A History of Science — Volume 3
Chapter 11
for, as has been said already, neither a current nor the action of waves upon an extensive beach produces such effects. The general direction of the channels and furrows indicates the direction of the general movement of the glacier, and the streaks which vary more or less from this direction are produced by the local effects of oscillation and retreat, as we shall presently see.
"4. The Lapiaz, or Lapiz, which the inhabitants of German Switzerland call Karrenfelder, cannot always be distinguished from erosions, because, both produced as they are by water, they do not differ in their exterior characteristics, but only in their positions. Erosions due to torrents are always found in places more or less depressed, and never occur upon large inclined surfaces. The Lapiaz, on the contrary, are frequently found upon the projecting parts of the sides of valleys in places where it is not possible to suppose that water has ever formed a current. Some geologists, in their embarrassment to explain these phenomena, have supposed that they were due to the infiltration of acidulated water, but this hypothesis is purely gratuitous.
"We will now describe the remains of these various phenomena as they are found in the Alps outside the actual glacial limits, in order to prove that at a certain epoch glaciers were much larger than they are to-day.
"The ancient moraines, situated as they are at a great distance from those of the present day, are nowhere so distinct or so frequent as in Valais, where MM. Venetz and J. de Charpentier noticed them for the first time; but as their observations are as yet unpublished, and they themselves gave me the information, it would be an appropriation of their discovery if I were to describe them here in detail. I will limit myself to say that there can be found traces, more or less distinct, of ancient terminal moraines in the form of vaulted dikes at the foot of every glacier, at a distance of a few minutes' walk, a quarter of an hour, a half-hour, an hour, and even of several leagues from their present extremities. These traces become less distinct in proportion to their distance from the glacier, and, since they are also often traversed by torrents, they are not as continuous as the moraines which are nearer to the glaciers. The farther these ancient moraines are removed from the termination of a glacier, the higher up they reach upon the sides of the valley, which proves to us that the thickness of the glacier must have been greater when its size was larger. At the same time, their number indicates so many stopping-places in the retreat of the glacier, or so many extreme limits of its extension--limits which were never reached again after it had retired. I insist upon this point, because if it is true that all these moraines demonstrate a larger extent of the glacier, they also prove that their retreat into their present boundaries, far from having been catastrophic, was marked on the contrary by periods of repose more or less frequent, which caused the formation of a series of concentric moraines which even now indicate their retrogression.
"The remains of longitudinal moraines are less frequent, less distinct, and more difficult to investigate, because, indicating as they do the levels to which the edges of the glacier reached at different epochs, it is generally necessary to look for them above the line of the paths along the escarpments of the valleys, and hence it is not always possible to follow them along a valley. Often, also, the sides of a valley which enclosed a glacier are so steep that it is only here and there that the stones have remained in place. They are, nevertheless, very distinct in the lower part of the valley of the Rhone, between Martigny and the Lake of Geneva, where several parallel ridges can be observed, one above the other, at a height of one thousand, one thousand two hundred, and even one thousand five hundred feet above the Rhone. It is between St. Maurice and the cascade of Pissevache, close to the hamlet of Chaux-Fleurie, that they are most accessible, for at this place the sides of the valley at different levels ascend in little terraces, upon which the moraines have been preserved. They are also very distinct above the Bains de Lavey, and above the village of Monthey at the entrance of the Val d'Illiers, where the sides of the valley are less inclined than in many other places.
"The perched bowlders which are found in the Alpine valleys, at considerable distances from the glaciers, occupy at times positions so extraordinary that they excite in a high degree the curiosity of those who see them. For instance, when one sees an angular stone perched upon the top of an isolated pyramid, or resting in some way in a very steep locality, the first inquiry of the mind is, When and how have these stones been placed in such positions, where the least shock would seem to turn them over? But this phenomenon is not in the least astonishing when it is seen to occur also within the limits of actual glaciers, and it is recalled by what circumstances it is occasioned.
"The most curious examples of perched stones which can be cited are those which command the northern part of the cascade of Pissevache, close to Chaux-Fleurie, and those above the Bains de Lavey, close to the village of Morcles; and those, even more curious, which I have seen in the valley of St. Nicolas and Oberhasli. At Kirchet, near Meiringen, can be seen some very remarkable crowns of bowlders around several domes of rock which appear to have been projected above the surface of the glacier which surrounded them. Something very similar can be seen around the top of the rock of St. Triphon.
"The extraordinary phenomenon of perched stones could not escape the observing eye of De Saussure, who noticed several at Saleve, of which he described the positions in the following manner: 'One sees,' said he, 'upon the slope of an inclined meadow, two of these great bowlders of granite, elevated one upon the other, above the grass at a height of two or three feet, upon a base of limestone rock on which both rest. This base is a continuation of the horizontal strata of the mountain, and is even united with it visibly on its lower face, being cut perpendicularly upon the other sides, and is not larger than the stone which it supports.' But seeing that the entire mountain is composed of the same limestone, De Saussure naturally concluded that it would be absurd to think that it was elevated precisely and only beneath the blocks of granite. But, on the other hand, since he did not know the manner in which these perched stones are deposited in our days by glacial action, he had recourse to another explanation: He supposes that the rock was worn away around its base by the continual erosion of water and air, while the portion of the rock which served as the base for the granite had been protected by it. This explanation, although very ingenious, could no longer be admitted after the researches of M. Elie de Beaumont had proved that the action of atmospheric agencies was not by a good deal so destructive as was theretofore supposed. De Saussure speaks also of a detached bowlder, situated upon the opposite side of the Tete-Noire, 'which is,' he says, 'of so great a size that one is tempted to believe that it was formed in the place it occupies; and it is called Barme russe, because it is worn away beneath in the form of a cave which can afford accommodation for more than thirty persons at a time."(4)
But the implications of the theory of glaciers extend, so Agassiz has come to believe, far beyond the Alps. If the Alps had been covered with an ice sheet, so had many other regions of the northern hemisphere. Casting abroad for evidences of glacial action, Agassiz found them everywhere in the form of transported erratics, scratched and polished outcropping rocks, and moraine-like deposits. Finally, he became convinced that the ice sheet that covered the Alps had spread over the whole of the higher latitudes of the northern hemisphere, forming an ice cap over the globe. Thus the common-sense induction of the chamois-hunter blossomed in the mind of Agassiz into the conception of a universal ice age.
In 1837 Agassiz had introduced his theory to the world, in a paper read at Neuchatel, and three years later he published his famous Etudes sur les Glaciers, from which we have just quoted. Never did idea make a more profound disturbance in the scientific world. Von Buch treated it with alternate ridicule, contempt, and rage; Murchison opposed it with customary vigor; even Lyell, whose most remarkable mental endowment was an unfailing receptiveness to new truths, could not at once discard his iceberg theory in favor of the new claimant. Dr. Buckland, however, after Agassiz had shown him evidence of former glacial action in his own Scotland, became a convert--the more readily, perhaps, as it seemed to him to oppose the uniformitarian idea. Gradually others fell in line, and after the usual imbittered controversy and the inevitable full generation of probation, the idea of an ice age took its place among the accepted tenets of geology. All manner of moot points still demanded attention--the cause of the ice age, the exact extent of the ice sheet, the precise manner in which it produced its effects, and the exact nature of these effects; and not all of these have even yet been determined. But, details aside, the ice age now has full recognition from geologists as an historical period. There may have been many ice ages, as Dr. Croll contends; there was surely one; and the conception of such a period is one of the very few ideas of our century that no previous century had even so much as faintly adumbrated.
THE GEOLOGICAL AGES
But, for that matter, the entire subject of historical geology is one that had but the barest beginning before our century. Until the paleontologist found out the key to the earth's chronology, no one--not even Hutton--could have any definite idea as to the true story of the earth's past. The only conspicuous attempt to classify the strata was that made by Werner, who divided the rocks into three systems, based on their supposed order of deposition, and called primary, transition, and secondary.
Though Werner's observations were confined to the small province of Saxony, he did not hesitate to affirm that all over the world the succession of strata would be found the same as there, the concentric layers, according to this conception, being arranged about the earth with the regularity of layers on an onion. But in this Werner was as mistaken as in his theoretical explanation of the origin of the "primary" rocks. It required but little observation to show that the exact succession of strata is never precisely the same in any widely separated regions. Nevertheless, there was a germ of truth in Werner's system. It contained the idea, however faultily interpreted, of a chronological succession of strata; and it furnished a working outline for the observers who were to make out the true story of geological development. But the correct interpretation of the observed facts could only be made after the Huttonian view as to the origin of strata had gained complete acceptance.
When William Smith, having found the true key to this story, attempted to apply it, the territory with which he had to deal chanced to be one where the surface rocks are of that later series which Werner termed secondary. He made numerous subdivisions within this system, based mainly on the fossils. Meantime it was found that, judged by the fossils, the strata that Brongniart and Cuvier studied near Paris were of a still more recent period (presumed at first to be due to the latest deluge), which came to be spoken of as tertiary. It was in these beds, some of which seemed to have been formed in fresh-water lakes, that many of the strange mammals which Cuvier first described were found.
But the "transition" rocks, underlying the "secondary" system that Smith studied, were still practically unexplored when, along in the thirties, they were taken in hand by Roderick Impey Murchison, the reformed fox-hunter and ex-captain, who had turned geologist to such notable advantage, and Adam Sedgwick, the brilliant Woodwardian professor at Cambridge.
Working together, these two friends classified the
transition rocks into chronological groups, since familiar to every one in the larger outlines as the Silurian system (age of invertebrates) and the Devonian system (age of fishes)--names derived respectively from the country of the ancient Silures, in Wales and Devonshire, England. It was subsequently discovered that these systems of strata, which crop out from beneath newer rocks in restricted areas in Britain, are spread out into broad, undisturbed sheets over thousands of miles in continental Europe and in America. Later on Murchison studied them in Russia, and described them, conjointly with Verneuil and Von Kerserling, in a ponderous and classical work. In America they were studied by Hall, Newberry, Whitney, Dana, Whitfield, and other pioneer geologists, who all but anticipated their English contemporaries.
The rocks that are of still older formation than those studied by Murchison and Sedgwick (corresponding in location to the "primary" rocks of Werner's conception) are the surface feature of vast areas in Canada, and were first prominently studied there by William I. Logan, of the Canadian Government Survey, as early as 1846, and later on by Sir William Dawson. These rocks--comprising the Laurentian system--were formerly supposed to represent parts of the original crust of the earth, formed on first cooling from a molten state; but they are now more generally regarded as once-stratified deposits metamorphosed by the action of heat.
Whether "primitive" or metamorphic, however, these Canadian rocks, and analogous ones beneath the fossiliferous strata of other countries, are the oldest portions of the earth's crust of which geology has any present knowledge. Mountains of this formation, as the Adirondacks and the Storm King range, overlooking the Hudson near West Point, are the patriarchs of their kind, beside which Alleghanies and Sierra Nevadas are recent upstarts, and Rockies, Alps, and Andes are mere parvenus of yesterday.
The Laurentian rocks were at first spoken of as representing "Azoic" time; but in 1846 Dawson found a formation deep in their midst which was believed to b e the fossil relic of a very low form of life, and after that it became customary to speak of the system as "Eozoic." Still more recently the title of Dawson's supposed fossil to rank as such has been questioned, and Dana's suggestion that the early rocks be termed merely Archman has met with general favor. Murchison and Sedgwick's Silurian, Devonian, and Carboniferous groups (the ages of invertebrates, of fishes, and of coal plants, respectively) are together spoken of as representing Paleozoic time. William Smith's system of strata, next above these, once called "secondary," represents Mesozoic time, or the age of reptiles. Still higher, or more recent, are Cuvier and Brongniart's tertiary rocks, representing the age of mammals. Lastly, the most recent formations, dating back, however, to a period far enough from recent in any but a geological sense, are classed as quaternary, representing the age of man.
It must not be supposed, however, that the successive "ages" of the geologist are shut off from one another in any such arbitrary way as this verbal classification might seem to suggest. In point of fact, these "ages" have no better warrant for existence than have the "centuries" and the "weeks" of every-day computation. They are convenient, and they may even stand for local divisions in the strata, but they are bounded by no actual gaps in the sweep of terrestrial events.
Moreover, it must be understood that the "ages" of different continents, though described under the same name, are not necessarily of exact contemporaneity. There is no sure test available by which it could be shown that the Devonian age, for instance, as outlined in the strata of Europe, did not begin millions of years earlier or later than the period whose records are said to represent the Devonian age in America. In attempting to decide such details as this, mineralogical data fail us utterly. Even in rocks of adjoining regions identity of structure is no proof of contemporaneous origin; for the veritable substance of the rock of one age is ground up to build the rocks of subsequent ages. Furthermore, in seas where conditions change but little the same form of rock may be made age after age. It is believed that chalk-beds still forming in some of our present seas may form one continuous mass dating back to earliest geologic ages. On the other hand, rocks different in character maybe formed at the same time in regions not far apart--say a sandstone along shore, a coral limestone farther seaward, and a chalk-bed beyond. This continuous stratum, broken in the process of upheaval, might seem the record of three different epochs.
Paleontology, of course, supplies far better chronological tests, but even these have their limitations. There has been no time since rocks now in existence were formed, if ever, when the earth had a uniform climate and a single undiversified fauna over its entire land surface, as the early paleontologists supposed. Speaking broadly, the same general stages have attended the evolution of organic forms everywhere, but there is nothing to show that equal periods of time witnessed corresponding changes in diverse regions, but quite the contrary. To cite but a single illustration, the marsupial order, which is the dominant mammalian type of the living fauna of Australia to-day, existed in Europe and died out there in the tertiary age. Hence a future geologist might think the Australia of to-day contemporaneous with a period in Europe which in reality antedated it by perhaps millions of years.
All these puzzling features unite to render the subject of historical geology anything but the simple matter the fathers of the science esteemed it. No one would now attempt to trace the exact sequence of formation of all the mountains of the globe, as Elie de Beaumont did a half-century ago. Even within the limits of a single continent, the geologist must proceed with much caution in attempting to chronicle the order in which its various parts rose from the matrix of the sea. The key to this story is found in the identification of the strata that are the surface feature in each territory. If Devonian rocks are at the surface in any given region, for example, it would appear that this region became a land surface in the Devonian age, or just afterwards. But a moment's consideration shows that there is an element of uncertainty about this, due to the steady denudation that all land surfaces undergo. The Devonian rocks may lie at the surface simply because the thousands of feet of carboniferous strata that once lay above them have been worn away. All that the cautious geologist dare assert, therefore, is that the region in question did not become permanent land surface earlier than the Devonian age.
But to know even this is much--sufficient, indeed, to establish the chronological order of elevation, if not its exact period, for all parts of any continent that have been geologically explored--understanding always that there must be no scrupling about a latitude of a few millions or perhaps tens of millions of years here and there.
Regarding our own continent, for example, we learn through the researches of a multitude of workers that in the early day it was a mere archipelago. Its chief island--the backbone of the future continent--was a great V-shaped area surrounding what is now Hudson Bay, an area built tip, perhaps, through denudation of a yet more ancient polar continent, whose existence is only conjectured. To the southeast an island that is now the Adirondack Mountains, and another that is now the Jersey Highlands rose above the waste of waters, and far to the south stretched probably a line of islands now represented by the Blue Ridge Mountains. Far off to the westward another line of islands foreshadowed our present Pacific border. A few minor islands in the interior completed the archipelago.
From this bare skeleton the continent grew, partly by the deposit of sediment from the denudation of the original islands (which once towered miles, perhaps, where now they rise thousands of feet), but largely also by the deposit of organic remains, especially in the interior sea, which teemed with life. In the Silurian ages, invertebrates--brachiopods and crinoids and cephalopods--were the dominant types. But very early--no one knows just when--there came fishes of many strange forms, some of the early ones enclosed in turtle-like shells. Later yet, large spaces within the interior sea having risen to the surface, great marshes or forests of strange types of vegetation grew and deposited their remains to form coal-beds. Many times over such forests were formed, only to be destroyed by the oscillations of the land surface. All told, the strata of this Paleozoic period aggregate several miles in thickness, and the time consumed in their formation stands to all later time up to the present, according to Professor Dana's estimate, as three to one.
Towards the close of this Paleozoic era the Appalachian Mountains were slowly upheaved in great convoluted folds, some of them probably reaching three or four miles above the sea-level, though the tooth of time has since gnawed them down to comparatively puny limits. The continental areas thus enlarged were peopled during the ensuing Mesozoic time with multitudes of strange reptiles, many of them gigantic in size. The waters, too, still teeming with invertebrates and fishes, had their quota of reptilian monsters; and in the air were flying reptiles, some of which measured twenty-five feet from tip to tip of their batlike wings. During this era the Sierra Nevada Mountains rose. Near the eastern border of the forming continent the strata were perhaps now too thick and stiff to bend into mountain folds, for they were rent into great fissures, letting out floods of molten lava, remnants of which are still in evidence after ages of denudation, as the Palisades along the Hudson, and such elevations as Mount Holyoke in western Massachusetts.
Still there remained a vast interior sea, which later on, in the tertiary age, was to be divided by the slow uprising of the land, which only yesterday--that is to say, a million, or three or five or ten million, years ago--became the Rocky Mountains. High and erect these young mountains stand to this day, their sharp angles and rocky contours vouching for their youth, in strange contrast with the shrunken forms of the old Adirondacks, Green Mountains, and Appalachians, whose lowered heads and rounded shoulders attest the weight of ages. In the vast lakes which still remained on either side of the Rocky range, tertiary strata were slowly formed to the ultimate depth of two or three miles, enclosing here and there those vertebrate remains which were to be exposed again to view by denudation when the land rose still higher, and then, in our own time, to tell so wonderful a story to the paleontologist.
Finally, the interior seas were filled, and the shore lines of the continent assumed nearly their present outline.
Then came the long winter of the glacial epoch--perhaps of a succession of glacial epochs. The ice sheet extended southward to about the fortieth parallel, driving some animals before it, and destroying those that were unable to migrate. At its fulness, the great ice mass lay almost a mile in depth over New England, as attested by the scratched and polished rock surfaces and deposited erratics in the White Mountains. Such a mass presses down with a weight of about one hundred and twenty-five tons to the square foot, according to Dr. Croll's estimate. It crushed and ground everything beneath it more or less, and in some regions planed off hilly surfaces into prairies. Creeping slowly forward, it carried all manner of debris with it. When it melted away its terminal moraine built up the nucleus of the land masses now known as Long Island and Staten Island; other of its deposits formed the "drumlins" about Boston famous as Bunker and Breed's hills; and it left a long, irregular line of ridges of "till" or bowlder clay and scattered erratics clear across the country at about the latitude of New York city.
As the ice sheet slowly receded it left minor moraines all along its course. Sometimes its deposits dammed up river courses or inequalities in the surface, to form the lakes which everywhere abound over Northern territories. Some glacialists even hold the view first suggested by Ramsey, of the British Geological Survey, that the great glacial sheets scooped out the basins of many lakes, including the system that feeds the St. Lawrence. At all events, it left traces of its presence all along the line of its retreat, and its remnants exist to this day as mountain glaciers and the polar ice cap. Indeed, we live on the border of the last glacial epoch, for with the closing of this period the long geologic past merges into the present.
PAST, PRESENT, AND FUTURE
And the present, no less than the past, is a time of change. This is the thought which James Hutton conceived more than a century ago, but which his contemporaries and successors were so very slow to appreciate. Now, however, it has become axiomatic--one can hardly realize that it was ever doubted. Every new scientific truth, says Agassiz, must pass through three stages--first, men say it is not true; then they declare it hostile to religion; finally, they assert that every one has known it always. Hutton's truth that natural law is changeless and eternal has reached this final stage. Nowhere now could you find a scientist who would dispute the truth of that text which Lyell, quoting from Playfair's Illustrations of the Huttonian Theory, printed on the title-page of his Principles: "Amid all the revolutions of the globe the economy of Nature has been uniform, and her laws are the only things that have resisted the general movement. The rivers and the rocks, the seas and the continents, have been changed in all their parts; but the laws which direct those changes, and the rules to which they are subject, have remained invariably the same."
But, on the other hand, Hutton and Playfair, and in particular Lyell, drew inferences from this principle which the modern physicist can by no means admit. To them it implied that the changes on the surface of the earth have always been the same in degree as well as in kind, and must so continue while present forces hold their sway. In other words, they thought of the world as a great perpetual-motion machine. But the modern physicist, given truer mechanical insight by the doctrines of the conservation and the dissipation of energy, will have none of that. Lord Kelvin, in particular, has urged that in the periods of our earth's in fancy and adolescence its developmental changes must have been, like those of any other infant organism, vastly more rapid and pronounced than those of a later day; and to every clear thinker this truth also must now seem axiomatic.
Whoever thinks of the earth as a cooling globe can hardly doubt that its crust, when thinner, may have heaved under strain of the moon's tidal pull--whether or not that body was nearer--into great billows, daily rising and falling, like waves of the present seas vastly magnified.
Under stress of that same lateral pressure from contraction which now produces the slow depression of the Jersey coast, the slow rise of Sweden, the occasional belching of an insignificant volcano, the jetting of a geyser, or the trembling of an earthquake, once large areas were rent in twain, and vast floods of lava flowed over thousands of square miles of the earth's surface, perhaps, at a single jet; and, for aught we know to the contrary, gigantic mountains may have heaped up their contorted heads in cataclysms as spasmodic as even the most ardent catastrophist of the elder day of geology could have imagined.
The atmosphere of that early day, filled with vast volumes of carbon, oxygen, and other chemicals that have since been stored in beds of coal, limestone, and granites, may have worn down the rocks on the one hand and built up organic forms on the other, with a rapidity that would now seem hardly conceivable.
And yet while all these anomalous things went on, the same laws held sway that now are operative; and a true doctrine of uniformitarianism would make no unwonted concession in conceding them all--though most of the imbittered geological controversies of the middle of the nineteenth century were due to the failure of both parties to realize that simple fact.
And as of the past and present, so of the future. The same forces will continue to operate; and under operation of these unchanging forces each day will differ from every one that has preceded it. If it be true, as every physicist believes, that the earth is a cooling globe, then, whatever its present stage of refrigeration, the time must come when its surface contour will assume a rigidity of level not yet attained. Then, just as surely, the slow action of the elements will continue to wear away the land surfaces, particle by particle, and transport them to the ocean, as it does to-day, until, compensation no longer being afforded by the upheaval of the continents, the last foot of dry land will sink for the last time beneath the water, the last mountain-peak melting away, and our globe, lapsing like any other organism into its second childhood, will be on the surface--as presumably it was before the first continent rose--one vast "waste of waters." As puny man conceives time and things, an awful cycle will have lapsed; in the sweep of the cosmic life, a pulse-beat will have throbbed.
V. THE NEW SCIENCE OF METEOROLOGY
METEORITES
"An astonishing miracle has just occurred in our district," wrote M. Marais, a worthy if undistinguished citizen of France, from his home at L'Aigle, under date of "the 13th Floreal, year 11"--a date which outside of France would be interpreted as meaning May 3, 1803. This "miracle" was the appearance of a "fireball" in broad daylight--"perhaps it was wildfire," says the naive chronicle--which "hung over the meadow," being seen by many people, and then exploded with a loud sound, scattering thousands of stony fragments over the surface of a territory some miles in extent.
Such a "miracle" could not have been announced at a more opportune time. For some years the scientific world had been agog over the question whether such a form of lightning as that reported--appearing in a clear sky, and hurling literal thunderbolts--had real existence. Such cases had been reported often enough, it is true. The "thunderbolts" themselves were exhibited as sacred relics before many an altar, and those who doubted their authenticity had been chided as having "an evil heart of unbelief." But scientific scepticism had questioned the evidence, and late in the eighteenth century a consensus of opinion in the French Academy had declined to admit that such stones had been "conveyed to the earth by lightning," let alone any more miraculous agency.
In 1802, however, Edward Howard had read a paper before the Royal Society in which, after reviewing the evidence recently put forward, he had reached the conclusion that the fall of stones from the sky, sometimes or always accompanied by lightning, must be admitted as an actual phenomenon, however inexplicable. So now, when the great stone-fall at L'Aigle was announced, the French Academy made haste to send the brilliant young physicist Jean Baptiste Biot to investigate it, that the matter might, if possible, be set finally at rest. The investigation was in all respects successful, and Biot's report transferred the stony or metallic lightning-bolt--the aerolite or meteorite--from the realm of tradition and conjecture to that of accepted science.
But how explain this strange phenomenon? At once speculation was rife. One theory contended that the stony masses had not actually fallen, but had been formed from the earth by the action of the lightning; but this contention was early abandoned. The chemists were disposed to believe that the aerolites had been formed by the combination of elements floating in the upper atmosphere. Geologists, on the other hand, thought them of terrestrial origin, urging that they might have been thrown up by volcanoes. The astronomers, as represented by Olbers and Laplace, modified this theory by suggesting that the stones might, indeed, have been cast out by volcanoes, but by volcanoes situated not on the earth, but on the moon.
And one speculator of the time took a step even more daring, urging that the aerolites were neither of telluric nor selenitic origin, nor yet children of the sun, as the old Greeks had, many of them, contended, but that they are visitants from the depths of cosmic space. This bold speculator was the distinguished German physicist Ernst F. F. Chladni, a man of no small repute in his day. As early as 1794 he urged his cosmical theory of meteorites, when the very existence of meteorites was denied by most scientists. And he did more: he declared his belief that these falling stones were really one in origin and kind with those flashing meteors of the upper atmosphere which are familiar everywhere as "shooting-stars."
Each of these coruscating meteors, he affirmed, must tell of the ignition of a bit of cosmic matter entering the earth's atmosphere. Such wandering bits of matter might be the fragments of shattered worlds, or, as Chladni thought more probable, merely aggregations of "world stuff" never hitherto connected with any large planetary mass.
Naturally enough, so unique a view met with very scant favor. Astronomers at that time saw little to justify it; and the non-scientific world rejected it with fervor as being "atheistic and heretical," because its acceptance would seem to imply that the universe is not a perfect mechanism.
Some light was thrown on the moot point presently by the observations of Brandes and Benzenberg, which tended to show that falling-stars travel at an actual speed of from fifteen to ninety miles a second. This observation tended to discredit the selenitic theory, since an object, in order to acquire such speed in falling merely from the moon, must have been projected with an initial velocity not conceivably to be given by any lunar volcanic impulse. Moreover, there was a growing conviction that there are no active volcanoes on the moon, and other considerations of the same tenor led to the complete abandonment of the selenitic theory.
But the theory of telluric origin of aerolites was by no means so easily disposed of. This was an epoch when electrical phenomena were exciting unbounded and universal interest, and there was a not unnatural tendency to appeal to electricity in explanation of every obscure phenomenon; and in this case the seeming similarity between a lightning flash and the flash of an aerolite lent color to the explanation. So we find Thomas Forster, a meteorologist of repute, still adhering to the atmospheric theory of formation of aerolites in his book published in 1823; and, indeed, the prevailing opinion of the time seemed divided between various telluric theories, to the neglect of any cosmical theory whatever.
But in 1833 occurred a phenomenon which set the matter finally at rest. A great meteoric shower occurred in November of that year, and in observing it Professor Denison Olmstead, of Yale, noted that all the stars of the shower appeared to come from a single centre or vanishing-point in the heavens, and that this centre shifted its position with the stars, and hence was not telluric. The full significance of this observation was at once recognized by astronomers; it demonstrated beyond all cavil the cosmical origin of the shooting-stars. Some conservative meteorologists kept up the argument for the telluric origin for some decades to come, as a matter of course--such a band trails always in the rear of progress. But even these doubters were silenced when the great shower of shooting-stars appeared again in 1866, as predicted by Olbers and Newton, radiating from the same point of the heavens as before.
Since then the spectroscope has added its confirmatory evidence as to the identity of meteorite and shooting-star, and, moreover, has linked these atmospheric meteors with such distant cosmic residents as comets and nebulae. Thus it appears that Chladni's daring hypothesis of 1794 has been more than verified, and that the fragments of matter dissociated from planetary connection--which be postulated and was declared atheistic for postulating--have been shown to be billions of times more numerous than any larger cosmic bodies of which we have cognizance--so widely does the existing universe differ from man's preconceived notions as to what it should be.
Thus also the "miracle" of the falling stone, against which the scientific scepticism of yesterday presented "an evil heart of unbelief," turns out to be the most natural phenomena, inasmuch as it is repeated in our atmosphere some millions of times each day.
THE AURORA BOREALIS
If fire-balls were thought miraculous and portentous in days of yore, what interpretation must needs have been put upon that vastly more picturesque phenomenon, the aurora? "Through all the city," says the Book of Maccabees, "for the space of almost forty days, there were seen horsemen running in the air, in cloth of gold, armed with lances, like a band of soldiers: and troops of horsemen in array encountering and running one against another, with shaking of shields and multitude of pikes, and drawing of swords, and casting of darts, and glittering of golden ornaments and harness." Dire omens these; and hardly less ominous the aurora seemed to all succeeding generations that observed it down well into the eighteenth century--as witness the popular excitement in England in 1716 over the brilliant aurora of that year, which became famous through Halley's description.
But after 1752, when Franklin dethroned the lightning, all spectacular meteors came to be regarded as natural phenomena, the aurora among the rest. Franklin explained the aurora--which was seen commonly enough in the eighteenth century, though only recorded once in the seventeenth--as due to the accumulation of electricity on the surface of polar snows, and its discharge to the equator through the upper atmosphere. Erasmus Darwin suggested that the luminosity might be due to the ignition of hydrogen, which was supposed by many philosophers to form the upper atmosphere. Dalton, who first measured the height of the aurora, estimating it at about one hundred miles, thought the phenomenon due to magnetism acting on ferruginous particles in the air, and his explanation was perhaps the most popular one at the beginning of the last century.
Since then a multitude of observers have studied the aurora, but the scientific grasp has found it as elusive in fact as it seems to casual observation, and its exact nature is as undetermined to-day as it was a hundred years ago. There has been no dearth of theories concerning it, however. Blot, who studied it in the Shetland Islands in 1817, thought it due to electrified ferruginous dust, the origin of which he ascribed to Icelandic volcanoes. Much more recently the idea of ferruginous particles has been revived, their presence being ascribed not to volcanoes, but to the meteorites constantly being dissipated in the upper atmosphere. Ferruginous dust, presumably of such origin, has been found on the polar snows, as well as on the snows of mountain-tops, but whether it could produce the phenomena of auroras is at least an open question.
Other theorists have explained the aurora as due to the accumulation of electricity on clouds or on spicules of ice in the upper air. Yet others think it due merely to the passage of electricity through rarefied air itself. Humboldt considered the matter settled in yet another way when Faraday showed, in 1831, that magnetism may produce luminous effects. But perhaps the prevailing theory of to-day assumes that the aurora is due to a current of electricity generated at the equator and passing through upper regions of space, to enter the earth at the magnetic poles--simply reversing the course which Franklin assumed.
The similarity of the auroral light to that generated in a vacuum bulb by the passage of electricity lends support to the long-standing supposition that the aurora is of electrical origin, but the subject still awaits complete elucidation. For once even that mystery-solver the spectroscope has been baffled, for the line it sifts from the aurora is not matched by that of any recognized substance. A like line is found in the zodiacal light, it is true, but this is of little aid, for the zodiacal light, though thought by some astronomers to be due to meteor swarms about the sun, is held to be, on the whole, as mysterious as the aurora itself.
Whatever the exact nature of the aurora, it has long been known to be intimately associated with the phenomena of terrestrial magnetism. Whenever a brilliant aurora is visible, the world is sure to be visited with what Humboldt called a magnetic storm--a "storm" which manifests itself to human senses in no way whatsoever except by deflecting the magnetic needle and conjuring with the electric wire. Such magnetic storms are curiously associated also with spots on the sun--just how no one has explained, though the fact itself is unquestioned. Sun-spots, too, seem directly linked with auroras, each of these phenomena passing through periods of greatest and least frequency in corresponding cycles of about eleven years' duration.
It was suspected a full century ago by Herschel that the variations in the number of sun-spots had a direct effect upon terrestrial weather, and he attempted to demonstrate it by using the price of wheat as a criterion of climatic conditions, meantime making careful observation of the sun-spots. Nothing very definite came of his efforts in this direction, the subject being far too complex to be determined without long periods of observation. Latterly, however, meteorologists, particularly in the tropics, are disposed to think they find evidence of some such connection between sun-spots and the weather as Herschel suspected. Indeed, Mr. Meldrum declares that there is a positive coincidence between periods of numerous sun-spots and seasons of excessive rain in India.
That some such connection does exist seems intrinsically probable. But the modern meteorologist, learning wisdom of the past, is extremely cautious about ascribing casual effects to astronomical phenomena. He finds it hard to forget that until recently all manner of climatic conditions were associated with phases of the moon; that not so very long ago showers of falling-stars were considered "prognostic" of certain kinds of weather; and that the "equinoctial storm" had been accepted as a verity by every one, until the unfeeling hand of statistics banished it from the earth.
Yet, on the other hand, it is easily within the possibilities that the science of the future may reveal associations between the weather and sun-spots, auroras, and terrestrial magnetism that as yet are hardly dreamed of. Until such time, however, these phenomena must feel themselves very grudgingly admitted to the inner circle of meteorology. More and more this science concerns itself, in our age of concentration and specialization, with weather and climate. Its votaries no longer concern themselves with stars or planets or comets or shooting-stars--once thought the very essence of guides to weather wisdom; and they are even looking askance at the moon, and asking her to show cause why she also should not be excluded from their domain. Equally little do they care for the interior of the earth, since they have learned that the central emanations of heat which Mairan imagined as a main source of aerial warmth can claim no such distinction. Even such problems as why the magnetic pole does not coincide with the geographical, and why the force of terrestrial magnetism decreases from the magnetic poles to the magnetic equator, as Humboldt first discovered that it does, excite them only to lukewarm interest; for magnetism, they say, is not known to have any connection whatever with climate or weather.
EVAPORATION, CLOUD FORMATION, AND DEW
There is at least one form of meteor, however, of those that interested our forebears whose meteorological importance they did not overestimate. This is the vapor of water. How great was the interest in this familiar meteor at the beginning of the century is attested by the number of theories then extant regarding it; and these conflicting theories bear witness also to the difficulty with which the familiar phenomenon of the evaporation of water was explained.
Franklin had suggested that air dissolves water much as water dissolves salt, and this theory was still popular, though Deluc had disproved it by showing that water evaporates even more rapidly in a vacuum than in air. Deluc's own theory, borrowed from earlier chemists, was that evaporation is the chemical union of particles of water with particles of the supposititious element heat. Erasmus Darwin combined the two theories, suggesting that the air might hold a variable quantity of vapor in mere solution, and in addition a permanent moiety in chemical combination with caloric.
Undisturbed by these conflicting views, that strangely original genius, John Dalton, afterwards to be known as perhaps the greatest of theoretical chemists, took the question in hand, and solved it by showing that water exists in the air as an utterly independent gas. He reached a partial insight into the matter in 1793, when his first volume of meteorological essays was published; but the full elucidation of the problem came to him in 1801. The merit of his studies was at once recognized, but the tenability of his hypothesis was long and ardently disputed.
While the nature of evaporation was in dispute, as a matter of course the question of precipitation must be equally undetermined. The most famous theory of the period was that formulated by Dr. Hutton in a paper read before the Royal Society of Edinburgh, and published in the volume of transactions which contained also the same author's epoch-making paper on geology. This "theory of rain" explained precipitation as due to the cooling of a current of saturated air by contact with a colder current, the assumption being that the surplusage of moisture was precipitated in a chemical sense, just as the excess of salt dissolved in hot water is precipitated when the water cools. The idea that the cooling of the saturated air causes the precipitation of its moisture is the germ of truth that renders this paper of Hutton's important. All correct later theories build on this foundation.
"Let us suppose the surface of this earth wholly covered with water," said Hutton, "and that the sun were stationary, being always vertical in one place; then, from the laws of heat and rarefaction, there would be formed a circulation in the atmosphere, flowing from the dark and cold hemisphere to the heated and illuminated place, in all directions, towards the place of the greatest cold.
"As there is for the atmosphere of this earth a constant cooling cause, this fluid body could only arrive at a certain degree of heat; and this would be regularly decreasing from the centre of illumination to the opposite point of the globe, most distant from the light and heat. Between these two regions of extreme heat and cold there would, in every place, be found two streams of air following in opposite directions. If those streams of air, therefore, shall be supposed as both sufficiently saturated with humidity, then, as they are of different temperatures, there would be formed a continual condensation of aqueous vapor, in some middle region of the atmosphere, by the commixtion of part of those two opposite streams.
"Hence there is reason to believe that in this supposed case there would be formed upon the surface of the globe three different regions--the torrid region, the temperate, and the frigid. These three regions would continue stationary; and the operations of each would be continual. In the torrid region, nothing but evaporation and heat would take place; no cloud could be formed, because in changing the transparency of the atmosphere to opacity it would be heated immediately by the operation of light, and thus the condensed water would be again evaporated. But this power of the sun would have a termination; and it is these that would begin the region of temperate heat and of continual rain. It is not probable that the region of temperance would reach far beyond the region of light; and in the hemisphere of darkness there would be found a region of extreme cold and perfect dryness.
"Let us now suppose the earth as turning on its axis in the equinoctial situation. The torrid region would thus be changed into a zone, in which there would be night and day; consequently, here would be much temperance, compared with the torrid region now considered; and here perhaps there would be formed periodical condensation and evaporation of humidity, corresponding to the seasons of night and day. As temperance would thus be introduced into the region of torrid extremity, so would the effect of this change be felt over all the globe, every part of which would now be illuminated, consequently heated in some degree. Thus we would have a line of great heat and evaporation, graduating each way into a point of great cold and congelation. Between these two extremes of heat and cold there would be found in each hemisphere a region of much temperance, in relation to heat, but of much humidity in the atmosphere, perhaps of continual rain and condensation.
"The supposition now formed must appear extremely unfit for making this globe a habitable world in every part; but having thus seen the effect of night and day in temperating the effects of heat and cold in every place, we are now prepared to contemplate the effects of supposing this globe to revolve around the sun with a certain inclination of its axis. By this beautiful contrivance, that comparatively uninhabited globe is now divided into two hemispheres, each of which is thus provided with a summer and a winter season. But our present view is limited to the evaporation and condensation of humidity; and, in this contrivance of the seasons, there must appear an ample provision for those alternate operations in every part; for as the place of the vertical sun is moved alternately from one tropic to the other, heat and cold, the original causes of evaporation and condensation, must be carried over all the globe, producing either annual seasons of rain or diurnal seasons of condensation and evaporation, or both these seasons, more or less--that is, in some degree.
"The original cause of motion in the atmosphere is the influence of the sun heating the surface of the earth exposed to that luminary. We have not supposed that surface to have been of one uniform shape and similar substance; from whence it has followed that the annual propers of the sun, perhaps also the diurnal propers, would produce a regular condensation of rain in certain regions, and the evaporation of humidity in others; and this would have a regular progress in certain determined seasons, and would not vary. But nothing can be more distant from this supposition, that is the natural constitution of the earth; for the globe is composed of sea and land, in no regular shape or mixture, while the surface of the land is also irregular with respect to its elevations and depressions, and various with regard to the humidity and dryness of that part which is exposed to heat as the cause of evaporation. Hence a source of the most valuable motions in the fluid atmosphere with aqueous vapor, more or less, so far as other natural operations will admit; and hence a source of the most irregular commixture of the several parts of this elastic fluid, whether saturated or not with aqueous vapor.
"According to the theory, nothing is required for the production of rain besides the mixture of portions of the atmosphere with humidity, and of mixing the parts that are in different degrees of heat. But we have seen the causes of saturating every portion of the atmosphere with humidity and of mixing the parts which are in different degrees of heat. Consequently, over all the surface of the globe there should happen occasionally rain and evaporation, more or less; and also, in every place, those vicissitudes should be observed to take place with some tendency to regularity, which, however, may be so disturbed as to be hardly distinguishable upon many occasions. Variable winds and variable rains should be found in proportion as each place is situated in an irregular mixture of land and water; whereas regular winds should be found in proportion to the uniformity of the surface; and regular rains in proportion to the regular changes of those winds by which the mixture of the atmosphere necessary to the rain may be produced. But as it will be acknowledged that this is the case in almost all this earth where rain appears according to the conditions here specified, the theory is found to be thus in conformity with nature, and natural appearances are thus explained by the theory."(1)
The next ambitious attempt to explain the phenomena of aqueous meteors was made by Luke Howard, in his remarkable paper on clouds, published in the Philosophical Magazine in 1803--the paper in which the names cirrus, cumulus, stratus, etc., afterwards so universally adopted, were first proposed. In this paper Howard acknowledges his indebtedness to Dalton for the theory of evaporation; yet he still clings to the idea that the vapor, though independent of the air, is combined with particles of caloric. He holds that clouds are composed of vapor that has previously risen from the earth, combating the opinions of those who believe that they are formed by the union of hydrogen and oxygen existing independently in the air; though he agrees with these theorists that electricity has entered largely into the modus operandi of cloud formation. He opposes the opinion of Deluc and De Saussure that clouds are composed of particles of water in the form of hollow vesicles (miniature balloons, in short, perhaps filled with hydrogen), which untenable opinion was a revival of the theory as to the formation of all vapor which Dr. Halley had advocated early in the eighteenth century.
Of particular interest are Howard's views as to the formation of dew, which he explains as caused by the particles of caloric forsaking the vapor to enter the cool body, leaving the water on the surface. This comes as near the truth, perhaps, as could be expected while the old idea as to the materiality of heat held sway. Howard believed, however, that dew is usually formed in the air at some height, and that it settles to the surface, opposing the opinion, which had gained vogue in France and in America (where Noah Webster prominently advocated it), that dew ascends from the earth.
The complete solution of the problem of dew formation--which really involved also the entire question of precipitation of watery vapor in any form--was made by Dr. W. C. Wells, a man of American birth, whose life, however, after boyhood, was spent in Scotland (where as a young man he enjoyed the friendship of David Hume) and in London. Inspired, no doubt, by the researches of Mack, Hutton, and their confreres of that Edinburgh school, Wells made observations on evaporation and precipitation as early as 1784, but other things claimed his attention; and though he asserts that the subject was often in his mind, he did not take it up again in earnest until about 1812.
Meantime the observations on heat of Rumford and Davy and Leslie had cleared the way for a proper interpretation of the facts--about the facts themselves there had long been practical unanimity of opinion. Dr. Black, with his latent-heat observations, had really given the clew to all subsequent discussions of the subject of precipitation of vapor; and from this time on it had been known that heat is taken up when water evaporates, and given out again when it condenses. Dr. Darwin had shown in 1788, in a paper before the Royal Society, that air gives off heat on contracting and takes it up on expanding; and Dalton, in his essay of 1793, had explained this phenomenon as due to the condensation and vaporization of the water contained in the air.
But some curious and puzzling observations which Professor Patrick Wilson, professor of astronomy in the University of Glasgow, had communicated to the Royal Society of Edinburgh in 1784, and some similar ones made by Mr. Six, of Canterbury, a few years later, had remained unexplained. Both these gentlemen observed that the air is cooler where dew is forming than the air a few feet higher, and they inferred that the dew in forming had taken up heat, in apparent violation of established physical principles.
It remained for Wells, in his memorable paper of 1816, to show that these observers had simply placed the cart before the horse. He made it clear that the air is not cooler because the dew is formed, but that the dew is formed because the air is cooler--having become so through radiation of heat from the solids on which the dew forms. The dew itself, in forming, gives out its latent heat, and so tends to equalize the temperature.
Wells's paper is so admirable an illustration of the lucid presentation of clearly conceived experiments and logical conclusions that we should do it injustice not to present it entire. The author's mention of the observations of Six and Wilson gives added value to his own presentation.
Dr. Wells's Essay on Dew
"I was led in the autumn of 1784, by the event of a rude experiment, to think it probable that the formation of dew is attended with the production of cold. In 1788, a paper on hoar-frost, by Mr. Patrick Wilson, of Glasgow, was published in the first volume of the Transactions of the Royal Society of Edinburgh, by which it appeared that this opinion bad been entertained by that gentleman before it had occurred to myself. In the course of the same year, Mr. Six, of Canterbury, mentioned in a paper communicated to the Royal Society that on clear and dewy nights he always found the mercury lower in a thermometer laid upon the ground in a meadow in his neighborhood than it was in a similar thermometer suspended in the air six feet above the former; and that upon one night the difference amounted to five degrees of Fahrenheit's scale. Mr. Six, however, did not suppose, agreeably to the opinion of Mr. Wilson and myself, that the cold was occasioned by the formation of dew, but imagined that it proceeded partly from the low temperature of the air, through which the dew, already formed in the atmosphere, had descended, and partly from the evaporation of moisture from the ground, on which his thermometer had been placed. The conjecture of Mr. Wilson and the observations of Mr. Six, together with many facts which I afterwards learned in the course of reading, strengthened my opinion; but I made no attempt, before the autumn of 1811, to ascertain by experiment if it were just, though it had in the mean time almost daily occurred to my thoughts. Happening, in that season, to be in that country in a clear and calm night, I laid a thermometer upon grass wet with dew, and suspended a second in the air, two feet above the other. An hour afterwards the thermometer on the grass was found to be eight degrees lower, by Fahrenheit's division, than the one in the air. Similar results having been obtained from several similar experiments, made during the same autumn, I determined in the next spring to prosecute the subject with some degree of steadiness, and with that view went frequently to the house of one of my friends who lives in Surrey.
"At the end of two months I fancied that I had collected information worthy of being published; but, fortunately, while preparing an account of it I met by accident with a small posthumous work by Mr. Six, printed at Canterbury in 1794, in which are related differences observed on dewy nights between thermometers placed upon grass and others in the air that are much greater than those mentioned in the paper presented by him to the Royal Society in 1788. In this work, too, the cold of the grass is attributed, in agreement with the opinion of Mr. Wilson, altogether to the dew deposited upon it. The value of my own observations appearing to me now much diminished, though they embraced many points left untouched by Mr. Six, I gave up my intentions of making them known. Shortly after, however, upon considering the subject more closely, I began to suspect that Mr. Wilson, Mr. Six, and myself had all committed an error regarding the cold which accompanies dew as an effect of the formation of that fluid. I therefore resumed my experiments, and having by means of them, I think, not only established the justness of my suspicions, but ascertained the real cause both of dew and of several other natural appearances which have hitherto received no sufficient explanation, I venture now to submit to the consideration of the learned an account of some of my labors, without regard to the order of time in which they were performed, and of various conclusions which may be drawn from them, mixed with facts and opinions already published by others:
"There are various occurrences in nature which seem to me strictly allied to dew, though their relation to it be not always at first sight perceivable. The statement and explanation of several of these will form the concluding part of the present essay.
"1. I observed one morning, in winter, that the insides of the panes of glass in the windows of my bedchamber were all of them moist, but that those which had been covered by an inside shutter during the night were much more so than the others which had been uncovered. Supposing that this diversity of appearance depended upon a difference of temperature, I applied the naked bulbs of two delicate thermometers to a covered and uncovered pane; on which I found that the former was three degrees colder than the latter. The air of the chamber, though no fire was kept in it, was at this time eleven and one-half degrees warmer than that without. Similar experiments were made on many other mornings, the results of which were that the warmth of the internal air exceeded that of the external from eight to eighteen degrees, the temperature of the covered panes would be from one to five degrees less than the uncovered; that the covered were sometimes dewed, while the uncovered were dry; that at other times both were free from moisture; that the outsides of the covered and uncovered panes had similar differences with respect to heat, though not so great as those of the inner surfaces; and that no variation in the quantity of these differences was occasioned by the weather's being cloudy or fair, provided the heat of the internal air exceeded that of the external equally in both of those states of the atmosphere.
"The remote reason of these differences did not immediately present itself. I soon, however, saw that the closed shutter shielded the glass which it covered from the heat that was radiated to the windows by the walls and furniture of the room, and thus kept it nearer to the temperature of the external air than those parts could be which, from being uncovered, received the heat emitted to them by the bodies just mentioned.
"In making these experiments, I seldom observed the inside of any pane to be more than a little damped, though it might be from eight to twelve degrees colder than the general mass of the air in the room; while, in the open air, I had often found a great dew to form on substances only three or four degrees colder than the atmosphere. This at first surprised me; but the cause now seems plain. The air of the chamber had once been a portion of the external atmosphere, and had afterwards been heated, when it could receive little accessories to its original moisture. It constantly required being cooled considerably before it was even brought back to its former nearness to repletion with water; whereas the whole external air is commonly, at night, nearly replete with moisture, and therefore readily precipitates dew on bodies only a little colder than itself.
"When the air of a room is warmer than the external atmosphere, the effect of an outside shutter on the temperature of the glass of the window will be directly opposite to what has just been stated; since it must prevent the radiation, into the atmosphere, of the heat of the chamber transmitted through the glass.
"2. Count Rumford appears to have rightly conjectured that the inhabitants of certain hot countries, who sleep at nights on the tops of their houses, are cooled during this exposure by the radiation of their heat to the sky; or, according to his manner of expression, by receiving frigorific rays from the heavens. Another fact of this kind seems to be the greater chill which we often experience upon passing at night from the cover of a house into the air than might have been expected from the cold of the external atmosphere. The cause, indeed, is said to be the quickness of transition from one situation to another. But if this were the whole reason, an equal chill would be felt in the day, when the difference, in point of heat, between the internal and external air was the same as at night, which is not the case. Besides, if I can trust my own observation, the feeling of cold from this cause is more remarkable in a clear than in a cloudy night, and in the country than in towns. The following appears to be the manner in which these things are chiefly to be explained:
"During the day our bodies while in the open air, although not immediately exposed to the sun's rays, are yet constantly deriving heat from them by means of the reflection of the atmosphere. This heat, though it produces little change on the temperature of the air which it traverses, affords us some compensation for the heat which we radiate to the heavens. At night, also, if the sky be overcast, some compensation will be made to us, both in the town and in the country, though in a less degree than during the day, as the clouds will remit towards the earth no inconsiderable quantity of heat. But on a clear night, in an open part of the country, nothing almost can be returned to us from above in place of the heat which we radiate upward. In towns, however, some compensation will be afforded even on the clearest nights for the heat which we lose in the open air by that which is radiated to us from the sun round buildings.
"To our loss of heat by radiation at times that we derive little compensation from the radiation of other bodies is probably to be attributed a great part of the hurtful effects of the night air. Descartes says that these are not owing to dew, as was the common opinion of his contemporaries, but to the descent of certain noxious vapors which have been exhaled from the earth during the heat of the day, and are afterwards condensed by the cold of a serene night. The effects in question certainly cannot be occasioned by dew, since that fluid does not form upon a healthy human body in temperate climates; but they may, notwithstanding, arise from the same cause that produces dew on those substances which do not, like the human body, possess the power of generating heat for the supply of what they lose by radiation or any other means."(2)
This explanation made it plain why dew forms on a clear night, when there are no clouds to reflect the radiant heat. Combined with Dalton's theory that vapor is an independent gas, limited in quantity in any given space by the temperature of that space, it solved the problem of the formation of clouds, rain, snow, and hoar-frost. Thus this paper of Wells's closed the epoch of speculation regarding this field of meteorology, as Hutton's paper of 1784 had opened it. The fact that the volume containing Hutton's paper contained also his epoch-making paper on geology finds curiously a duplication in the fact that Wells's volume contained also his essay on Albinism, in which the doctrine of natural selection was for the first time formulated, as Charles Darwin freely admitted after his own efforts had made the doctrine famous.
ISOTHERMS AND OCEAN CURRENTS
The very next year after Dr. Wells's paper was published there appeared in France the third volume of the Memoires de Physique et de Chimie de la Societe d'Arcueil, and a new epoch in meteorology was inaugurated. The society in question was numerically an inconsequential band, listing only a dozen members; but every name was a famous one: Arago, Berard, Berthollet, Biot, Chaptal, De Candolle, Dulong, Gay-Lussac, Humboldt, Laplace, Poisson, and Thenard--rare spirits every one. Little danger that the memoirs of such a band would be relegated to the dusty shelves where most proceedings of societies belong--no milk-for-babes fare would be served to such a company.
The particular paper which here interests us closes this third and last volume of memoirs. It is entitled "Des Lignes Isothermes et de la Distribution de la Chaleursurle Globe." The author is Alexander Humboldt. Needless to say, the topic is handled in a masterly manner. The distribution of heat on the surface of the globe, on the mountain-sides, in the interior of the earth; the causes that regulate such distribution; the climatic results--these are the topics discussed. But what gives epochal character to the paper is the introduction of those isothermal lines circling the earth in irregular course, joining together places having the same mean annual temperature, and thus laying the foundation for a science of comparative climatology.
It is true the attempt to study climates comparatively was not new. Mairan had attempted it in those papers in which he developed his bizarre ideas as to central emanations of heat. Euler had brought his profound mathematical genius to bear on the topic, evolving the "extraordinary conclusion that under the equator at midnight the cold ought to be more rigorous than at the poles in winter." And in particular Richard Kirwan, the English chemist, had combined the mathematical and the empirical methods and calculated temperatures for all latitudes. But Humboldt differs from all these predecessors in that he grasps the idea that the basis of all such computations should be not theory, but fact. He drew his isothermal lines not where some occult calculation would locate them on an ideal globe, but where practical tests with the thermometer locate them on our globe as it is. London, for example, lies in the same latitude as the southern extremity of Hudson Bay; but the isotherm of London, as Humboldt outlines it, passes through Cincinnati.
Of course such deviations of climatic conditions between places in the same latitude had long been known. As Humboldt himself observes, the earliest settlers of America were astonished to find themselves subjected to rigors of climate for which their European experience had not at all prepared them. Moreover, sagacious travellers, in particular Cook's companion on his second voyage, young George Forster, had noted as a general principle that the western borders of continents in temperate regions are always warmer than corresponding latitudes of their eastern borders; and of course the general truth of temperatures being milder in the vicinity of the sea than in the interior of continents had long been familiar. But Humboldt's isothermal lines for the first time gave tangibility to these ideas, and made practicable a truly scientific study of comparative climatology.
In studying these lines, particularly as elaborated by further observations, it became clear that they are by no means haphazard in arrangement, but are dependent upon geographical conditions which in most cases are not difficult to determine. Humboldt himself pointed out very clearly the main causes that tend to produce deviations from the average--or, as Dove later on called it, the normal--temperature of any given latitude. For example, the mean annual temperature of a region (referring mainly to the northern hemisphere) is raised by the proximity of a western coast; by a divided configuration of the continent into peninsulas; by the existence of open seas to the north or of radiating continental surfaces to the south; by mountain ranges to shield from cold winds; by the infrequency of swamps to become congealed; by the absence of woods in a dry, sandy soil; and by the serenity of sky in the summer months and the vicinity of an ocean current bringing water which is of a higher temperature than that of the surrounding sea.
Conditions opposite to these tend, of course, correspondingly to lower the temperature. In a word, Humboldt says the climatic distribution of heat depends on the relative distribution of land and sea, and on the "hypsometrical configuration of the continents"; and he urges that "great meteorological phenomena cannot be comprehended when considered independently of geognostic relations"--a truth which, like most other general principles, seems simple enough once it is pointed out.
With that broad sweep of imagination which characterized him, Humboldt speaks of the atmosphere as the "aerial ocean, in the lower strata and on the shoals of which we live," and he studies the atmospheric phenomena always in relation to those of that other ocean of water. In each of these oceans there are vast permanent currents, flowing always in determinate directions, which enormously modify the climatic conditions of every zone. The ocean of air is a vast maelstrom, boiling up always under the influence of the sun's heat at the equator, and flowing as an upper current towards either pole, while an undercurrent from the poles, which becomes the trade-winds, flows towards the equator to supply its place.
But the superheated equatorial air, becoming chilled, descends to the surface in temperate latitudes, and continues its poleward journey as the anti-trade-winds. The trade-winds are deflected towards the west, because in approaching the equator they constantly pass over surfaces of the earth having a greater and greater velocity of rotation, and so, as it were, tend to lag behind--an explanation which Hadley pointed out in 1735, but which was not accepted until Dalton independently worked it out and promulgated it in 1793. For the opposite reason, the anti-trades are deflected towards the east; hence it is that the western, borders of continents in temperate zones are bathed in moist sea-breezes, while their eastern borders lack this cold-dispelling influence.
In the ocean of water the main currents run as more sharply circumscribed streams--veritable rivers in the sea. Of these the best known and most sharply circumscribed is the familiar Gulf Stream, which has its origin in an equatorial current, impelled westward by trade-winds, which is deflected northward in the main at Cape St. Roque, entering the Caribbean Sea and Gulf of Mexico, to emerge finally through the Strait of Florida, and journey off across the Atlantic to warm the shores of Europe.
Such, at least, is the Gulf Stream as Humboldt understood it. Since his time, however, ocean currents in general, and this one in particular, have been the subject of no end of controversy, it being hotly disputed whether either causes or effects of the Gulf Stream are just what Humboldt, in common with others of his time, conceived them to be. About the middle of the century Lieutenant M. F. Maury, the distinguished American hydrographer and meteorologist, advocated a theory of gravitation as the chief cause of the currents, claiming that difference in density, due to difference in temperature and saltness, would sufficiently account for the oceanic circulation. This theory gained great popularity through the wide circulation of Maury's Physical Geography of the Sea, which is said to have passed through more editions than any other scientific book of the period; but it was ably and vigorously combated by Dr. James Croll, the Scottish geologist, in his Climate and Time, and latterly the old theory that ocean currents are due to the trade-winds has again come into favor. Indeed, very recently a model has been constructed, with the aid of which it is said to have been demonstrated that prevailing winds in the direction of the actual trade-winds would produce such a current as the Gulf Stream.
Meantime, however, it is by no means sure that gravitation does not enter into the case to the extent of producing an insensible general oceanic circulation, independent of the Gulf Stream and similar marked currents, and similar in its larger outlines to the polar-equatorial circulation of the air. The idea of such oceanic circulation was first suggested in detail by Professor Lenz, of St. Petersburg, in 1845, but it was not generally recognized until Dr. Carpenter independently hit upon the idea more than twenty years later. The plausibility of the conception is obvious; yet the alleged fact of such circulation has been hotly disputed, and the question is still sub judice.
But whether or not such general circulation of ocean water takes place, it is beyond dispute that the recognized currents carry an enormous quantity of heat from the tropics towards the poles. Dr. Croll, who has perhaps given more attention to the physics of the subject than almost any other person, computes that the Gulf Stream conveys to the North Atlantic one-fourth as much heat as that body receives directly from the sun, and he argues that were it not for the transportation of heat by this and similar Pacific currents, only a narrow tropical region of the globe would be warm enough for habitation by the existing faunas. Dr. Croll argues that a slight change in the relative values of northern and southern trade-winds (such as he believes has taken place at various periods in the past) would suffice to so alter the equatorial current which now feeds the Gulf Stream that its main bulk would be deflected southward instead of northward, by the angle of Cape St. Roque. Thus the Gulf Stream would be nipped in the bud, and, according to Dr. Croll's estimates, the results would be disastrous for the northern hemisphere. The anti-trades, which now are warmed by the Gulf Stream, would then blow as cold winds across the shores of western Europe, and in all probability a glacial epoch would supervene throughout the northern hemisphere.
The same consequences, so far as Europe is concerned at least, would apparently ensue were the Isthmus of Panama to settle into the sea, allowing the Caribbean current to pass into the Pacific. But the geologist tells us that this isthmus rose at a comparatively recent geological period, though it is hinted that there had been some time previously a temporary land connection between the two continents. Are we to infer, then, that the two Americas in their unions and disunions have juggled with the climate of the other hemisphere? Apparently so, if the estimates made of the influence of the Gulf Stream be tenable. It is a far cry from Panama to Russia. Yet it seems within the possibilities that the meteorologist may learn from the geologist of Central America something that will enable him to explain to the paleontologist of Europe how it chanced that at one time the mammoth and rhinoceros roamed across northern Siberia, while at another time the reindeer and musk-ox browsed along the shores of the Mediterranean.
Possibilities, I said, not probabilities. Yet even the faint glimmer of so alluring a possibility brings home to one with vividness the truth of Humboldt's perspicuous observation that meteorology can be properly comprehended only when studied in connection with the companion sciences. There are no isolated phenomena in nature.
CYCLONES AND ANTI-CYCLONES
Yet, after all, it is not to be denied that the chief concern of the meteorologist must be with that other medium, the "ocean of air, on the shoals of which we live." For whatever may be accomplished by water currents in the way of conveying heat, it is the wind currents that effect the final distribution of that heat. As Dr. Croll has urged, the waters of the Gulf Stream do not warm the shores of Europe by direct contact, but by warming the anti-trade-winds, which subsequently blow across the continent. And everywhere the heat accumulated by water becomes effectual in modifying climate, not so much by direct radiation as by diffusion through the medium of the air.
This very obvious importance of aerial currents led to their practical study long before meteorology had any title to the rank of science, and Dalton's explanation of the trade-winds had laid the foundation for a science of wind dynamics before the beginning of the nineteenth century. But no substantial further advance in this direction was effected until about 1827, when Heinrich W. Dove, of Konigsberg, afterwards to be known as perhaps the foremost meteorologist of his generation, included the winds among the subjects of his elaborate statistical studies in climatology.
Dove classified the winds as permanent, periodical, and variable. His great discovery was that all winds, of whatever character, and not merely the permanent winds, come under the influence of the earth's rotation in such a way as to be deflected from their course, and hence to take on a gyratory motion--that, in short, all local winds are minor eddies in the great polar-equatorial whirl, and tend to reproduce in miniature the character of that vast maelstrom. For the first time, then, temporary or variable winds were seen to lie within the province of law.
A generation later, Professor William Ferrel, the American meteorologist, who had been led to take up the subject by a perusal of Maury's discourse on ocean winds, formulated a general mathematical law, to the effect that any body moving in a right line along the surface of the earth in any direction tends to have its course deflected, owing to the earth's rotation, to the right hand in the northern and to the left hand in the southern hemisphere. This law had indeed been stated as early as 1835 by the French physicist Poisson, but no one then thought of it as other than a mathematical curiosity; its true significance was only understood after Professor Ferrel had independently rediscovered it (just as Dalton rediscovered Hadley's forgotten law of the trade-winds) and applied it to the motion of wind currents.
Then it became clear that here is a key to the phenomena of atmospheric circulation, from the great polar-equatorial maelstrom which manifests itself in the trade-winds to the most circumscribed riffle which is announced as a local storm. And the more the phenomena were studied, the more striking seemed the parallel between the greater maelstrom and these lesser eddies. Just as the entire atmospheric mass of each hemisphere is seen, when viewed as a whole, to be carried in a great whirl about the pole of that hemisphere, so the local disturbances within this great tide are found always to take the form of whirls about a local storm-centre--which storm-centre, meantime, is carried along in the major current, as one often sees a little whirlpool in the water swept along with the main current of the stream. Sometimes, indeed, the local eddy, caught as it were in an ancillary current of the great polar stream, is deflected from its normal course and may seem to travel against the stream; but such deviations are departures from the rule. In the great majority of cases, for example, in the north temperate zone, a storm-centre (with its attendant local whirl) travels to the northeast, along the main current of the anti-trade-wind, of which it is a part; and though exceptionally its course may be to the southeast instead, it almost never departs so widely from the main channel as to progress to the westward. Thus it is that storms sweeping over the United States can be announced, as a rule, at the seaboard in advance of their coming by telegraphic communication from the interior, while similar storms come to Europe off the ocean unannounced. Hence the more practical availability of the forecasts of weather bureaus in the former country.
But these local whirls, it must be understood, are local only in a very general sense of the word, inasmuch as a single one may be more than a thousand miles in diameter, and a small one is two or three hundred miles across. But quite without regard to the size of the whirl, the air composing it conducts itself always in one of two ways. It never whirls in concentric circles; it always either rushes in towards the centre in a descending spiral, in which case it is called a cyclone, or it spreads out from the centre in a widening spiral, in which case it is called an anti-cyclone. The word cyclone is associated in popular phraseology with a terrific storm, but it has no such restriction in technical usage. A gentle zephyr flowing towards a "storm-centre" is just as much a cyclone to the meteorologist as is the whirl constituting a West-Indian hurricane. Indeed, it is not properly the wind itself that is called the cyclone in either case, but the entire system of whirls--including the storm-centre itself, where there may be no wind at all.
What, then, is this storm-centre? Merely an area of low barometric pressure--an area where the air has become lighter than the air of surrounding regions. Under influence of gravitation the air seeks its level just as water does; so the heavy air comes flowing in from all sides towards the low-pressure area, which thus becomes a "storm-centre." But the inrushing currents never come straight to their mark. In accordance with Ferrel's law, they are deflected to the right, and the result, as will readily be seen, must be a vortex current, which whirls always in one direction--namely, from left to right, or in the direction opposite to that of the hands of a watch held with its face upward. The velocity of the cyclonic currents will depend largely upon the difference in barometric pressure between the storm-centre and the confines of the cyclone system. And the velocity of the currents will determine to some extent the degree of deflection, and hence the exact path of the descending spiral in which the wind approaches the centre. But in every case and in every part of the cyclone system it is true, as Buys Ballot's famous rule first pointed out, that a person standing with his back to the wind has the storm-centre at his left.
The primary cause of the low barometric pressure which marks the storm-centre and establishes the cyclone is expansion of the air through excess of temperature. The heated air, rising into cold upper regions, has a portion of its vapor condensed into clouds, and now a new dynamic factor is added, for each particle of vapor, in condensing, gives up its modicum of latent heat. Each pound of vapor thus liberates, according to Professor Tyndall's estimate, enough heat to melt five pounds of cast iron; so the amount given out where large masses of cloud are forming must enormously add to the convection currents of the air, and hence to the storm-developing power of the forming cyclone. Indeed, one school of meteorologists, of whom Professor Espy was the leader, has held that, without such added increment of energy constantly augmenting the dynamic effects, no storm could long continue in violent action. And it is doubted whether any storm could ever attain, much less continue, the terrific force of that most dreaded of winds of temperate zones, the tornado--a storm which obeys all the laws of cyclones, but differs from ordinary cyclones in having a vortex core only a few feet or yards in diameter--without the aid of those great masses of condensing vapor which always accompany it in the form of storm-clouds.
The anti-cyclone simply reverses the conditions of the cyclone. Its centre is an area of high pressure, and the air rushes out from it in all directions towards surrounding regions of low pressure. As before, all parts of the current will be deflected towards the right, and the result, clearly, is a whirl opposite in direction to that of the cyclone. But here there is a tendency to dissipation rather than to concentration of energy, hence, considered as a storm-generator, the anti-cyclone is of relative insignificance.
In particular the professional meteorologist who conducts a "weather bureau"--as, for example, the chief of the United States signal-service station in New York--is so preoccupied with the observation of this phenomenon that cyclone-hunting might be said to be his chief pursuit. It is for this purpose, in the main, that government weather bureaus or signal-service departments have been established all over the world. Their chief work is to follow up cyclones, with the aid of telegraphic reports, mapping their course and recording the attendant meteorological conditions. Their so-called predictions or forecasts are essentially predications, gaining locally the effect of predictions because the telegraph outstrips the wind.
At only one place on the globe has it been possible as yet for the meteorologist to make long-time forecasts meriting the title of predictions. This is in the middle Ganges Valley of northern India. In this country the climatic conditions are largely dependent upon the periodical winds called monsoons, which blow steadily landward from April to October, and seaward from October to April. The summer monsoons bring the all-essential rains; if they are delayed or restricted in extent, there will be drought and consequent famine. And such restriction of the monsoon is likely to result when there has been an unusually deep or very late snowfall on the Himalayas, because of the lowering of spring temperature by the melting snow. Thus here it is possible, by observing the snowfall in the mountains, to predict with some measure of success the average rainfall of the following summer. The drought of 1896, with the consequent famine and plague that devastated India the following winter, was thus predicted some months in advance.
This is the greatest present triumph of practical meteorology. Nothing like it is yet possible anywhere in temperate zones. But no one can say what may not be possible in times to come, when the data now being gathered all over the world shall at last be co-ordinated, classified, and made the basis of broad inductions. Meteorology is pre-eminently a science of the future.
VI. MODERN THEORIES OF HEAT AND LIGHT
THE eighteenth-century philosopher made great strides in his studies of the physical properties of matter and the application of these properties in mechanics, as the steam-engine, the balloon, the optic telegraph, the spinning-jenny, the cotton-gin, the chronometer, the perfected compass, the Leyden jar, the lightning-rod, and a host of minor inventions testify. In a speculative way he had thought out more or less tenable conceptions as to the ultimate nature of matter, as witness the theories of Leibnitz and Boscovich and Davy, to which we may recur. But he had not as yet conceived the notion of a distinction between matter and energy, which is so fundamental to the physics of a later epoch. He did not speak of heat, light, electricity, as forms of energy or "force"; he conceived them as subtile forms of matter--as highly attenuated yet tangible fluids, subject to gravitation and chemical attraction; though he had learned to measure none of them but heat with accuracy, and this one he could test only within narrow limits until late in the century, when Josiah Wedgwood, the famous potter, taught him to gauge the highest temperatures with the clay pyrometer.
He spoke of the matter of heat as being the most universally distributed fluid in nature; as entering in some degree into the composition of nearly all other substances; as being sometimes liquid, sometimes condensed or solid, and as having weight that could be detected with the balance. Following Newton, he spoke of light as a "corpuscular emanation" or fluid, composed of shining particles which possibly are transmutable into particles of heat, and which enter into chemical combination with the particles of other forms of matter. Electricity he considered a still more subtile kind of matter-perhaps an attenuated form of light. Magnetism, "vital fluid," and by some even a "gravic fluid," and a fluid of sound were placed in the same scale; and, taken together, all these supposed subtile forms of matter were classed as "imponderables."
This view of the nature of the "imponderables" was in some measure a retrogression, for many seventeenth-century philosophers, notably Hooke and Huygens and Boyle, had held more correct views; but the materialistic conception accorded so well with the eighteenth-century tendencies of thought that only here and there a philosopher like Euler called it in question, until well on towards the close of the century. Current speech referred to the materiality of the "imponderables" unquestioningly. Students of meteorology--a science that was just dawning--explained atmospheric phenomena on the supposition that heat, the heaviest imponderable, predominated in the lower atmosphere, and that light, electricity, and magnetism prevailed in successively higher strata. And Lavoisier, the most philosophical chemist of the century, retained heat and light on a par with oxygen, hydrogen, iron, and the rest, in his list of elementary substances.
COUNT RUMFORD AND THE VIBRATORY THEORY OF HEAT
But just at the close of the century the confidence in the status of the imponderables was rudely shaken in the minds of philosophers by the revival of the old idea of Fra Paolo and Bacon and Boyle, that heat, at any rate, is not a material fluid, but merely a mode of motion or vibration among the particles of "ponderable" matter. The new champion of the old doctrine as to the nature of heat was a very distinguished philosopher and diplomatist of the time, who, it may be worth recalling, was an American. He was a sadly expatriated American, it is true, as his name, given all the official appendages, will amply testify; but he had been born and reared in a Massachusetts village none the less, and he seems always to have retained a kindly interest in the land of his nativity, even though he lived abroad in the service of other powers during all the later years of his life, and was knighted by England, ennobled by Bavaria, and honored by the most distinguished scientific bodies of Europe. The American, then, who championed the vibratory theory of heat, in opposition to all current opinion, in this closing era of the eighteenth century, was Lieutenant-General Sir Benjamin Thompson, Count Rumford, F.R.S.
Rumford showed that heat may be produced in indefinite quantities by friction of bodies that do not themselves lose any appreciable matter in the process, and claimed that this proves the immateriality of heat. Later on he added force to the argument by proving, in refutation of the experiments of Bowditch, that no body either gains or loses weight in virtue of being heated or cooled. He thought he had proved that heat is only a form of motion.
His experiment for producing indefinite quantities of heat by friction is recorded by him in his paper entitled, "Inquiry Concerning the Source of Heat Excited by Friction."
"Being engaged, lately, in superintending the boring of cannon in the workshops of the military arsenal at Munich," he says, "I was struck with the very considerable degree of heat which a brass gun acquires in a short time in being bored; and with the still more intense heat (much greater than that of boiling water, as I found by experiment) of the metallic chips separated from it by the borer.
"Taking a cannon (a brass six-pounder), cast solid, and rough, as it came from the foundry, and fixing it horizontally in a machine used for boring, and at the same time finishing the outside of the cannon by turning, I caused its extremity to be cut off; and by turning down the metal in that part, a solid cylinder was formed, 7 3/4 inches in diameter and 9 8/10 inches long; which, when finished, remained joined to the rest of the metal (that which, properly speaking, constituted the cannon) by a small cylindrical neck, only 2 1/5 inches in diameter and 3 8/10 inches long.
"This short cylinder, which was supported in its horizontal position, and turned round its axis by means of the neck by which it remained united to the cannon, was now bored with the horizontal borer used in boring cannon.
"This cylinder being designed for the express purpose of generating heat by friction, by having a blunt borer forced against its solid bottom at the same time that it should be turned round its axis by the force of horses, in order that the heat accumulated in the cylinder might from time to time be measured, a small, round hole 0.37 of an inch only in diameter and 4.2 inches in depth, for the purpose of introducing a small cylindrical mercurial thermometer, was made in it, on one side, in a direction perpendicular to the axis of the cylinder, and ending in the middle of the solid part of the metal which formed the bottom of the bore.
"At the beginning of the experiment, the temperature of the air in the shade, as also in the cylinder, was just sixty degrees Fahrenheit. At the end of thirty minutes, when the cylinder had made 960 revolutions about its axis, the horses being stopped, a cylindrical mercury thermometer, whose bulb was 32/100 of an inch in diameter and 3 1/4 inches in length, was introduced into the hole made to receive it in the side of the cylinder, when the mercury rose almost instantly to one hundred and thirty degrees.
"In order, by one decisive experiment, to determine whether the air of the atmosphere had any part or not in the generation of the heat, I contrived to repeat the experiment under circumstances in which it was evidently impossible for it to produce any effect whatever. By means of a piston exactly fitted to the mouth of the bore of the cylinder, through the middle of which piston the square iron bar, to the end of which the blunt steel borer was fixed, passed in a square hole made perfectly air-tight, the excess of the external air, to the inside of the bore of the cylinder, was effectually prevented. I did not find, however, by this experiment that the exclusion of the air diminished in the smallest degree the quantity of heat excited by the friction.
"There still remained one doubt, which, though it appeared to me to be so slight as hardly to deserve any attention, I was, however, desirous to remove. The piston which choked the mouth of the bore of the cylinder, in order that it might be air-tight, was fitted into it with so much nicety, by means of its collars of leather, and pressed against it with so much force, that, notwithstanding its being oiled, it occasioned a considerable degree of friction when the hollow cylinder was turned round its axis. Was not the heat produced, or at least some part of it, occasioned by this friction of the piston? and, as the external air had free access to the extremity of the bore, where it came into contact with the piston, is it not possible that this air may have had some share in the generation of the heat produced?
"A quadrangular oblong deal box, water-tight, being provided with holes or slits in the middle of each of its ends, just large enough to receive, the one the square iron rod to the end of which the blunt steel borer was fastened, the other the small cylindrical neck which joined the hollow cylinder to the cannon; when this box (which was occasionally closed above by a wooden cover or lid moving on hinges) was put into its place--that is to say, when, by means of the two vertical opening or slits in its two ends, the box was fixed to the machinery in such a manner that its bottom being in the plane of the horizon, its axis coincided with the axis of the hollow metallic cylinder, it is evident, from the description, that the hollow, metallic cylinder would occupy the middle of the box, without touching it on either side; and that, on pouring water into the box and filling it to the brim, the cylinder would be completely covered and surrounded on every side by that fluid. And, further, as the box was held fast by the strong, square iron rod which passed in a square hole in the centre of one of its ends, while the round or cylindrical neck which joined the hollow cylinder to the end of the cannon could turn round freely on its axis in the round hole in the centre of the other end of it, it is evident that the machinery could be put in motion without the least danger of forcing the box out of its place, throwing the water out of it, or deranging any part of the apparatus."
Everything being thus ready, the box was filled with cold water, having been made water-tight by means of leather collars, and the machinery put in motion. "The result of this beautiful experiment," says Rumford, "was very striking, and the pleasure it afforded me amply repaid me for all the trouble I had had in contriving and arranging the complicated machinery used in making it. The cylinder, revolving at the rate of thirty-two times in a minute, had been in motion but a short time when I perceived, by putting my hand into the water and touching the outside of the cylinder, that heat was generated, and it was not long before the water which surrounded the cylinder began to be sensibly warm.
"At the end of one hour I found, by plunging a thermometer into the box,... that its temperature had been raised no less than forty-seven degrees Fahrenheit, being now one hundred and seven degrees Fahrenheit. ... One hour and thirty minutes after the machinery had been put in motion the heat of the water in the box was one hundred and forty-two degrees. At the end of two hours... it was raised to one hundred and seventy-eight degrees; and at two hours and thirty minutes it ACTUALLY BOILED!
"It would be difficult to describe the surprise and astonishment expressed in the countenances of the bystanders on seeing so large a quantity of cold water heated, and actually made to boil, without any fire. Though there was, in fact, nothing that could justly be considered as a surprise in this event, yet I acknowledge fairly that it afforded me a degree of childish pleasure which, were I ambitious of the reputation of a GRAVE PHILOSOPHER, I ought most certainly rather to hide than to discover...."
Having thus dwelt in detail on these experiments, Rumford comes now to the all-important discussion as to the significance of them--the subject that had been the source of so much speculation among the philosophers--the question as to what heat really is, and if there really is any such thing (as many believed) as an igneous fluid, or a something called caloric.
"From whence came this heat which was continually given off in this manner, in the foregoing experiments?" asks Rumford. "Was it furnished by the small particles of metal detached from the larger solid masses on their being rubbed together? This, as we have already seen, could not possibly have been the case.
"Was it furnished by the air? This could not have been the case; for, in three of the experiments, the machinery being kept immersed in water, the access of the air of the atmosphere was completely prevented.
"Was it furnished by the water which surrounded the machinery? That this could not have been the case is evident: first, because this water was continually RECEIVING heat from the machinery, and could not, at the same time, be GIVING TO and RECEIVING HEAT FROM the same body; and, secondly, because there was no chemical decomposition of any part of this water. Had any such decomposition taken place (which, indeed, could not reasonably have been expected), one of its component elastic fluids (most probably hydrogen) must, at the same time, have been set at liberty, and, in making its escape into the atmosphere, would have been detected; but, though I frequently examined the water to see if any air-bubbles rose up through it, and had even made preparations for catching them if they should appear, I could perceive none; nor was there any sign of decomposition of any kind whatever, or other chemical process, going on in the water.
"Is it possible that the heat could have been supplied by means of the iron bar to the end of which the blunt steel borer was fixed? Or by the small neck of gun-metal by which the hollow cylinder was united to the cannon? These suppositions seem more improbable even than either of the before-mentioned; for heat was continually going off, or OUT OF THE MACHINERY, by both these passages during the whole time the experiment lasted.
"And in reasoning on this subject we must not forget to consider that most remarkable circumstance, that the source of the heat generated by friction in these experiments appeared evidently to be INEXHAUSTIBLE.
"It is hardly necessary to add that anything which any INSULATED body, or system of bodies, can continue to furnish WITHOUT LIMITATION cannot possibly be a MATERIAL substance; and it appears to me to be extremely difficult, if not quite impossible, to form any distinct idea of anything capable of being excited and communicated, in the manner the heat was excited and communicated in these experiments, except in MOTION."(1)
THOMAS YOUNG AND THE WAVE THEORY OF LIGHT
But contemporary judgment, while it listened respectfully to Rumford, was little minded to accept his verdict. The cherished beliefs of a generation are not to be put down with a single blow. Where many minds have a similar drift, however, the first blow may precipitate a general conflict; and so it was here. Young Humphry Davy had duplicated Rumford's experiments, and reached similar conclusions; and soon others fell into line. Then, in 1800, Dr. Thomas Young--"Phenomenon Young" they called him at Cambridge, because he was reputed to know everything--took up the cudgels for the vibratory theory of light, and it began to be clear that the two "imponderables," heat and light, must stand or fall together; but no one as yet made a claim against the fluidity of electricity.
Before we take up the details of the assault made by Young upon the old doctrine of the materiality of light, we must pause to consider the personality of Young himself. For it chanced that this Quaker physician was one of those prodigies who come but few times in a century, and the full list of whom in the records of history could be told on one's thumbs and fingers. His biographers tell us things about him that read like the most patent fairy-tales. As a mere infant in arms he had been able to read fluently. Before his fourth birthday came he had read the Bible twice through, as well as Watts's Hymns--poor child!--and when seven or eight he had shown a propensity to absorb languages much as other children absorb nursery tattle and Mother Goose rhymes. When he was fourteen, a young lady visiting the household of his tutor patronized the pretty boy by asking to see a specimen of his penmanship. The pretty boy complied readily enough, and mildly rebuked his interrogator by rapidly writing some sentences for her in fourteen languages, including such as, Arabian, Persian, and Ethiopic.
Meantime languages had been but an incident in the education of the lad. He seems to have entered every available field of thought--mathematics, physics, botany, literature, music, painting, languages, philosophy, archaeology, and so on to tiresome lengths--and once he had entered any field he seldom turned aside until he had reached the confines of the subject as then known and added something new from the recesses of his own genius. He was as versatile as Priestley, as profound as Newton himself. He had the range of a mere dilettante, but everywhere the full grasp of the master. He took early for his motto the saying that what one man has done, another man may do. Granting that the other man has the brain of a Thomas Young, it is a true motto.
Such, then, was the young Quaker who came to London to follow out the humdrum life of a practitioner of medicine in the year 1801. But incidentally the young physician was prevailed upon to occupy the interims of early practice by fulfilling the duties of the chair of Natural Philosophy at the Royal Institution, which Count Rumford had founded, and of which Davy was then Professor of Chemistry--the institution whose glories have been perpetuated by such names as Faraday and Tyndall, and which the Briton of to-day speaks of as the "Pantheon of Science." Here it was that Thomas Young made those studies which have insured him a niche in the temple of fame not far removed from that of Isaac Newton.
As early as 1793, when he was only twenty, Young had begun to Communicate papers to the Royal Society of London, which were adjudged worthy to be printed in full in the Philosophical Transactions; so it is not strange that he should have been asked to deliver the Bakerian lecture before that learned body the very first year after he came to London. The lecture was delivered November 12, 1801. Its subject was "The Theory of Light and Colors," and its reading marks an epoch in physical science; for here was brought forward for the first time convincing proof of that undulatory theory of light with which every student of modern physics is familiar--the theory which holds that light is not a corporeal entity, but a mere pulsation in the substance of an all-pervading ether, just as sound is a pulsation in the air, or in liquids or solids.
Young had, indeed, advocated this theory at an earlier date, but it was not until 1801 that he hit upon the idea which enabled him to bring it to anything approaching a demonstration. It was while pondering over the familiar but puzzling phenomena of colored rings into which white light is broken when reflected from thin films--Newton's rings, so called--that an explanation occurred to him which at once put the entire undulatory theory on a new footing. With that sagacity of insight which we call genius, he saw of a sudden that the phenomena could be explained by supposing that when rays of light fall on a thin glass, part of the rays being reflected from the upper surface, other rays, reflected from the lower surface, might be so retarded in their course through the glass that the two sets would interfere with one another, the forward pulsation of one ray corresponding to the backward pulsation of another, thus quite neutralizing the effect. Some of the component pulsations of the light being thus effaced by mutual interference, the remaining rays would no longer give the optical effect of white light; hence the puzzling colors.
Here is Young's exposition of the subject:
Of the Colors of Thin Plates
"When a beam of light falls upon two refracting surfaces, the partial reflections coincide perfectly in direction; and in this case the interval of retardation taken between the surfaces is to their radius as twice the cosine of the angle of refraction to the radius.
"Let the medium between the surfaces be rarer than the surrounding mediums; then the impulse reflected at the second surface, meeting a subsequent undulation at the first, will render the particles of the rarer medium capable of wholly stopping the motion of the denser and destroying the reflection, while they themselves will be more strongly propelled than if they had been at rest, and the transmitted light will be increased. So that the colors by reflection will be destroyed, and those by transmission rendered more vivid, when the double thickness or intervals of retardation are any multiples of the whole breadth of the undulations; and at intermediate thicknesses the effects will be reversed according to the Newtonian observation.
"If the same proportions be found to hold good with respect to thin plates of a denser medium, which is, indeed, not improbable, it will be necessary to adopt the connected demonstrations of Prop. IV., but, at any rate, if a thin plate be interposed between a rarer and a denser medium, the colors by reflection and transmission may be expected to change places."
OF THE COLORS OF THICK PLATES
"When a beam of light passes through a refracting surface, especially if imperfectly polished, a portion of it is irregularly scattered, and makes the surface visible in all directions, but most conspicuously in directions not far distant from that of the light itself; and if a reflecting surface be placed parallel to the refracting surface, this scattered light, as well as the principal beam, will be reflected, and there will be also a new dissipation of light, at the return of the beam through the refracting surface. These two portions of scattered light will coincide in direction; and if the surfaces be of such a form as to collect the similar effects, will exhibit rings of colors. The interval of retardation is here the difference between the paths of the principal beam and of the scattered light between the two surfaces; of course, wherever the inclination of the scattered light is equal to that of the beam, although in different planes, the interval will vanish and all the undulations will conspire. At other inclinations, the interval will be the difference of the secants from the secant of the inclination, or angle of refraction of the principal beam. From these causes, all the colors of concave mirrors observed by Newton and others are necessary consequences; and it appears that their production, though somewhat similar, is by no means as Newton imagined, identical with the production of thin plates."(2)
By following up this clew with mathematical precision, measuring the exact thickness of the plate and the space between the different rings of color, Young was able to show mathematically what must be the length of pulsation for each of the different colors of the spectrum. He estimated that the undulations of red light, at the extreme lower end of the visible spectrum, must number about thirty-seven thousand six hundred and forty to the inch, and pass any given spot at a rate of four hundred and sixty-three millions of millions of undulations in a second, while the extreme violet numbers fifty-nine thousand seven hundred and fifty undulations to the inch, or seven hundred and thirty-five millions of millions to the second.
The Colors of Striated Surfaces
Young similarly examined the colors that are produced by scratches on a smooth surface, in particular testing the light from "Mr. Coventry's exquisite micrometers," which consist of lines scratched on glass at measured intervals. These microscopic tests brought the same results as the other experiments. The colors were produced at certain definite and measurable angles, and the theory of interference of undulations explained them perfectly, while, as Young affirmed with confidence, no other hypothesis hitherto advanced would explain them at all. Here are his words:
"Let there be in a given plane two reflecting points very near each other, and let the plane be so situated that the reflected image of a luminous object seen in it may appear to coincide with the points; then it is obvious that the length of the incident and reflected ray, taken together, is equal with respect to both points, considering them as capable of reflecting in all directions. Let one of the points be now depressed below the given plane; then the whole path of the light reflected from it will be lengthened by a line which is to the depression of the point as twice the cosine of incidence to the radius.
"If, therefore, equal undulations of given dimensions be reflected from two points, situated near enough to appear to the eye but as one, whenever this line is equal to half the breadth of a whole undulation the reflection from the depressed point will so interfere with the reflection from the fixed point that the progressive motion of the one will coincide with the retrograde motion of the other, and they will both be destroyed; but when this line is equal to the whole breadth of an undulation, the effect will be doubled, and when to a breadth and a half, again destroyed; and thus for a considerable number of alternations, and if the reflected undulations be of a different kind, they will be variously affected, according to their proportions to the various length of the line which is the difference between the lengths of their two paths, and which may be denominated the interval of a retardation.
"In order that the effect may be the more perceptible, a number of pairs of points must be united into two parallel lines; and if several such pairs of lines be placed near each other, they will facilitate the observation. If one of the lines be made to revolve round the other as an axis, the depression below the given plane will be as the sine of the inclination; and while the eye and the luminous object remain fixed the difference of the length of the paths will vary as this sine.
"The best subjects for the experiment are Mr. Coventry's exquisite micrometers; such of them as consist of parallel lines drawn on glass, at a distance of one-five-hundredth of an inch, are the most convenient. Each of these lines appears under a microscope to consist of two or more finer lines, exactly parallel, and at a distance of somewhat more than a twentieth more than the adjacent lines. I placed one of these so as to reflect the sun's light at an angle of forty-five degrees, and fixed it in such a manner that while it revolved round one of the lines as an axis, I could measure its angular motion; I found that the longest red color occurred at the inclination 10 1/4 degrees, 20 3/4 degrees, 32 degrees, and 45 degrees; of which the sines are as the numbers 1, 2, 3, and 4. At all other angles also, when the sun's light was reflected from the surface, the color vanished with the inclination, and was equal at equal inclinations on either side.
This experiment affords a very strong confirmation of the theory. It is impossible to deduce any explanation of it from any hypothesis hitherto advanced; and I believe it would be difficult to invent any other that would account for it. There is a striking analogy between this separation of colors and the production of a musical note by successive echoes from equidistant iron palisades, which I have found to correspond pretty accurately with the known velocity of sound and the distances of the surfaces.
"It is not improbable that the colors of the integuments of some insects, and of some other natural bodies, exhibiting in different lights the most beautiful versatility, may be found to be of this description, and not to be derived from thin plates. In some cases a single scratch or furrow may produce similar effects, by the reflection of its opposite edges."(3)
This doctrine of interference of undulations was the absolutely novel part of Young's theory. The all-compassing genius of Robert Hooke had, indeed, very nearly apprehended it more than a century before, as Young himself points out, but no one else bad so much as vaguely conceived it; and even with the sagacious Hooke it was only a happy guess, never distinctly outlined in his own mind, and utterly ignored by all others. Young did not know of Hooke's guess until he himself had fully formulated the theory, but he hastened then to give his predecessor all the credit that could possibly be adjudged his due by the most disinterested observer. To Hooke's contemporary, Huygens, who was the originator of the general doctrine of undulation as the explanation of light, Young renders full justice also. For himself he claims only the merit of having demonstrated the theory which these and a few others of his predecessors had advocated without full proof.
The following year Dr. Young detailed before the Royal Society other experiments, which threw additional light on the doctrine of interference; and in 1803 he cited still others, which, he affirmed, brought the doctrine to complete demonstration. In applying this demonstration to the general theory of light, he made the striking suggestion that "the luminiferous ether pervades the substance of all material bodies with little or no resistance, as freely, perhaps, as the wind passes through a grove of trees." He asserted his belief also that the chemical rays which Ritter had discovered beyond the violet end of the visible spectrum are but still more rapid undulations of the same character as those which produce light. In his earlier lecture he had affirmed a like affinity between the light rays and the rays of radiant heat which Herschel detected below the red end of the spectrum, suggesting that "light differs from heat only in the frequency of its undulations or vibrations--those undulations which are within certain limits with respect to frequency affecting the optic nerve and constituting light, and those which are slower and probably stronger constituting heat only." From the very outset he had recognized the affinity between sound and light; indeed, it had been this affinity that led him on to an appreciation of the undulatory theory of light.
But while all these affinities seemed so clear to the great co-ordinating brain of Young, they made no such impression on the minds of his contemporaries. The immateriality of light had been substantially demonstrated, but practically no one save its author accepted the demonstration. Newton's doctrine of the emission of corpuscles was too firmly rooted to be readily dislodged, and Dr. Young had too many other interests to continue the assault unceasingly. He occasionally wrote something touching on his theory, mostly papers contributed to the Quarterly Review and similar periodicals, anonymously or under pseudonym, for he had conceived the notion that too great conspicuousness in fields outside of medicine would injure his practice as a physician. His views regarding light (including the original papers from the Philosophical Transactions of the Royal Society) were again given publicity in full in his celebrated volume on natural philosophy, consisting in part of his lectures before the Royal Institution, published in 1807; but even then they failed to bring conviction to the philosophic world. Indeed, they did not even arouse a controversial spirit, as his first papers had done.
ARAGO AND FRESNEL CHAMPION THE WAVE THEORY
So it chanced that when, in 1815, a young French military engineer, named Augustin Jean Fresnel, returning from the Napoleonic wars, became interested in the phenomena of light, and made some experiments concerning diffraction which seemed to him to controvert the accepted notions of the materiality of light, he was quite unaware that his experiments had been anticipated by a philosopher across the Channel. He communicated his experiments and results to the French Institute, supposing them to be absolutely novel. That body referred them to a committee, of which, as good fortune would have it, the dominating member was Dominique Francois Arago, a man as versatile as Young himself, and hardly less profound, if perhaps not quite so original. Arago at once recognized the merit of Fresnel's work, and soon became a convert to the theory. He told Fresnel that Young had anticipated him as regards the general theory, but that much remained to be done, and he offered to associate himself with Fresnel in prosecuting the investigation. Fresnel was not a little dashed to learn that his original ideas had been worked out by another while he was a lad, but he bowed gracefully to the situation and went ahead with unabated zeal.
The championship of Arago insured the undulatory theory a hearing before the French Institute, but by no means sufficed to bring about its general acceptance. On the contrary, a bitter feud ensued, in which Arago was opposed by the "Jupiter Olympus of the Academy," Laplace, by the only less famous Poisson, and by the younger but hardly less able Biot. So bitterly raged the feud that a life-long friendship between Arago and Biot was ruptured forever. The opposition managed to delay the publication of Fresnel's papers, but Arago continued to fight with his customary enthusiasm and pertinacity, and at last, in 1823, the Academy yielded, and voted Fresnel into its ranks, thus implicitly admitting the value of his work.
It is a humiliating thought that such controversies as this must mar the progress of scientific truth; but fortunately the story of the introduction of the undulatory theory has a more pleasant side. Three men, great both in character and in intellect, were concerned in pressing its claims--Young, Fresnel, and Arago--and the relations of these men form a picture unmarred by any of those petty jealousies that so often dim the lustre of great names. Fresnel freely acknowledged Young's priority so soon as his attention was called to it; and Young applauded the work of the Frenchman, and aided with his counsel in the application of the undulatory theory to the problems of polarization of light, which still demanded explanation, and which Fresnel's fertility of experimental resource and profundity of mathematical insight sufficed in the end to conquer.
After Fresnel's admission to the Institute in 1823 the opposition weakened, and gradually the philosophers came to realize the merits of a theory which Young had vainly called to their attention a full quarter-century before. Now, thanks largely to Arago, both Young and Fresnel received their full meed of appreciation. Fresnel was given the Rumford medal of the Royal Society of England in 1825, and chosen one of the foreign members of the society two years later, while Young in turn was elected one of the eight foreign members of the French Academy. As a fitting culmination of the chapter of felicities between the three friends, it fell to the lot of Young, as Foreign Secretary of the Royal Society, to notify Fresnel of the honors shown him by England's representative body of scientists; while Arago, as Perpetual Secretary of the French Institute, conveyed to Young in the same year the notification that he had been similarly honored by the savants of France.
A few months later Fresnel was dead, and Young survived him only two years. Both died prematurely, but their great work was done, and the world will remember always and link together these two names in connection with a theory which in its implications and importance ranks little below the theory of universal gravitation.
VII. THE MODERN DEVELOPMENT OF ELECTRICITY AND MAGNETISM
GALVANI AND VOLTA
The full importance of Young's studies of light might perhaps have gained earlier recognition had it not chanced that, at the time when they were made, the attention of the philosophic world was turned with the fixity and fascination of a hypnotic stare upon another field, which for a time brooked no rival. How could the old, familiar phenomenon, light, interest any one when the new agent, galvanism, was in view? As well ask one to fix attention on a star while a meteorite blazes across the sky.
Galvanism was so called precisely as the Roentgen ray was christened at a later day--as a safe means of begging the question as to the nature of the phenomena involved. The initial fact in galvanism was the discovery of Luigi Galvani (1737-1798), a physician of Bologna, in 1791, that by bringing metals in contact with the nerves of a frog's leg violent muscular contractions are produced. As this simple little experiment led eventually to the discovery of galvanic electricity and the invention of the galvanic battery, it may be regarded as the beginning of modern electricity.
The story is told that Galvani was led to his discovery while preparing frogs' legs to make a broth for his invalid wife. As the story runs, he had removed the skins from several frogs' legs, when, happening to touch the exposed muscles with a scalpel which had lain in close proximity to an electrical machine, violent muscular action was produced. Impressed with this phenomenon, he began a series of experiments which finally resulted in his great discovery. But be this story authentic or not, it is certain that Galvani experimented for several years upon frogs' legs suspended upon wires and hooks, until he finally constructed his arc of two different metals, which, when arranged so that one was placed in contact with a nerve and the other with a muscle, produced violent contractions.
These two pieces of metal form the basic principle of the modern galvanic battery, and led directly to Alessandro Volta's invention of his "voltaic pile," the immediate ancestor of the modern galvanic battery. Volta's experiments were carried on at the same time as those of Galvani, and his invention of his pile followed close upon Galvani's discovery of the new form of electricity. From these facts the new form of electricity was sometimes called "galvanic" and sometimes "voltaic" electricity, but in recent years the term "galvanism" and "galvanic current" have almost entirely supplanted the use of the term voltaic.
It was Volta who made the report of Galvani's wonderful discovery to the Royal Society of London, read on January 31, 1793. In this letter he describes Galvani's experiments in detail and refers to them in glowing terms of praise. He calls it one of the "most beautiful and important discoveries," and regarded it as the germ or foundation upon which other discoveries were to be made. The prediction proved entirely correct, Volta himself being the chief discoverer.
Working along lines suggested by Galvani's discovery, Volta constructed an apparatus made up of a number of disks of two different kinds of metal, such as tin and silver, arranged alternately, a piece of some moist, porous substance, like paper or felt, being interposed between each pair of disks. With this "pile," as it was called, electricity was generated, and by linking together several such piles an electric battery could be formed.
This invention took the world by storm. Nothing like the enthusiasm it created in the philosophic world had been known since the invention of the Leyden jar, more than half a century before. Within a few weeks after Volta's announcement, batteries made according to his plan were being experimented with in every important laboratory in Europe.
As the century closed, half the philosophic world was speculating as to whether "galvanic influence" were a new imponderable, or only a form of electricity; and the other half was eagerly seeking to discover what new marvels the battery might reveal. The least imaginative man could see that here was an invention that would be epoch-making, but the most visionary dreamer could not even vaguely adumbrate the real measure of its importance.
It was evident at once that almost any form of galvanic battery, despite imperfections, was a more satisfactory instrument for generating electricity than the frictional machine hitherto in use, the advantage lying in the fact that the current from the galvanic battery could be controlled practically at will, and that the apparatus itself was inexpensive and required comparatively little attention. These advantages were soon made apparent by the practical application of the electric current in several fields.
It will be recalled that despite the energetic endeavors of such philosophers as Watson, Franklin, Galvani, and many others, the field of practical application of electricity was very limited at the close of the eighteenth century. The lightning-rod had come into general use, to be sure, and its value as an invention can hardly be overestimated. But while it was the result of extensive electrical discoveries, and is a most practical instrument, it can hardly be called one that puts electricity to practical use, but simply acts as a means of warding off the evil effects of a natural manifestation of electricity. The invention, however, had all the effects of a mechanism which turned electricity to practical account. But with the advent of the new kind of electricity the age of practical application began.
DAVY AND ELECTRIC LIGHT
Volta's announcement of his pile was scarcely two months old when two Englishmen, Messrs. Nicholson and Carlisle, made the discovery that the current from the galvanic battery had a decided effect upon certain chemicals, among other things decomposing water into its elements, hydrogen and oxygen. On May 7, 1800, these investigators arranged the ends of two brass wires connected with the poles of a voltaic pile, composed of alternate silver and zinc plates, so that the current coming from the pile was discharged through a small quantity of "New River water." "A fine stream of minute bubbles immediately began to flow from the point of the lower wire in the tube which communicated with the silver," wrote Nicholson, "and the opposite point of the upper wire became tarnished, first deep orange and then black...." The product of gas during two hours and a half was two-thirtieths of a cubic inch. "It was then mixed with an equal quantity of common air," continues Nicholson, "and exploded by the application of a lighted waxen thread."
This demonstration was the beginning of the very important science of electro-chemistry.
The importance of this discovery was at once recognized by Sir Humphry Davy, who began experimenting immediately in this new field. He constructed a series of batteries in various combinations, with which he attacked the "fixed alkalies," the composition of which was then unknown. Very shortly he was able to decompose potash into bright metallic globules, resembling quicksilver. This new substance he named "potassium." Then in rapid succession the elementary substances sodium, calcium, strontium, and magnesium were isolated.
It was soon discovered, also, that the new electricity, like the old, possessed heating power under certain conditions, even to the fusing of pieces of wire. This observation was probably first made by Frommsdorff, but it was elaborated by Davy, who constructed a battery of two thousand cells with which he produced a bright light from points of carbon--the prototype of the modern arc lamp. He made this demonstration before the members of the Royal Institution in 1810. But the practical utility of such a light for illuminating purposes was still a thing of the future. The expense of constructing and maintaining such an elaborate battery, and the rapid internal destruction of its plates, together with the constant polarization, rendered its use in practical illumination out of the question. It was not until another method of generating electricity was discovered that Davy's demonstration could be turned to practical account.
In Davy's own account of his experiment he says:
"When pieces of charcoal about an inch long and one-sixth of an inch in diameter were brought near each other (within the thirtieth or fortieth of an inch), a bright spark was produced, and more than half the volume of the charcoal became ignited to whiteness; and, by withdrawing the points from each other, a constant discharge took place through the heated air, in a space equal to at least four inches, producing a most brilliant ascending arch of light, broad and conical in form in the middle. When any substance was introduced into this arch, it instantly became ignited; platina melted as readily in it as wax in a common candle; quartz, the sapphire, magnesia, lime, all entered into fusion; fragments of diamond and points of charcoal and plumbago seemed to evaporate in it, even when the connection was made in the receiver of an air-pump; but there was no evidence of their having previously undergone fusion. When the communication between the points positively and negatively electrified was made in the air rarefied in the receiver of the air-pump, the distance at which the discharge took place increased as the exhaustion was made; and when the atmosphere in the vessel supported only one-fourth of an inch of mercury in the barometrical gauge, the sparks passed through a space of nearly half an inch; and, by withdrawing the points from each other, the discharge was made through six or seven inches, producing a most brilliant coruscation of purple light; the charcoal became intensely ignited, and some platina wire attached to it fused with brilliant scintillations and fell in large globules upon the plate of the pump. All the phenomena of chemical decomposition were produced with intense rapidity by this combination."(1)
But this experiment demonstrated another thing besides the possibility of producing electric light and chemical decomposition, this being the heating power capable of being produced by the electric current. Thus Davy's experiment of fusing substances laid the foundation of the modern electric furnaces, which are of paramount importance in several great commercial industries.
While some of the results obtained with Davy's batteries were practically as satisfactory as could be obtained with modern cell batteries, the batteries themselves were anything but satisfactory. They were expensive, required constant care and attention, and, what was more important from an experimental standpoint at least, were not constant in their action except for a very limited period of time, the current soon "running down." Numerous experimenters, therefore, set about devising a satisfactory battery, and when, in 1836, John Frederick Daniell produced the cell that bears his name, his invention was epoch-making in the history of electrical progress. The Royal Society considered it of sufficient importance to bestow the Copley medal upon the inventor, whose device is the direct parent of all modern galvanic cells. From the time of the advent of the Daniell cell experiments in electricity were rendered comparatively easy. In the mean while, however, another great discovery was made.
ELECTRICITY AND MAGNETISM
For many years there had been a growing suspicion, amounting in many instances to belief in the close relationship existing between electricity and magnetism. Before the winter of 1815, however, it was a belief that was surmised but not demonstrated. But in that year it occurred to Jean Christian Oersted, of Denmark, to pass a current of electricity through a wire held parallel with, but not quite touching, a suspended magnetic needle. The needle was instantly deflected and swung out of its position.
"The first experiments in connection with the subject which I am undertaking to explain," wrote Oersted, "were made during the course of lectures which I held last winter on electricity and magnetism. From those experiments it appeared that the magnetic needle could be moved from its position by means of a galvanic battery--one with a closed galvanic circuit. Since, however, those experiments were made with an apparatus of small power, I undertook to repeat and increase them with a large galvanic battery.
"Let us suppose that the two opposite ends of the galvanic apparatus are joined by a metal wire. This I shall always call the conductor for the sake of brevity. Place a rectilinear piece of this conductor in a horizontal position over an ordinary magnetic needle so that it is parallel to it. The magnetic needle will be set in motion and will deviate towards the west under that part of the conductor which comes from the negative pole of the galvanic battery. If the wire is not more than four-fifths of an inch distant from the middle of this needle, this deviation will be about forty-five degrees. At a greater distance the angle of deviation becomes less. Moreover, the deviation varies according to the strength of the battery. The conductor can be moved towards the east or west, so long as it remains parallel to the needle, without producing any other result than to make the deviation smaller.
"The conductor can consist of several combined wires or metal coils. The nature of the metal does not alter the result except, perhaps, to make it greater or less. We have used wires of platinum, gold, silver, brass, and iron, and coils of lead, tin, and quicksilver with the same result. If the conductor is interrupted by water, all effect is not cut off, unless the stretch of water is several inches long.
"The conductor works on the magnetic needle through glass, metals, wood, water, and resin, through clay vessels and through stone, for when we placed a glass plate, a metal plate, or a board between the conductor and the needle the effect was not cut off; even the three together seemed hardly to weaken the effect, and the same was the case with an earthen vessel, even when it was full of water. Our experiments also demonstrated that the said effects were not altered when we used a magnetic needle which was in a brass case full of water.
"When the conductor is placed in a horizontal plane under the magnetic needle all the effects we have described take place in precisely the same way, but in the opposite direction to what took place when the conductor was in a horizontal plane above the needle.
"If the conductor is moved in a horizontal plane so that it gradually makes ever-increasing angles with the magnetic meridian, the deviation of the magnetic needle from the magnetic meridian is increased when the wire is turned towards the place of the needle; it decreases, on the other hand, when it is turned away from that place.
"A needle of brass which is hung in the same way as the magnetic needle is not set in motion by the influence of the conductor. A needle of glass or rubber likewise remains static under similar experiments. Hence the electrical conductor affects only the magnetic parts of a substance. That the electrical current is not confined to the conducting wire, but is comparatively widely diffused in the surrounding space, is sufficiently demonstrated from the foregoing observations."(2)
The effect of Oersted's demonstration is almost incomprehensible. By it was shown the close relationship between magnetism and electricity. It showed the way to the establishment of the science of electrodynamics; although it was by the French savant Andre Marie Ampere (1775-1836) that the science was actually created, and this within the space of one week after hearing of Oersted's experiment in deflecting the needle. Ampere first received the news of Oersted's experiment on September 11, 1820, and on the 18th of the same month he announced to the Academy the fundamental principles of the science of electro-dynamics--seven days of rapid progress perhaps unequalled in the history of science.
Ampere's distinguished countryman, Arago, a few months later, gave the finishing touches to Oersted's and Ampere's discoveries, by demonstrating conclusively that electricity not only influenced a magnet, but actually produced magnetism under proper circumstances--a complemental fact most essential in practical mechanics.
Some four years after Arago's discovery, Sturgeon made the first "electro-magnet" by winding a soft iron core with wire through which a current of electricity was passed. This study of electro-magnets was taken up by Professor Joseph Henry, of Albany, New York, who succeeded in making magnets of enormous lifting power by winding the iron core with several coils of wire. One of these magnets, excited by a single galvanic cell of less than half a square foot of surface, and containing only half a pint of dilute acids, sustained a weight of six hundred and fifty pounds.
Thus by Oersted's great discovery of the intimate relationship of magnetism and electricity, with further elaborations and discoveries by Ampere, Volta, and Henry, and with the invention of Daniell's cell, the way was laid for putting electricity to practical use. Soon followed the invention and perfection of the electro-magnetic telegraph and a host of other but little less important devices.
FARADAY AND ELECTRO-MAGNETIC INDUCTION
With these great discoveries and inventions at hand, electricity became no longer a toy or a "plaything for philosophers," but of enormous and growing importance commercially. Still, electricity generated by chemical action, even in a very perfect cell, was both feeble and expensive, and, withal, only applicable in a comparatively limited field. Another important scientific discovery was necessary before such things as electric traction and electric lighting on a large scale were to become possible; but that discovery was soon made by Sir Michael Faraday.
Faraday, the son of a blacksmith and a bookbinder by trade, had interested Sir Humphry Davy by his admirable notes on four of Davy's lectures, which he had been able to attend. Although advised by the great scientist to "stick to his bookbinding" rather than enter the field of science, Faraday became, at twenty-two years of age, Davy's assistant in the Royal Institution. There, for several years, he devoted all his spare hours to scientific investigations and experiments, perfecting himself in scientific technique.
A few years later he became interested, like all the scientists of the time, in Arago's experiment of rotating a copper disk underneath a suspended compass-needle. When this disk was rotated rapidly, the needle was deflected, or even rotated about its axis, in a manner quite inexplicable. Faraday at once conceived the idea that the cause of this rotation was due to electricity, induced in the revolving disk--not only conceived it, but put his belief in writing. For several years, however, he was unable to demonstrate the truth of his assumption, although he made repeated experiments to prove it. But in 1831 he began a series of experiments that established forever the fact of electro-magnetic induction.
In his famous paper, read before the Royal Society in 1831, Faraday describes the method by which he first demonstrated electro-magnetic induction, and then explained the phenomenon of Arago's revolving disk.
"About twenty-six feet of copper wire, one-twentieth of an inch in diameter, were wound round a cylinder of wood as a helix," he said, "the different spires of which were prevented from touching by a thin interposed twine. This helix was covered with calico, and then a second wire applied in the same manner. In this way twelve helices were "superposed, each containing an average length of wire of twenty-seven feet, and all in the same direction. The first, third, fifth, seventh, ninth, and eleventh of these helices were connected at their extremities end to end so as to form one helix; the others were connected in a similar manner; and thus two principal helices were produced, closely interposed, having the same direction, not touching anywhere, and each containing one hundred and fifty-five feet in length of wire.
One of these helices was connected with a galvanometer, the other with a voltaic battery of ten pairs of plates four inches square, with double coppers and well charged; yet not the slightest sensible deflection of the galvanometer needle could be observed.
"A similar compound helix, consisting of six lengths of copper and six of soft iron wire, was constructed. The resulting iron helix contained two hundred and eight feet; but whether the current from the trough was passed through the copper or the iron helix, no effect upon the other could be perceived at the galvanometer.
"In these and many similar experiments no difference in action of any kind appeared between iron and other metals.
"Two hundred and three feet of copper wire in one length were passed round a large block of wood; other two hundred and three feet of similar wire were interposed as a spiral between the turns of the first, and metallic contact everywhere prevented by twine. One of these helices was connected with a galvanometer and the other with a battery of a hundred pairs of plates four inches square, with double coppers and well charged. When the contact was made, there was a sudden and very slight effect at the galvanometer, and there was also a similar slight effect when the contact with the battery was broken. But whilst the voltaic current was continuing to pass through the one helix, no galvanometrical appearances of any effect like induction upon the other helix could be perceived, although the active power of the battery was proved to be great by its heating the whole of its own helix, and by the brilliancy of the discharge when made through charcoal.
"Repetition of the experiments with a battery of one hundred and twenty pairs of plates produced no other effects; but it was ascertained, both at this and at the former time, that the slight deflection of the needle occurring at the moment of completing the connection was always in one direction, and that the equally slight deflection produced when the contact was broken was in the other direction; and, also, that these effects occurred when the first helices were used.
"The results which I had by this time obtained with magnets led me to believe that the battery current through one wire did, in reality, induce a similar current through the other wire, but that it continued for an instant only, and partook more of the nature of the electrical wave passed through from the shock of a common Leyden jar than of that from a voltaic battery, and, therefore, might magnetize a steel needle although it scarcely affected the galvanometer.
"This expectation was confirmed; for on substituting a small hollow helix, formed round a glass tube, for the galvanometer, introducing a steel needle, making contact as before between the battery and the inducing wire, and then removing the needle before the battery contact was broken, it was found magnetized.
"When the battery contact was first made, then an unmagnetized needle introduced, and lastly the battery contact broken, the needle was found magnetized to an equal degree apparently with the first; but the poles were of the contrary kinds."(3)
To Faraday these experiments explained the phenomenon of Arago's rotating disk, the disk inducing the current from the magnet, and, in reacting, deflecting the needle. To prove this, he constructed a disk that revolved between the poles of an electro-magnet, connecting the axis and the edge of the disk with a galvanometer. "... A disk of copper, twelve inches in diameter, fixed upon a brass axis," he says, "was mounted in frames so as to be revolved either vertically or horizontally, its edge being at the same time introduced more or less between the magnetic poles. The edge of the plate was well amalgamated for the purpose of obtaining good but movable contact; a part round the axis was also prepared in a similar manner.
"Conductors or collectors of copper and lead were constructed so as to come in contact with the edge of the copper disk, or with other forms of plates hereafter to be described. These conductors we're about four inches long, one-third of an inch wide, and one-fifth of an inch thick; one end of each was slightly grooved, to allow of more exact adaptation to the somewhat convex edge of the plates, and then amalgamated. Copper wires, one-sixteenth of an inch in thickness, attached in the ordinary manner by convolutions to the other ends of these conductors, passed away to the galvanometer.
"All these arrangements being made, the copper disk was adjusted, the small magnetic poles being about one-half an inch apart, and the edge of the plate inserted about half their width between them. One of the galvanometer wires was passed twice or thrice loosely round the brass axis of the plate, and the other attached to a conductor, which itself was retained by the hand in contact with the amalgamated edge of the disk at the part immediately between the magnetic poles. Under these circumstances all was quiescent, and the galvanometer exhibited no effect. But the instant the plate moved the galvanometer was influenced, and by revolving the plate quickly the needle could be deflected ninety degrees or more."(4)
This rotating disk was really a dynamo electric machine in miniature, the first ever constructed, but whose direct descendants are the ordinary dynamos. Modern dynamos range in power from little machines operating machinery requiring only fractions of a horsepower to great dynamos operating street-car lines and lighting cities; but all are built on the same principle as Faraday's rotating disk. By this discovery the use of electricity as a practical and economical motive power became possible.
STORAGE BATTERIES
When the discoveries of Faraday of electro-magnetic induction had made possible the means of easily generating electricity, the next natural step was to find a means of storing it or accumulating it. This, however, proved no easy matter, and as yet a practical storage or secondary battery that is neither too cumbersome, too fragile, nor too weak in its action has not been invented. If a satisfactory storage battery could be made, it is obvious that its revolutionary effects could scarcely be overestimated. In the single field of aeronautics, it would probably solve the question of aerial navigation. Little wonder, then, that inventors have sought so eagerly for the invention of satisfactory storage batteries. As early as 1803 Ritter had attempted to make such a secondary battery. In 1843 Grove also attempted it. But it was not until 1859, when Gaston Planche produced his invention, that anything like a reasonably satisfactory storage battery was made. Planche discovered that sheets of lead immersed in dilute sulphuric acid were very satisfactory for the production of polarization effects. He constructed a battery of sheets of lead immersed in sulphuric acid, and, after charging these for several hours from the cells of an ordinary Bunsen battery, was able to get currents of great strength and considerable duration. This battery, however, from its construction of lead, was necessarily heavy and cumbersome. Faure improved it somewhat by coating the lead plates with red-lead, thus increasing the capacity of the cell. Faure's invention gave a fresh impetus to inventors, and shortly after the market was filled with storage batteries of various kinds, most of them modifications of Planche's or Faure's. The ardor of enthusiastic inventors soon flagged, however, for all these storage batteries proved of little practical account in the end, as compared with other known methods of generating power.
Three methods of generating electricity are in general use: static or frictional electricity is generated by "plate" or "static" machines; galvanic, generated by batteries based on Volta's discovery; and induced, or faradic, generated either by chemical or mechanical action. There is still another kind, thermo-electricity, that may be generated in a most simple manner. In 1821 Seebecle, of Berlin, discovered that when a circuit was formed of two wires of different metals, if there be a difference in temperature at the juncture of these two metals an electrical current will be established. In this way heat may be transmitted directly into the energy of the current without the interposition of the steam-engine. Batteries constructed in this way are of low resistance, however, although by arranging several of them in "series," currents of considerable strength can be generated. As yet, however, they are of little practical importance.
About the middle of the century Clerk-Maxwell advanced the idea that light waves were really electro-magnetic waves. If this were true and light proved to be simply one form of electrical energy, then the same would be true of radiant heat. Maxwell advanced this theory, but failed to substantiate it by experimental confirmation. But Dr. Heinrich Hertz, a few years later, by a series of experiments, demonstrated the correctness of Maxwell's surmises. What are now called "Hertzian waves" are waves apparently identical with light waves, but of much lower pitch or period. In his experiments Hertz showed that, under proper conditions, electric sparks between polished balls were attended by ether waves of the same nature as those of light, but of a pitch of several millions of vibrations per second. These waves could be dealt with as if they were light waves--reflected, refracted, and polarized. These are the waves that are utilized in wireless telegraphy.
ROENTGEN RAYS, OR X-RAYS
In December of 1895 word came out of Germany of a scientific discovery that startled the world. It came first as a rumor, little credited; then as a pronounced report; at last as a demonstration. It told of a new manifestation of energy, in virtue of which the interior of opaque objects is made visible to human eyes. One had only to look into a tube containing a screen of a certain composition, and directed towards a peculiar electrical apparatus, to acquire clairvoyant vision more wonderful than the discredited second-sight of the medium. Coins within a purse, nails driven into wood, spectacles within a leather case, became clearly visible when subjected to the influence of this magic tube; and when a human hand was held before the tube, its bones stood revealed in weird simplicity, as if the living, palpitating flesh about them were but the shadowy substance of a ghost.
Not only could the human eye see these astounding revelations, but the impartial evidence of inanimate chemicals could be brought forward to prove that the mind harbored no illusion. The photographic film recorded the things that the eye might see, and ghostly pictures galore soon gave a quietus to the doubts of the most sceptical. Within a month of the announcement of Professor Roentgen's experiments comment upon the "X-ray" and the "new photography" had become a part of the current gossip of all Christendom.
It is hardly necessary to say that such a revolutionary thing as the discovery of a process whereby opaque objects became transparent, or translucent, was not achieved at a single bound with no intermediate discoveries. In 1859 the German physicist Julius Plucker (1801-1868) noticed that when there was an electrical discharge through an exhausted tube at a low pressure, on the surrounding walls of the tube near the negative pole, or cathode, appeared a greenish phosphorescence. This discovery was soon being investigated by a number of other scientists, among others Hittorf, Goldstein, and Professor (now Sir William) Crookes. The explanations given of this phenomenon by Professor Crookes concern us here more particularly, inasmuch as his views did not accord exactly with those held by the other two scientists, and as his researches were more directly concerned in the discovery of the Roentgen rays. He held that the heat and phosphorescence produced in a low-pressure tube were caused by streams of particles, projected from the cathode with great velocity, striking the sides of the glass tube. The composition of the glass seemed to enter into this phosphorescence also, for while lead glass produced blue phosphorescence, soda glass produced a yellowish green. The composition of the glass seemed to be changed by a long-continued pelting of these particles, the phosphorescence after a time losing its initial brilliancy, caused by the glass becoming "tired," as Professor Crookes said. Thus when some opaque substance, such as iron, is placed between the cathode and the sides of the glass tube so that it casts a shadow in a certain spot on the glass for some little time, it is found on removing the opaque substance or changing its position that the area of glass at first covered by the shadow now responded to the rays in a different manner from the surrounding glass.
The peculiar ray's, now known as the cathode rays, not only cast a shadow, but are deflected by a magnet, so that the position of the phosphorescence on the sides of the tube may be altered by the proximity of a powerful magnet. From this it would seem that the rays are composed of particles charged with negative electricity, and Professor J. J. Thomson has modified the experiment of Perrin to show that negative electricity is actually associated with the rays. There is reason for believing, therefore, that the cathode rays are rapidly moving charges of negative electricity. It is possible, also, to determine the velocity at which these particles are moving by measuring the deflection produced by the magnetic field.
From the fact that opaque substances cast a shadow in these rays it was thought at first that all solids were absolutely opaque to them. Hertz, however, discovered that a small amount of phosphorescence occurred on the glass even when such opaque substances as gold-leaf or aluminium foil were interposed between the cathode and the sides of the tube. Shortly afterwards Lenard discovered that the cathode rays can be made to pass from the inside of a discharge tube to the outside air. For convenience these rays outside the tube have since been known as "Lenard rays."
In the closing days of December, 1895, Professor Wilhelm Konrad Roentgen, of Wurzburg, announced that he had made the discovery of the remarkable effect arising from the cathode rays to which reference was made above. He found that if a plate covered with a phosphorescent substance is placed near a discharge tube exhausted so highly that the cathode rays produced a green phosphorescence, this plate is made to glow in a peculiar manner. The rays producing this glow were not the cathode rays, although apparently arising from them, and are what have since been called the Roentgen rays, or X-rays.
Roentgen found that a shadow is thrown upon the screen by substances held between it and the exhausted tube, the character of the shadow depending upon the density of the substance. Thus metals are almost completely opaque to the rays; such substances as bone much less so, and ordinary flesh hardly so at all. If a coin were held in the hand that had been interposed between the tube and the screen the picture formed showed the coin as a black shadow; and the bones of the hand, while casting a distinct shadow, showed distinctly lighter; while the soft tissues produced scarcely any shadow at all. The value of such a discovery was obvious from the first; and was still further enhanced by the discovery made shortly that, photographic plates are affected by the rays, thus making it possible to make permanent photographic records of pictures through what we know as opaque substances.
What adds materially to the practical value of Roentgen's discovery is the fact that the apparatus for producing the X-rays is now so simple and relatively inexpensive that it is within the reach even of amateur scientists. It consists essentially of an induction coil attached either to cells or a street-current plug for generating the electricity, a focus tube, and a phosphorescence screen. These focus tubes are made in various shapes, but perhaps the most popular are in the form of a glass globe, not unlike an ordinary small-sized water-bottle, this tube being closed and exhausted, and having the two poles (anode and cathode) sealed into the glass walls, but protruding at either end for attachment to the conducting wires from the induction coil. This tube may be mounted on a stand at a height convenient for manipulation. The phosphorescence screen is usually a plate covered with some platino-cyanide and mounted in the end of a box of convenient size, the opposite end of which is so shaped that it fits the contour of the face, shutting out the light and allowing the eyes of the observer to focalize on the screen at the end. For making observations the operator has simply to turn on the current of electricity and apply the screen to his eyes, pointing it towards the glowing tube, when the shadow of any substance interposed between the tube and the screen will appear upon the phosphorescence plate.
The wonderful shadow pictures produced on the phosphorescence screen, or the photographic plate, would seem to come from some peculiar form of light, but the exact nature of these rays is still an open question. Whether the Roentgen rays are really a form of light--that is, a form of "electro-magnetic disturbance propagated through ether," is not fully determined. Numerous experiments have been undertaken to determine this, but as yet no proof has been found that the rays are a form of light, although there appears to be nothing in their properties inconsistent with their being so. For the moment most investigators are content to admit that the term X-ray virtually begs the question as to the intimate nature of the form of energy involved.
VIII. THE CONSERVATION OF ENERGY
As we have seen, it was in 1831 that Faraday opened up the field of magneto-electricity. Reversing the experiments of his predecessors, who had found that electric currents may generate magnetism, he showed that magnets have power under certain circumstances to generate electricity; he proved, indeed, the interconvertibility of electricity and magnetism. Then he showed that all bodies are more or less subject to the influence of magnetism, and that even light may be affected by magnetism as to its phenomena of polarization. He satisfied himself completely of the true identity of all the various forms of electricity, and of the convertibility of electricity and chemical action. Thus he linked together light, chemical affinity, magnetism, and electricity. And, moreover, he knew full well that no one of these can be produced in indefinite supply from another. "Nowhere," he says, "is there a pure creation or production of power without a corresponding exhaustion of something to supply it."
When Faraday wrote those words in 1840 he was treading on the very heels of a greater generalization than any which he actually formulated; nay, he had it fairly within his reach. He saw a great truth without fully realizing its import; it was left for others, approaching the same truth along another path, to point out its full significance.
The great generalization which Faraday so narrowly missed is the truth which since then has become familiar as the doctrine of the conservation of energy--the law that in transforming energy from one condition to another we can never secure more than an equivalent quantity; that, in short, "to create or annihilate energy is as impossible as to create or annihilate matter; and that all the phenomena of the material universe consist in transformations of energy alone." Some philosophers think this the greatest generalization ever conceived by the mind of man. Be that as it may, it is surely one of the great intellectual landmarks of the nineteenth century. It stands apart, so stupendous and so far-reaching in its implications that the generation which first saw the law developed could little appreciate it; only now, through the vista of half a century, do we begin to see it in its true proportions.
A vast generalization such as this is never a mushroom growth, nor does it usually spring full grown from the mind of any single man. Always a number of minds are very near a truth before any one mind fully grasps it. Pre-eminently true is this of the doctrine of the conservation of energy. Not Faraday alone, but half a dozen different men had an inkling of it before it gained full expression; indeed, every man who advocated the undulatory theory of light and heat was verging towards the goal. The doctrine of Young and Fresnel was as a highway leading surely on to the wide plain of conservation. The phenomena of electro-magnetism furnished another such highway. But there was yet another road which led just as surely and even more readily to the same goal. This was the road furnished by the phenomena of heat, and the men who travelled it were destined to outstrip their fellow-workers; though, as we have seen, wayfarers on other roads were within hailing distance when the leaders passed the mark.
In order to do even approximate justice to the men who entered into the great achievement, we must recall that just at the close of the eighteenth century Count Rumford and Humphry Davy independently showed that labor may be transformed into heat; and correctly interpreted this fact as meaning the transformation of molar into molecular motion. We can hardly doubt that each of these men of genius realized--vaguely, at any rate--that there must be a close correspondence between the amount of the molar and the molecular motions; hence that each of them was in sight of the law of the mechanical equivalent of heat. But neither of them quite grasped or explicitly stated what each must vaguely have seen; and for just a quarter of a century no one else even came abreast their line of thought, let alone passing it.
But then, in 1824, a French philosopher, Sadi Carnot, caught step with the great Englishmen, and took a long leap ahead by explicitly stating his belief that a definite quantity of work could be transformed into a definite quantity of heat, no more, no less. Carnot did not, indeed, reach the clear view of his predecessors as to the nature of heat, for he still thought it a form of "imponderable" fluid; but he reasoned none the less clearly as to its mutual convertibility with mechanical work. But important as his conclusions seem now that we look back upon them with clearer vision, they made no impression whatever upon his contemporaries. Carnot's work in this line was an isolated phenomenon of historical interest, but it did not enter into the scheme of the completed narrative in any such way as did the work of Rumford and Davy.
The man who really took up the broken thread where Rumford and Davy had dropped it, and wove it into a completed texture, came upon the scene in 1840. His home was in Manchester, England; his occupation that of a manufacturer. He was a friend and pupil of the great Dr. Dalton. His name was James Prescott Joule. When posterity has done its final juggling with the names of the nineteenth century, it is not unlikely that the name of this Manchester philosopher will be a household word, like the names of Aristotle, Copernicus, and Newton.
For Joule's work it was, done in the fifth decade of the century, which demonstrated beyond all cavil that there is a precise and absolute equivalence between mechanical work and heat; that whatever the form of manifestation of molar motion, it can generate a definite and measurable amount of heat, and no more. Joule found, for example, that at the sea-level in Manchester a pound weight falling through seven hundred and seventy-two feet could generate enough heat to raise the temperature of a pound of water one degree Fahrenheit. There was nothing haphazard, nothing accidental, about this; it bore the stamp of unalterable law. And Joule himself saw, what others in time were made to see, that this truth is merely a particular case within a more general law. If heat cannot be in any sense created, but only made manifest as a transformation of another kind of motion, then must not the same thing be true of all those other forms of "force"--light, electricity, magnetism--which had been shown to be so closely associated, so mutually convertible, with heat? All analogy seemed to urge the truth of this inference; all experiment tended to confirm it. The law of the mechanical equivalent of heat then became the main corner-stone of the greater law of the conservation of energy.
But while this citation is fresh in mind, we must turn our attention with all haste to a country across the Channel--to Denmark, in short--and learn that even as Joule experimented with the transformation of heat, a philosopher of Copenhagen, Colding by name, had hit upon the same idea, and carried it far towards a demonstration. And then, without pausing, we must shift yet again, this time to Germany, and consider the work of three other men, who independently were on the track of the same truth, and two of whom, it must be admitted, reached it earlier than either Joule or Colding, if neither brought it to quite so clear a demonstration. The names of these three Germans are Mohr, Mayer, and Helmholtz. Their share in establishing the great doctrine of conservation must now claim our attention.
As to Karl Friedrich Mohr, it may be said that his statement of the doctrine preceded that of any of his fellows, yet that otherwise it was perhaps least important. In 1837 this thoughtful German had grasped the main truth, and given it expression in an article published in the Zeitschrift fur Physik, etc. But the article attracted no attention whatever, even from Mohr's own countrymen. Still, Mohr's title to rank as one who independently conceived the great truth, and perhaps conceived it before any other man in the world saw it as clearly, even though he did not demonstrate its validity, is not to be disputed.
It was just five years later, in 1842, that Dr. Julius Robert Mayer, practising physician in the little German town of Heilbronn, published a paper in Liebig's Annalen on "The Forces of Inorganic Nature," in which not merely the mechanical theory of heat, but the entire doctrine of the conservation of energy, is explicitly if briefly stated. Two years earlier Dr. Mayer, while surgeon to a Dutch India vessel cruising in the tropics, had observed that the venous blood of a patient seemed redder than venous blood usually is observed to be in temperate climates. He pondered over this seemingly insignificant fact, and at last reached the conclusion that the cause must be the lesser amount of oxidation required to keep up the body temperature in the tropics. Led by this reflection to consider the body as a machine dependent on outside forces for its capacity to act, he passed on into a novel realm of thought, which brought him at last to independent discovery of the mechanical theory of heat, and to the first full and comprehensive appreciation of the great law of conservation. Blood-letting, the modern physician holds, was a practice of very doubtful benefit, as a rule, to the subject; but once, at least, it led to marvellous results. No straw is go small that it may not point the receptive mind of genius to new and wonderful truths.
MAYER'S PAPER OF 1842
The paper in which Mayer first gave expression to his revolutionary ideas bore the title of "The Forces of Inorganic Nature," and was published in 1842. It is one of the gems of scientific literature, and fortunately it is not too long to be quoted in its entirety. Seldom if ever was a great revolutionary doctrine expounded in briefer compass:
"What are we to understand by 'forces'? and how are different forces related to each other? The term force conveys for the most part the idea of something unknown, unsearchable, and hypothetical; while the term matter, on the other hand, implies the possession, by the object in question, of such definite properties as weight and extension. An attempt, therefore, to render the idea of force equally exact with that of matter is one which should be welcomed by all those who desire to have their views of nature clear and unencumbered by hypothesis.
"Forces are causes; and accordingly we may make full application in relation to them of the principle causa aequat effectum. If the cause c has the effect e, then c = e; if, in its turn, e is the cause of a second effect of f, we have e = f, and so on: c = e = f... = c. In a series of causes and effects, a term or a part of a term can never, as is apparent from the nature of an equation, become equal to nothing. This first property of all causes we call their indestructibility.
"If the given cause c has produced an effect e equal to itself, it has in that very act ceased to be--c has become e. If, after the production of e, c still remained in the whole or in part, there must be still further effects corresponding to this remaining cause: the total effect of c would thus be > e, which would be contrary to the supposition c = e. Accordingly, since c becomes e, and e becomes f, etc., we must regard these various magnitudes as different forms under which one and the same object makes its appearance. This capability of assuming various forms is the second essential property of all causes. Taking both properties together, we may say, causes an INDESTRUCTIBLE quantitatively, and quantitatively CONVERTIBLE objects.
"There occur in nature two causes which apparently never pass one into the other," said Mayer. "The first class consists of such causes as possess the properties of weight and impenetrability. These are kinds of matter. The other class is composed of causes which are wanting in the properties just mentioned--namely, forces, called also imponderables, from the negative property that has been indicated. Forces are therefore INDESTRUCTIBLE, CONVERTIBLE, IMPONDERABLE OBJECTS.
"As an example of causes and effects, take matter: explosive gas, H + O, and water, HO, are related to each other as cause and effect; therefore H + O = HO. But if H + O becomes HO, heat, cal., makes its appearance as well as water; this heat must likewise have a cause, x, and we have therefore H + O + X = HO + cal. It might be asked, however, whether H + O is really = HO, and x = cal., and not perhaps H + O = cal., and x = HO, whence the above equation could equally be deduced; and so in many other cases. The phlogistic chemists recognized the equation between cal. and x, or phlogiston as they called it, and in so doing made a great step in advance; but they involved themselves again in a system of mistakes by putting x in place of O. In this way they obtained H = HO + x.
"Chemistry teaches us that matter, as a cause, has matter for its effect; but we may say with equal justification that to force as a cause corresponds force as effect. Since c = e, and e = c, it is natural to call one term of an equation a force, and the other an effect of force, or phenomenon, and to attach different notions to the expression force and phenomenon. In brief, then, if the cause is matter, the effect is matter; if the cause is a force, the effect is also a force.
"The cause that brings about the raising of a weight is a force. The effect of the raised weight is, therefore, also a force; or, expressed in a more general form, SEPARATION IN SPACE OF PONDERABLE OBJECTS IS A FORCE; and since this force causes the fall of bodies, we call it FALLING FORCE. Falling force and fall, or, still more generally, falling force and motion, are forces related to each other as cause and effect--forces convertible into each other--two different forms of one and the same object. For example, a weight resting on the ground is not a force: it is neither the cause of motion nor of the lifting of another weight. It becomes so, however, in proportion as it is raised above the ground. The cause--that is, the distance between a weight and the earth, and the effect, or the quantity of motion produced, bear to each other, as shown by mechanics, a constant relation.
"Gravity being regarded as the cause of the falling of bodies, a gravitating force is spoken of; and thus the ideas of PROPERTY and of FORCE are confounded with each other. Precisely that which is the essential attribute of every force--that is, the UNION of indestructibility with convertibility--is wanting in every property: between a property and a force, between gravity and motion, it is therefore impossible to establish the equation required for a rightly conceived causal relation. If gravity be called a force, a cause is supposed which produces effects without itself diminishing, and incorrect conceptions of the causal connections of things are thereby fostered. In order that a body may fall, it is just as necessary that it be lifted up as that it should be heavy or possess gravity. The fall of bodies, therefore, ought not to be ascribed to their gravity alone. The problem of mechanics is to develop the equations which subsist between falling force and motion, motion and falling force, and between different motions. Here is a case in point: The magnitude of the falling force v is directly proportional (the earth's radius being assumed--oo) to the magnitude of the mass m, and the height d, to which it is raised--that is, v = md. If the height d = l, to which the mass m is raised, is transformed into the final velocity c = l of this mass, we have also v = mc; but from the known relations existing between d and c, it results that, for other values of d or of c, the measure of the force v is mc squared; accordingly v = md = mcsquared. The law of the conservation of vis viva is thus found to be based on the general law of the indestructibility of causes.
"In many cases we see motion cease without having caused another motion or the lifting of a weight. But a force once in existence cannot be annihilated--it can only change its form. And the question therefore arises, what other forms is force, which we have become acquainted with as falling force and motion, capable of assuming? Experience alone can lead us to a conclusion on this point. That we may experiment to advantage, we must select implements which, besides causing a real cessation of motion, are as little as possible altered by the objects to be examined. For example, if we rub together two metal plates, we see motion disappear, and heat, on the other hand, make its appearance, and there remains to be determined only whether MOTION is the cause of heat. In order to reach a decision on this point, we must discuss the question whether, in the numberless cases in which the expenditure of motion is accompanied by the appearance of heat, the motion has not some other effect than the production of heat, and the heat some other cause than the motion.
"A serious attempt to ascertain the effects of ceasing motion has never been made. Without wishing to exclude a priori the hypothesis which it may be possible to establish, therefore, we observe only that, as a rule, this effect cannot be supposed to be an alteration in the state of aggregation of the moved (that is, rubbing, etc.) bodies. If we assume that a certain quantity of motion v is expended in the conversion of a rubbing substance m into n, we must then have m + v - n, and n = m + v; and when n is reconverted into m, v must appear again in some form or other.
"By the friction of two metallic plates continued for a very long time, we can gradually cause the cessation of an immense quantity of movement; but would it ever occur to us to look for even the smallest trace of the force which has disappeared in the metallic dust that we could collect, and to try to regain it thence? We repeat, the motion cannot have been annihilated; and contrary, or positive and negative, motions cannot be regarded as = o any more than contrary motions can come out of nothing, or a weight can raise itself.
"Without the recognition of a causal relation between motion and heat, it is just as difficult to explain the production of heat as it is to give any account of the motion that disappears. The heat cannot be derived from the diminution of the volume of the rubbing substances. It is well known that two pieces of ice may be melted by rubbing them together in vacuo; but let any one try to convert ice into water by pressure, however enormous. The author has found that water undergoes a rise of temperature when shaken violently. The water so heated (from twelve to thirteen degrees centigrade) has a greater bulk after being shaken than it had before. Whence now comes this quantity of heat, which by repeated shaking may be called into existence in the same apparatus as often as we please? The vibratory hypothesis of heat is an approach towards the doctrine of heat being the effect of motion, but it does not favor the admission of this causal relation in its full generality. It rather lays the chief stress on restless oscillations.
"If it be considered as now established that in many cases no other effect of motion can be traced except heat, and that no other cause than motion can be found for the heat that is produced, we prefer the assumption that heat proceeds from motion to the assumption of a cause without effect and of an effect without a cause. Just as the chemist, instead of allowing oxygen and hydrogen to disappear without further investigation, and water to be produced in some inexplicable manner, establishes a connection between oxygen and hydrogen on the one hand, and water on the other.
"We may conceive the natural connection existing between falling force, motion, and heat as follows: We know that heat makes its appearance when the separate particles of a body approach nearer to each other; condensation produces heat. And what applies to the smallest particles of matter, and the smallest intervals between them, must also apply to large masses and to measurable distances. The falling of a weight is a diminution of the bulk of the earth, and must therefore without doubt be related to the quantity of heat thereby developed; this quantity of heat must be proportional to the greatness of the weight and its distance from the ground. From this point of view we are easily led to the equations between falling force, motion, and heat that have already been discussed.
"But just as little as the connection between falling force and motion authorizes the conclusion that the essence of falling force is motion, can such a conclusion be adopted in the case of heat. We are, on the contrary, rather inclined to infer that, before it can become heat, motion must cease to exist as motion, whether simple, or vibratory, as in the case of light and radiant heat, etc.
"If falling force and motion are equivalent to heat, heat must also naturally be equivalent to motion and falling force. Just as heat appears as an EFFECT of the diminution of bulk and of the cessation of motion, so also does heat disappear as a CAUSE when its effects are produced in the shape of motion, expansion, or raising of weight.
"In water-mills the continual diminution in bulk which the earth undergoes, owing to the fall of the water, gives rise to motion, which afterwards disappears again, calling forth unceasingly a great quantity of heat; and, inversely, the steam-engine serves to decompose heat again into motion or the raising of weights. A locomotive with its train may be compared to a distilling apparatus; the heat applied under the boiler passes off as motion, and this is deposited again as heat at the axles of the wheels."
Mayer then closes his paper with the following deduction: "The solution of the equations subsisting between falling force and motion requires that the space fallen through in a given time--e. g., the first second--should be experimentally determined. In like manner, the solution of the equations subsisting between falling force and motion on the one hand and heat on the other requires an answer to the question, How great is the quantity of heat which corresponds to a given quantity of motion or falling force? For instance, we must ascertain how high a given weight requires to be raised above the ground in order that its falling force maybe equivalent to the raising of the temperature of an equal weight of water from 0 degrees to 1 degrees centigrade. The attempt to show that such an equation is the expression of a physical truth may be regarded as the substance of the foregoing remarks.
"By applying the principles that have been set forth to the relations subsisting between the temperature and the volume of gases, we find that the sinking of a mercury column by which a gas is compressed is equivalent to the quantity of heat set free by the compression; and hence it follows, the ratio between the capacity for heat of air under constant pressure and its capacity under constant volume being taken as = 1.421, that the warming of a given weight of water from 0 degrees to equal weight from the height of about three hundred and sixty-five metres. If we compare with this result the working of our best steam-engines, we see how small a part only of the heat applied under the boiler is really transformed into motion or the raising of weights; and this may serve as justification for the attempts at the profitable production of motion by some other method than the expenditure of the chemical difference between carbon and oxygen--more particularly by the transformation into motion of electricity obtained by chemical means."(1)
MAYER AND HELMHOLTZ
Here, then, was this obscure German physician, leading the humdrum life of a village practitioner, yet seeing such visions as no human being in the world had ever seen before.
The great principle he had discovered became the dominating thought of his life, and filled all his leisure hours. He applied it far and wide, amid all the phenomena of the inorganic and organic worlds. It taught him that both vegetables and animals are machines, bound by the same laws that hold sway over inorganic matter, transforming energy, but creating nothing. Then his mind reached out into space and met a universe made up of questions. Each star that blinked down at him as he rode in answer to a night-call seemed an interrogation-point asking, How do I exist? Why have I not long since burned out if your theory of conservation be true? No one had hitherto even tried to answer that question; few had so much as realized that it demanded an answer. But the Heilbronn physician understood the question and found an answer. His meteoric hypothesis, published in 1848, gave for the first time a tenable explanation of the persistent light and heat of our sun and the myriad other suns--an explanation to which we shall recur in another connection.
All this time our isolated philosopher, his brain aflame with the glow of creative thought, was quite unaware that any one else in the world was working along the same lines. And the outside world was equally heedless of the work of the Heilbronn physician. There was no friend to inspire enthusiasm and give courage, no kindred spirit to react on this masterful but lonely mind. And this is the more remarkable because there are few other cases where a master-originator in science has come upon the scene except as the pupil or friend of some other master-originator. Of the men we have noticed in the present connection, Young was the friend and confrere of Davy; Davy, the protege of Rumford; Faraday, the pupil of Davy; Fresnel, the co-worker with Arago; Colding, the confrere of Oersted; Joule, the pupil of Dalton. But Mayer is an isolated phenomenon--one of the lone mountain-peak intellects of the century. That estimate may be exaggerated which has called him the Galileo of the nineteenth century, but surely no lukewarm praise can do him justice.
Yet for a long time his work attracted no attention whatever. In 1847, when another German physician, Hermann von Helmholtz, one of the most massive and towering intellects of any age, had been independently led to comprehension of the doctrine of the conservation of energy and published his treatise on the subject, he had hardly heard of his countryman Mayer. When he did hear of him, however, he hastened to renounce all claim to the doctrine of conservation, though the world at large gives him credit of independent even though subsequent discovery.
JOULE'S PAPER OF 1843
Meantime, in England, Joule was going on from one experimental demonstration to another, oblivious of his German competitors and almost as little noticed by his own countrymen. He read his first paper before the chemical section of the British Association for the Advancement of Science in 1843, and no one heeded it in the least. It is well worth our while, however, to consider it at length. It bears the title, "On the Calorific Effects of Magneto-Electricity, and the Mechanical Value of Heat." The full text, as published in the Report of the British Association, is as follows:
"Although it has been long known that fine platinum wire can be ignited by magneto-electricity, it still remained a matter of doubt whether heat was evolved by the COILS in which the magneto-electricity was generated; and it seemed indeed not unreasonable to suppose that COLD was produced there in order to make up for the heat evolved by the other part of the circuit. The author therefore has endeavored to clear up this uncertainty by experiment. His apparatus consisted of a small compound electro-magnet, immersed in water, revolving between the poles of a powerful stationary magnet. The magneto-electricity developed in the coils of the revolving electro-magnet was measured by an accurate galvanometer; and the temperature of the water was taken before and after each experiment by a very delicate thermometer. The influence of the temperature of the surrounding atmospheric air was guarded against by covering the revolving tube with flannel, etc., and by the adoption of a system of interpolation. By an extensive series of experiments with the above apparatus the author succeeded in proving that heat is evolved by the coils of the magneto-electrical machine, as well as by any other part of the circuit, in proportion to the resistance to conduction of the wire and the square of the current; the magneto having, under comparable circumstances, the same calorific power as the voltaic electricity.
"Professor Jacobi, of St. Petersburg, bad shown that the motion of an electro-magnetic machine generates magneto-electricity in opposition to the voltaic current of the battery. The author had observed the same phenomenon on arranging his apparatus as an electro-magnetic machine; but had found that no additional heat was evolved on account of the conflict of forces in the coil of the electro-magnet, and that the heat evolved by the coil remained, as before, proportional to the square of the current. Again, by turning the machine contrary to the direction of the attractive forces, so as to increase the intensity of the voltaic current by the assistance of the magneto-electricity, he found that the evolution of heat was still proportional to the square of the current. The author discovered, therefore, that the heat evolved by the voltaic current is invariably proportional to the square of the current, however the intensity of the current may be varied by magnetic induction. But Dr. Faraday has shown that the chemical effects of the current are simply as its quantity. Therefore he concluded that in the electro-magnetic engine a part of the heat due to the chemical actions of the battery is lost by the circuit, and converted into mechanical power; and that when the electro-magnetic engine is turned CONTRARY to the direction of the attractive forces, a greater quantity of heat is evolved by the circuit than is due to the chemical reactions of the battery, the over-plus quantity being produced by the conversion of the mechanical force exerted in turning the machine. By a dynamometrical apparatus attached to his machine, the author has ascertained that, in all the above cases, a quantity of heat, capable of increasing the temperature of a pound of water by one degree of Fahrenheit's scale, is equal to the mechanical force capable of raising a weight of about eight hundred and thirty pounds to the height of one foot."(2)
JOULE OR MAYER?
Two years later Joule wished to read another paper, but the chairman hinted that time was limited, and asked him to confine himself to a brief verbal synopsis of the results of his experiments. Had the chairman but known it, he was curtailing a paper vastly more important than all the other papers of the meeting put together. However, the synopsis was given, and one man was there to hear it who had the genius to appreciate its importance. This was William Thomson, the present Lord Kelvin, now known to all the world as among the greatest of natural philosophers, but then only a novitiate in science. He came to Joule's aid, started rolling the ball of controversy, and subsequently associated himself with the Manchester experimenter in pursuing his investigations.
But meantime the acknowledged leaders of British science viewed the new doctrine askance. Faraday, Brewster, Herschel--those were the great names in physics at that day, and no one of them could quite accept the new views regarding energy. For several years no older physicist, speaking with recognized authority, came forward in support of the doctrine of conservation. This culminating thought of the first half of the nineteenth century came silently into the world, unheralded and unopposed. The fifth decade of the century had seen it elaborated and substantially demonstrated in at least three different countries, yet even the leaders of thought did not so much as know of its existence. In 1853 Whewell, the historian of the inductive sciences, published a second edition of his history, and, as Huxley has pointed out, he did not so much as refer to the revolutionizing thought which even then was a full decade old.
By this time, however, the battle was brewing. The rising generation saw the importance of a law which their elders could not appreciate, and soon it was noised abroad that there were more than one claimant to the honor of discovery. Chiefly through the efforts of Professor Tyndall, the work of Mayer became known to the British public, and a most regrettable controversy ensued between the partisans of Mayer and those of Joule--a bitter controversy, in which Davy's contention that science knows no country was not always regarded, and which left its scars upon the hearts and minds of the great men whose personal interests were involved.
And so to this day the question who is the chief discoverer of the law of the conservation of energy is not susceptible of a categorical answer that would satisfy all philosophers. It is generally held that the first choice lies between Joule and Mayer. Professor Tyndall has expressed the belief that in future each of these men will be equally remembered in connection with this work. But history gives us no warrant for such a hope. Posterity in the long run demands always that its heroes shall stand alone. Who remembers now that Robert Hooke contested with Newton the discovery of the doctrine of universal gravitation? The judgment of posterity is unjust, but it is inexorable. And so we can little doubt that a century from now one name will be mentioned as that of the originator of the great doctrine of the conservation of energy. The man whose name is thus remembered will perhaps be spoken of as the Galileo, the Newton, of the nineteenth century; but whether the name thus dignified by the final verdict of history will be that of Colding, Mohr, Mayer, Helmholtz, or Joule, is not as, yet decided.
LORD KELVIN AND THE DISSIPATION OF ENERGY
The gradual permeation of the field by the great doctrine of conservation simply repeated the history of the introduction of every novel and revolutionary thought. Necessarily the elder generation, to whom all forms of energy were imponderable fluids, must pass away before the new conception could claim the field. Even the word energy, though Young had introduced it in 1807, did not come into general use till some time after the middle of the century. To the generality of philosophers (the word physicist was even less in favor at this time) the various forms of energy were still subtile fluids, and never was idea relinquished with greater unwillingness than this. The experiments of Young and Fresnel had convinced a large number of philosophers that light is a vibration and not a substance; but so great an authority as Biot clung to the old emission idea to the end of his life, in 1862, and held a following.
Meantime, however, the company of brilliant young men who had just served their apprenticeship when the doctrine of conservation came upon the scene had grown into authoritative positions, and were battling actively for the new ideas. Confirmatory evidence that energy is a molecular motion and not an "imponderable" form of matter accumulated day by day. The experiments of two Frenchmen, Hippolyte L. Fizeau and Leon Foucault, served finally to convince the last lingering sceptics that light is an undulation; and by implication brought heat into the same category, since James David Forbes, the Scotch physicist, had shown in 1837 that radiant heat conforms to the same laws of polarization and double refraction that govern light. But, for that matter, the experiments that had established the mechanical equivalent of heat hardly left room for doubt as to the immateriality of this "imponderable." Doubters had indeed, expressed scepticism as to the validity of Joule's experiments, but the further researches, experimental and mathematical, of such workers as Thomson (Lord Kelvin), Rankine, and Tyndall in Great Britain, of Helmholtz and Clausius in Germany, and of Regnault in France, dealing with various manifestations of heat, placed the evidence beyond the reach of criticism.
Out of these studies, just at the middle of the century, to which the experiments of Mayer and Joule had led, grew the new science of thermo-dynamics. Out of them also grew in the mind of one of the investigators a new generalization, only second in importance to the doctrine of conservation itself. Professor William Thomson (Lord Kelvin) in his studies in thermodynamics was early impressed with the fact that whereas all the molar motion developed through labor or gravity could be converted into heat, the process is not fully reversible. Heat can, indeed, be converted into molar motion or work, but in the process a certain amount of the heat is radiated into space and lost. The same thing happens whenever any other form of energy is converted into molar motion. Indeed, every transmutation of energy, of whatever character, seems complicated by a tendency to develop heat, part of which is lost. This observation led Professor Thomson to his doctrine of the dissipation of energy, which he formulated before the Royal Society of Edinburgh in 1852, and published also in the Philosophical Magazine the same year, the title borne being, "On a Universal Tendency in Nature to the Dissipation of Mechanical Energy."
From the principle here expressed Professor Thomson drew the startling conclusion that, "since any restoration of this mechanical energy without more than an equivalent dissipation is impossible," the universe, as known to us, must be in the condition of a machine gradually running down; and in particular that the world we live on has been within a finite time unfit for human habitation, and must again become so within a finite future. This thought seems such a commonplace to-day that it is difficult to realize how startling it appeared half a century ago. A generation trained, as ours has been, in the doctrines of the conservation and dissipation of energy as the very alphabet of physical science can but ill appreciate the mental attitude of a generation which for the most part had not even thought it problematical whether the sun could continue to give out heat and light forever. But those advance thinkers who had grasped the import of the doctrine of conservation could at once appreciate the force of Thomson's doctrine of dissipation, and realize the complementary character of the two conceptions.
Here and there a thinker like Rankine did, indeed, attempt to fancy conditions under which the energy lost through dissipation might be restored to availability, but no such effort has met with success, and in time Professor Thomson's generalization and his conclusions as to the consequences of the law involved came to be universally accepted.
The introduction of the new views regarding the nature of energy followed, as I have said, the course of every other growth of new ideas. Young and imaginative men could accept the new point of view; older philosophers, their minds channelled by preconceptions, could not get into the new groove. So strikingly true is this in the particular case now before us that it is worth while to note the ages at the time of the revolutionary experiments of the men whose work has been mentioned as entering into the scheme of evolution of the idea that energy is merely a manifestation of matter in motion. Such a list will tell the story better than a volume of commentary.
Observe, then, that Davy made his epochal experiment of melting ice by friction when he was a youth of twenty. Young was no older when he made his first communication to the Royal Society, and was in his twenty-seventh year when he first actively espoused the undulatory theory. Fresnel was twenty-six when he made his first important discoveries in the same field; and Arago, who at once became his champion, was then but two years his senior, though for a decade he had been so famous that one involuntarily thinks of him as belonging to an elder generation.
Forbes was under thirty when he discovered the polarization of heat, which pointed the way to Mohr, then thirty-one, to the mechanical equivalent. Joule was twenty-two in 1840, when his great work was begun; and Mayer, whose discoveries date from the same year, was then twenty-six, which was also the age of Helmholtz when he published his independent discovery of the same law. William Thomson was a youth just past his majority when he came to the aid of Joule before the British Society, and but seven years older when he formulated his own doctrine of the dissipation of energy. And Clausius and Rankine, who are usually mentioned with Thomson as the great developers of thermo-dynamics, were both far advanced with their novel studies before they were thirty. With such a list in mind, we may well agree with the father of inductive science that "the man who is young in years may be old in hours."
Yet we must not forget that the shield has a reverse side. For was not the greatest of observing astronomers, Herschel, past thirty-five before he ever saw a telescope, and past fifty before he discovered the heat rays of the spectrum? And had not Faraday reached middle life before he turned his attention especially to electricity? Clearly, then, to make this phrase complete, Bacon should have added that "the man who is old in years may be young in imagination." Here, however, even more appropriate than in the other case--more's the pity--would have been the application of his qualifying clause: "but that happeneth rarely."
THE FINAL UNIFICATION
There are only a few great generalizations as yet thought out in any single field of science. Naturally, then, after a great generalization has found definitive expression, there is a period of lull before another forward move. In the case of the doctrines of energy, the lull has lasted half a century. Throughout this period, it is true, a multitude of workers have been delving in the field, and to the casual observer it might seem as if their activity had been boundless, while the practical applications of their ideas--as exemplified, for example, in the telephone, phonograph, electric light, and so on--have been little less than revolutionary. Yet the most competent of living authorities, Lord Kelvin, could assert in 1895 that in fifty years he had learned nothing new regarding the nature of energy.
This, however, must not be interpreted as meaning that the world has stood still during these two generations. It means rather that the rank and file have been moving forward along the road the leaders had already travelled. Only a few men in the world had the range of thought regarding the new doctrine of energy that Lord Kelvin had at the middle of the century. The few leaders then saw clearly enough that if one form of energy is in reality merely an undulation or vibration among the particles of "ponderable" matter or of ether, all other manifestations of energy must be of the same nature. But the rank and file were not even within sight of this truth for a long time after they had partly grasped the meaning of the doctrine of conservation. When, late in the fifties, that marvellous young Scotchman, James Clerk-Maxwell, formulating in other words an idea of Faraday's, expressed his belief that electricity and magnetism are but manifestations of various conditions of stress and motion in the ethereal medium (electricity a displacement of strain, magnetism a whirl in the ether), the idea met with no immediate popularity. And even less cordial was the reception given the same thinker's theory, put forward in 1863, that the ethereal undulations producing the phenomenon we call light differ in no respect except in their wave-length from the pulsations of electro-magnetism.
At about the same time Helmholtz formulated a somewhat similar electro-magnetic theory of light; but even the weight of this combined authority could not give the doctrine vogue until very recently, when the experiments of Heinrich Hertz, the pupil of Helmholtz, have shown that a condition of electrical strain may be developed into a wave system by recurrent interruptions of the electric state in the generator, and that such waves travel through the ether with the rapidity of light. Since then the electro-magnetic theory of light has been enthusiastically referred to as the greatest generalization of the century; but the sober thinker must see that it is really only what Hertz himself called it--one pier beneath the great arch of conservation. It is an interesting detail of the architecture, but the part cannot equal the size of the whole.
More than that, this particular pier is as yet by no means a very firm one. It has, indeed, been demonstrated that waves of electro-magnetism pass through space with the speed of light, but as yet no one has developed electric waves even remotely approximating the shortness of the visual rays. The most that can positively be asserted, therefore, is that all the known forms of radiant energy-heat, light, electro-magnetism--travel through space at the same rate of speed, and consist of traverse vibrations--"lateral quivers," as Fresnel said of light--known to differ in length, and not positively known to differ otherwise. It has, indeed, been suggested that the newest form of radiant energy, the famous X-ray of Professor Roentgen's discovery, is a longitudinal vibration, but this is a mere surmise. Be that as it may, there is no one now to question that all forms of radiant energy, whatever their exact affinities, consist essentially of undulatory motions of one uniform medium.
A full century of experiment, calculation, and controversy has thus sufficed to correlate the "imponderable fluids" of our forebears, and reduce them all to manifestations of motion among particles of matter. At first glimpse that seems an enormous change of view. And yet, when closely considered, that change in thought is not so radical as the change in phrase might seem to imply. For the nineteenth-century physicist, in displacing the "imponderable fluids" of many kinds--one each for light, heat, electricity, magnetism--has been obliged to substitute for them one all-pervading fluid, whose various quivers, waves, ripples, whirls or strains produce the manifestations which in popular parlance are termed forms of force. This all-pervading fluid the physicist terms the ether, and he thinks of it as having no weight. In effect, then, the physicist has dispossessed the many imponderables in favor of a single imponderable--though the word imponderable has been banished from his vocabulary. In this view the ether--which, considered as a recognized scientific verity, is essentially a nineteenth-century discovery--is about the most interesting thing in the universe. Something more as to its properties, real or assumed, we shall have occasion to examine as we turn to the obverse side of physics, which demands our attention in the next chapter.
IX. THE ETHER AND PONDERABLE MATTER
"Whatever difficulties we may have in forming a consistent idea of the constitution of the ether, there can be no doubt that the interplanetary and interstellar spaces are not empty, but are occupied by a material substance or body which is certainly the largest and probably the most uniform body of which we have any knowledge."
Such was the verdict pronounced some thirty years ago by James Clerk-Maxwell, one of the very greatest of nineteenth-century physicists, regarding the existence of an all-pervading plenum in the universe, in which every particle of tangible matter is immersed. And this verdict may be said to express the attitude of the entire philosophical world of our day. Without exception, the authoritative physicists of our time accept this plenum as a verity, and reason about it with something of the same confidence they manifest in speaking of "ponderable" matter or of, energy. It is true there are those among them who are disposed to deny that this all-pervading plenum merits the name of matter. But that it is a something, and a vastly important something at that, all are agreed. Without it, they allege, we should know nothing of light, of radiant heat, of electricity or magnetism; without it there would probably be no such thing as gravitation; nay, they even hint that without this strange something, ether, there would be no such thing as matter in the universe. If these contentions of the modern physicist are justified, then this intangible ether is incomparably the most important as well as the "largest and most uniform substance or body" in the universe. Its discovery may well be looked upon as one of the most important feats of the nineteenth century.
For a discovery of that century it surely is, in the sense that all the known evidences of its existence were gathered in that epoch. True dreamers of all ages have, for metaphysical reasons, imagined the existence of intangible fluids in space--they had, indeed, peopled space several times over with different kinds of ethers, as Maxwell remarks--but such vague dreamings no more constituted the discovery of the modern ether than the dream of some pre-Columbian visionary that land might lie beyond the unknown waters constituted the discovery of America. In justice it must be admitted that Huyghens, the seventeenth-century originator of the undulatory theory of light, caught a glimpse of the true ether; but his contemporaries and some eight generations of his successors were utterly deaf to his claims; so he bears practically the same relation to the nineteenth-century discoverers of ether that the Norseman bears to Columbus.
The true Columbus of the ether was Thomas Young. His discovery was consummated in the early days of the nineteenth century, when he brought forward the first, conclusive proofs of the undulatory theory of light. To say that light consists of undulations is to postulate something that undulates; and this something could not be air, for air exists only in infinitesimal quantity, if at all, in the interstellar spaces, through which light freely penetrates. But if not air, what then? Why, clearly, something more intangible than air; something supersensible, evading all direct efforts to detect it, yet existing everywhere in seemingly vacant space, and also interpenetrating the substance of all transparent liquids and solids, if not, indeed, of all tangible substances. This intangible something Young rechristened the Luminiferous Ether.
In the early days of his discovery Young thought of the undulations which produce light and radiant heat as being longitudinal--a forward and backward pulsation, corresponding to the pulsations of sound--and as such pulsations can be transmitted by a fluid medium with the properties of ordinary fluids, he was justified in thinking of the ether as being like a fluid in its properties, except for its extreme intangibility. But about 1818 the experiments of Fresnel and Arago with polarization of light made it seem very doubtful whether the theory of longitudinal vibrations is sufficient, and it was suggested by Young, and independently conceived and demonstrated by Fresnel, that the luminiferous undulations are not longitudinal, but transverse; and all the more recent experiments have tended to confirm this view. But it happens that ordinary fluids--gases and liquids--cannot transmit lateral vibrations; only rigid bodies are capable of such a vibration. So it became necessary to assume that the luminiferous ether is a body possessing elastic rigidity--a familiar property of tangible solids, but one quite unknown among fluids.
The idea of transverse vibrations carried with it another puzzle. Why does not the ether, when set aquiver with the vibration which gives us the sensation we call light, have produced in its substance subordinate quivers, setting out at right angles from the path of the original quiver? Such perpendicular vibrations seem not to exist, else we might see around a corner; how explain their absence? The physicist could think of but one way: they must assume that the ether is incompressible. It must fill all space--at any rate, all space with which human knowledge deals--perfectly full.
These properties of the ether, incompressibility and elastic rigidity, are quite conceivable by themselves; but difficulties of thought appear when we reflect upon another quality which the ether clearly must possess--namely, frictionlessness. By hypothesis this rigid, incompressible body pervades all space, imbedding every particle of tangible matter; yet it seems not to retard the movements of this matter in the slightest degree. This is undoubtedly the most difficult to comprehend of the alleged properties of the ether. The physicist explains it as due to the perfect elasticity of the ether, in virtue of which it closes in behind a moving particle with a push exactly counterbalancing the stress required to penetrate it in front.
To a person unaccustomed to think of seemingly solid matter as really composed of particles relatively wide apart, it is hard to understand the claim that ether penetrates the substance of solids--of glass, for example--and, to use Young's expression, which we have previously quoted, moves among them as freely as the wind moves through a grove of trees. This thought, however, presents few difficulties to the mind accustomed to philosophical speculation. But the question early arose in the mind of Fresnel whether the ether is not considerably affected by contact with the particles of solids. Some of his experiments led him to believe that a portion of the ether which penetrates among the molecules of tangible matter is held captive, so to speak, and made to move along with these particles. He spoke of such portions of the ether as "bound" ether, in contradistinction to the great mass of "free" ether. Half a century after Fresnel's death, when the ether hypothesis had become an accepted tenet of science, experiments were undertaken by Fizeau in France, and by Clerk-Maxwell in England, to ascertain whether any portion of ether is really thus bound to particles of matter; but the results of the experiments were negative, and the question is still undetermined.
While the undulatory theory of light was still fighting its way, another kind of evidence favoring the existence of an ether was put forward by Michael Faraday, who, in the course of his experiments in electrical and magnetic induction, was led more and more to perceive definite lines or channels of force in the medium subject to electro-magnetic influence. Faraday's mind, like that of Newton and many other philosophers, rejected the idea of action at a distance, and he felt convinced that the phenomena of magnetism and of electric induction told strongly for the existence of an invisible plenum everywhere in space, which might very probably be the same plenum that carries the undulations of light and radiant heat.
Then, about the middle of the century, came that final revolution of thought regarding the nature of energy which we have already outlined in the preceding chapter, and with that the case for ether was considered to be fully established. The idea that energy is merely a "mode of motion" (to adopt Tyndall's familiar phrase), combined with the universal rejection of the notion of action at a distance, made the acceptance of a plenum throughout space a necessity of thought--so, at any rate, it has seemed to most physicists of recent decades. The proof that all known forms of radiant energy move through space at the same rate of speed is regarded as practically a demonstration that but one plenum--one ether--is concerned in their transmission. It has, indeed, been tentatively suggested, by Professor J. Oliver Lodge, that there may be two ethers, representing the two opposite kinds of electricity, but even the author of this hypothesis would hardly claim for it a high degree of probability.
The most recent speculations regarding the properties of the ether have departed but little from the early ideas of Young and Fresnel. It is assumed on all sides that the ether is a continuous, incompressible body, possessing rigidity and elasticity. Lord Kelvin has even calculated the probable density of this ether, and its coefficient of rigidity. As might be supposed, it is all but infinitely tenuous as compared with any tangible solid, and its rigidity is but infinitesimal as compared with that of steel. In a word, it combines properties of tangible matter in a way not known in any tangible substance. Therefore we cannot possibly conceive its true condition correctly. The nearest approximation, according to Lord Kelvin, is furnished by a mould of transparent jelly. It is a crude, inaccurate analogy, of course, the density and resistance of jelly in particular being utterly different from those of the ether; but the quivers that run through the jelly when it is shaken, and the elastic tension under which it is placed when its mass is twisted about, furnish some analogy to the quivers and strains in the ether, which are held to constitute radiant energy, magnetism, and electricity.
The great physicists of the day being at one regarding the existence of this all-pervading ether, it would be a manifest presumption for any one standing without the pale to challenge so firmly rooted a belief. And, indeed, in any event, there seems little ground on which to base such a challenge. Yet it may not be altogether amiss to reflect that the physicist of to-day is no more certain of his ether than was his predecessor of the eighteenth century of the existence of certain alleged substances which he called phlogiston, caloric, corpuscles of light, and magnetic and electric fluids. It would be but the repetition of history should it chance that before the close of another century the ether should have taken its place along with these discarded creations of the scientific imagination of earlier generations. The philosopher of to-day feels very sure that an ether exists; but when he says there is "no doubt" of its existence he speaks incautiously, and steps beyond the bounds of demonstration. He does not KNOW that action cannot take place at a distance; he does not KNOW that empty space itself may not perform the functions which he ascribes to his space-filling ether.
Meantime, however, the ether, be it substance or be it only dream-stuff, is serving an admirable purpose in furnishing a fulcrum for modern physics. Not alone to the student of energy has it proved invaluable, but to the student of matter itself as well. Out of its hypothetical mistiness has been reared the most tenable theory of the constitution of ponderable matter which has yet been suggested--or, at any rate, the one that will stand as the definitive nineteenth-century guess at this "riddle of the ages." I mean, of course, the vortex theory of atoms--that profound and fascinating doctrine which suggests that matter, in all its multiform phases, is neither more nor less than ether in motion.
The author of this wonderful conception is Lord Kelvin. The idea was born in his mind of a happy union of mathematical calculations with concrete experiments. The mathematical calculations were largely the work of Hermann von Helmholtz, who, about the year 1858, had undertaken to solve some unique problems in vortex motions. Helmholtz found that a vortex whirl, once established in a frictionless medium, must go on, theoretically, unchanged forever. In a limited medium such a whirl may be V-shaped, with its ends at the surface of the medium. We may imitate such a vortex by drawing the bowl of a spoon quickly through a cup of water. But in a limitless medium the vortex whirl must always be a closed ring, which may take the simple form of a hoop or circle, or which may be indefinitely contorted, looped, or, so to speak, knotted. Whether simple or contorted, this endless chain of whirling matter (the particles revolving about the axis of the loop as the particles of a string revolve when the string is rolled between the fingers) must, in a frictionless medium, retain its form and whirl on with undiminished speed forever.
While these theoretical calculations of Helmholtz were fresh in his mind, Lord Kelvin (then Sir William Thomson) was shown by Professor P. G. Tait, of Edinburgh, an apparatus constructed for the purpose of creating vortex rings in air. The apparatus, which any one may duplicate, consisted simply of a box with a hole bored in one side, and a piece of canvas stretched across the opposite side in lieu of boards. Fumes of chloride of ammonia are generated within the box, merely to render the air visible. By tapping with the band on the canvas side of the box, vortex rings of the clouded air are driven out, precisely similar in appearance to those smoke-rings which some expert tobacco-smokers can produce by tapping on their cheeks, or to those larger ones which we sometimes see blown out from the funnel of a locomotive.
The advantage of Professor Tait's apparatus is its manageableness and the certainty with which the desired result can be produced. Before Lord Kelvin's interested observation it threw out rings of various sizes, which moved straight across the room at varying rates of speed, according to the initial impulse, and which behaved very strangely when coming in contact with one another. If, for example, a rapidly moving ring overtook another moving in the same path, the one in advance seemed to pause, and to spread out its periphery like an elastic band, while the pursuer seemed to contract, till it actually slid through the orifice of the other, after which each ring resumed its original size, and continued its course as if nothing had happened. When, on the other hand, two rings moving in slightly different directions came near each other, they seemed to have an attraction for each other; yet if they impinged, they bounded away, quivering like elastic solids. If an effort were made to grasp or to cut one of these rings, the subtle thing shrank from the contact, and slipped away as if it were alive.
And all the while the body which thus conducted itself consisted simply of a whirl in the air, made visible, but not otherwise influenced, by smoky fumes. Presently the friction of the surrounding air wore the ring away, and it faded into the general atmosphere--often, however, not until it had persisted for many seconds, and passed clear across a large room. Clearly, if there were no friction, the ring's inertia must make it a permanent structure. Only the frictionless medium was lacking to fulfil all the conditions of Helmholtz's indestructible vortices. And at once Lord Kelvin bethought him of the frictionless medium which physicists had now begun to accept--the all-pervading ether. What if vortex rings were started in this ether, must they not have the properties which the vortex rings in air had exhibited--inertia, attraction, elasticity? And are not these the properties of ordinary tangible matter? Is it not probable, then, that what we call matter consists merely of aggregations of infinitesimal vortex rings in the ether?
Thus the vortex theory of atoms took form in Lord Kelvin's mind, and its expression gave the world what many philosophers of our time regard as the most plausible conception of the constitution of matter hitherto formulated. It is only a theory, to be sure; its author would be the last person to claim finality for it. "It is only a dream," Lord Kelvin said to me, in referring to it not long ago. But it has a basis in mathematical calculation and in analogical experiment such as no other theory of matter can lay claim to, and it has a unifying or monistic tendency that makes it, for the philosophical mind, little less than fascinating. True or false, it is the definitive theory of matter of the twentieth century.
Quite aside from the question of the exact constitution of the ultimate particles of matter, questions as to the distribution of such particles, their mutual relations, properties, and actions, came in for a full share of attention during the nineteenth century, though the foundations for the modern speculations were furnished in a previous epoch. The most popular eighteenth-century speculation as to the ultimate constitution of matter was that of the learned Italian priest, Roger Joseph Boscovich, published in 1758, in his Theoria Philosophiae Naturalis. "In this theory," according to an early commentator, "the whole mass of which the bodies of the universe are composed is supposed to consist of an exceedingly great yet finite number of simple, indivisible, inextended atoms. These atoms are endued by the Creator with REPULSIVE and ATTRACTIVE forces, which vary according to the distance. At very small distances the particles of matter repel each other; and this repulsive force increases beyond all limits as the distances are diminished, and will consequently forever prevent actual contact. When the particles of matter are removed to sensible distances, the repulsive is exchanged for an attractive force, which decreases in inverse ratio with the squares of the distances, and extends beyond the spheres of the most remote comets."
This conception of the atom as a mere centre of force was hardly such as could satisfy any mind other than the metaphysical. No one made a conspicuous attempt to improve upon the idea, however, till just at the close of the century, when Humphry Davy was led, in the course of his studies of heat, to speculate as to the changes that occur in the intimate substance of matter under altered conditions of temperature. Davy, as we have seen, regarded heat as a manifestation of motion among the particles of matter. As all bodies with which we come in contact have some temperature, Davy inferred that the intimate particles of every substance must be perpetually in a state of vibration. Such vibrations, he believed, produced the "repulsive force" which (in common with Boscovich) he admitted as holding the particles of matter at a distance from one another. To heat a substance means merely to increase the rate of vibration of its particles; thus also, plainly, increasing the repulsive forces and expanding the bulk of the mass as a whole. If the degree of heat applied be sufficient, the repulsive force may become strong enough quite to overcome the attractive force, and the particles will separate and tend to fly away from one another, the solid then becoming a gas.
Not much attention was paid to these very suggestive ideas of Davy, because they were founded on the idea that heat is merely a motion, which the scientific world then repudiated; but half a century later, when the new theories of energy had made their way, there came a revival of practically the same ideas of the particles of matter (molecules they were now called) which Davy had advocated. Then it was that Clausius in Germany and Clerk-Maxwell in England took up the investigation of what came to be known as the kinetic theory of gases--the now familiar conception that all the phenomena of gases are due to the helter-skelter flight of the showers of widely separated molecules of which they are composed. The specific idea that the pressure or "spring" of gases is due to such molecular impacts was due to Daniel Bournelli, who advanced it early in the eighteenth century. The idea, then little noticed, had been revived about a century later by William Herapath, and again with some success by J. J. Waterston, of Bombay, about 1846; but it gained no distinct footing until taken in hand by Clausius in 1857 and by Clerk-Maxwell in 1859.
The considerations that led Clerk-Maxwell to take up the computations may be stated in his own words, as formulated in a paper "On the Motions and Collisions of Perfectly Elastic Spheres."
"So many of the properties of matter, especially when in the gaseous form," he says, "can be deduced from the hypothesis that their minute parts are in rapid motion, the velocity increasing with the temperature, that the precise nature of this motion becomes a subject of rational curiosity. Daniel Bournelli, Herapath, Joule, Kronig, Clausius, etc., have shown that the relations between pressure, temperature, and density in a perfect gas can be explained by supposing the particles to move with uniform velocities in straight lines, striking against the sides of the containing vessel and thus producing pressure. It is not necessary to suppose each particle to travel to any great distance in the same straight line; for the effect in producing pressure will be the same if the particles strike against each other; so that the straight line described may be very short. M. Clausius has determined the mean length of path in terms of the average of the particles, and the distance between the centres of two particles when the collision takes place. We have at present no means of ascertaining either of these distances; but certain phenomena, such as the internal friction of gases, the conduction of heat through a gas, and the diffusion of one gas through another, seem to indicate the possibility of determining accurately the mean length of path which a particle describes between two successive collisions. In order to lay the foundation of such investigations on strict mechanical principles, I shall demonstrate the laws of motion of an indefinite number of small, hard, and perfectly elastic spheres acting on one another only during impact. If the properties of such a system of bodies are found to correspond to those of gases, an important physical analogy will be established, which may lead to more accurate knowledge of the properties of matter. If experiments on gases are inconsistent with the hypothesis of these propositions, then our theory, though consistent with itself, is proved to be incapable of explaining the phenomena of gases. In either case it is necessary to follow out these consequences of the hypothesis.
"Instead of saying that the particles are hard, spherical, and elastic, we may, if we please, say the particles are centres of force, of which the action is insensible except at a certain very small distance, when it suddenly appears as a repulsive force of very great intensity. It is evident that either assumption will lead to the same results. For the sake of avoiding the repetition of a long phrase about these repulsive bodies, I shall proceed upon the assumption of perfectly elastic spherical bodies. If we suppose those aggregate molecules which move together to have a bounding surface which is not spherical, then the rotatory motion of the system will close up a certain proportion of the whole vis viva, as has been shown by Clausius, and in this way we may account for the value of the specific heat being greater than on the more simple hypothesis."(1)
The elaborate investigations of Clerk-Maxwell served not merely to substantiate the doctrine, but threw a flood of light upon the entire subject of molecular dynamics. Soon the physicists came to feel as certain of the existence of these showers of flying molecules making up a gas as if they could actually see and watch their individual actions. Through study of the viscosity of gases--that is to say, of the degree of frictional opposition they show to an object moving through them or to another current of gas--an idea was gained, with the aid of mathematics, of the rate of speed at which the particles of the gas are moving, and the number of collisions which each particle must experience in a given time, and of the length of the average free path traversed by the molecule between collisions, These measurements were confirmed by study of the rate of diffusion at which different gases mix together, and also by the rate of diffusion of heat through a gas, both these phenomena being chiefly due to the helter-skelter flight of the molecules.
It is sufficiently astonishing to be told that such measurements as these have been made at all, but the astonishment grows when one hears the results. It appears from Clerk-Maxwell's calculations that the mean free path, or distance traversed by the molecules between collisions in ordinary air, is about one-half-millionth of an inch; while the speed of the molecules is such that each one experiences about eight billions of collisions per second! It would be hard, perhaps, to cite an illustration showing the refinements of modern physics better than this; unless, indeed, one other result that followed directly from these calculations be considered such--the feat, namely, of measuring the size of the molecules themselves. Clausius was the first to point out how this might be done from a knowledge of the length of free path; and the calculations were made by Loschmidt in Germany and by Lord Kelvin in England, independently.
The work is purely mathematical, of course, but the results are regarded as unassailable; indeed, Lord Kelvin speaks of them as being absolutely demonstrative within certain limits of accuracy. This does not mean, however, that they show the exact dimensions of the molecule; it means an estimate of the limits of size within which the actual size of the molecule may lie. These limits, Lord Kelvin estimates, are about the one-ten-millionth of a centimetre for the maximum, and the one-one-hundred-millionth of a centimetre for the minimum. Such figures convey no particular meaning to our blunt senses, but Lord Kelvin has given a tangible illustration that aids the imagination to at least a vague comprehension of the unthinkable smallness of the molecule. He estimates that if a ball, say of water or glass, about "as large as a football, were to be magnified up to the size of the earth, each constituent molecule being magnified in the same proportion, the magnified structure would be more coarse-grained than a heap of shot, but probably less coarse-grained than a heap of footballs."
Several other methods have been employed to estimate the size of molecules. One of these is based upon the phenomena of contact electricity; another upon the wave-theory of light; and another upon capillary attraction, as shown in the tense film of a soap-bubble! No one of these methods gives results more definite than that due to the kinetic theory of gases, just outlined; but the important thing is that the results obtained by these different methods (all of them due to Lord Kelvin) agree with one another in fixing the dimensions of the molecule at somewhere about the limits already mentioned. We may feel very sure indeed, therefore, that the molecules of matter are not the unextended, formless points which Boscovich and his followers of the eighteenth century thought them. But all this, it must be borne in mind, refers to the molecule, not to the ultimate particle of matter, about which we shall have more to say in another connection. Curiously enough, we shall find that the latest theories as to the final term of the series are not so very far afield from the dreamings of the eighteenth-century philosophers; the electron of J. J. Thompson shows many points of resemblance to the formless centre of Boscovich.
Whatever the exact form of the molecule, its outline is subject to incessant variation; for nothing in molecular science is regarded as more firmly established than that the molecule, under all ordinary circumstances, is in a state of intense but variable vibration. The entire energy of a molecule of gas, for example, is not measured by its momentum, but by this plus its energy of vibration and rotation, due to the collisions already referred to. Clausius has even estimated the relative importance of these two quantities, showing that the translational motion of a molecule of gas accounts for only three-fifths of its kinetic energy. The total energy of the molecule (which we call "heat") includes also another factor--namely, potential energy, or energy of position, due to the work that has been done on expanding, in overcoming external pressure, and internal attraction between the molecules themselves. This potential energy (which will be recovered when the gas contracts) is the "latent heat" of Black, which so long puzzled the philosophers. It is latent in the same sense that the energy of a ball thrown into the air is latent at the moment when the ball poises at its greatest height before beginning to fall.
It thus appears that a variety of motions, real and potential, enter into the production of the condition we term heat. It is, however, chiefly the translational motion which is measurable as temperature; and this, too, which most obviously determines the physical state of the substance that the molecules collectively compose--whether, that is to say, it shall appear to our blunt perceptions as a gas, a liquid, or a solid. In the gaseous state, as we have seen, the translational motion of the molecules is relatively enormous, the molecules being widely separated. It does not follow, as we formerly supposed, that this is evidence of a repulsive power acting between the molecules. The physicists of to-day, headed by Lord Kelvin, decline to recognize any such power. They hold that the molecules of a gas fly in straight lines by virtue of their inertia, quite independently of one another, except at times of collision, from which they rebound by virtue of their elasticity; or on an approach to collision, in which latter case, coming within the range of mutual attraction, two molecules may circle about each other, as a comet circles about the sun, then rush apart again, as the comet rushes from the sun.
It is obvious that the length of the mean free path of the molecules of a gas may be increased indefinitely by decreasing the number of the molecules themselves in a circumscribed space. It has been shown by Professors Tait and Dewar that a vacuum may be produced artificially of such a degree of rarefaction that the mean free path of the remaining molecules is measurable in inches. The calculation is based on experiments made with the radiometer of Professor Crookes, an instrument which in itself is held to demonstrate the truth of the kinetic theory of gases. Such an attenuated gas as this is considered by Professor Crookes as constituting a fourth state of matter, which he terms ultra-gaseous.
If, on the other hand, a gas is subjected to pressure, its molecules are crowded closer together, and the length of their mean free path is thus lessened. Ultimately, the pressure being sufficient, the molecules are practically in continuous contact. Meantime the enormously increased number of collisions has set the molecules more and more actively vibrating, and the temperature of the gas has increased, as, indeed, necessarily results in accordance with the law of the conservation of energy. No amount of pressure, therefore, can suffice by itself to reduce the gas to a liquid state. It is believed that even at the centre of the sun, where the pressure is almost inconceivably great, all matter is to be regarded as really gaseous, though the molecules must be so packed together that the consistency is probably more like that of a solid.
If, however, coincidently with the application of pressure, opportunity be given for the excess of heat to be dissipated to a colder surrounding medium, the molecules, giving off their excess of energy, become relatively quiescent, and at a certain stage the gas becomes a liquid. The exact point at which this transformation occurs, however, differs enormously for different substances. In the case of water, for example, it is a temperature more than four hundred degrees above zero, centigrade; while for atmospheric air it is one hundred and ninety-four degrees centigrade below zero, or more than a hundred and fifty degrees below the point at which mercury freezes.
Be it high or low, the temperature above which any substance is always a gas, regardless of pressure, is called the critical temperature, or absolute boiling-point, of that substance. It does not follow, however, that below this point the substance is necessarily a liquid. This is a matter that will be determined by external conditions of pressure. Even far below the critical temperature the molecules have an enormous degree of activity, and tend to fly asunder, maintaining what appears to be a gaseous, but what technically is called a vaporous, condition--the distinction being that pressure alone suffices to reduce the vapor to the liquid state. Thus water may change from the gaseous to the liquid state at four hundred degrees above zero, but under conditions of ordinary atmospheric pressure it does not do so until the temperature is lowered three hundred degrees further. Below four hundred degrees, however, it is technically a vapor, not a gas; but the sole difference, it will be understood, is in the degree of molecular activity.
It thus appeared that the prevalence of water in a vaporous and liquid rather than in a "permanently" gaseous condition here on the globe is a mere incident of telluric evolution. Equally incidental is the fact that the air we breathe is "permanently" gaseous and not liquid or solid, as it might be were the earth's surface temperature to be lowered to a degree which, in the larger view, may be regarded as trifling. Between the atmospheric temperature in tropical and in arctic regions there is often a variation of more than one hundred degrees; were the temperature reduced another hundred, the point would be reached at which oxygen gas becomes a vapor, and under increased pressure would be a liquid. Thirty-seven degrees more would bring us to the critical temperature of nitrogen.
Nor is this a mere theoretical assumption; it is a determination of experimental science, quite independent of theory. The physicist in the laboratory has produced artificial conditions of temperature enabling him to change the state of the most persistent gases. Some fifty years since, when the kinetic theory was in its infancy, Faraday liquefied carbonic-acid gas, among others, and the experiments thus inaugurated have been extended by numerous more recent investigators, notably by Cailletet in Switzerland, by Pictet in France, and by Dr. Thomas. Andrews and Professor James Dewar in England. In the course of these experiments not only has air been liquefied, but hydrogen also, the most subtle of gases; and it has been made more and more apparent that gas and liquid are, as Andrews long ago asserted, "only distant stages of a long series of continuous physical changes." Of course, if the temperature be lowered still further, the liquid becomes a solid; and this change also has been effected in the case of some of the most "permanent" gases, including air.
The degree of cold--that is, of absence of heat--thus produced is enormous, relatively to anything of which we have experience in nature here at the earth now, yet the molecules of solidified air, for example, are not absolutely quiescent. In other words, they still have a temperature, though so very low. But it is clearly conceivable that a stage might be reached at which the molecules became absolutely quiescent, as regards either translational or vibratory motion. Such a heatless condition has been approached, but as yet not quite attained, in laboratory experiments. It is called the absolute zero of temperature, and is estimated to be equivalent to two hundred and seventy-three degrees Centigrade below the freezing-point of water, or ordinary zero.
A temperature (or absence of temperature) closely approximating this is believed to obtain in the ethereal ocean of interplanetary and interstellar space, which transmits, but is thought not to absorb, radiant energy. We here on the earth's surface are protected from exposure to this cold, which would deprive every organic thing of life almost instantaneously, solely by the thin blanket of atmosphere with which the globe is coated. It would seem as if this atmosphere, exposed to such a temperature at its surface, must there be incessantly liquefied, and thus fall back like rain to be dissolved into gas again while it still is many miles above the earth's surface. This may be the reason why its scurrying molecules have not long ago wandered off into space and left the world without protection.
But whether or not such liquefaction of the air now occurs in our outer atmosphere, there can be no question as to what must occur in its entire depth were we permanently shut off from the heating influence of the sun, as the astronomers threaten that we may be in a future age. Each molecule, not alone of the atmosphere, but of the entire earth's substance, is kept aquiver by the energy which it receives, or has received, directly or indirectly, from the sun. Left to itself, each molecule would wear out its energy and fritter it off into the space about it, ultimately running completely down, as surely as any human-made machine whose power is not from time to time restored. If, then, it shall come to pass in some future age that the sun's rays fail us, the temperature of the globe must gradually sink towards the absolute zero. That is to say, the molecules of gas which now fly about at such inconceivable speed must drop helpless to the earth; liquids must in turn become solids; and solids themselves, their molecular quivers utterly stilled, may perhaps take on properties the nature of which we cannot surmise.
Yet even then, according to the current hypothesis, the heatless molecule will still be a thing instinct with life. Its vortex whirl will still go on, uninfluenced by the dying-out of those subordinate quivers that produced the transitory effect which we call temperature. For those transitory thrills, though determining the physical state of matter as measured by our crude organs of sense, were no more than non-essential incidents; but the vortex whirl is the essence of matter itself. Some estimates as to the exact character of this intramolecular motion, together with recent theories as to the actual structure of the molecule, will claim our attention in a later volume. We shall also have occasion in another connection to make fuller inquiry as to the phenomena of low temperature.
APPENDIX
REFERENCE-LIST