | Baryta \ | Strontia | | Strontia |With | Lime | In all | Lime |intermittent | Magnesia } proportions. | Magnesia }flame | Glucina | | Glucina |opaque | Yttria | | Yttria |white. | Zirconia | | Zirconia | | Thoria | | Thoria / | Oxide of Lanthanum | | Oxide of Lanthanum/ | | | " " Cerium | Niobic Acid / | Niobic Acid | Pelopic " _/ | Pelopic " | Tantalic " | Tantalic " | Titanic " | Titanic " | Tungstic " _ | Tungstic " | Oxide of Zinc \ In small | Oxide of Zinc | " " Cadmium \ quantity only. | " " Cadmium | " " Lead } In large | " " Lead | " " Bismuth | quantity | " " Bismuth | " " Antimony / yellow. | " " Antimony | _/ | --+--------------------------------------+-------------------------------- Yellow, orange, red and brown. --+--------------------------------------+-------------------------------- | Tantalic Acid _ | | Titanic " \ | | Tungstic " | | | Oxide of Zinc | In large | | " " Cadmium } quantity. | | " " Lead | | | " " Bismuth | | | " " Antimony _/ | | " " Silver | Oxide of Silver. | " " Cerium | | " " Iron | Oxide of Iron. | " " Nickel | " " Nickel. | " " Uranium | " " Uranium, | | yellowish-green. | Vanadic Acid | Vanadic Acid. | Oxide of Chromium | --+--------------------------------------+-------------------------------- Violet or Amethyst. --+--------------------------------------+-------------------------------- | Oxide of Manganese | Oxide of Manganese. | " " Didymium | " " Didymium. --+--------------------------------------+-------------------------------- Blue. --+--------------------------------------+-------------------------------- | Oxide of Cobalt | Oxide of Cobalt | | Oxide of Copper, to | | greenish-blue. --+--------------------------------------+-------------------------------- Green. --+--------------------------------------+-------------------------------- | Molybdic Acid, yellowish-green | Molybdic Acid, yellowish-green. | Oxide of Copper | Oxide of Uranium, | | yellowish-green. | | Oxide of Chromium, | | emerald-green. --+--------------------------------------+--------------------------------

B. MICROCOSMIC SALT.

2. Reducing flame.

--+--------------------------------------+-------------------------------- Color of Bead. --+----------------------------------------------------------------------- | Substances which produce this color +--------------------------------------+--------------------------------- | in the hot bead. | in the cold bead. --+--------------------------------------+-------------------------------- Colorless --+--------------------------------------+-------------------------------- | Silica (only slightly soluble) | Silica (only slightly soluble). | Alumina | Alumina. | Oxide of Tin | Oxide of Tin. _ | Baryta | Baryta \ | Strontia | Strontia \ | Lime | Lime | | Magnesia | Magnesia |With an | Glucina | Glucina }intermittent | Yttria | Yttria |flame | Zirconia | Zirconia |opaque- | Thoria | Thoria only when |white. | | saturated / | Oxide of Lanthanum | Oxide of Lanthanum/ | " " Cerium | " " Cerium. | " " Didymium | " " Didymium. | " " Manganese | " " Manganese. | Tantalic Acid _ | Tantalic Acid. | Oxide of Silver \ | Oxide of Silver _ | " " Zinc \ | " " Zinc \ After | " " Cadmium | After long | " " Cadmium \ long | " " Lead } continued | " " Lead | continued | " " Bismuth | blowing. | " " Bismuth } blowing. | " " Antimony | Otherwise grey. | " " Antimony | Otherwise | " " Nickel / | " " Nickel / grey. | Telluric Acid _/ | Telluric Acid _/ --+--------------------------------------+-------------------------------- Yellow, red, and brown. --+--------------------------------------+-------------------------------- | Oxide of Iron, red | Oxide of Iron. | Titanic Acid, yellow | | Pelopic Acid, brown | Pelopic Acid. | Ferruginous Titanic Acid, blood red | Ferruginous Titanic Acid. | " Niobic " " | " Niobic " | " Pelopic " " | " Pelopic " | " Tungstic " " | " Tungstic " | Vanadic Acid, brownish | | Oxide of Chromium, reddish | --+--------------------------------------+-------------------------------- Violet or Amethyst. --+--------------------------------------+-------------------------------- | Niobic Acid in large proportion | Niobic Acid in large proportion. | | Titanic Acid. --+--------------------------------------+-------------------------------- Blue. --+--------------------------------------+-------------------------------- | Oxide of Cobalt | Oxide of Cobalt. | Tungstic Acid | Tungstic Acid. | Niobic Acid in very large proportion.| Niobic Acid in very large | | proportion. --+--------------------------------------+-------------------------------- Green. --+--------------------------------------+-------------------------------- | Oxide of Uranium | Oxide of Uranium. | Molybdic Acid | Molybdic Acid. | | Vanadic " | | Oxide of Chromium. --+--------------------------------------+-------------------------------- Opaque-grey. (The opacity generally becomes distinct during cooling.) --+--------------------------------------+-------------------------------- | Oxide of Silver | Oxide of Silver. | " " Zinc | " " Zinc. | " " Cadmium | " " Cadmium. | " " Lead | " " Lead. | " " Bismuth | " " Bismuth. | " " Antimony | " " Antimony. | " " Nickel | " " Nickel. | Telluric Acid | Telluric Acid. --+--------------------------------------+-------------------------------- Opaque-red and reddish brown. --+--------------------------------------+-------------------------------- | Oxide of Copper | Oxide of Copper. --+--------------------------------------+--------------------------------

* * * * *

TABLE II.

Metallic Oxides

1. Oxide of Cerium, C^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves into a red or dark yellow glass (similar to that produced by iron). During cooling, the color diminishes in the intensity and becomes finally yellow. If much oxide be dissolved, an opaque bead may be obtained with an intermittent flame, and a still larger quantity renders it opaque spontaneously.

in the reducing flame.

The color of the bead becomes paler, so that a bead, which is yellow in the oxidizing flame, is rendered colorless. With a large quantity of oxide the bead becomes white and crystalline on cooling.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax. During the process of cooling the color entirely disappears.

in the reducing flame.

Both, when hot and cold, the bead is colorless, by which character oxide of cerium may be distinguished from oxide of iron. The glass remains clear even when containing a large quantity of the oxide.

* * * * *

2. Oxide of Lanthanum, LaO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves into a colorless glass, which, when sufficient oxide is present, may be rendered opaque with an intermittent flame, and becomes so spontaneously on cooling, when a still larger amount is dissolved.

in the reducing flame.

As in the oxidizing flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax.

in the reducing flame.

No reaction.

* * * * *

3. Oxide of Didymium, DO.

Behavior with Borax on Platinum wire

in the oxidizing flame:

Dissolves to a clear dark amethystine glass.

in the reducing flame.

No reaction.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax.

in the reducing flame.

No reaction.

* * * * *

4. Oxide of Manganese, Mn^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Affords an intense amethyst color, which on cooling becomes violet. A large quantity of the oxide produces an apparently black bead, which however, if pressed flat, is seen to be transparent.

in the reducing flame.

The colored bead becomes colorless. With a large amount of the oxide, this reaction is best obtained upon charcoal, and is facilitated by the addition of tin foil.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

With a considerable quantity of oxide an amethyst color is obtained, but never so dark as in borax. With but little oxide a colorless bead is obtained, in which, however, the amethyst-color may be brought out by adding a little nitre. While the bead is kept fused, it froths and gives off bubbles of gas.

in the reducing flame.

The colored bead immediately loses its color, either on platinum wire or on charcoal. After the reduction the fluid bead remains still.

* * * * *

5. Oxide of Iron, Fe^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

With a small proportion of oxide, the glass is of a yellow color, while warm, and colorless when cold; with a larger proportion, red, while warm, and yellow, when cold; and with a still larger amount, dark-red, while warm, and dark-yellow, when cold.

in the reducing flame.

Treated alone on platinum wire, the glass becomes of a bottle-green color (F^{3}O^{4}), and if touched with tin, it becomes of a pale sea-green. On charcoal with tin, it assumes at first a bottle-green color, which by continued blowing changes to a sea-green (FeO).

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

With a certain amount of oxide, the glass is of a yellowish-red color, which on cooling changes to yellow, then green, and finally becomes colorless. With a large addition of oxide, the color is, when warm, dark red, and passes, while cooling, into brownish-red, dark green, and finally brownish-red. During the cooling process, the colors change more rapidly than with borax.

in the reducing flame.

With a small proportion of oxide there is no reaction. With a larger amount the bead is red, while warm, and becomes on cooling successively yellow, green, and russet. With the addition of tin the glass becomes, during cooling, first green and then colorless.

* * * * *

6. Oxide of Cobalt, CoO.

Behavior with Borax on Platinum wire

in the oxidizing flame:

Colors the glass of an intense smalt blue both whilst hot and when cold. When much oxide is present, the color is so deep as to appear black.

in the reducing flame:

As in the oxidizing flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax, but less intensively colored. During cooling the color becomes somewhat paler.

in the reducing flame.

As in the oxidizing flames.

* * * * *

7. Oxide of Nickel, NiO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Colors intensely. A small amount of oxide affords a glass which, while warm, is violet, and becomes of a pale reddish-brown on cooling. A larger addition produces a dark violet color in the warm and reddish-brown in the cold bead.

in the reducing flame.

The oxide is reduced and the metallic particles give the bead a turbid grey appearance. If the blast be continued the metallic particles fall together without fusing, and the glass becomes colorless. This reaction is readily obtained with tin upon charcoal, and the reduced nickel fuses to a bead with the tin.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves into a reddish glass which becomes yellow on cooling. With a large addition of the oxide, the glass is brownish while hot, and orange when cold.

in the reducing flame.

On platinum wire the nickeliferous bead undergoes no change. Treated with tin upon charcoal, it becomes at first opaque and grey, and after long continued blowing the reduced nickel forms a bead, and the glass remains colorless.

* * * * *

8. Oxide of Zinc, ZnO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves easily into a clear colorless glass, which, when much oxide is present, may be rendered opaque and flocculent by an intermittent flame, and becomes so spontaneously with a still larger addition. When a considerable quantity is dissolved, a glass is obtained which is pale yellow, while hot, and colorless when cold.

in the reducing flame.

On platinum wire the saturated glass becomes at first opaque and grey, but by a sustained blast is again rendered clear. On charcoal the oxide is gradually reduced; the metal is volatilized and in crusts the charcoal with oxide.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax.

in the reducing flame.

As with borax.

* * * * *

9. Oxide of Cadmium, CdO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

When in very large proportion, dissolves to a clear yellow glass, which becomes nearly colorless on cooling. When the oxide is present in any considerable quantity, the glass can be rendered opaque with an intermittent flame, and, with a larger addition, it becomes so spontaneously on cooling.

in the reducing flame.

Upon charcoal ebullition takes place and the oxide is reduced. The metallic cadmium is volatilized and incrusts the charcoal with its characteristic deep yellow oxide.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

When in very large proportion dissolves to a clear glass, having a yellow tinge, while hot, which disappears on cooling, and when perfectly saturated, becomes milk-white.

in the reducing flame.

On charcoal the oxide is slowly and imperfectly reduced. The reduced metal forms the characteristic incrustation on the charcoal, but the is thin and does not exhibit its color clearly until quite cold. The addition of tin hastens the reaction.

* * * * *

10. Oxide of Lead, PbO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear yellow glass, which loses its color upon cooling, and when containing much oxide can be rendered dull under an intermittent flame. With a still larger addition of oxide it becomes opaline yellow on cooling.

in the reducing flame.

The plumbiferous glass spreads out on charcoal, becomes turbid, bubbles up, until the whole of the oxide is reduced, when it again becomes clear. It is, however, difficult to bring the lead together into a bead.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax, but a larger addition of oxide, required to produce a yellow color in the warm bead.

in the reducing flame.

On charcoal the plumbiferous glass becomes grey and dull. With an over dose of oxide a part is volatilized and forms an incrustation on the charcoal beyond the bead. The addition of tin does not render the glass opaque, but somewhat more dull and grey than in its absence.

* * * * *

11. Oxide of Tin, SnO^{2}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

In small quantity dissolves slowly into a clear colorless glass, which, when cold, remains clear, and cannot be rendered opaque with an intermittent flame. If a saturated bead, which has been allowed to cool, be reheated to incipient redness, it loses its rounded form and exhibits imperfect crystallization.

in the reducing flame.

A glass containing but little oxide undergoes no change. If much of the latter be present, a part may be reduced upon charcoal.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

In small quantity dissolves very slowly to a colorless glass, which remains clear on cooling.

in the reducing flame.

The glass undergoes no change, either on charcoal or platinum wire.

* * * * *

12. Oxide of Bismuth, BiO^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear glass which with a small amount of the oxide is yellow, while warm, and becomes colorless on cooling. With a larger addition, the glass is, in the hot state, of a deep orange color, which changes to yellow and finally becomes opaline in process of cooling.

in the reducing flame.

A glass becomes at first grey and turbid, then begins to effervesce, which action continues during the reduction of the oxide, and it finally becomes perfectly clear. If tin be added, the glass becomes at first grey from the reduced bismuth, but, when the metal is collected into a bead, the glass is again clear and colorless.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves in small quantity to a clear colorless glass. A larger addition affords a glass which, while warm, is yellow, and becomes colorless on cooling. When in sufficient proportion the glass may be rendered opaque under an intermittent flame, and a still larger addition of oxide renders the bead spontaneously opaque on cooling.

in the reducing flame.

On charcoal, and especially with the addition of tin, the glass remains colorless and clear, while warm, but becomes on cooling of a dark grey color and opaque.

* * * * *

13. Oxide of Uranium, U^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Behaves similarly to oxide of iron, with the exception that the color of the former is somewhat paler. When sufficiently saturated, the glass may be rendered of an opaque yellow by an intermittent flame.

in the reducing flame.

Affords the same color as the oxide of iron. The green glass obtained in this flame, if sufficiently saturated, can be rendered black by an intermittent flame, but it has under these circumstances no enameline appearance. On charcoal, with the addition of tin, the glass takes a dark green color.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves to a clear yellow glass, which assumes a yellowish-green color on cooling.

in the reducing flame.

The glass assumes a beautiful green color, which becomes more brilliant as the bead cools. The addition of tin upon charcoal produces no further change.

* * * * *

14. Oxide of Copper, CuO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Produces an intense coloration. If in small quantity, the glass is green, while warm, and becomes blue on cooling. If in large proportion, the green color is so intense as to appear black. When cool, this becomes paler, and changes to a greenish blue.

in the reducing flame.

If not too saturated, the cupriferous glass soon becomes nearly colorless, but immediately on solidifying assumes a red color and becomes opaque. By long continued blowing on charcoal, the copper in the bead is reduced and separates out as a small metallic bead, leaving the glass colorless. With the addition of tin, the glass becomes of an opaque dull-red on cooling.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

With an equal proportion of oxide, this salt is not so strongly colored as borax. A small amount imparts a green color in the warm and a blue in the cold. With a very large addition of oxide, the glass is opaque in the hot state, and after cooling of a greenish-blue.

in the reducing flame.

A tolerably saturated glass assumes a dark green color under a good flame, and on cooling becomes of an opaque brick-red, the moment it solidifies. A glass containing but a small proportion of the oxide becomes equally red and opaque on cooling, if treated with tin upon charcoal.

* * * * *

15. Oxide of Mercury, HgO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

No reaction.

in the reducing flame.

No reaction.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

No reaction.

in the reducing flame.

No reaction.

* * * * *

16. Oxide of Silver, AgO.

Behavior with Borax on Platinum wire

in the oxidizing flame.

The oxide is partly dissolved and partly reduced. In small quantity, it colors the glass yellow while warm, the color disappearing on cooling. In larger quantity, the glass is yellow while warm, but during cooling becomes paler to a certain point, and then again deeper. If reheated slightly, the glass becomes opalescent.

in the reducing flame.

On charcoal the argentiferous glass becomes at first grey from the reduced metal, but afterwards, when the silver is collected into a bead, it becomes clear and colorless.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Both the oxide and the metal afford a yellowish glass, which, when containing much oxide becomes opaline, exhibiting a yellow color by daylight and a red one by artificial light.

in the reducing flame.

As in borax.

* * * * *

17. Oxide of Platinum, PtO^{2}. 18. Oxide of Palladium, PdO^{2}. 19. Oxide of Rhodium, R^{2}O^{3}. 20. Oxide of Iridium, Ir^{2}O^{3}. 21. Oxide of Ruthenium, Ru^{2}O^{9}. 22. Oxide of Osmium OsO^{2}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Are reduced without being dissolved. The reduced metal, being infusible, cannot however be collected into a bead.

in the reducing flame.

As in the oxidizing flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As in borax.

in the reducing flame.

As in borax.

* * * * *

23. Oxide of Gold, Au^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Is reduced without being dissolved and can be collected into a bead on charcoal.

in the reducing flame.

As in the oxidizing flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As in borax.

in the reducing flame.

As in borax.

* * * * *

24. Titanic Acid, TiO^{2}

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear glass which, when but little acid is present, is colorless, but when in larger proportion, yellow, and, on cooling, colorless. When sufficiently saturated, it may be rendered opaque with an intermittent flame, and with a still larger addition of the acid becomes so spontaneously on cooling.

in the reducing flame.

In small proportion, it renders the glass yellow in larger quantity dark-yellow or brown. A saturated bead assumes a blue enamel-like appearance under an intermittent flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear glass, which, when sufficiently saturated, is yellow white hot, and becomes colorless on cooling.

in the reducing flame.

The glass obtained in the oxidizing glame becomes yellow in the hot state, but on cooling assumes a beautiful violet color. If too saturated, this color is so deep as to appear opaque, but is not enameline. If the titanic acid contains iron, the glass becomes on cooling of a brownish-yellow or red color. The addition of tin neutralizes the iron, and the glass then becomes violet.

* * * * *

25. Tantalic Acid, TaO^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear colorless glass, which, when sufficiently saturated, may be rendered opaque with an intermittent flame, and with a larger addition of the acid becomes spontaneously enameline on cooling.

in the reducing flame.

As in the oxidizing flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear glass, which, when it contains a large proportion of the acid, is yellow while warm, but becomes colorless on cooling.

in the reducing flame.

The glass obtained in the oxidizing flame undergoes no change, nor does it, according to _H. Rose_, alter by the addition of sulphate of iron.

* * * * *

26. Niobic Acid, Ni^{2}O{3}

Behavior with Borax on Platinum wire

in the oxidizing flame.

Behaves in a similar manner to tantalic acid, but the glass requires a very large dose of the acid to render it opaque under an intermittent flame. With an increased amount of the acid, the glass is clear and yellow, while warm, but becomes on cooling turbid, and when quite cold is white.

in the reducing flame.

The glass obtained in the oxidizing flame and which has become opalescent on cooling, is rendered clear in the reducing flame. With a larger addition of the acid, it becomes dull, and of a bluish-grey color on cooling, and a still larger amount of renders it opaque and bluish grey.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves in large quantities to a clear colorless glass.

in the reducing flame.

If the acid be not present in too large a proportion, the glass remains unchanged. An additional amount of the acid renders it violet, and a still larger quantity affords a beautiful pure blue color, similar to that produced by tungstic acid. If to such a bead some sulphate of iron be added, the glass becomes blood-red. The addition of peroxide of iron renders the glass deep yellow while warm, the color becomes paler on cooling.

* * * * *

27. Pelopic Acid, Pp^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Behaves similarly to the preceding.

in the reducing flame.

A bead containing sufficient of the acid to render it spontaneously opaque on cooling, has a greyish color.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves even in large quantity to a colorless glass.

in the reducing flame.

With sufficient dose of the acid, the bead becomes brown with a violet tinge. This reaction is readily obtained upon charcoal. Sulphate of iron renders the bead blood-red.

* * * * *

28. Oxide of Antimony, SbO^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Even when in large proportion, dissolves to a clear glass, which is yellow when warm, but almost entirely loses its color on cooling. On charcoal, the antimonious acid may be almost expelled, so that tin produces no further change.

in the reducing flame.

A bead, that has only been treated for a short time in the oxidizing flame, when submitted to the reducing flame becomes grey and turbid from the reduced antimony. This soon volatizes and the glass again becomes clear. The addition of tin renders the glass ash-grey or black, according to the amount of oxide it contains.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves with ebullition to a glass of a pale yellow color while warm.

in the reducing flame.

On charcoal, the saturated glass becomes at first dull, but as soon as the reduced antimony is volatilized, it again becomes clear. With tin, the glass is at first rendered grey by the reduced antimony, but by continued blowing is restored to clearness. Even when the glass contains but little oxide, tin produces this reaction.

* * * * *

29. Tungstic Acid, WO^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves readily to a clear colorless glass. In large proportion it renders the borax yellow, while warm, and with a still greater addition the bead may be made opaque with an intermittent flame. If more be then added, this reaction takes place spontaneously.

in the reducing flame.

When the oxide is present in small quantity, the glass undergoes no change. With a larger proportion, the glass is deep yellow while warm, and yellowish-brown when cold. This reaction takes place upon charcoal, with a small quantity of the acid. Tin produces a dark coloration, when the acid is not present in too great a quantity.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves to a clear glass, which, when saturated, is yellow in the hot state.

in the reducing flame.

The glass is of a pure blue. If the tungstic acid contain iron, the glass becomes blood-red on cooling, similar to titanic acid. In this case, tin restores the blue color, or, if iron be in considerable quantity, renders it green.

* * * * *

30. Molydbic Acid, MO^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves readily and in large quantity. When but little is dissolved, the glass is yellow while hot and colorless when cold. When in larger quantity yellow while warm and opaline when cold, and a further addition of acid renders it yellow when warm, the color, on cooling, changing first to a pale enamel blue, and then to an enamel white.

in the reducing flame.

The glass, which has been treated in the oxidizing flame, becomes, when the acid is not present in too large a quantity, brown, and when in large quantity, perfectly opaque. In a strong flame, oxide of molybdenum is formed which is visible in the yellow glass in the form of black flakes. If the glass appear opaque, it should be flattened with the forceps.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves to a clear glass, which, when sufficient acid is present, is of a yellowish-green color when warm, and becomes nearly colorless on cooling. On charcoal, the glass becomes dark, and when cool has a beautiful green color.

in the reducing flame.

The glass becomes of a bottle-green color, which on cooling, changes to a brilliant green, similar to that produced by oxide of chromium. The reaction on charcoal is precisely similar. Tin renders the color somewhat darker.

* * * * *

31. Vanadic Acid, VaO^{8}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves to a clear glass, which is colorless when only a small quantity of acid is present, and yellow when containing a larger proportion.

in the reducing flame.

The yellow color of the glass changes to a brown when warm and a chrome-green on cooling.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax.

in the reducing flame.

As with borax.

* * * * *

32. Oxide of Chromium, Cr^{2}O^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Affords an intense color, but dissolves slowly. A small proportion colors the glass yellow when warm, and yellowish green when cold; a larger addition produces a dark red color when warm, which, on cooling, becomes yellow and finally a brilliant green with a tinge of yellow.

in the reducing flame.

A small quantity of the oxide renders the glass beautifully green both when warm and when cold. A larger addition changes it to a darker emerald green. Tin produces no change in the color.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

Dissolves to a clear glass which has a pink tinge while warm, but on cooling becomes dusky green, and finally brilliantly green.

in the reducing flame.

As in the oxidizing flame, except that the colors are somewhat darker. Tin produces no further change.

* * * * *

33. Arsenious Acid, AsO^{3}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

No reaction.

in the reducing flame.

No reaction.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

No reaction.

in the reducing flame.

No reaction.

* * * * *

34. Tellurous Acid, TeO^{2}.

Behavior with Borax on Platinum wire

in the oxidizing flame.

Dissolves to a clear colorless glass which, when treated on charcoal, becomes grey and dull from particles of reduced tellurium.

in the reducing flame.

As in the oxidizing flame.

Behavior with Mic. Salt on Platinum wire

in the oxidizing flame.

As with borax.

in the reducing flame.

As with borax.

* * * * *

7. EXAMINATIONS WITH CARBONATE OF SODA.

The carbonate of soda is pulverized and then kneaded to a paste with water; the substance to be examined, in fine powder, is also mixed with it. A small portion of this paste is placed on the charcoal, and gradually heated until the moisture is expelled, when the heat is brought to the fusion of the bead, or as high as it can be raised. Several phenomena will take place, which must be closely observed. Notice whether the substance fuses with the bead, and if so, whether there is intumescence or not. Or, whether the substance undergoes reduction; or, whether neither of these reactions takes place, and, on the contrary, the soda sinks into the charcoal, leaving the substance intact upon its surface. If intumescence takes place, the presence of either tartaric acid, molybdic acid, silicic, or tungstic acid, is indicated. The silicic acid will fuse into a bead, which becomes clear when it is cold. Titanic acid will fuse into the bead, but may be easily distinguished from the silicic acid by the bead remaining opaque when cold.

Strontia and baryta will flow into the charcoal, but lime will not. The molybdic and tungstic acids combine with the soda, forming the respective salts. These salts are absorbed by the charcoal. If too great a quantity of soda is used, the bead will be quite likely to become opaque upon cooling, while, if too small a quantity of soda is used, a portion of the substance will remain undissolved. These can be equally avoided by either the addition of soda, or the substance experimented upon, as may be required.

As silica and titanic acid are the only two substances that produce a clear bead, the student, if he gets a clear bead, may almost conclude that he is experimenting with silica, titanic acid being a rare substance. When soda is heated with silica, a slight effervescence will be the first phenomenon noticed. This is the escape of the carbonic acid of the carbonate of soda, while the silicic acid takes its place, forming a glass with the soda. As titanic acid will not act in the same manner as silica, it can be easily distinguished by its bead not being perfectly pellucid. If the bead with which silica is fused should be tinted of a hyacinth or yellow color, this may be attributed to the presence of a small quantity of sulphur or a sulphate, and this sometimes happens from the fact of the flux containing sulphate of soda. The following metals, when exposed with carbonate of soda to the reducing flame, are wholly or partially reduced, viz. the oxides of all the noble metals, the oxides and acids of tungsten, molybdenum, arsenic, antimony, mercury, copper, tellurium, zinc, lead, bismuth, tin, cadmium, iron, nickel, and cobalt. Mercury and arsenic, as soon as they are reduced, are dissipated, while tellurium, bismuth, lead, antimony, cadmium, and zinc, are only partially volatilized, and, therefore, form sublimates on the charcoal. Those metals which are difficult of reduction should be fused with oxalate of potassa, instead of the carbonate of soda. The carbonic oxide formed from the combustion of the acid of this salt is very efficient in the reduction of these metals. Carbonate of soda is very efficient for the detection of minute quantities of manganese. The mixture of the carbonate of soda with a small addition of nitrate of potassa, and the mineral containing manganese, must be fused on platinum foil. The fused mass, when cooled, presents a fine blue color.

* * * * *

1. The following minerals, according to Griffin, produce beads with soda, but do not fuse when heated alone: quartz, agalmatolyte, dioptase, hisingerite, sideroschilosite, leucite, rutile, pyrophyllite, wolckonskoite.

2. The following minerals produce only slags with soda: allophane, cymophane, polymignite, æschynite, oerstedtite, titaniferous iron, tantalite, oxides of iron, yttro-tantalite, oxides of manganese, peroxide of tin (is reduced), hydrate of alumina, hydrate of magnesia, spinel, gahnite, worthite, carbonate of zinc, pechuran, zircon, thorite, andalusite, staurolite, gehlenite, chlorite spar, chrome ochre, uwarowite, chromate of iron, carbonates of the earths, carbonates of the metallic oxides, basic phosphate of yttria, do. of alumina, do. of lime, persulphate of iron, sulphate of alumina, aluminite, alumstone, fluoride of cerium, yttrocerite, topaz, corundum, pleonaste, chondrodite.

3. The following minerals produce beads with a small quantity of soda, but produce slags if too much soda is added: phenakite, pierosmine, olivine, cerite, cyanite, talc, gadolinite, lithium-tourmaline.

* * * * *

1. The following minerals, when fused alone, produce beads. Of these minerals the following produce beads with soda: the zeolites, spodumene, soda-spodumene, labrador, scapolite, sodalite (Greenland), elæolite, mica from primitive lime-stone, black talc, acmite, krokidolite, lievrite, cronstedtite, garnet, cerine, helvine, gadolinite, boracic acid, hydroboracite, tincal, boracite, datholite, botryolite, axinite, lapis lazuli, eudialyte, pyrosmalite, cryolite.

2. The following minerals produce beads with a small quantity of soda, but if too much is added they produce slags: okenite, pectolite, red silicate of manganese, black hydro-silicate of manganese, idocrase, manganesian garnets, orthite, pyrorthite, sordawalite, sodalite, fluorspar.

3. The following minerals produce a slag with soda: brevicite, amphodelite, chlorite, fahlunite, pyrope, soap-stone (Cornish) red dichroite, pyrargillite, black potash tourmaline, wolfram, pharmacolite, scorodite, arseniate of iron, tetraphyline, hetepozite, uranite, phosphate of iron, do. of strontia, do. of magnesia, polyhalite, hauyne.

4. The following metals are reduced by soda: tungstate of lead, molybdate of lead, vanadate of lead, chromate of lead, vauquelinite, cobalt bloom, nickel ochre, phosphate of copper, sulphate of lead, chloride of lead, and chloride of silver.

* * * * *

The following minerals fuse on the edges alone, when heated in the blowpipe flame:

1. The following produce beads with soda: steatite, meerschaum, felspar, albite, petalite, nepheline, anorthite, emerald, euclase, turquois, sodalite (Vesuvius).

2. The following minerals produce beads with a small quantity of soda, but with the addition of more produce slags: tabular spar, diallage, hypersthene, epidote, zoisite.

3. The following minerals produce slags only with soda: stilpnosiderite, plombgomme, serpentine, silicate of manganese (from Piedmont), mica from granite, pimelite, pinite, blue dichroite, sphenc, karpholite, pyrochlore, tungstate of lime, green soda tourmaline, lazulite, heavy spar, gypsum.

* * * * *

The reactions of substances, when fused with soda in the flame of oxidation may be of use to the student. A few of them are therefore given. Silica gives a clear glass.

The oxide of tellurium and telluric acid gives a clear bead when it is hot, but white after it is cooled.

Titanic acid gives a yellow bead when hot.

The oxide of chromium gives also a clear yellow glass when hot, but is opaque when cold.

Molybdic acid gives a clear bead when hot, but is turbid and white after cooling.

The oxides and acids of antimony give a clear and colorless bead while hot, and white after cooling.

Vanadic acid is absorbed by the charcoal, although it is not reduced.

Tungstic acid gives a dark yellow clear bead while hot, but is opaque and yellow when cold.

The oxides of manganese give to the soda bead a fine characteristic green color. This is the case with a very small quantity. This reaction is best exhibited on platinum foil.

Oxide of cobalt gives to the bead while hot a red color, which, upon being cooled, becomes grey.

The oxide of copper gives a clear green bead while hot.

The oxide of lead gives a clear colorless bead while hot, which becomes, upon cooling, of a dirty yellow color and opaque.

* * * * *

The following metals, when they are fused with soda on charcoal, in the flame of reduction, produce volatile oxides, and leave an incrustation around the assay, viz. bismuth, zinc, lead, cadmium, antimony, selenium, tellurium, and arsenic.

_Bismuth_, under the reduction flame, yields small particles of metal, which are brittle and easily crushed. The incrustation is of a flesh color, or orange, when hot, but gets lighter as it cools. The sublimate may be driven about the charcoal from place to place, by either flame, but is finally dissipated. While antimony and tellurium, in the act of dissipation, give color to the flame, bismuth does not, and may thus be distinguished from them.

_Zinc_ deposits an incrustation about the assay, which is yellow while hot, but fades to white when cold. The reduction flame dissipates this deposit, but not that of oxidation. All the zinc minerals deposit the oxide incrustation about the assay, which, when moistened with a solution of cobalt and heated, changes to green.

_Lead_ is very easily reduced, in small particles, and may be easily distinguished by its flattening under the hammer, unlike bismuth. It leaves an incrustation around the assay resembling that of bismuth, in the color of it, and in the peculiar manner in which it lies around the assay.

_Cadmium_ deposits a dull reddish incrustation around the assay. Either of the flames dissipate the sublimate with the greatest readiness.

_Antimony_ reduces with readiness. At the same time it yields considerable vapor, and deposits an incrustation around the assay. This deposit can be driven about on the charcoal by either of the flames. The flame of reduction, however, produces the light blue color of the antimony.

_Selenium_ is deposited on the charcoal as a grey metallic-looking sublimate, but sometimes appearing purple or blue. If the reduction flame is directed on this deposit, it is dissipated with a blue light.

_Tellurium_ is deposited on the charcoal as a white sublimate, sometimes changing at the margin to an orange or red color. The oxidation flame drives the deposit over the charcoal, while the reduction-flame dissipates it with a greenish color.

_Arsenic_ is vaporized rapidly, while there is deposited around the assay a white incrustation of arsenious acid. This deposit will extend to some distance from the assay, and is readily volatilized, the reducing flame producing the characteristic alliaceous color.

* * * * *

The following metals, or their compounds, are reduced when fused with soda on charcoal, in the flame of reduction. They are reduced to metallic particles, but give no incrustation, viz. nickel, cobalt, iron, tin, copper, gold, silver, platinum, tungsten, and molybdenum.

The particles of iron, nickel, and cobalt, it should be borne in mind, are attracted by the magnet.

The following substances are neither fused nor reduced in soda, viz. alumina, magnesia, lime, baryta, strontia, the oxide of uranium, the oxides of cerium, zirconia, tantalic acid, thorina, glucina, and yttria. Neither are the alkalies, as they sink into the charcoal. The carbonates of the earths, strontia, and baryta fuse.

* * * * *